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Dovyrenite
A valid IMA mineral species
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About Dovyrenite
Formula:
Ca6Zr(Si2O7)2(OH)4
Colour:
Colorless
Lustre:
Vitreous
Hardness:
3 - 4
Specific Gravity:
3.034 (Calculated)
Crystal System:
Orthorhombic
Name:
After the type locality, the Dovyren Bald Mountain, Yoko-Dovyren layered massif, Northern Baikal Region, Russia.
Exhibits a new type of modular structure with stacking of the tobermorite-like and the rosenbuschite-like layers parallel to (010). Single-crystal structural data point to an incompletely occupied Ca(2) site from the rosenbuschite module which is confirmed by microprobe analysis.
Unique Identifiers
Mindat ID:
31589
Long-form identifier:
mindat:1:1:31589:2
Similar Names
| Dufrénite | A valid IMA mineral species - grandfathered | Ca0.5Fe2+Fe53+(PO4)4(OH)6 · 2H2O |
IMA Classification of Dovyrenite
Approved
IMA Formula:
Ca6Zr4+(Si2O7)2(OH)4
Approval year:
2007
First published:
2007
Classification of Dovyrenite
9.BE.23
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Dov | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Dovyrenite
Vitreous
Transparency:
Transparent
Colour:
Colorless
Streak:
White
Hardness:
3 - 4 on Mohs scale
Hardness:
VHN10=108 - 165 kg/mm2 - Vickers
Comment:
Two distinct Vickers hardness groupings
Cleavage:
Perfect
A perfect cleavage on (010) and imperfect cleavages on (100), (001) and (140).
A perfect cleavage on (010) and imperfect cleavages on (100), (001) and (140).
Fracture:
Irregular/Uneven, Step-Like
Density:
3.034 g/cm3 (Calculated)
Comment:
Could not be measured due to small crystal size.
Optical Data of Dovyrenite
Type:
Biaxial (+)
RI values:
nα = 1.659(2) nβ = 1.660(2) nγ = 1.676(2)
2V:
Measured: 30° (5), Calculated: 28°
Max. Birefringence:
δ = 0.017
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Optical Extinction:
X = b; Y = c; Z = a;
Chemistry of Dovyrenite
Mindat Formula:
Ca6Zr(Si2O7)2(OH)4
Element Weights:
Crystallography of Dovyrenite
Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnnm
Setting:
Pnnm
Cell Parameters:
a = 5.666 Å, b = 18.844 Å, c = 3.728 Å
Ratio:
a:b:c = 0.301 : 1 : 0.198
Unit Cell V:
398.04 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Prismatic crystals flattened along [100], elongated along [001] and with an orthorhombic cross-section. Crystals are typically characterized by three simple forms: {100}, {140} and {081}?. The forms {010} and {410}? occur as narrow faces.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.0727 Å | (100) |
| 5.4620 Å | (63) |
| 2.9570 Å | (56) |
| 3.1406 Å | (39) |
| 2.7468 Å | (36) |
| 1.8640 Å | (33) |
| 1.8786 Å | (26) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Dovyrenite
Co-Type Localities:
General Appearance of Type Material:
Xenomorphic crystals up to 100 µm, rare colorless crystals (< 300 µm long) and stellate growths, and as polycrystalline reaction rims (< 200–250 µm thick) on calzirtite.
Place of Conservation of Type Material:
Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia (#3545).
Geological Setting of Type Material:
Altered pyroxene and melilite-monticellite skarn in carbonate xenoliths in ultra-basic rocks. Secondary low temperature mineral.
Associated Minerals at Type Locality:
Synonyms of Dovyrenite
Other Language Names for Dovyrenite
Dutch:Dovyreniet
German:Dovyrenit
Related Minerals - Strunz-mindat Grouping
| 9.BE. | Zinkgruvanite | Ba4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2 |
| 9.BE. | Calciomurmanite | (Na,◻)2Ca(Ti,Mg,Nb)4[Si2O7]2O2(OH,O)2(H2O)4 |
| 9.BE. | Cámaraite | Ba3Na(Fe2+,Mn)8Ti4(Si2O7)4O4(OH,F)7 |
| 9.BE. | Alfredcasparite | Sr2TiO(Si2O7) |
| 9.BE. | Batievaite-(Y) | Y2Ca2Ti(Si2O7)2(OH)2(H2O)4 |
| 9.BE. | Nacareniobsite-(Y) | Na3Ca3YNb(Si2O7)2OF3 |
| 9.BE. | Alexkuznetsovite-(Ce) | Ce2Mn(CO3)(Si2O7) |
| 9.BE. | Bobshannonite | Na2KBa(Mn,Na)8(Nb,Ti)4(Si2O7)4O4(OH)4(O,F)2 |
| 9.BE. | Paralomonosovite | Na6◻4Ti4(Si2O7)2[PO3OH][PO2(OH)2]O2(OF) |
| 9.BE. | Madeiraite | Na2Ca2Fe2Zr2(Si2O7)2O2F2 |
| 9.BE. | Bortolanite | Ca2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(OF)F2 |
| 9.BE. | Longshoushanite-(Ce) | Ce4MgAl2Ti2(Si2O7)2O8 |
| 9.BE. | Moxuanxueite | NaCa6Zr(Si2O7)2OF3 |
| 9.BE. | Delhuyarite-(Ce) | Ce4Mg(Fe3+,W)3◻(Si2O7)2O6(OH)2 |
| 9.BE. | Christofschäferite-(Ce) | Ce3CaMnTiFe3+Ti2(Si2O7)2O8 |
| 9.BE.X | Asimowite | Fe2+4O(Si2O7) |
| 9.BE. | Biraite-(La) | La2Fe2+(CO3)(Si2O7) |
| 9.BE. | Pilanesbergite | Na2Ca2Fe2Ti2(Si2O7)2O2F2 |
| 9.BE.02 | Wadsleyite | Mg4O(Si2O7) |
| 9.BE.02 | Ohtaniite | Mg3(Si0.5◻0.5)Si2O8 |
| 9.BE.05 | Lawsonite | CaAl2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Hennomartinite | SrMn3+2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Cortesognoite | CaV2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Noelbensonite | BaMn3+2(Si2O7)(OH)2 · H2O |
| 9.BE.05 | Itoigawaite | SrAl2(Si2O7)(OH)2 · H2O |
| 9.BE.07 | Ilvaite | CaFe3+Fe2+2(Si2O7)O(OH) |
| 9.BE.07 | Amamoorite | CaMn2+2Mn3+(Si2O7)O(OH) |
| 9.BE.07 | Manganilvaite | CaFe2+Fe3+Mn2+(Si2O7)O(OH) |
| 9.BE.10 | Suolunite | Ca2(H2Si2O7) · H2O |
| 9.BE.12 | Jaffeite | Ca6(Si2O7)(OH)6 |
| 9.BE.15 | Fresnoite | Ba2Ti(Si2O7)O |
| 9.BE.17 | Janhaugite | (Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2 |
| 9.BE.17 | Burpalite | Na2CaZr(Si2O7)F2 |
| 9.BE.17 | Niocalite | (Ca,Nb)4(Si2O7)(O,OH,F)2 |
| 9.BE.17 | Normandite | NaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OF |
| 9.BE.17 | Hiortdahlite | Na2Ca4(Ca0.5Zr0.5)Zr(Si2O7)2OF3 |
| 9.BE.17 | Låvenite | Na2Ca2Mn2Zr2(Si2O7)2O2F2 |
| 9.BE.17 | Cuspidine | Ca8(Si2O7)2F4 |
| 9.BE.17 | Wöhlerite | Na2Ca4ZrNb(Si2O7)2O3F |
| 9.BE.17 | Baghdadite | Ca6Zr2(Si2O7)2O4 |
| 9.BE.20 | Nacareniobsite-(Ce) | Na3Ca3(Ce,REE)Nb(Si2O7)2OF3 |
| 9.BE.20 | Roumaite | (Ca,Na,REE,◻)7(Nb,Ti)[Si2O7]2OF3 |
| 9.BE.20 | Rinkite-(Ce) | (Ca3Ce)Na(NaCa)Ti(Si2O7)2(OF)F2 |
| 9.BE.20 | Nacareniobsite-(Nd) | Ca2(CaNd)Na3Nb(Si2O7)2(OF)F2 |
| 9.BE.20 | Rinkite-(Y) | Na2Ca4YTi(Si2O7)2OF3 |
| 9.BE.20 | Mosandrite-(Ce) | (Ca3REE)[(H2O)2Ca0.5◻0.5]Ti(Si2O7)2(OH)2(H2O)2 |
| 9.BE.22 | Hainite-(Y) | Na2Ca4(Y,REE)Ti(Si2O7)2OF3 |
| 9.BE.22 | Rosenbuschite | Na6Ca6Zr3Ti(Si2O7)4O2F6 |
| 9.BE.22 | Götzenite | NaCa6Ti(Si2O7)2OF3 |
| 9.BE.22 | Fogoite-(Y) | Na3Ca2Y2Ti(Si2O7)2OF3 |
| 9.BE.22 | Kochite | Na3Ca2MnZrTi(Si2O7)2OF3 |
| 9.BE.25 | Lamprophyllite | (Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2 |
| 9.BE.25 | Seidozerite | Na4MnZr2Ti(Si2O7)2O2F2 |
| 9.BE.25 | Nabalamprophyllite | (BaNa)Ti2Na3Ti(Si2O7)2O2(OH)2 |
| 9.BE.25 | Schüllerite | Ba2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4 |
| 9.BE.25 | Ericssonite | BaMn2+2Fe3+(Si2O7)O(OH) |
| 9.BE.25 | Grenmarite | Na4MnZr3(Si2O7)2O2F2 |
| 9.BE.25 | Kazanskyite | BaNa3Ti2Nb(Si2O7)2O2(OH)2(H2O)4 |
| 9.BE.25 | Saamite | Ba◻Na3Ti2Nb(Si2O7)2O2(OH)F(H2O)2 |
| 9.BE.25 | Emmerichite | Ba2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2 |
| 9.BE.25 | Barytolamprophyllite | (Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F) |
| 9.BE.25 | 'Ericssonite-2O' | BaMn2+2Fe3+(Si2O7)O(OH) |
| 9.BE.25 | Fluorbarytolamprophyllite | (Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2] |
| 9.BE.25 | Fluorlamprophyllite | Na3(SrNa)Ti3(Si2O7)2O2F2 |
| 9.BE.25 | Lileyite | Ba2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2 |
| 9.BE.27 | Kolskyite | CaNa2Ti4(Si2O7)2O4(H2O)7 |
| 9.BE.27 | Vigrishinite | NaZnTi4(Si2O7)2O3(OH)(H2O)4 |
| 9.BE.27 | Selivanovaite | NaFe3+Ti4(Si2O7)2O4(H2O)4 |
| 9.BE.27 | Murmanite | Na2Ti2(Si2O7)O2 · 2H2O |
| 9.BE.30 | Epistolite | (Na◻)Nb2Na3Ti(Si2O7)2O2(OH)2(H2O)4 |
| 9.BE.32 | Lomonosovite | Na5Ti2(Si2O7)(PO4)O2 |
| 9.BE.35 | Vuonnemite | Na11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH) |
| 9.BE.37 | Sobolevite | Na13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3 |
| 9.BE.40 | Ferroinnelite | Ba4Ti2Na(NaFe2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)] |
| 9.BE.40 | Phosphoinnelite | Na3Ba4Ti3(Si2O7)2(PO4,SO4)2O2F |
| 9.BE.40 | Innelite | Ba4Ti2Na(NaMn2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)] |
| 9.BE.42 | Yoshimuraite | Ba2Mn2Ti(Si2O7)(PO4)O(OH) |
| 9.BE.42 | Horiite | Ba2Mn2Mn4Ti2(Si2O7)2(PO4)2O2(OH)2 |
| 9.BE.45 | Quadruphite | Na6Na2(CaNa)2Na2Ti2Na2Ti2(Si2O7)2(PO4)4O4F2 |
| 9.BE.47 | Polyphite | Na5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2 |
| 9.BE.50 | Shkatulkalite | Na2Nb2Na3Ti(Si2O7)2O2(FO)(H2O)4(H2O)3 |
| 9.BE.50 | Bornemanite | Na6BaTi2Nb(Si2O7)2(PO4)O2(OH)F |
| 9.BE.55 | Hejtmanite | Ba2Mn2+4Ti2(Si2O7)2O2(OH)2F2 |
| 9.BE.55 | Bykovaite | (Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2O |
| 9.BE.55 | Nechelyustovite | (Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2O |
| 9.BE.55 | Bafertisite | Ba2Fe2+4Ti2(Si2O7)2O2(OH)2F2 |
| 9.BE.60 | Delindeite | (Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2O |
| 9.BE.62 | 'Orthochevkinite' | (Ce,La,Ca,Na,Th)4(Fe2+,Mg)2(Ti,Fe3+)3Si4O22 |
| 9.BE.62 va | 'Strontium Perrierite' | (Ce,Sr,La,Ca)4Fe2+(Ti,Zr,Fe)2Ti2(Si2O7)2O8 |
| 9.BE.62 | 'Chevkinite-(Nd)' | (Nd,REE)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8 ? |
| 9.BE.62 | 'Perrierite-(Nd)' | Nd4MgFe3+2Ti2(Si2O7)2O8 ? |
| 9.BE.65 | Bussenite | Na2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3F |
| 9.BE.67 | Jinshajiangite | BaNaFe2+4Ti2(Si2O7)2O2(OH)2F |
| 9.BE.67 | Perraultite | BaNaMn2+4Ti2(Si2O7)2O2(OH)2F |
| 9.BE.70 | Dingdaohengite-(Ce) | (Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe3+)2Ti2(Si2O7)2O8 |
| 9.BE.70 | Perrierite-(Ce) | Ce4MgFe3+2Ti2(Si2O7)2O8 |
| 9.BE.70 | Karnasurtite-(Ce) | (Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2O |
| 9.BE.70 | Maoniupingite-(Ce) | (Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8 |
| 9.BE.70 | Matsubaraite | Sr4Ti5(Si2O7)2O8 |
| 9.BE.70 | Rengeite | Sr4ZrTi4(Si2O7)2O8 |
| 9.BE.70 | Polyakovite-(Ce) | (Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8 |
| 9.BE.70 | Hezuolinite | (Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8 |
| 9.BE.70 | 'UM2008-53-SiO:SrTiZr' | Sr4ZrTi4(Si2O7)2O8 |
| 9.BE.70 | Chevkinite-(Ce) | Ce4(Ti,Fe2+,Fe3+)5O8(Si2O7)2 |
| 9.BE.70 | Perrierite-(La) | (La,Ce,Ca)4(Fe2+,Mn)(Ti,Fe3+,Al)4[(Si2O7)O4]2 |
| 9.BE.70 | Strontiochevkinite | (Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8 |
| 9.BE.72 | Fersmanite | Ca4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3 |
| 9.BE.75 | Belkovite | Ba3(Nb,Ti)6(Si2O7)2O12 |
| 9.BE.77 | Nasonite | Pb6Ca4(Si2O7)3Cl2 |
| 9.BE.80 | Melanotekite | Pb2Fe3+2(Si2O7)O2 |
| 9.BE.80 | Kentrolite | Pb2Mn3+2(Si2O7)O2 |
| 9.BE.82 | Alexkuznetsovite-(La) | La2Mn(CO3)(Si2O7) |
| 9.BE.82 | Tilleyite | Ca5(Si2O7)(CO3)2 |
| 9.BE.85 | Killalaite | Ca6.4(H0.6Si2O7)2(OH)2 |
| 9.BE.87 | Stavelotite-(La) | (La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30 |
| 9.BE.90 | Magnesiorowlandite-(Y) | Y4(Mg,Fe)(Si2O7)2F2 |
| 9.BE.90 | Biraite-(Ce) | Ce2Fe2+(Si2O7)(CO3) |
| 9.BE.92 | Cervandonite-(Ce) | (Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH) |
| 9.BE.92 | Chirvinskyite | (Na,Ca)13(Fe,Mn,◻)2(Ti,Zr)5(Si2O7)4(OH,O)12 · 2H2O |
| 9.BE.95 | Rusinovite | Ca10(Si2O7)3Cl2 |
| 9.BE.95 | Batisivite | BaV3+8Ti6(Si2O7)O22 |
| 9.BE.97 | Schlüterite-(Y) | (Y,REE)2AlSi2O7(OH)2F |
Other Information
Notes:
Blue cathodoluminescence.
Soluble in dilute HCl but insoluble in water.
Soluble in dilute HCl but insoluble in water.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Dovyrenite
mindat.org URL:
https://www.mindat.org/min-31589.html
Please feel free to link to this page.
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References for Dovyrenite
Reference List:
Kadiyski, M., Armbruster, T., Galuskin, E. V., Pertsev, N. N., Zadov, A. E., Galuskina, I. O., Wrzalik, R., Dzierzanowski, P., Kislov, E. V. (2008) The modular structure of dovyrenite, Ca6Zr[Si2O7]2(OH)4: Alternate stacking of tobermorite and rosenbuschite-like units. American Mineralogist, 93 (2) 456-462 doi:10.2138/am.2008.2669
Localities for Dovyrenite
Showing 3 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Russia (TL) | |
| Galuskin (2007) |
| Kislov +1 other reference |
| Bailau |
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The
Yoko-Dovyrensky Massif, Dovyren Highlands, Severo-Baykalsky District, Buryatia, Russia