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Holmquistite

A valid IMA mineral species - grandfathered
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About HolmquistiteHide

02868400017271923853771.jpg
Per J. Holmquist
Formula:
◻Li2(Mg3Al2)(Si8O22)(OH)2
The holmquistite group comprises orthorhombic amphiboles in the lithium amphibole subgroup.

Holmquistite is defined within the group as having Mg>Fe2+ in the B position and Al>Fe3+ in the C position.
Colour:
Black, dark-violet, light sky-blue.
Lustre:
Vitreous
Hardness:
5 - 6
Specific Gravity:
2.95 - 3.13
Crystal System:
Orthorhombic
Name:
Named in honor of Per Johan Holmquist (23 January 1866, Gothenburg, Sweden - 3 March 1946, Djursholm, Sweden), petrologist from Stockholm, Sweden.
Holmquistite is the most common of the lithium amphiboles. It is almost exclusively formed in the reaction zone between Li-pegmatites and their host rock, predominantly as a metasomatic alteration product of pre-existing amphiboles. It generally occurs as mm- to cm-sized fibres or fibrous crystal aggregates in the pegmatite and/or the host rock.

Holmquistite form a series with ferro-holmquistite, and Quéméneur and Lagache (1994) show a significant variation of Fe content in holmquistite from different localities, and they suggest that the holmquistite minerals retain their Fe/Mg ratio from the original amphibole. They consider their data to confirm this hypothesis.

The “holmquistite” from the Koktokay No. 3 pegmatite, China is not holmquistite, but tourmaline. Holmquistite has only been found as acicular, sky-blue to bluish crystals up to 0.5-0.1 mm length in the gabbro and gabbro-diorite host rock of Li-pegmatite (Rubia and Shaoxu, 1985).




Unique IdentifiersHide

Mindat ID:
1923
Long-form identifier:
mindat:1:1:1923:7

IMA Classification of HolmquistiteHide

Classification of HolmquistiteHide

9.DD.05

9 : SILICATES (Germanates)
D : Inosilicates
D : Inosilicates with 2-periodic double chains, Si4O11; Orthoamphiboles
66.1.2.9

66 : INOSILICATES Double-Width,Unbranched Chains,(W=2)
1 : Amphiboles - Mg-Fe-Mn-Li subgroup
16.1.9

16 : Silicates Containing Aluminum and other Metals
1 : Aluminosilicates of Li

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
HlmIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
HqSiivolam & Schmid (2007)Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download
HlmWhitney & Evans (2010)Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371
HmqThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of HolmquistiteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
Black, dark-violet, light sky-blue.
Streak:
White with sky-blue tinge.
Hardness:
5 - 6 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
{210}
Parting:
partings on {001}, {112}, and {113}
Density:
2.95 - 3.13 g/cm3 (Measured)    3.09 g/cm3 (Calculated)

Optical Data of HolmquistiteHide

Type:
Biaxial (-)
RI values:
nα = 1.613 - 1.625 nβ = 1.634 - 1.645 nγ = 1.646 - 1.666
2V:
Measured: 45° to 52°, Calculated: 72° to 90°
Max. Birefringence:
δ = 0.033 - 0.041
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 ”m thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v strong
Pleochroism:
Strong
Comments:
shades of violet when dark-colored.

Chemistry of HolmquistiteHide

Mindat Formula:
◻Li2(Mg3Al2)(Si8O22)(OH)2

The holmquistite group comprises orthorhombic amphiboles in the lithium amphibole subgroup.

Holmquistite is defined within the group as having Mg>Fe2+ in the B position and Al>Fe3+ in the C position.
Element Weights:
Element% weight
O51.100 %
Si29.900 %
Mg9.703 %
Al7.181 %
Li1.847 %
H0.268 %

Calculated from ideal end-member formula.
O
Si
Mg
Al
Li
H
Common Impurities:
Ti,Mn,Ca,Na,K,F

Chemical AnalysisHide

Oxide wt%:
 123
SiO258.84 %59.79 %60.45 %
TiO20.02 %0.01 %
Al2O38.21 %12.59 %7.7 %
Cr2O30.02 %
MgO12.16 %8.39 %12.12 %
CaO0.02 %0.04 %
MnO0.036 %0.17 %
Fe2O35.83 %1.96 %9.68 %
FeO6.06 %12.00 %4.38 %
ZnO0.14 %
Na2O0.37 %0.08 %1.12 %
K2O0.02 %0.54 %
F0.40 %0.43 %
Cl0.01 %
Li2O3.58 %3.10 %2.13 %
H2O2.10 %1.75 %2.28 %
O=F/Cl-0.13 %
Total:97.686 %99.88 %100.83 %
Empirical formulas:
Sample IDEmpirical Formula
1Na0.02(Li1.92Na0.08) 2(Mg2.32Fe2+0.62Mn2+0.06Zn2+0.01Li0.01Al1.30Fe3+0,68) 5.00Si8O22((OH1.87F0.13) 2
2(Li1.67Fe0.21Na0.02Mn0.02Ca0.01) 1.93 (Al1.99Mg1.68Fe2+1.13Fe3+0.20) 5.00 (Si8.02) O22 ((OH) 1.55O0.43) 2
3K0.09 (Li1.14Na0.29Fe0. 07) 1.50 (Mg2.40Al1.20 Fe3+0.97 Fe2+0.42) 5 Si8.04O22 ((OH) 1.84F0.16) 2

Crystallography of HolmquistiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnma
Setting:
Pnma
Cell Parameters:
a = 18.30 Å, b = 17.69 Å, c = 5.30 Å
Ratio:
a:b:c = 1.034 : 1 : 0.3
Unit Cell V:
1,715.75 ų (Calculated from Unit Cell)
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0003818HolmquistiteCamara F, Oberti R (2005) The crystal-chemistry of holmquistites: Ferroholmquistite from Greenbushes (Western Australia) and hints for compositional constraints in B-Li amphiboles American Mineralogist 90 1167-117620050293
0003817HolmquistiteCamara F, Oberti R (2005) The crystal-chemistry of holmquistites: Ferroholmquistite from Greenbushes (Western Australia) and hints for compositional constraints in B-Li amphiboles American Mineralogist 90 1167-117620050293
0003816HolmquistiteCamara F, Oberti R (2005) The crystal-chemistry of holmquistites: Ferroholmquistite from Greenbushes (Western Australia) and hints for compositional constraints in B-Li amphiboles American Mineralogist 90 1167-117620050293
0003815HolmquistiteCamara F, Oberti R (2005) The crystal-chemistry of holmquistites: Ferroholmquistite from Greenbushes (Western Australia) and hints for compositional constraints in B-Li amphiboles American Mineralogist 90 1167-117620050293
0003814HolmquistiteCamara F, Oberti R (2005) The crystal-chemistry of holmquistites: Ferroholmquistite from Greenbushes (Western Australia) and hints for compositional constraints in B-Li amphiboles American Mineralogist 90 1167-117620050293
0003813HolmquistiteCamara F, Oberti R (2005) The crystal-chemistry of holmquistites: Ferroholmquistite from Greenbushes (Western Australia) and hints for compositional constraints in B-Li amphiboles American Mineralogist 90 1167-117620050293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.107 Å(100)
3.00 Å(90)
4.43 Å(70)
3.34 Å(60)
3.61 Å(50)
2.538 Å(50)
2.797 Å(40)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
22 : Hydration and low-𝑇 subsurface aqueous alteration (see also #23)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of HolmquistiteHide

Empirical Formula of Type Material:
K0.09 (Li1.14Na0.29Fe0. 07) 1.50 (Mg2.40Al1.20 Fe3+0.97 Fe2+0.42) 5 Si8.04O22 ((OH) 1.84F0.16) 2
Geological Setting of Type Material:
metasomatic replacements near the outer margins of lithium-rich pegmatites

Synonyms of HolmquistiteHide

Other Language Names for HolmquistiteHide

Relationship of Holmquistite to other SpeciesHide

Other Members of Holmquistite Root Name Group:
Ferro-ferri-holmquistite◻Li2(Fe2+3Fe3+2)(Si8O22)(OH)2Orth. mmm(2/m2/m2/m) : Pmma
Ferro-holmquistite◻Li2(Fe2+3Al2)(Si8O22)(OH)2Orth. mmm(2/m2/m2/m) : Pnma

Common AssociatesHide

Associations Based on Photo Data:
4 photos of Holmquistite associated with SpodumeneLiAlSi2O6
4 photos of Holmquistite associated with FairfielditeCa2Mn2+(PO4)2 · 2H2O
2 photos of Holmquistite associated with QuartzSiO2
2 photos of Holmquistite associated with MagnetiteFe2+Fe3+2O4
1 photo of Holmquistite associated with Fluorcalciomicrolite(Ca,Na)2(Ta,Nb)2O6F
1 photo of Holmquistite associated with ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)

Related Minerals - Strunz-mindat GroupingHide

9.DD.05Suenoite◻Mn2+2Mg5Si8O22(OH)2Orth. mmm(2/m2/m2/m) : Pnma
9.DD.05Proto-ferro-anthophyllite◻Fe2+2Fe2+5(Si8O22)(OH)2Orth. mmm(2/m2/m2/m)
9.DD.05Proto-ferro-suenoite◻Mn2+2(Fe2+5)(Si8O22)(OH)2Orth. mmm(2/m2/m2/m)
9.DD.05PapikeiteNaMg2(Mg3Al2}(Al3Si5O22)(OH)2Orth. mmm(2/m2/m2/m) : Pnma
9.DD.05Gedrite◻Mg2(Mg3Al2)(Al2Si6O22)(OH)2Orth. mmm(2/m2/m2/m)
9.DD.05'Sodic-anthophyllite'{Na}{Mg2}{Mg5}(AlSi7O22)(OH)2Orth.
9.DD.05'Sodic-ferro-anthophyllite'NaFe2+2Fe2+5(AlSi7O22)(OH)2Orth.
9.DD.05Ferro-papikeiteNaFe2+2(Fe2+3Al2)(Si5Al3O22)(OH)2Orth. mmm(2/m2/m2/m) : Pnma
9.DD.05Ferro-anthophyllite◻Fe2+2Fe2+5(Si8O22)(OH)2Orth. mmm(2/m2/m2/m) : Pnma
9.DD.05Proto-anthophyllite◻Mg2Mg5(Si8O22)(OH)2Orth. mmm(2/m2/m2/m) : Pnnm
9.DD.05Ferro-gedrite◻Fe2+2(Fe2+3Al2)(Al2Si6O22)(OH)2Orth. mmm(2/m2/m2/m) : Pnma
9.DD.05'Ferri-holmquistite'◻{Li2}{Mg3Fe3+2}(Si8O22)(OH)2
9.DD.05Ferro-ferri-holmquistite◻Li2(Fe2+3Fe3+2)(Si8O22)(OH)2Orth. mmm(2/m2/m2/m) : Pmma
9.DD.05Ferro-holmquistite◻Li2(Fe2+3Al2)(Si8O22)(OH)2Orth. mmm(2/m2/m2/m) : Pnma
9.DD.05Anthophyllite◻Mg2Mg5(Si8O22)(OH)2Orth. mmm(2/m2/m2/m) : Pnma

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HolmquistiteHide

References for HolmquistiteHide

Reference List:

Localities for HolmquistiteHide

Showing 69 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Angola
 
  • Namibe Province
    • Moçùmedes
      • GiraĂșl pegmatite field
Gonçalves +3 other references
Gonçalves +2 other references
Argentina
 
  • CĂłrdoba Province
    • San Javier Department
      • Rosas District
        • Las Tapias
Porta et al. (1994)
  • San Luis Province
    • Coronel Pringles Department
      • Estancia Grande
        • Las Águilas deposit
Galliski +4 other references
Australia
 
  • Western Australia
    • Bridgetown-Greenbushes Shire
      • Greenbushes tinfield
Econ Geol (1995) +1 other reference
Frost et al. (1987)
Frost et al. (1987)
Frost et al. (1987)
    • Coolgardie Shire
Wilkins et al. (1970) +1 other reference
Austria
 
  • Carinthia
    • Spittal an der Drau District
      • Spittal an der Drau
Steiner (2017)
Walter (2009) +1 other reference
    • Wolfsberg District
      • Frantschach-Sankt Gertraud
        • BrandrĂŒcken
Niedermayr et al. (1987) +3 other references
Brazil
 
  • Minas Gerais
    • Nazareno
Quéméneur et al. (1994) +1 other reference
Canada
 
  • Manitoba
Černá et al. (2002)
    • Lac-du-Bonnet area
      • Bernic Lake
Econ Geol (1995)
Bannatyne (1985)
153-155. +3 other references
      • Cat Lake - Winnipeg River pegmatite field
        • Donner Lake
Bannatyne (1985)
    • Red Cross Lake
ČernĂœ et al. (2012)
  • Nova Scotia
    • Yarmouth Co.
Kontak (2004)
  • Ontario
    • Kenora District
      • Fort Hope
Breaks et al. (2008)
      • Lilypad Lakes pegmatites
        • Ferguson Lake Area
Pedersen (2000)
        • Opikeigan Lake Area
Pedersen (2000)
      • Pakeagama Lake Area
        • PAK Lithium Project
Ontario MDI Number: MDI53C11SW00003
McCracken (2023)
      • Paterson Lake Area
Tindle et al. (2002) +1 other reference
      • Root Lake pegmatite group
        • Root Lake Area
Tindle et al. (2005)
  • QuĂ©bec
    • Abitibi-TĂ©miscamingue
      • Abitibi RCM
        • La Corne
Nickel et al. (1960) +1 other reference
        • Preissac–La Corne area
Mvondo et al. (2026)
China
 
  • Xinjiang
    • Ili Kazakh Autonomous Prefecture
      • Altay Prefecture (Aletai Prefecture)
        • Fuyun Co. (Koktokay Co.)
          • Koktokay pegmatite field (Keketuohai pegmatite field)
            • Altay Mine
Rubia et al. (1985) +1 other reference
        • Qinghe Co. (Qinggil Co.; Chinggil Co.)
          • Qinghe pegmatite field
Chen et al. (2022)
Ethiopia
 
  • Oromia Region
    • Kenticha pegmatite field
KĂŒster (2009)
Italy
 
  • Piedmont
    • Verbano-Cusio-Ossola Province
      • Trontano
Francesco Vanini et al. (†)
Francesco Vanini et al. (†)
Mozambique
 
  • Zambezia Province
Wilson et al. (2000)
    • Alto MĂłlocuĂš District
Gomes et al. (2022)
    • Mulevala District
Wilson et al. (2000)
Niger
 
  • TillabĂ©ri
    • TĂ©ra
      • Dibilo
        • East Dibilo
Abdourahamane Attourabi et al. (2022)
Russia
 
  • Irkutsk Oblast
webmineral.ru (2021)
  • Murmansk Oblast
    • Voron'i Tundry
Gavrilenko (2001) +2 other references
Rwanda
 
  • Southern Province
    • Muhanga District
      • Nyarusange
Petrov (n.d.)
  • Western Province
    • Ngororero District
Pohl et al. (2013)
Hulsbosch et al. (2019)
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
        • Candelaria
          • Barranco Hondo
Dill et al. (2023)
        • Granadilla de Abona
Dill et al. (2023)
Dill et al. (2023)
Sweden (TL)
 
  • Stockholm County
    • Haninge
      • Utö
Osann (1913) +3 other references
Selway et al. (2002)
Ukraine
 
  • Kirovohrad Oblast
    • Holovanivsk Raion
Kurylo et al. (2022) +1 other reference
  • Zaporizhia Oblast
    • Berdyansk Raion
      • Middle Berda River
        • Rodionovskoe pegmatite field
Shatalov (2017)
USA
 
  • Maine
    • Knox County
      • Rockport
King et al. (1994)
  • New Mexico
    • Taos County
      • Picuris District
Jahns et al. (1977)
  • North Carolina
Davidson (1927)
Bernard et al. (2004)
Bernard et al. (2004)
    • Cleveland County
Wilson et al. (1978)
      • Kings Mountain
... +2 other references
Kloprogge et al. (2001)
    • Gaston County
Kloprogge et al. (2001)
  • South Dakota
    • Pennington County
      • Keystone Mining District
        • Keystone
AmMin 73:324 (1988) +1 other reference
Zimbabwe
 
  • Mashonaland East
    • Mudzi District
Hornung. G. PhD thesis. Pegmatites of ...
von Knorring et al. (1961)
von Knorring et al. (1961) +1 other reference
von Knorring et al. (1961)
  • Matabeleland South
    • Insiza District
      • Pioneer village No. 2
Wolfgang Hampel (2017)
  • Midlands
    • Mberengwa District
      • Sandawana-Belingwe District
- (2002) +1 other reference
 
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