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Keystoneite

A valid IMA mineral species
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About KeystoneiteHide

Formula:
Mg0.5Ni2+Fe3+(Te4+O3)3 · 4.5H2O
Colour:
Golden yellow
Lustre:
Adamantine
Specific Gravity:
4.4 (Calculated)
Crystal System:
Hexagonal
Member of:
Name:
For the type locality.

Unique IdentifiersHide

Mindat ID:
2192
Long-form identifier:
mindat:1:1:2192:6

IMA Classification of KeystoneiteHide

Approved
IMA Formula:
Mg0.5Ni2+Fe3+(Te4+O3)3·4H2O
Approval year:
1987

Classification of KeystoneiteHide

4.JM.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
J : Arsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodates
M : Tellurites without additional anions, with H2O
34.3.2.3

34 : SELENITES, TELLURITES AND SULFITES
3 : A2(XO3)3·xH2O
28.3.28

28 : Selenites, Selenates, Tellurites, and Tellurates
3 : Tellurites

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
KysIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KeystoneiteHide

Adamantine
Transparency:
Translucent
Colour:
Golden yellow
Streak:
Pale yellow-green
Density:
4.4 g/cm3 (Calculated)

Optical Data of KeystoneiteHide

Type:
Uniaxial (+)
RI values:
nω = 1.85(1) nε = 1.99(1)
Max. Birefringence:
δ = 0.140
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of KeystoneiteHide

Mindat Formula:
Mg0.5Ni2+Fe3+(Te4+O3)3 · 4.5H2O
Element Weights:
Element% weight
Te52.113 %
O29.405 %
Ni7.990 %
Fe7.603 %
Mg1.654 %
H1.235 %

Calculated from ideal end-member formula.
Te
O
Ni
Fe
Mg
H

Crystallography of KeystoneiteHide

Crystal System:
Hexagonal
Class (H-M):
6 - Pyramidal
Space Group:
P63
Cell Parameters:
a = 9.3667(5) Å, c = 7.6173(3) Å
Ratio:
a:c = 1 : 0.813
Unit Cell V:
578.77 ų
Z:
2
Morphology:
Acicular hexagonal crystals, parallel aggregates and radiating sprays.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.12 Å(90)
4.05 Å(80)
2.952 Å(50)
2.838 Å(50)
2.774 Å(100)
1.720 Å(60)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47e : [Vanadates, chromates, manganates]

Type Occurrence of KeystoneiteHide

Place of Conservation of Type Material:
Canadian Museum of Nature, Ottawa, Canada 56561
Geological Setting of Type Material:
Oxidation zone of a complex polymetallic hydrothermal deposit.

Synonyms of KeystoneiteHide

Other Language Names for KeystoneiteHide

Relationship of Keystoneite to other SpeciesHide

Member of:
Other Members of Zemannite Group:
IlirneyiteMg0.5ZnMn3+(Te4+O3)3 · 4.5H2OHex. 6/m : P63/m
KinichiliteMg0.5Mn2+Fe3+(Te4+O3)3 · 4.5H2OHex. 6/m : P63/m
ZemanniteMg0.5ZnFe3+(Te4+O3)3 · 4.5H2OTrig. 3 : P3

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Keystoneite associated with Choloalite(Cu,Sb)3(Pb,Ca)3(TeO3)6Cl
5 photos of Keystoneite associated with QuartzSiO2
1 photo of Keystoneite associated with HessiteAg2Te
1 photo of Keystoneite associated with Native GoldAu
1 photo of Keystoneite associated with AltaitePbTe
1 photo of Keystoneite associated with MeloniteNiTe2
1 photo of Keystoneite associated with PetziteAg3AuTe2

Related Minerals - Strunz-mindat GroupingHide

4.JM.WortupaiteMgNi2+2(Te4+O3)3 · 3H2OHex. 6/m : P63/m
4.JM.RudolfhermanniteFe3+2(Te4+O3)3(H2O)Hex. 6/m : P63/m
4.JM.05ZemanniteMg0.5ZnFe3+(Te4+O3)3 · 4.5H2OTrig. 3 : P3
4.JM.05KinichiliteMg0.5Mn2+Fe3+(Te4+O3)3 · 4.5H2OHex. 6/m : P63/m
4.JM.05IlirneyiteMg0.5ZnMn3+(Te4+O3)3 · 4.5H2OHex. 6/m : P63/m
4.JM.10EmmonsiteFe3+2(TeO3)3 · 2H2OTric. 1 : P1
4.JM.10BlakeiteFe3+2[TeO3]3 (?)
4.JM.15GraemiteCu[TeO3] · H2OOrth. mmm(2/m2/m2/m) : Pmma
4.JM.20TelluromandarinoiteFe3+2Te3O9 · 6H2OMon. 2/m : P21/c
4.JM.20TeineiteCu2+(Te4+O3) · 2H2OOrth. 222 : P212121
4.JM.25MillsiteCu2+(Te4+O3) · 2H2OMon. 2/m : P21/c

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KeystoneiteHide

References for KeystoneiteHide

Localities for KeystoneiteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Armenia
 
  • Gegharkunik Province
    • Sotk
Pavel M. Kartashov analytical data (2003)
USA
 
  • California
    • Tuolumne County
      • Coulterville Mining District
        • Peñon Blanco Peak
Roberts et al. (1994) +1 other reference
  • Colorado
    • Boulder County
      • Magnolia Mining District
Eckel et al. (1997) +2 other references
Eckel et al. (1997)
 
and/or  
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