Log In
Maricopaite
A valid IMA mineral species
This page is currently not sponsored. Click here to sponsor this page.
About Maricopaite
Formula:
Pb7Ca2(Si,Al)48O100 · 32H2O
Colour:
White, colorless
Lustre:
Vitreous, Silky
Hardness:
1 - 1½
Specific Gravity:
2.94
Crystal System:
Orthorhombic
Member of:
Name:
Named after Maricopa County, Arizona, USA, which includes the type locality.
Chemically similar to wickenburgite and 'UM1985-25-SiO:AlCaMgPb'.
The only currently known natural zeolite representative with lead as an essential cation.
The only currently known natural zeolite representative with lead as an essential cation.
Unique Identifiers
Mindat ID:
2577
Long-form identifier:
mindat:1:1:2577:1
IMA Classification of Maricopaite
Approved
IMA Formula:
Ca2Pb2+7(Si36Al12)O99·n(H2O,OH)
First published:
1988
Classification of Maricopaite
9.GD.35
9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
D : Chains of 6-membered rings – tabular zeolites
9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
D : Chains of 6-membered rings – tabular zeolites
77.1.6.3
77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
16.14.15
16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb
16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Mrp | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Maricopaite
Vitreous, Silky
Transparency:
Transparent, Translucent
Colour:
White, colorless
Streak:
White
Hardness:
1 - 1½ on Mohs scale
Tenacity:
Very brittle
Cleavage:
Imperfect/Fair
{010} imperfect.
{010} imperfect.
Density:
2.94 g/cm3 (Measured) 2.90 g/cm3 (Calculated)
Comment:
Measured with heavy liquids.
Optical Data of Maricopaite
Type:
Biaxial (-)
RI values:
nα = 1.563(3) nβ = 1.582(3) nγ = 1.592
2V:
Measured: 70° (10), Calculated: 70°
Max. Birefringence:
δ = 0.029
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v strong
Optical Extinction:
X = a; Y = c; Z = b.
Comments:
γ calculated.
Chemistry of Maricopaite
Mindat Formula:
Pb7Ca2(Si,Al)48O100 · 32H2O
Element Weights:
Crystallography of Maricopaite
Crystal System:
Orthorhombic
Cell Parameters:
a = 19.434(2) Å, b = 19.702(2) Å, c = 7.538(1) Å
Ratio:
a:b:c = 0.986 : 1 : 0.383
Unit Cell V:
2,886.21 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Thin bundles of crystals elongated along [001]; in radial sprays, to 1 mm.
Comment:
Point Group: 2/m 2/m 2/m; mm2; or 222:; Space Group: Cmmm; Cm2m; Cmm2; or C222
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File Best | x | y | z | a | b | c
CIF File Best | x | y | z | a | b | c
Rotation
Stop | Start
Stop | Start
Labels
Console Off | On | Grey | Yellow
Console Off | On | Grey | Yellow
Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0001636 | Maricopaite | Rouse R C, Peacor D R (1994) Maricopaite, an unusual lead calcium zeolite with an interrupted mordenite-like framework and intrachannel Pb4 tetrahedral clusters American Mineralogist 79 175-184 | ![]() | 1994 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 13.7 Å | (100) |
| 3.216 Å | (50) |
| 9.86 Å | (40) |
| 3.357 Å | (40) |
| 2.978 Å | (40) |
| 2.845 Å | (40) |
| 4.35 Å | (30) |
Locality:
Comments:
Moon Anchor Mine, Arizona, USA. The data are from the type description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-𝑇 alteration and/or metamorphism | |
| 32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits | |
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] |
Type Occurrence of Maricopaite
General Appearance of Type Material:
Sprays of translucent white, acicular crystals. Thin bundles of extremely elongate acicular crystals, frequently as mats with admixed mimetite. Radial sprays up to 1.0 mm in diameter.
Place of Conservation of Type Material:
National Museum of Natural History (Smithsonian Institution), Washington, D.C., USA, numbers NMNH 163248 and 163247.
Geological Setting of Type Material:
Au-Pb-Ag mineralization in a vein deposit with pod-like ore bodies. Host rock is gneiss and schist. The type material came from the hanging wall of the vein which consists of calcite-fluorite gangue with many square voids thought to be from former galena.
Associated Minerals at Type Locality:
Other Language Names for Maricopaite
Relationship of Maricopaite to other Species
Member of:
Other Members of Zeolite Group:
| Alflarsenite | NaCa2Be3Si4O13(OH) · 2H2O | Mon. 2 : P21 |
| Amicite | K2Na2Al4Si4O16 · 5H2O | Mon. 2 |
| Ammonioleucite | (NH4)(AlSi2O6) | Tet. 4/m : I41/a |
| Analcime | Na(AlSi2O6) · H2O | Tric. 1 : P1 |
| Arzamastsevite | K6Al5Si6O20(OH)4Cl | Tet. 42m : I42m |
| Bellbergite | (K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2O | Hex. |
| Bikitaite | LiAlSi2O6 · H2O | Tric. 1 : P1 |
| Boggsite | Ca8Na3(Si,Al)96O192 · 70H2O | Orth. mmm(2/m2/m2/m) : Imma |
| Brewsterite Subgroup | Zeolite Group. | |
| Chabazite-Levyne Subgroup | M[Al2Si4O12] · 6H2O | |
| Chiavennite | CaMnBe2Si5O13(OH)2 · 2H2O | Mon. 2/m : P21/c |
| Clinoptilolite Subgroup | (Na/Ca/K)3-6[Al6-7Si29-30O72] · 20H2O | |
| Cowlesite | CaAl2Si3O10 · 6H2O | Orth. mmm(2/m2/m2/m) |
| Dachiardite Subgroup | Zeolite Group. | |
| Direnzoite | NaK6MgCa2(Al13Si47O120) · 36H2O | Orth. mmm(2/m2/m2/m) : Pmmn |
| Edingtonite | Ba[Al2Si3O10] · 4H2O | Orth. 222 : P212121 |
| Epistilbite | CaAl2Si6O16 · 5H2O | Mon. |
| Erionite Subgroup | M2[Al4Si14O36] · 15H2O | |
| Fabrièsite | Na3Al3Si3O12 · 2H2O | Orth. mm2 : Pmm2 |
| Faujasite Subgroup | M3.5[Al7Si17O48] · 32H2O | |
| Ferrierite Subgroup | Name used for unanalysed specimens that could be either ferrierite-K, ferrierite-Mg, ... | |
| Ferrochiavennite | Ca1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2O | Mon. 2/m : P21/c |
| Flörkeite | (K3Ca2Na)[Al8Si8O32] · 12H2O | Tric. 1 : P1 |
| Garronite Subgroup | ||
| Gaultite | Na4Zn2Si7O18 · 5H2O | Orth. mm2 : Fdd2 |
| Gismondine Subgroup | Zeolite Group. | |
| Gmelinite Subgroup | In 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K. | |
| Gobbinsite | Na5(Si11Al5)O32 · 11H2O | Orth. mmm(2/m2/m2/m) : Pnma |
| Goosecreekite | Ca[Al2Si6O16] · 5H2O | Mon. 2 : P21 |
| Gottardiite | Na3Mg3Ca5Al19Si117O272 · 93H2O | Orth. mmm(2/m2/m2/m) : Cmca |
| Heulandite Subgroup | (Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O | |
| Hsianghualite | Ca3Li2(Be3Si3O12)F2 | Iso. 23 : I213 |
| Kalborsite | K6Al4BSi6O20(OH)4Cl | Tet. 42m : P421c |
| Kirchhoffite | Cs(BSi2O6) | Tet. 4/mmm(4/m2/m2/m) : I41/acd |
| Laumontite | CaAl2Si4O12 · 4H2O | Mon. 2/m : B2/m |
| Leucite | K(AlSi2O6) | Tet. 4/m : I41/a |
| Limousinite | BaCa[Be4P4O16] · 6H2O | Mon. 2/m : P21/c |
| Lithosite | K6Al4Si8O25 · 2H2O | Mon. |
| Loomisite | Ba[Be2P2O8] · H2O | Mon. m |
| Lovdarite | K2Na6Be4Si14O36 · 9H2O | Orth. mm2 |
| Martinandresite | Ba2(Al4Si12O32) · 10H2O | Orth. mmm(2/m2/m2/m) : Pmmn |
| Mazzite Subgroup | Zeolite Group. | |
| Meierite | Ba44Si66Al30O192Cl25(OH)33 | Iso. m3m(4/m32/m) : Im3m |
| Merlinoite | K5Ca2(Si23Al9)O64 · 24H2O | Orth. mmm(2/m2/m2/m) : Immm |
| Montesommaite | (K,Na)9Al9Si23O64 · 10H2O | Orth. mm2 : Fdd2 |
| Mordenite | (Na2,Ca,K2)4(Al8Si40)O96 · 28H2O | Orth. |
| Mountainite | KNa2Ca2[Si8O19(OH)] · 6H2O | Mon. 2/m : P2/b |
| Mutinaite | Na3Ca4Si85Al11O192 · 60H2O | Orth. mmm(2/m2/m2/m) : Pnma |
| Nabesite | Na2BeSi4O10 · 4H2O | Orth. 222 : P212121 |
| Natrolite Subgroup | A subgroup of the Zeolite Group. | |
| Offretite | KCaMg(Si13Al5)O36 · 15H2O | Hex. 6m2 : P6m2 |
| Pahasapaite | Li8(Ca,Li,K)10.5Be24(PO4)24 · 38H2O | Iso. 23 : I23 |
| Parthéite | Ca2(Si4Al4) O15 (OH)2 · 4H2O | Mon. 2/m : B2/b |
| Paulingite Subgroup | Paulingite was originally described in 1960. | |
| Perlialite | K9Na(Ca,Sr)[Al2Si4O12]6 · 15H2O | Hex. 6/mmm(6/m2/m2/m) : P6/mmm |
| Phillipsite Subgroup | (Ca0.5,K,Na,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O | |
| Pollucite | (Cs,Na)2(Al2Si4O12) · 2H2O | Iso. m3m(4/m32/m) : Ia3d |
| Roggianite | Ca2Be(OH)2Al2Si4O13 · 2.5H2O | Tet. 4/mmm(4/m2/m2/m) : I4/mcm |
| Rongibbsite | Pb2(Si4Al)O11(OH) | Mon. 2/m : B2/m |
| Stilbite Subgroup | M6-7[Al8-9Si27-28O72] · nH2O | |
| Terranovaite | (Na,Ca)8(Si68Al12)O160 · 29H2O | Orth. |
| Thomsonite Subgroup | The large majority of "thomsonite" is thomsonite-Ca. | |
| Thornasite | Na12Th4+3(Si8O19)4 · 18H2O | Trig. 3m : R3m |
| Tschernichite | (Ca,Na2)[Al2Si4O12] · 4-8H2O | Tet. 4/mmm(4/m2/m2/m) : P4/mmm |
| Tschörtnerite | Ca4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2O | Iso. m3m(4/m32/m) : Fm3m |
| 'UM1996-38-SiO:AlCaHNa' | Na-Ca-Al-Si-O-H | |
| 'UM1999-33-SiO:AlHKNa' | K7Na5Al12Si20O64 · 24H2O | |
| 'UM2002-40-SiO:AlCaHKMgNa' | (Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2O | Tet. 422 : P4122 |
| 'Unnamed (Ca analogue of Merlinoite)' | (Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ? | |
| Wairakite | Ca(Al2Si4O12) · 2H2O | Mon. 2/m : B2/b |
| Weinebeneite | CaBe3(PO4)2(OH)2 · 4H2O | Mon. m : Bb |
| Wenkite | (Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2O | Hex. 6m2 : P62m |
| Wilancookite | (Ba5Li2◻)Ba6Be24P24O96 · 26H2O | Iso. 23 : I23 |
| Willhendersonite | KCa[Al3Si3O12] · 5H2O | Tric. 1 : P1 |
| Yugawaralite | CaAl2Si6O16 · 4H2O | Mon. m : Pb |
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 9.GD.05 | Gmelinite-Ca | Ca2(Si8Al4)O24 · 11H2O |
| 9.GD.05 | Gmelinite-K | K4(Si8Al4O24) · 11H2O |
| 9.GD.05 | Gmelinite-Na | Na4(Si8Al4)O24 · 11H2O |
| 9.GD.10 | Chabazite-Mg | (Mg0.7K0.5Ca0.5Na0.1)[Al3Si9O24] · 10H2O |
| 9.GD.10 | Willhendersonite | KCa[Al3Si3O12] · 5H2O |
| 9.GD.10 | Chabazite-Ca | (Ca,K2,Na2)2[Al2Si4O12]2 · 12H2O |
| 9.GD.10 | Chabazite-K | (K2,Ca,Na2,Sr,Mg)2[Al2Si4O12]2 · 12H2O |
| 9.GD.10 | Chabazite-Na | (Na2,K2,Ca,Sr,Mg)2[Al2Si4O12]2 · 12H2O |
| 9.GD.10 | Chabazite-Sr | Sr2[Al2Si4O12]2 · 12H2O |
| 9.GD.15 | Lévyne-Ca | (Ca,Na2,K2)[Al2Si4O12] · 6H2O |
| 9.GD.15 | Lévyne-Na | (Na2,Ca,K2)[Al2Si4O12] · 6H2O |
| 9.GD.20 | Erionite-Ca | (Ca,K2,Na2)2[Al4Si14O36] · 15H2O |
| 9.GD.20 | Erionite-K | (K2,Ca,Na2)2[Al4Si14O36] · 15H2O |
| 9.GD.20 | Erionite-Na | (Na2,K2,Ca)2[Al4Si14O36] · 15H2O |
| 9.GD.20 | Bellbergite | (K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2O |
| 9.GD.25 | Offretite | KCaMg(Si13Al5)O36 · 15H2O |
| 9.GD.25 | Wenkite | (Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2O |
| 9.GD.30 | Faujasite-Ca | (Ca,Na2,Mg)3.5[Al7Si17O48] · 32H2O |
| 9.GD.30 | Faujasite-Mg | (Mg,Na2,Ca)3.5[Al7Si17O48] · 32H2O |
| 9.GD.30 | Faujasite-Na | (Na2,Ca,Mg)3.5[Al7Si17O48] · 32H2O |
| 9.GD.35 | Mordenite | (Na2,Ca,K2)4(Al8Si40)O96 · 28H2O |
| 9.GD.40 | Dachiardite-K | K4(Si20Al4O48) · 13H2O |
| 9.GD.40 | Dachiardite-Ca | (Ca,Na2,K2)5Al10Si38O96 · 25H2O |
| 9.GD.40 | Dachiardite-Na | (Na2,Ca,K2)5Al10Si38O96 · 25H2O |
| 9.GD.45 | Epistilbite | CaAl2Si6O16 · 5H2O |
| 9.GD.50 | Ferrierite-K | (K,Na)5(Si31Al5)O72 · 18H2O |
| 9.GD.50 | Ferrierite-Mg | [Mg2(K,Na)2Ca0.5](Si29Al7)O72 · 18H2O |
| 9.GD.50 | Ferrierite-Na | (Na,K)5(Si31Al5)O72 · 18H2O |
| 9.GD.50 | Ferrierite-NH4 | (NH4,Mg0.5)5(Al5Si31O72) · 22H2O |
| 9.GD.55 | Bikitaite | LiAlSi2O6 · H2O |
Fluorescence of Maricopaite
None observed.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Maricopaite
mindat.org URL:
https://www.mindat.org/min-2577.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
Mineral Dealers:
References for Maricopaite
Reference List:
Rouse, Roland C., Peacor, Donald R. (1994) Maricopaite, an unusual lead calcium zeolite with an interrupted mordenite-like framework and intrachannel Pb4, tetrahedral clusters. American Mineralogist, 79 (1-2) 175-184
Coombs, Douglas S., Alberti, Alberto, Armbruster, Thomas, Artioli, Gilberto, Colella, Carmine, Galli, Ermanno, Grice, Joel D., Liebau, Friedrich, Mandarino, Joseph A., Minato, Hideo, et al. (1997) Recommended nomenclature for zeolite minerals; report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. The Canadian Mineralogist, 35 (6). 1571-1606
Localities for Maricopaite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
USA (TL) | |
| Peacor et al. (1988) +1 other reference |
Quick NavTopAbout MaricopaiteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence Other LanguagesRelationshipsCommon AssociatesStrunz-MindatFluorescence Other InformationInternet Links References Localities Locality List





symbol to view information about a locality.
The
Moon Anchor Mine, Hummingbird Springs, Osborn Mining District, Maricopa County, Arizona, USA