Log InRegister
Search For:
Mineral Name:
Locality Name:
Keyword(s):
 
Home PageAbout MindatThe Mindat ManualHistory of MindatCopyright StatusWho We AreOur ScienceMindat Newsletter [Free Download]Contact Us
Donate to MindatSponsor a PageCorporate SponsorshipSponsored Pages
Learning CenterWhat Is a Mineral?The Most Common Minerals on EarthInformation for EducatorsMindat ArticlesMindat Newsletter [Free Download]The ElementsThe Mineral Quiz
Search FormMinerals by PropertiesMinerals by ChemistryMineral Visual ExplorerAdvanced Locality SearchRandom MineralRandom LocalitySearch by minIDMinerals by CountryAlphabetical Mineral IndexAlphabetical Locality SearchMineral Association SearchList of CountriesLocalities Near MePhoto SearchSearch ArticlesSearch GlossaryThe Rock H. Currier Digital LibraryMore Search Options
The Mindat ManualAdd a New PhotoRate PhotosLocality Edit ReportCoordinate Completion ReportAdd Glossary Item
MineralsPetrologyFossilsMeteoritesGeologic Time
Mining CompaniesStatisticsMineral MuseumsClubs & OrganizationsMineral Shows & EventsDevice SettingsTime Machine
Read DiscussionsIdentification Request
Photo SearchPhoto GalleriesSearch by ColourPhoto Colour ExplorerNew Photos TodayNew Photos YesterdayMembers' Photo GalleriesPast Photo of the Day GalleryPhotography

Wolfeite

A valid IMA mineral species - grandfathered
This page is currently not sponsored. Click here to sponsor this page.
Hide all sections | Show all sections

About WolfeiteHide

02723350017271927757361.jpg
Caleb Wroe Wolfe
Formula:
Fe2+2(PO4)(OH)
Colour:
Red-brown to dark brown, green (rare); light brown in transmitted light.
Lustre:
Sub-Adamantine, Sub-Vitreous, Resinous, Greasy
Hardness:
4½ - 5
Specific Gravity:
3.79 - 3.82
Crystal System:
Monoclinic
Member of:
Name:
Named in 1949 by Clifford Frondel in honour of Dr. Caleb Wroe Wolfe (22 October 1908, Washington, D.C., USA - 17 July 1980), American crystallographer and Professor of Geology at Boston University, Boston, Massachusetts, USA, who was also a systematic mineralogist interested in granite pegmatite phosphates.
The mineral wroewolfeite is also named after him.

Unique IdentifiersHide

Mindat ID:
4304
Long-form identifier:
mindat:1:1:4304:1

Similar NamesHide

WulffiteA valid IMA mineral speciesK3NaCu4O2(SO4)4

IMA Classification of WolfeiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Fe2+2PO4(OH)

Classification of WolfeiteHide

8.BB.15

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
B : With only medium-sized cations, (OH, etc.):RO4 about 1:1
41.6.3.1

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
6 : A2(XO4)Zq
19.12.12

19 : Phosphates
12 : Phosphates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
WolIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of WolfeiteHide

Sub-Adamantine, Sub-Vitreous, Resinous, Greasy
Transparency:
Transparent, Translucent
Colour:
Red-brown to dark brown, green (rare); light brown in transmitted light.
Streak:
White, off-white.
Hardness:
4½ - 5 on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
On {010}, good; on {120}, fair; on {110}, very poor.
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
3.79 - 3.82 g/cm3 (Measured)    3.88 g/cm3 (Calculated)
Comment:
Density value of 3.83 estimated for the pure Fe2+ end member.

Optical Data of WolfeiteHide

Type:
Biaxial (+)
RI values:
nα = 1.741 - 1.750 nβ = 1.742 - 1.750 nγ = 1.746 - 1.759
2V:
Measured: 51°
Birefringence:
0.005
Max. Birefringence:
δ = 0.005 - 0.009
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 ”m thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
strong
Pleochroism:
Weak
Comments:
Faintly pleochroic in thick grains.

Chemistry of WolfeiteHide

Mindat Formula:
Fe2+2(PO4)(OH)
Element Weights:
Element% weight
Fe49.936 %
O35.766 %
P13.848 %
H0.451 %

Calculated from ideal end-member formula.
Fe
O
P
H

Crystallography of WolfeiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/c
Setting:
P21/a
Cell Parameters:
a = 12.20 Å, b = 13.17 Å, c = 9.79 Å
β = 108°
Ratio:
a:b:c = 0.926 : 1 : 0.743
Unit Cell V:
1,496.01 ų (Calculated from Unit Cell)
Z:
16
Morphology:
Almost always massive, rare crystals prismatic [001], with the prism zone striated vertically.

Crystal StructureHide

Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File    Best | x | y | z | a | b | c
Rotation
Stop | Start
Labels
Console Off | On | Grey | Yellow
IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0010412WolfeiteKolitsch U (2003) Mg-rich wolfeite, (Fe,Mg)2(PO4)(OH): structure refinement and Raman spectroscopic data Acta Crystallographica E59 i125-i1282003Big Fish River area, Yukon Territory, Canada0293
0010339WolfeiteHatert F (2007) Fe2(PO4)(OH), a synthetic analogue of wolfeite Acta Crystallographica C63 i119-i1212007synthetic2.5293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.649 Å(25)
3.381 Å(20)
3.191 Å(80)
3.098 Å(100)
2.929 Å(70)
2.881 Å(30)
2.817 Å(60)
Comments:
Hagendorf, Germany

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
21 : Chemically precipitated carbonate, phosphate, iron formations
High-𝑇 alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
Stage 5: Initiation of plate tectonics<3.5-2.5
40 : Regional metamorphism (greenschist, amphibolite, granulite facies)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]
Geological Setting:
Granitic pegmatites.

Type Occurrence of WolfeiteHide

Geological Setting of Type Material:
Granitic pegmatite.
Associated Minerals at Type Locality:

Other Language Names for WolfeiteHide

Relationship of Wolfeite to other SpeciesHide

Member of:
Other Members of Triplite Group:
TripliteMn2+2(PO4)FMon. 2/m : B2/b
TriploiditeMn2+2(PO4)(OH)Mon. 2/m : P21/c
ZwieseliteFe2+2(PO4)FMon. 2/m : B2/b
Forms a series with:

Common AssociatesHide

Associations Based on Photo Data:
13 photos of Wolfeite associated with TriphyliteLiFe2+PO4
4 photos of Wolfeite associated with PyriteFeS2
4 photos of Wolfeite associated with HagendorfiteNaCaMn2+Fe2+2(PO4)3
3 photos of Wolfeite associated with VivianiteFe2+Fe2+2(PO4)2 · 8H2O
3 photos of Wolfeite associated with SideriteFeCO3
3 photos of Wolfeite associated with LudlamiteFe2+3(PO4)2 · 4H2O
2 photos of Wolfeite associated with ChalcopyriteCuFeS2
2 photos of Wolfeite associated with SphaleriteZnS
2 photos of Wolfeite associated with 'Ferrisicklerite'Li1-x(Fe3+xFe2+1-x)PO4
2 photos of Wolfeite associated with HeterositeFe3+(PO4)

Related Minerals - Strunz-mindat GroupingHide

8.BB.MoabiteNiFe3+(PO4)OOrth. mmm(2/m2/m2/m) : Pnma
8.BB.TilasiteCaMg(AsO4)FMon.
8.BB.PaulgrothiteCu9Fe3+O4(PO4)4Cl3Orth. mm2 : Cmc21
8.BB.KarlditmariteCu9O4(PO4)2(SO4)2Tric. 1 : P1
8.BB.MilkovoiteCu4O(PO4)(AsO4)Orth. mmm(2/m2/m2/m) : Pnma
8.BB.XArsenowagneriteMg2(AsO4)FMon. 2/m : P21/c
8.BB.05TavoriteLiFe3+(PO4)(OH)Tric. 1 : P1
8.BB.05AmblygoniteLiAl(PO4)FTric. 1 : P1
8.BB.05MontebrasiteLiAl(PO4)(OH)Tric. 1 : P1
8.BB.10ZwieseliteFe2+2(PO4)FMon. 2/m : B2/b
8.BB.10TripliteMn2+2(PO4)FMon. 2/m : B2/b
8.BB.15'Unnamed (Sb-analogue of Auriacusite)'Fe3+Cu2+[(Sb,As)O4]O
8.BB.15JoosteiteMn2+(Mn3+,Fe3+)(PO4)OMon. 2/m : B2/b
8.BB.15HydroxylwagneriteMg2(PO4)(OH)Mon. 2/m : P21/c
8.BB.15WagneriteMg2(PO4)FMon. 2/m : P21/c
8.BB.15Stanĕkite(Mn2+,Fe2+,Mg)Fe3+(PO4)OMon. 2/m : P21/c
8.BB.15TriploiditeMn2+2(PO4)(OH)Mon. 2/m : P21/c
8.BB.15SarkiniteMn2+2(AsO4)(OH)Mon. 2/m : P21/c
8.BB.20HoltedahliteMg2(PO4)(OH)Trig. 3m : P31m
8.BB.20Satterlyite(Fe2+,Mg,Fe)12(PO4)5(PO3OH)(OH,O)6Trig. 3m(32/m) : P31m
8.BB.25AlthausiteMg4(PO4)2(OH,O)(F,◻)Orth. mmm(2/m2/m2/m) : Pnma
8.BB.30ZincoliveniteCuZn(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30AdamiteZn2(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30LibetheniteCu2(PO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30ZincolibetheniteCuZn(PO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30EveiteMn2+2(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30OliveniteCu2(AsO4)(OH)Mon. 2/m : P21/m
8.BB.30AuriacusiteFe3+Cu2+(AsO4)OOrth. mmm(2/m2/m2/m) : Pnnm
8.BB.35ParadamiteZn2(AsO4)(OH)Tric. 1 : P1
8.BB.35TarbuttiteZn2(PO4)(OH)Tric. 1 : P1
8.BB.40BarbosaliteFe2+Fe3+2(PO4)2(OH)2Mon. 2/m : P21/c
8.BB.40ScorzaliteFe2+Al2(PO4)2(OH)2Mon. 2/m : P21/c
8.BB.40LazuliteMgAl2(PO4)2(OH)2Mon. 2/m : P21/c
8.BB.40MeizhouiteFe2+V3+2(PO4)2(OH)2Mon. 2/m : P21/c
8.BB.40HentscheliteCuFe3+2(PO4)2(OH)2Mon. 2/m : P21/m
8.BB.40WilhelmkleiniteZnFe3+2(AsO4)2(OH)2Mon. 2/m : P21/m
8.BB.45DokuchaeviteCu8O2(VO4)3Cl3Tric. 1 : P1
8.BB.45TrolleiteAl4(PO4)3(OH)3Mon. 2/m : B2/b
8.BB.45YaroshevskiteCu9O2(VO4)4Cl2 Tric. 1 : P1
8.BB.50NamibiteCu(BiO)2(VO4)(OH)Tric. 1 : P1
8.BB.50Aleutite[Cu5O2](AsO4)(VO4) · (Cu,K,Pb,Rb,Cs,)ClMon. 2/m : B2/m
8.BB.52aEriclaxmaniteCu4O(AsO4)2Tric. 1 : P1
8.BB.52bKozyrevskiteCu4O(AsO4)2Orth. mmm(2/m2/m2/m) : Pnma
8.BB.55Phosphoellenbergerite(Mg,◻)2Mg12(PO4,PO3OH)6(PO3OH,CO3)2(OH)6Hex. 6mm : P63mc
8.BB.55PopoviteCu5O2(AsO4)2Tric. 1 : P1
8.BB.60UrusoviteCuAl(AsO4)OMon. 2/m : P21/c
8.BB.65TheoparacelsiteCu3(As2O7)(OH)2Orth. mmm(2/m2/m2/m) : Pmma
8.BB.70TuraniteCu5(VO4)2(OH)4Tric. 1 : P1
8.BB.75StoiberiteCu5(VO4)2O2Mon. 2/m : P21/c
8.BB.80FingeriteCu11(VO4)6O2Tric. 1 : P1
8.BB.85AverieviteCu6(VO4)2O2Cl2Trig. 3 : P3
8.BB.90RichelliteCaFe3+2(PO4)2(OH,F)2Amor.
8.BB.90LipscombiteFe2+Fe3+2(PO4)2(OH)2Tet. 422 : P41212
8.BB.90ZinclipscombiteZnFe3+2(PO4)2(OH)2Tet. 422 : P43212

Fluorescence of WolfeiteHide

Not fluorescent in UV

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for WolfeiteHide

References for WolfeiteHide

Reference List:

Localities for WolfeiteHide

Showing 57 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • CĂłrdoba Province
Colombo et al. (2012)
  • La Rioja Province
    • General Ángel V. Peñaloza Department
Colombo et al. (2018)
Australia
 
  • New South Wales
    • Yancowinna Co.
      • Thackaringa District
Plimer et al. (1979)
  • Victoria
    • East Gippsland Shire
      • Glen Valley
Birch (2018)
Eagle et al. (2015) +1 other reference
Eagle et al. (2015)
Brazil
 
  • Minas Gerais
    • Conselheiro Pena
      • Barra do CuietĂ©
Cassedanne et al. (1982) +1 other reference
    • GalilĂ©ia
      • Laranjeiras
Cassedanne et al. (1981)
Canada
 
  • Yukon
    • Dawson mining district
Robinson et al. (1992)
Pacific Mineral Museum collection (now at the Pacific Museum of the Earth, UBC)
Robinson et al. (1992)
150-152. +2 other references
China
 
  • Fujian
    • Nanping
      • Yanping District
        • Nanping pegmatite field
Rao et al. (2014)
Czech Republic
 
  • Plzeƈ Region
    • DomaĆŸlice District
      • Otov
Masau et al. (2000)
  • Vysočina Region
    • ĆœÄĂĄr nad SĂĄzavou District
      • Bory
        • HornĂ­ Bory
          • Cyrilov (Cyrillhof)
Ć koda et al. (2007) +1 other reference
Finland
 
  • South Ostrobothnia
Ilkka Mikkola sample
France
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Bellac
        • RazĂšs
          • Chanteloube
            • Vilatte Quarries (La Vilate)
Anthony et al. (2000)
Germany
 
  • Bavaria
    • Lower Bavaria
      • Regen District
        • Zwiesel
          • Rabenstein
Weiß (1990)
    • Upper Palatinate
      • Neustadt an der Waldnaab District
        • Pleystein
Dill et al. (2009)
Dill et al. (2008) +1 other reference
        • Waidhaus
Dill et al. (2011)
Weiß (1990)
Antenucci et al. (1989) +2 other references
Dill et al. (2008)
Italy
 
  • Lombardy
    • Lecco Province
      • Colico
VIGNOLA et al. (2007)
Vignola et al. (2011)
  • Sardinia
    • Nuoro Province
      • Orotelli
Raudsepp M. and Pani E. (1994)
  • Trentino-Alto Adige/SĂŒdtirol
    • Trento Province
      • Rabbi
        • CeresĂš
Vignola et al. (2018)
Poland
 
  • Lower Silesian Voivodeship
    • Úwidnica County
      • Gmina Úwidnica
Pieczka et al. (2015)
ƁodziƄski M. & Sitarz M. 2008: Chemical and Spectroscopic Characterization of Some Phosphates Accessory Minerals from Pegmatites of the Sowie Mts (Owles Mts) +1 other reference
Pieczka et al. (2017)
Portugal
 
Fleischer et al. (1982) +1 other reference
  • Viana do Castelo
    • Ponte da Barca
      • Touvedo (SĂŁo Lourenço e Salvador)
Leal Gomes et al. (2009)
Romania
 
  • Maramureș County
    • TĂąrgu Lăpuș
Udubasa et al. (1996) +1 other reference
  • Sibiu County
    • Lotru-Cibin Mountains
Calin et al. (2014) +2 other references
South Africa
 
  • Northern Cape
    • Namakwa District Municipality
      • KhĂąi-Ma Local Municipality
        • Aggeneys
Stalder et al. (2002)
Spain
 
  • Castile and Leon
    • Salamanca
      • Aldehuela de la BĂłveda
Roda et al. (2001)
      • Garcirrey
EncarnaciĂłn Roda-Robles (2007)
  • Catalonia
    • Girona
      • Alt EmpordĂ 
        • CadaquĂ©s
Bareche (2005)
& locality references +1 other reference
Sweden
 
  • JĂ€mtland County
    • BrĂ€cke
Smeds et al. (1998)
  • Östergötland County
    • Motala
      • GodegĂ„rd
Palache et al. (1951)
  • Stockholm County
    • Haninge
Smeds et al. (1998)
      • Norrö
Gustafsson et al. (1991)
Smeds et al. (1998)
Wik et al. (2005)
Smeds et al. (1998)
    • Sigtuna
      • Arlanda
  • VĂ€sternorrland County
    • SollefteĂ„
Smeds et al. (1998)
USA
 
  • Maine
    • Oxford County
      • Newry
Malcolm Back
  • New Hampshire
    • Cheshire County
      • Walpole
Anna Wilken collection
    • Grafton County
      • Groton
Frondel (1949) +3 other references
Geological Society of America Abstracts ... +2 other references
      • Orange
Robinson (1986) +2 other references
  • South Dakota
    • Custer County
      • Custer Mining District
        • Custer
Smith et al. (2000)
    • Pennington County
      • Keystone Mining District
        • Glendale
Smith et al. (2000)
 
and/or  
Mindat.orgÂź is an outreach project of the Hudson Institute of Mineralogy, a 501(c)(3) not-for-profit organization. MindatÂź and mindat.orgÂź are registered trademarks of the Hudson Institute of Mineralogy.
Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2026, except where stated. Most political location boundaries are © OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 by Jolyon Ralph and Ida Chau.
Content on this site may not be used to train, fine-tune, or otherwise develop artificial intelligence or machine learning models without prior written permission - see our Terms & Conditions.
To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
Privacy Policy - Terms & Conditions - Contact Us / DMCA issues - Report a bug/vulnerability Current server date and time: November 2, 2026 05:00:02 Page updated: October 29, 2026 10:16:05
Go to top of page