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Friisite
A valid IMA mineral species
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Formula:
Pb8Al3Si8O27Cl3
Colour:
white to colorless
Lustre:
Sub-Adamantine
Hardness:
4 - 5
Specific Gravity:
5.54 (Calculated)
Crystal System:
Hexagonal
Name:
Named in honor of the Danish mineralogist Henrik Friis (b. 1977), professor at the Natural History Museum, University of Oslo, Norway, in recognition of his significant contributions to Nordic (including Greenlandic) mineralogy.
Isostructural with:
Was found in a museum specimen of jagoite with heterogeneous skarn associated with hematite ore, collected from the Canberra stope at 220 m depth in the mine.
Unique Identifiers
Mindat ID:
471483
Long-form identifier:
mindat:1:1:471483:1
Similar Names
IMA Classification of Friisite
Approved
IMA Formula:
Pb8Al3Si8O27Cl3
Approval year:
2024
Classification of Friisite
9.EG.50
9 : SILICATES (Germanates)
E : Phyllosilicates
G : Double nets with 6-membered and larger rings
9 : SILICATES (Germanates)
E : Phyllosilicates
G : Double nets with 6-membered and larger rings
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Fii | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Friisite
Sub-Adamantine
Transparency:
Transparent
Colour:
White to colorless
Streak:
White
Hardness:
4 - 5 on Mohs scale
Comment:
by analogy with jagoite
Tenacity:
Brittle
Cleavage:
Perfect
on {001}
on {001}
Parting:
none
Fracture:
Irregular/Uneven
Density:
5.54(1) g/cm3 (Calculated)
Optical Data of Friisite
Type:
Uniaxial (-)
Pleochroism:
Non-pleochroic
Comments:
with a calculated average refractive index of n=1.88 using Gladstone–Dale constants
Chemistry of Friisite
Mindat Formula:
Pb8Al3Si8O27Cl3
Element Weights:
Chemical Analysis
Oxide wt%:
| 1 | |
|---|---|
| Na2O | 0.14 % |
| Al2O3 | 4.42 % |
| SiO2 | 19.80 % |
| Cl | 4.19 % |
| CaO | 0.19 % |
| MnO | 0.31 % |
| Fe2O3 | 0.63 % |
| ZnO | 0.42 % |
| PbO | 69.83 % |
| O=Cl | -0.94 % |
| Total: | 98.99 % |
Empirical formulas:
| Sample ID | Empirical Formula |
|---|---|
| 1 | (Pb7.89Na0.11CaO0.08)Σ8.8(Al2.19Si0.31Fe3+0.20Zn0.13Mn2+0.11)Σ2.94Si8O27.02Cl2.98 |
Sample references:
| ID | Locality | Reference | Notes |
|---|---|---|---|
| 1 | Långban Mine, Långban Ore District, Filipstad, Värmland County, Sweden | EMPA data, normalized on a basis of 30 anions (O + Cl) |
Crystallography of Friisite
Crystal System:
Hexagonal
Class (H-M):
6m2 - Ditrigonal Dipyramidal
Space Group:
P62c
Cell Parameters:
a = 8.5955(1) Å, c = 23.4092(2) Å
Ratio:
a:c = 1 : 2.723
Unit Cell V:
1,497.82 ų (Calculated from Unit Cell)
Z:
2
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 5.848 Å | (31) |
| 5.375 Å | (20) |
| 4.040 Å | (96) |
| 3.680 Å | (40) |
| 3.463 Å | (10) |
| 2.886 Å | (21) |
| 2.795 Å | (20) |
| 2.483 Å | (35) |
Type Occurrence of Friisite
General Appearance of Type Material:
subhedral, flaky grains up to 150 µm in size, forming aggregates
Place of Conservation of Type Material:
Type material is deposited in the collections of the Department of Geosciences, Swedish Museum of Natural History, Box 50007, SE-10405 Stockholm, Sweden, collection number GEO-NRM #19610234
Geological Setting of Type Material:
within a medium-grained skarn matrix and contiguous to jagoite. friisite likely crystallized after the main skarn-forming event (post-peak metamorphism) from the transformation of earlier-formed lead silicates, melanotekite (Mtk), or barysilite (Bsl).
Associated Minerals at Type Locality:
Synonyms of Friisite
Other Language Names for Friisite
Related Minerals - Strunz-mindat Grouping
| 9.EG.05 | Cymrite | BaAl2Si2(O,OH)8 · H2O |
| 9.EG.10 | Naujakasite | (Na,K)6(Fe2+,Mn2+,Ca)(Al,Fe)4Si8O26 |
| 9.EG.10 | Manganonaujakasite | Na6(Mn2+,Fe2+)Al4Si8O26 |
| 9.EG.15 | Dmisteinbergite | Ca(Al2Si2O8) |
| 9.EG.20 | Kampfite | Ba12(Si11Al5)O31(CO3)8Cl5 |
| 9.EG.25 | Vertumnite | Ca4Al4Si4O6(OH)24 · 3H2O |
| 9.EG.25 | Strätlingite | Ca2Al2SiO7 · 8H2O |
| 9.EG.30 | Eggletonite | (Na,K,Ca)xMn6(Si,Al)10O24(OH)4 · nH2O (x = 1-2; n = 7-11) |
| 9.EG.30 | Ganophyllite | (K,Na)xMn2+6(Si,Al)10O24(OH)4 · nH2O (x = 1-2; n = 7-11) |
| 9.EG.30 | Tamaite | (Ca,K,Na)xMn6(Si,Al)10O24(OH)4 · nH2O (x = 1-2; n = 7-11) |
| 9.EG.35 | Zussmanite | K(Fe,Mg,Mn)13(Si,Al)18O42(OH)14 |
| 9.EG.35 | Coombsite | KMn2+13(Si,Al)18O42(OH)14 |
| 9.EG.40 | 'Chalcodite' | K(Fe3+,Mg,Fe2+)8(Si,Al)12(O,OH)27 |
| 9.EG.40 | Parsettensite | (K,Na,Ca)7.5(Mn,Mg)49Si72O168(OH)50 · nH2O |
| 9.EG.40 | Lennilenapeite | K4Mn2+48[Si64Al8]O164(OH)52 · nH2O |
| 9.EG.40 | Stilpnomelane | K4Fe2+48[Si64Al8]O164(OH)52 · nH2O |
| 9.EG.45 | Latiumite | (Ca,K)4(Si,Al)5O11(SO4,CO3) |
| 9.EG.45 | Levantite | KCa3Al2(SiO4)(Si2O7)(PO4) |
| 9.EG.45 | Tuscanite | KCa6(Si,Al)10O22(SO4,CO3)2(OH) · H2O |
| 9.EG.50 | Jagoite | Pb18Fe3+4[Si4(Si,Fe3+)6][Pb4Si16(Si,Fe)4]O82Cl6 |
| 9.EG.55 | Wickenburgite | CaPb3Al2Si10O24(OH)6 |
| 9.EG.60 | Hyttsjöite | Pb18Ba2Ca5Mn2+2Fe3+2Si30O90Cl · 6H2O |
| 9.EG.65 | Armbrusterite | K5Na7Mn15[(Si9O22)4](OH)10 · 4H2O |
| 9.EG.70 | Roymillerite | Pb24Mg9(Si10O28)(CO3)10(BO3)(SiO4)(OH)13O5 |
| 9.EG.70 | Britvinite | [Pb7(OH)3F(BO3)2(CO3)][Mg4.5(OH)3(Si5O14)] |
| 9.EG.75 | Kayupovaite | Na2Mn10[(Si14Al2)O38(OH)8] · 7H2O |
| 9.EG.75 | 'UM1989-30-SiO:AlBaCaFeHKMgMn' | (Ba,Ca)(Mn,Fe,Mg)22(Si,Al)32O76(OH)16 · 12H2O |
| 9.EG.75 | Bannisterite | (Ca,K,Na)(Mn2+,Fe2+)10(Si,Al)16O38(OH)8 · nH2O |
Fluorescence of Friisite
does not fluoresce under UV light
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Friisite
mindat.org URL:
https://www.mindat.org/min-471483.html
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References for Friisite
Localities for Friisite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Sweden (TL) | |
| Holtstam et al. (2024) +1 other reference |
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