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Mutinaite

A valid IMA mineral species
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Formula:
Na3Ca4Si85Al11O192 · 60H2O
Colour:
Colorless to milky white
Lustre:
Vitreous, Silky
Specific Gravity:
2.13
Crystal System:
Orthorhombic
Member of:
Name:
Named after Mutina, the ancient Latin name of Modena, Italy, a center of zeolite research.
The natural counterpart of zeolite ZSM-5 (ZSM-5 - Zeolite Socony Mobil–5).

The ZSM-5 molecular sieve boasts unique and exceptional properties, which are widely employed in important processes and applications across a broad range of industries. Commonly used in converting methanol to gasoline and diesel as well as oil refining, ZSM-5 has proved superior to amorphous solid acid catalysts in reactions such as xylene isomerization, toluene disproportionation and toluene alkylation etc. Upon ion exchange or modification, H-ZSM-5 zeolites can be derived to also possess enhanced para-selectivity. All in all, the high versatility of this zeolite makes it a truly indispensable material across many industries.


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Unique IdentifiersHide

Mindat ID:
7184
Long-form identifier:
mindat:1:1:7184:6

Similar NamesHide

KutinaiteA valid IMA mineral speciesAg6Cu14As7
Mottanaite-(Ce)A valid IMA mineral speciesCa4(Ce,REE)Σ2Al(Be1.5◻0.5)Σ2[B4Si4O22]O2
MuteniteA synonym of 'Muntenite'

IMA Classification of MutinaiteHide

Classification of MutinaiteHide

9.GF.35

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
F : Other Rare Zeolites

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MutIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MutinaiteHide

Vitreous, Silky
Transparency:
Transparent
Colour:
Colorless to milky white
Streak:
White
Tenacity:
Brittle
Cleavage:
Distinct/Good
good {100}
Fracture:
Irregular/Uneven
Density:
2.13(3) g/cm3 (Measured)    2.17 g/cm3 (Calculated)

Optical Data of MutinaiteHide

Type:
Biaxial (-)
RI values:
nα = 1.485(2) nβ = 1.487(2) nγ = 1.488(2)
2V:
Measured: 70° , Calculated: 70°
Max. Birefringence:
δ = 0.003
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
none
Comments:
2V could not be measured

Chemistry of MutinaiteHide

Mindat Formula:
Na3Ca4Si85Al11O192 · 60H2O
Element Weights:
Element% weight
O57.059 %
Si33.785 %
Al4.200 %
Ca2.269 %
H1.712 %
Na0.976 %

Calculated from ideal end-member formula.
O
Si
Al
Ca
H
Na

Crystallography of MutinaiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pnma
Setting:
Pnma
Cell Parameters:
a = 20.223(7) Å, b = 20.052(8) Å, c = 13.491(5) Å
Ratio:
a:b:c = 1.009 : 1 : 0.673
Unit Cell V:
5,470.76 ų (Calculated from Unit Cell)
Twinning:
none

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0015873MutinaiteVezzalini G, Quartieri S, Galli E, Alberti A, Cruciani G, Kvick A (1997) Crystal structure of the zeolite mutinaite, the natural analog of ZSM-5 Zeolites 19 323-3251997Mt. Adamson, Northern Victoria Land, Antarctica0293
0009842Mutinaitevan Koningsveld H (1990) High-temperature (350 K) orthorhombic framework structure of zeolite H-ZSM-5 Acta Crystallographica B46 731-7351990synthetic0293
0010960MutinaiteTaylor J C, Miller S A, Bibby D M (1986) A study of decomposition methods for refinement of H+-ZSM5 zeolite with powder diffraction data Zeitschrift fur Kristallographie 176 183-1921986synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
10 : Basalt-hosted zeolite minerals

Type Occurrence of MutinaiteHide

General Appearance of Type Material:
subspherical aggregates (up to 1.8 mm in diameter)
Place of Conservation of Type Material:
holotype material has been deposited at the Museo di Storia Naturale e de1 Territorio, University of Pisa, Italy, with accession number 15520.
Geological Setting of Type Material:
Dolerite above sedimentary rock
Associated Minerals at Type Locality:

Synonyms of MutinaiteHide

Other Language Names for MutinaiteHide

Dutch:Mutinaiet
German:Mutinait
Spanish:Mutinaita

Relationship of Mutinaite to other SpeciesHide

Member of:
Other Members of Zeolite Group:
AlflarseniteNaCa2Be3Si4O13(OH) · 2H2OMon. 2 : P21
AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
Ammonioleucite(NH4)(AlSi2O6)Tet. 4/m : I41/a
AnalcimeNa(AlSi2O6) · H2OTric. 1 : P1
ArzamastseviteK6Al5Si6O20(OH)4ClTet. 42m : I42m
Bellbergite(K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2OHex.
BikitaiteLiAlSi2O6 · H2OTric. 1 : P1
BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm(2/m2/m2/m) : Imma
Brewsterite SubgroupZeolite Group.
Chabazite-Levyne SubgroupM[Al2Si4O12] · 6H2O
ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2OMon. 2/m : P21/c
Clinoptilolite Subgroup(Na/Ca/K)3-6[Al6-7Si29-30O72] · 20H2O
CowlesiteCaAl2Si3O10 · 6H2OOrth. mmm(2/m2/m2/m)
Dachiardite SubgroupZeolite Group.
DirenzoiteNaK6MgCa2(Al13Si47O120) · 36H2OOrth. mmm(2/m2/m2/m) : Pmmn
EdingtoniteBa[Al2Si3O10] · 4H2OOrth. 222 : P212121
EpistilbiteCaAl2Si6O16 · 5H2OMon.
Erionite SubgroupM2[Al4Si14O36] · 15H2O
FabrièsiteNa3Al3Si3O12 · 2H2OOrth. mm2 : Pmm2
Faujasite SubgroupM3.5[Al7Si17O48] · 32H2O
Ferrierite SubgroupName used for unanalysed specimens that could be either ferrierite-K, ferrierite-Mg, ...
FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/c
Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
Garronite Subgroup
GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
Gismondine SubgroupZeolite Group.
Gmelinite SubgroupIn 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth. mmm(2/m2/m2/m) : Pnma
GoosecreekiteCa[Al2Si6O16] · 5H2OMon. 2 : P21
GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm(2/m2/m2/m) : Cmca
Heulandite Subgroup(Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O
HsianghualiteCa3Li2(Be3Si3O12)F2Iso. 23 : I213
KalborsiteK6Al4BSi6O20(OH)4ClTet. 42m : P421c
KirchhoffiteCs(BSi2O6)Tet. 4/mmm(4/m2/m2/m) : I41/acd
LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
LeuciteK(AlSi2O6)Tet. 4/m : I41/a
LimousiniteBaCa[Be4P4O16] · 6H2OMon. 2/m : P21/c
LithositeK6Al4Si8O25 · 2H2OMon.
Loomisite Ba[Be2P2O8] · H2OMon. m
LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
MaricopaitePb7Ca2(Si,Al)48O100 · 32H2OOrth.
MartinandresiteBa2(Al4Si12O32) · 10H2OOrth. mmm(2/m2/m2/m) : Pmmn
Mazzite SubgroupZeolite Group.
MeieriteBa44Si66Al30O192Cl25(OH)33Iso. m3m(4/m32/m) : Im3m
MerlinoiteK5Ca2(Si23Al9)O64 · 24H2OOrth. mmm(2/m2/m2/m) : Immm
Montesommaite(K,Na)9Al9Si23O64 · 10H2OOrth. mm2 : Fdd2
Mordenite(Na2,Ca,K2)4(Al8Si40)O96 · 28H2OOrth.
MountainiteKNa2Ca2[Si8O19(OH)] · 6H2OMon. 2/m : P2/b
NabesiteNa2BeSi4O10 · 4H2OOrth. 222 : P212121
Natrolite SubgroupA subgroup of the Zeolite Group.
OffretiteKCaMg(Si13Al5)O36 · 15H2OHex. 6m2 : P6m2
PahasapaiteLi8(Ca,Li,K)10.5Be24(PO4)24 · 38H2OIso. 23 : I23
ParthéiteCa2(Si4Al4) O15 (OH)2 · 4H2OMon. 2/m : B2/b
Paulingite SubgroupPaulingite was originally described in 1960.
PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex. 6/mmm(6/m2/m2/m) : P6/mmm
Phillipsite Subgroup(Ca0.5,K,Na,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O
Pollucite(Cs,Na)2(Al2Si4O12) · 2H2OIso. m3m(4/m32/m) : Ia3d
RoggianiteCa2Be(OH)2Al2Si4O13 · 2.5H2OTet. 4/mmm(4/m2/m2/m) : I4/mcm
RongibbsitePb2(Si4Al)O11(OH) Mon. 2/m : B2/m
Stilbite SubgroupM6-7[Al8-9Si27-28O72] · nH2O
Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
Thomsonite SubgroupThe large majority of "thomsonite" is thomsonite-Ca.
ThornasiteNa12Th4+3(Si8O19)4 · 18H2OTrig. 3m : R3m
Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm(4/m2/m2/m) : P4/mmm
TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m(4/m32/m) : Fm3m
'UM1996-38-SiO:AlCaHNa'Na-Ca-Al-Si-O-H
'UM1999-33-SiO:AlHKNa'K7Na5Al12Si20O64 · 24H2O
'UM2002-40-SiO:AlCaHKMgNa'(Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2OTet. 422 : P4122
'Unnamed (Ca analogue of Merlinoite)'(Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ?
WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m : B2/b
WeinebeneiteCaBe3(PO4)2(OH)2 · 4H2OMon. m : Bb
Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex. 6m2 : P62m
Wilancookite(Ba5Li2◻)Ba6Be24P24O96 · 26H2OIso. 23 : I23
WillhendersoniteKCa[Al3Si3O12] · 5H2OTric. 1 : P1
YugawaraliteCaAl2Si6O16 · 4H2OMon. m : Pb

Related Minerals - Strunz-mindat GroupingHide

9.GF.05Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
9.GF.10GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm(2/m2/m2/m) : Cmca
9.GF.15LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
9.GF.20GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
9.GF.25FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/c
9.GF.25ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2OMon. 2/m : P21/c
9.GF.30Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm(4/m2/m2/m) : P4/mmm
9.GF.40TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m(4/m32/m) : Fm3m
9.GF.55DirenzoiteNaK6MgCa2(Al13Si47O120) · 36H2OOrth. mmm(2/m2/m2/m) : Pmmn
9.GF.60MeieriteBa44Si66Al30O192Cl25(OH)33Iso. m3m(4/m32/m) : Im3m
9.GF.65RongibbsitePb2(Si4Al)O11(OH) Mon. 2/m : B2/m

Fluorescence of MutinaiteHide

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MutinaiteHide

References for MutinaiteHide

Localities for MutinaiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Antarctica (TL)
 
  • East Antarctica
    • Victoria Land
- (1998) +1 other reference
 
and/or  
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