该文研究了非离子表面活性剂CnH2n+1(CH2CH2O)mOH与过渡金属[Ni, Co, Cd, Zn]水合物形成的液晶相行为。水分子的协调作用诱导产生了六角形和/或立方结构的液晶相。NiII和CoII复合物在高浓度下经历再结晶和相分离，而ZnII和CdII复合物在室温下形成立方相，金属/表面活性剂摩尔比超过3.2/1。
摘要：
Coordinated water molecules induce the aggregation and self-assembly of the lyotropic liquid crystalline phase formed from non-ionic surfactants CnH2n+1(CH2CH2O)mOH and transition metal aqua complexes ([Ni(H2O)6](NO3)2, [Co(H2O)6](NO3)2, [Cd(H2O)4](NO3)2, and [Co(H2O)6]Cl2) into hexagonal (see schematic representation) and/or cubic structures. While the NiII and CoII complexes undergo recrystallization and phase separation at high complex concentrations, the ZnII and CdII complexes form cubic phases above metal/surfactant molar ratios of 3.2/1 at room temperature.
展开
扫一扫
被折叠的 条评论
为什么被折叠?
到【灌水乐园】发言
