本文介绍了一种用于通过光电设备如光电二极管和图像传感器检测化学物质的无校准相位读出电路。该系统凭借其高灵敏度、高精度、低噪声、简洁电路设计（适用于芯片集成）、良好线性、相位信号检测能力及输入信号独立性等特点，特别适合集成到单芯片系统中，尤其适用于便携式信号检测。实验结果显示，即使微小的相位变化也能准确捕捉，且已成功应用于甲基蓝浓度测量，分辨率可达44皮摩尔。
摘要：
In this paper, we present an uncalibrated phase read-out circuit for the detection of chemical substances through optoelectronic devices such as photodiodes and image sensors. The system, based on an automatic analogue circuit operating a phase-to-voltage conversion, shows the following main characteristics: high sensitivity and resolution, high accuracy and precision, low noise, reduced circuitry complexity (minimum required silicon area for the integration on chip), good linearity, capability of phase sign detection, independence from input signal amplitudes and waveforms, setting and zeroing of the output voltage offset and autocalibration. For these reasons, since several sensor applications need an array management performed by a single chip, the developed read-out analogue circuit can be easily integrated on a single chip together with optoelectronic devices, so it can be considered as a suitable solution for signal detection portable systems. Experimental measurements, conducted through the fabricated prototype PCB and employing a single commercial photodiode as light power sensor, have shown a high circuit sensitivity and resolution, in the three considered phase full-scales equal to ±10°, ±1° and ±0.1°, confirming the very good performances of the proposed system to reveal also very small phase shifts. The complete measurement system has been utilised to detect and quantify variations of the molar concentration of methylene blue diluted in distilled water by employing a suitable optical set-up that allowed to achieve resolutions lower than 44pM.
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