About: Zirconium perchlorate

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Zirconium perchlorate is a molecular substance containing zirconium and perchlorate groups with formula Zr(ClO4)4. Zr(ClO4)4 is a volatile crystalline product. It can be formed by reacting zirconium tetrachloride with dry perchloric acid at liquid nitrogen temperatures. Zr(ClO4)4 sublimes slowly in a vacuum at 70°C showing that the molecule is covalently bound rather than being ionic. The reaction also forms some zirconyl perchlorate (or zirconium oxyperchlorate) ZrO(ClO4)2 as even apparently pure perchloric acid is in equilibrium with dichlorine heptoxide, hydronium ions and perchlorate ions. This side product can be minimised by adding more dichlorine heptoxide or doing the reaction as cold as possible.

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  • Zirconium perchlorate is a molecular substance containing zirconium and perchlorate groups with formula Zr(ClO4)4. Zr(ClO4)4 is a volatile crystalline product. It can be formed by reacting zirconium tetrachloride with dry perchloric acid at liquid nitrogen temperatures. Zr(ClO4)4 sublimes slowly in a vacuum at 70°C showing that the molecule is covalently bound rather than being ionic. The reaction also forms some zirconyl perchlorate (or zirconium oxyperchlorate) ZrO(ClO4)2 as even apparently pure perchloric acid is in equilibrium with dichlorine heptoxide, hydronium ions and perchlorate ions. This side product can be minimised by adding more dichlorine heptoxide or doing the reaction as cold as possible. (en)
  • 高氯酸锆（英語：Zirconium perchlorate）是一种无机化合物，化学式为Zr(ClO4)4，它是挥发性晶体，由四氯化锆和无水高氯酸在液氮温度下反应得到。它在真空中于70°C缓慢升华，这表面该分子是共价型的。 高氯酸锆可以形成复盐，如Cs2Zr(ClO4)6和(NO2)2Zr(ClO4)6。 (zh)
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  • Zirconium perchlorate (en)
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  • Zirconium perchlorate is a molecular substance containing zirconium and perchlorate groups with formula Zr(ClO4)4. Zr(ClO4)4 is a volatile crystalline product. It can be formed by reacting zirconium tetrachloride with dry perchloric acid at liquid nitrogen temperatures. Zr(ClO4)4 sublimes slowly in a vacuum at 70°C showing that the molecule is covalently bound rather than being ionic. The reaction also forms some zirconyl perchlorate (or zirconium oxyperchlorate) ZrO(ClO4)2 as even apparently pure perchloric acid is in equilibrium with dichlorine heptoxide, hydronium ions and perchlorate ions. This side product can be minimised by adding more dichlorine heptoxide or doing the reaction as cold as possible. (en)
  • 高氯酸锆（英語：Zirconium perchlorate）是一种无机化合物，化学式为Zr(ClO4)4，它是挥发性晶体，由四氯化锆和无水高氯酸在液氮温度下反应得到。它在真空中于70°C缓慢升华，这表面该分子是共价型的。 高氯酸锆可以形成复盐，如Cs2Zr(ClO4)6和(NO2)2Zr(ClO4)6。 (zh)
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  • Zirconium perchlorate (en)
  • 高氯酸锆 (zh)
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  • Zirconium perchlorate (en)
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