Working with Oracle and raw types in and out worked like the following for me.
<?php
$conn = DBOpen( DB_DEV_USER );
$sql = "begin p_loader.open_session( hextoraw( :instance_id ), :session_id, :errcode, :errmsg ); end;";
$stmt = oci_parse( $conn, $sql );
$instanceId = DB_INSTANCE_ID;
oci_bind_by_name( $stmt, ":instance_id", $instanceId, 1, SQLT_CHR );
oci_bind_by_name( $stmt, ":session_id", $sessionId, 16, SQLT_BIN );
oci_bind_by_name( $stmt, ":errcode", $errcode, 12, SQLT_INT );
oci_bind_by_name( $stmt, ":errmsg", $errmsg, 4000, SQLT_CHR );
oci_execute( $stmt );
$sessionId = bin2hex( $sessionId ); DBClose( $conn );
?>