PRA RANCANGAN PABRIK SEPARATOR G

DESTILASI 1
Fungsi : Memisahkan antara Nitrogen dan argon

Feed Masuk
Komponen Masuk (kmol) Masuk (kg) Xi BM
Nitrogen 599.90671005 16797.387881465 0.78110 28
Argon 7.1719525219 286.5051593435 0.00930 39.948
Oksigen 160.80138214 5145.6442283394 0.20950 32
Karbondioksida 0.0118294051 0.5204938262 0.00000 44
Total 767.89187411 22230.0577629741 1.0000

Persamaan Antoine : Ln (P) = A − (B / (T + C))

T= -193.8539401 C 79.1460598711 K
Pt= 1 atm 760.00000 mmhg
NO Komponen Xi ANT A ANT B ANT C
4 Nitrogen 0.78110 14.9342 588.72 -6.6
5 Argon 0.00930 15.233 700.51 -5.84
6 Oksigen 0.20950 15.4075 734.55 -6.45
9 Carbon dioxide 0.00000 22.5898 3103.39 -0.16
1.00

RUMUS
ά= Kf
Khk
Kf : Ki tiap komponen feed
Khk : Ki tiap komponen heavy key

LIGHT Key (LK) : N2

(N2)D 90.000% ´ 599.90671
(N2)B 10.0000% ´ 599.90671
TOTAL 100.00%

LOG (N2)D
(N2)B

HEAVY Key (HK) : ARGON

(Ar)D 10.000% ´ 7.17195
(Ar)B 90.000% ´ 7.17195
100.00%
 LOG (Ar)D
(Ar)B

NO komponen Ki αi (Ki/Khk) log αi log id/ib

4 Nitrogen 1.20413 3.13316 0.49598 0.95424
5 Argon 0.38432 1.00000 0.00000 -0.95424
6 Oksigen 0.26442 0.68802 -0.16240
9 Carbon dioxide 0.00000 0.00000 -9.71846

Persamaan VAN WINKLE

LOG α= (log id/ib) + b

dimana : m = (log αi)lk - (log αi)hk

(log id/ib)lk - (log id/ib)hk

= 0.4960 - 0.0000
0.9542 - -0.9542

m= 0.2599

b = (log αi)lk - m (log id/ib)lk

= 0.4960 - 0.2480
b= 0.2480

Persamaan menjadi = Log (id/ib)i = (log αi - b )

m
Maka = log αi - 0.2480
0.2599

Log (CO2)D = -9.7185 - 0.2480

(CO2)B 0.2599

(CO2)D = 4.46922013466567E-39
(CO2)B

(CO2)B = 0.0118
4.46922013466567E-39 + 1.0000

(CO2)D = 0.0118 - 0.0118

Log (O2)D = -0.1624 - 0.2480
(O2)B 0.2599

(O2)D = 0.0264
(O2)B

(O2)B = 160.8014
0.0264 + 1.0000

(O2)D = 160.8014 - 156.6722

Log (N2)D = 0.4960 - 0.2480

(N2)B 0.2599

(N2)D = 9.00000
(N2)B

(N2)B = 599.9067
9.00000 + 1.0000

(N2)D = 599.9067 - 59.9907

Log (Ar)D = 0.0000 - 0.2480

Ar2)B 0.2599

Ar)D = 0.11111
(Ar)B

(Ar)B = 7.1720
0.11111 + 1.0000

(Ar)D = 7.1720 - 6.4548

Kondisi Bottom (Bubble Point)

T= -188.0971 OC 84.9029 OK
P= 1.000000 atm 760.00000 mmHg
 No KOMPONEN BM
kg/jam n (kmol)
5 Nitrogen 28 1679.7388 59.99067
6 Argon 39.948 257.8546 6.4548
7 Oksigen 32 5013.5118 156.6722
10 Carbon dioxide 44 0.5205 0.0118
TOTAL 6951.6257 223.1295

Kondisi Top (Dew Point)

T= -195.2128 OC 77.7872 OK
P= 1.000000 atm 760.00000 mmHg
No KOMPONEN BM kg/jam n (kmol)

5 Nitrogen LD 28 15117.6491 539.9160

6 Argon HD 39.948 28.6505 0.7172
7 Oksigen 32 132.1324 4.1291
10 Carbon dioxide 44 0.0000 0.0000
TOTAL 15278.4320 544.7624

SEHINGGA DIPEROLEH NERACA MASSA KOLOM DESTILASI MULTIKOMPONEN :

MASUK (ALIRAN 9)
No KOMPONEN BM
kmol kg/jam
5 Nitrogen 28 599.9067 16797.3879
6 Argon 39.948 7.1720 286.5052
7 Oksigen 32 160.8014 5145.6442
10 Carbon dioxide 44 0.0118 0.5205

TOTAL
22230.0578
RANCANGAN PABRIK SEPARATOR GAS

Titik Didih (°C)

-196 lk
-186 hk
-183
-78

Ln Pi (mmHg) Pi ki (pi/pt) Yi = Ki x Xi
6.81908 915.14246 1.20413 0.94055 lk
5.67704 292.08269 0.38432 0.00357 hk
5.30310 200.95900 0.26442 0.05540
-16.70055 0.00000 0.00000 0.00000
0.99952

3.13316

kmol = 539.91604 kmol 15117.649093319

kmol = 59.99067 kmol 1679.7387881465
16797.387881465

(N2)D : 0.95424
(N2)B

kmol = 7.172E-01 kmol 28.65052

kmol = 6.455E+00 kmol 257.85464
286.50516
(Ar)D : -0.95424
(Ar)B

id/ib
2.59670 LK
0.38510 HK

= -38.3498

= 0.0118 kmol = 0.5205 kg

= 0 kmol = 0.0000 kg
Total 0.5205 kg
= -1.5791

= 156.6722 kmol = 5013.5118 kg

= 4.1291 kmol = 132.1324 Kg

Total 5145.6442 kg

= 0.9542

= 59.9907 kmol = 1679.7388 kg

= 539.9160 kmol = 15117.6491 kg

Total 16797.3879 kg

= -0.9542

= 6.4548 kmol = 257.8546 kg

= 0.7172 kmol = 28.6505 kg

Total 286.5052 kg
 Xi ANT A ANT B ANT C Ln Pi (mmHg)
2.689E-01 14.9342 588.72 -6.6 7.4157063519
2.893E-02 15.233 700.51 -5.84 6.3728414347
7.022E-01 15.4075 734.55 -6.45 6.0445596751
5.302E-05 22.5898 3103.39 -0.16 -14.0314308046
1

2.83733

YD ANT A ANT B ANT C Ln Pi (mmHg)

0.9911 14.9342 588.72 -6.6 6.664169528

0.0013 15.233 700.51 -5.84 5.496549259
0.0076 15.4075 734.55 -6.45 5.110622775
0.0000 22.5898 3103.39 -0.16 -17.3883457286
1

KOMPONEN :

Keluar
Produk Atas (ALIRAN 10) Produk Bawah (ALIRAN 4)
n (kmol) kg/jam n (kmol) kg/jam
539.9160 15117.6491 59.9907 1679.7388
0.7172 28.6505 6.4548 257.8546
4.1291 132.1324 156.6722 5013.5118
0.0000 0.0000 0.0118 0.5205
544.7624 15278.432030503 223.1295 6951.6257
22230.0578
 -122.313

kg
kg
kg

kg
kg
kg
 Yi = Xi x Ki
Pi Ki (Pi/Pt) alpa id
1661.8826 2.1867 0.5879 2.837334109
585.7198 0.7707 0.0223
421.8120 0.5550 0.3897
0.0000 0.0000 0.0000
0.9999

Pi Ki (Pi/Pt) Xi=YD / Ki
APHA ld
783.8123 1.0313 0.9610 3.214334279
243.8490 0.3209 0.0041
165.7736 0.2181 0.0347
0.0000 0.0000 0.0000
0.9998

3.21433
 Kolom Distilasi 1
Fungsi : Memisahkan gas Nitrogen dan Oksigen
Bahan Konstruksi : Carbon steel (SA-285, Cr C)

T d= -195.2128378733 C 77.7871621267 K
T b= -188.0970808841 C 84.9029191159 K

eratur rata-rata kolom = -191.6549593787 C

Relatif volatilitas

RUMUS
ά= Kf
Khk Efecienci Korelasi O'connell, figure 4-9, hal 12

ά feed = 3.133162258
ά distilat = 3.2143342789
ά bottom = 2.8373341086

ά average TB= 3.01996

ά average TF= 3.17349

ά L,AV =

3.0199570007

αavg = 3.0199570007
µcamp = 0.133 cP
αavg x µcamp = 0.4016542811
Eo = 0.6

XLD XHD XHW XLW W D XHF

0.96099 0.00410 0.02893 0.26886 6951.62573 15278.43203 0.00930

jumlah plate minimam

(Nm)
Nm= 2.919566

Menentukan Refluk Minimum

Komponen αtop αbottom αavg

Nitrogen 234.2058741 26.3702521924 78.587963232
Argon 1 1 1
Oksigen 8.4689145611 17.4799904766 12.1670269941
Carbon dioxide 0 2.52127460757E-12 0

nilai, θ = 11.8258024314
 Komponen αavg Xi, F αavg x Xi, F
Nitrogen 78.587963232 0.7811 61.3850580805
Argon 1 0.0093 0.0093
Oksigen 12.1670269941 0.2095 2.5489921553
Carbon dioxide 0 0 0
Jumlah 91.7549902261 0.9999 63.9433502358

nilai Rm =

Komponen αavg Xi, D αavg x Xi, D

Nitrogen 78.587963232 0.9609939781 75.5225594187
Argon 1 0.0041032019 0.0041032019
Oksigen 12.1670269941 0.034749666 0.422800124
Carbon dioxide 0 0 0
Jumlah 91.7549902261 0.999846846 75.9494627445

= Rm + 1

Rm = 1.3699060845

R operasi berkisar antara 1,2 - 1,5 Rm

diambil R operasi = 1,5 Rm
R operasi = 2.0548591268
1-q

Penentuan jumlah Stage ideal

0.672652663

0.5780423509

0.6

N= 4.8659436185

Nactual = N/Eo
8.1099060308

Menentukan letak plate umpan =

= -774.3513424178

= 0

Ne = 0 Ns
Ne + Ns = N
Ne + Ns = 4.8659436185
0 Ns + Ns = 4.8659436185
Ns = 4.8659436185
'connell, figure 4-9, hal 126.backhurst

XLF
0.78110

Komponen α distilate αbottom

Nitrogen 0.9609939781 0.5879135638
Argon 0.0041032019 0.0222945749
Oksigen 0.034749666 0.3897089577
Carbon dioxide 0 5.62107457E-14
αavg x Xi, F/(αavg - θ) 0.8
0.9194588273 0.8
-0.0008590587 63.9433502358 73.403992 + 0.5 0
7.470130916 -9.4606419451 -0.8
0 11.8258024314
8.3887306846

-18
-95.3074
αavg x Xi, D/(αavg - θ)
1.131218021
-0.0003790206
1.2390670841
0
2.3699060845

-0.5 = -0.5

0= (aavh*xf)-aavg
hal 173, figure 9-9. backhurst
(coulson vol. 6 hal.566)