Input
Sp. Time = Senyawa
REAKTORFixed Bed 1 Oksigen
310 , in 2 Nitrogen
340 C, out 3 C. Dioksida
3 atm 4 Amoniak
r1= 0.78 5 N-Heptana
r2= 1.35 6 Air (H2O)
r3= 5.42 7 Toluene
8 Benzonitrile
Konversi= 0.99 Total
Yield = 0.98
Basis : 1 mol
Reaksi 1
C7H8 + NH3 + 3/2 O2 --> C7H5N + 3 H2O
FF 1.00 1.00 12.00 - -
reaksi 0.85 0.85 1.28 0.85 2.55
sisa 0.1500 0.1500 10.7250 0.8500 2.5500
Reaksi 2
C7H8 + 9 O2 --> 7 CO2 + 4 H2O
mula 0.1500 10.7250 - -
reaksi 0.1485 1.3365 1.0395 0.5940
sisa 0.0015 9.3885 1.0395 0.5940
Reaksi 3
2 NH3 + 3/2 O2 --> N2 + 3 H2O
mula 0.15000 9.38850 - -
reaksi 0.14925 0.11194 0.07463 0.22388
sisa 0.00075 9.27656 0.07463 0.22388
0.0177 output
kgmol BM kg Senyawa kgmol BM
12.0000 31.999 383.9880 Oksigen 9.2766 31.999
45.1429 28.013 1264.5869 Nitrogen 45.2175 28.013
- 44.0135 C. Dioksida 1.0395 44.0135
1.0000 17.031 17.0310 Amoniak 0.0008 17.031
- 100.25 N-Heptana - 100.25
- 18.015 Air (H2O) 3.3679 18.015
1.0000 92.141 92.1410 Toluene 0.0015 92.141
- 103.124 Benzonitrile 0.8500 103.124
1757.75 Total
mol O2= 12 P total = 3.00000 atm
mol N2= 45.14285714 2280 mmHg
kon benzonitril= 0.85
data antoine VP
4 Vapor Pressure, ; log10 P = A + B/
No
1 206n
kemurnian toluena= 0.99 2 182n
3 60n
4 171n
5 747
6 127n
7 680
kemurnian ammonia= 0.995 8 655
untuk menentukan T in dan T out condensor
komp kmol/jam zi Pio (atm) (TD)
condensable
1 n-heptane
2 Air (H2O) 3.3678750 0.7981929 0.0000270
3 Toluene 0.0015000 0.0003555 0.0000753
4 Benzonitrile 0.8500000 0.2014516 0.0000004
> 4.2194 1.000000
non condensable
Oksigen 9.2766
Nitrogen 45.2175
CO2 1.0395
Amoniak 0.0008
> 55.5343
TOTAL 59.7537
P total 3.0000 atm trial
P condensable 0.2118 atm Tdew
P noncond. 2.7882 atm
komponen
n-heptana
Air (H2O)
Toluene
Benzonitrile
CONDENSOR
kg zi Pi0 mmHg
296.8407 0.1688755152
1266.6773 0.7206247973
45.7520 0.0260287675
0.0128 7.266823597913E-06
0
60.6723 0.0345170313
0.1382 7.862983889792E-05
87.6554 0.049867992
1757.75 1
por Pressure, ; log10 P = A + B/T + C log10 T + D.T + E.T2 ; (P – mmHg, T – K)
Komponen A B C D E Tmin
Oksigen 20.670 -5.27E+02 -6.71E+00 1.29E-02 -9.88E-13 54.35
Nitrogen 23.857 -4.77E+02 -8.67E+00 2.01E-02 -2.41E-11 63.15
CO2 35.019 -1.51E+03 -1.13E+01 9.34E-03 7.76E-10 216.58
Ammonia 37.158 -2.03E+03 -1.16E+01 7.46E-03 -9.58E-12 195.41
n-heptana 65.026 -3.82E+03 -2.17E+01 1.04E-02 1.02E-14 182.56
Air (H2O) 29.861 -3.15E+03 -7.30E+00 2.42E-09 1.81E-06 273.16
Toluene 34.078 -3.04E+03 -9.1635 1.03E-11 2.70E-06 178.18
Benzonitrile 5.606 -2.86E+03 2.45E+00 -8.46E-03 3.98E-06 260.4
K xi Pio (atm) (TB) K yi
0.0001276 0.0001598
0.0003554 0.9998198
0.0000017 0.0000083
1.000
N-HEP
B/T -1.77E+01 p= 9.97E-01
CLOG T -5.06E+01
d*t 2.25E+00
e*t2 4.771002E-10
-1.34E-03
trial
-56.94 C Tbubble C
216.21 K 357.79 K
A B/T ClogT D.T E.T2 P
65.026 -1.77E+01 -5.06E+01 2.25E+00 4.771002E-10 -1.020 0.095
29.861 -1.46E+01 -1.71E+01 5.24E-07 0.084565372 -1.687 0.020536
34.078 -1.41E+01 -2.14E+01 2.22E-09 0.126380588 -1.242 0.057225
5.606 -1.32E+01 5.71E+00 -1.83E+00 0.186006421 -3.571 0.000268
Tmax
154.58
126.1
304.19
405.65
540.26
647.13
591.79
699.35
760
0.000125541
2.702141E-05
7.529562E-05
3.531705E-07
