Safety Matches

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Identification
Product form : Mixture
Product name : Safety Matches
Product code : 21010,21050,21060,21065,21080,21220 ( BRANDED NDuR )
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Matches for use in outdoor conditions.
1.3. Details of the supplier of the safety data sheet
Proforce Equipment, Inc.
3230 Executive Way
Miramar, FL 33025
T 305-436-7984
1.4. Emergency telephone number
Emergency number : Call CHEMTREC Day or Night Within USA and Canada: 1-800-424-9300 CCN725304 or
+1 703-527-3887 (collect calls accepted)

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
Classification (GHS-US)
Ox. Sol. 1 H271 - May cause fire or explosion; strong oxidiser
Acute Tox. 3 (Oral) H301 - Toxic if swallowed
Full text of H-phrases: see section 16

2.2. Label elements

GHS-US labeling
Hazard pictograms (GHS-US) :

GHS03 GHS06
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H271 - May cause fire or explosion; strong oxidizer
H301 - Toxic if swallowed
Precautionary statements (GHS-US) : P210 - Keep away from open flames. - No smoking
P220 - Keep/Store away from clothing, combustible materials
P221 - Take any precaution to avoid mixing with combustible materials
P264 - Wash hands thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P280 - Wear eye protection
P283 - Wear fire/flame resistant/retardant clothing
P301+P310 - If swallowed: Immediately call a POISON CENTER
P306+P360 - If on clothing: Rinse immediately contaminated clothing and skin with plenty of
water before removing clothes
P321 - Specific treatment (see Carefully comply with the instructions for use on this label)
P330 - Rinse mouth
P370+P378 - In case of fire: Use sand, foam, extinguishing powder, carbon dioxide (CO2) to
extinguish
P371+P380+P375 - In case of major fire and large quantities: Evacuate area. Fight fire
remotely due to the risk of explosion
P405 - Store locked up
P501 - Dispose of contents/container to an authorized waste collection point
P102 - Keep out of reach of children

2.3. Other hazards

No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
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Safety Matches
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification (GHS-US)
Potassium chlorate (CAS No) 3811-04-9 30 - 40 Ox. Sol. 1, H271
Acute Tox. 4 (Oral), H302
Acute Tox. 4 (Inhalation:dust,mist),
H332
Aquatic Chronic 2, H411
Phosphorus elemental (CAS No) 7723-14-0 3-5 Acute Tox. 1 (Oral), H300
Acute Tox. 2 (Dermal), H310
Acute Tox. 4 (Inhalation:dust,mist),
H332
Potassium dichromate (CAS No) 7778-50-9 < 0.1 Ox. Sol. 2, H272
Acute Tox. 2 (Oral), H300
Acute Tox. 4 (Dermal), H312
Acute Tox. 2 (Inhalation:dust,mist),
H330
Skin Corr. 1B, H314
Resp. Sens. 1, H334
Skin Sens. 1, H317
Muta. 1B, H340
Carc. 1A, H350
STOT RE 1, H372
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : IF ON CLOTHING: Remove contaminated clothing. Rinse immediately contaminated clothing
and skin with plenty of water before removing clothes.
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Immediately call a
poison center or doctor/physician. Specific treatment (see Guidance - Health on this label).
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Irritating to respiratory system.
Symptoms/injuries after skin contact : Slight irritation.
Symptoms/injuries after eye contact : Mild eye irritation.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : May cause fire or explosion; strong oxidizer.
Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of
burns and injuries.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment. In case of major fire and
large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

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Safety Matches
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : No open flames. No smoking.

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away
from other materials. Notify authorities if product enters sewers or public waters.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : Hazardous waste due to potential risk of explosion.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. Take any precaution to avoid mixing with combustible materials. Do not handle until
all safety precautions have been read and understood. Do not breathe smoke.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : open flames.
Keep container closed when not in use. Keep in fireproof place. Keep out of reach of children.
Store in a dry place.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. Combustible materials.
Maximum storage period : Physically and chemically stable for at least 4 years when stored in the original unopened sales
container at ambient temperatures.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
No additional information available

8.2. Exposure controls

Personal protective equipment : Avoid all unnecessary exposure. Wear fire/flame resistant/retardant clothing.

Hand protection : Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : Matches, safety.
Color : Brown
Odor : characteristic
Odor threshold : No data available
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Safety Matches
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : Does not flash
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : May intensify fire; oxidizer. May cause fire or explosion; strong oxidizer.
Vapor pressure : No data available
Relative density : No data available
Relative vapor density at 20 °C : No data available
Solubility : Water: Solubility in water of component(s) of the mixture :
• Potassium dichromate: 115 - 130 g/l (at 20 °C) • Phosphorus elemental: 4.1 mg/l (at 25 °C)
Log Pow : No data available
Auto-ignition temperature : > 100 °C
Decomposition temperature : No data available
Viscosity : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
No additional information available
10.2. Chemical stability
May cause fire or explosion; strong oxidizer.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Overheating. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Oral: Toxic if swallowed. Dermal: Not classified. Inhalation:dust,mist: Not classified.
Safety Matches
ATE US (oral) 59.825 mg/kg body weight
Potassium chlorate (3811-04-9)
LD50 oral rat 1870 mg/kg
LD50 dermal rabbit > 2000 mg/kg
ATE US (oral) 1870.000 mg/kg body weight
ATE US (dust, mist) 1.500 mg/l/4h
Potassium dichromate (7778-50-9)
LD50 oral rat 48 mg/kg
LD50 dermal rabbit 1150 mg/kg

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Safety Matches
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Potassium dichromate (7778-50-9)

ATE US (oral) 48.000 mg/kg body weight
ATE US (dermal) 1150.000 mg/kg body weight
ATE US (dust, mist) 0.050 mg/l/4h
Phosphorus elemental (7723-14-0)
LD50 oral rat 3030 µg/kg
LD50 dermal rat 100 mg/kg
LC50 inhalation rat (mg/l) 4.3 mg/l (Exposure time: 1 h)
ATE US (oral) 3.030 mg/kg body weight
ATE US (dermal) 100.000 mg/kg body weight
ATE US (vapors) 4.300 mg/l/4h
ATE US (dust, mist) 4.300 mg/l/4h
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Potassium dichromate (7778-50-9)

IARC group 1 - Carcinogenic to humans
In OSHA Hazard Communication Carcinogen Yes
list
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated : Not classified

exposure)

Aspiration hazard : Not classified

Potential Adverse human health effects and : Toxic if swallowed.

symptoms
Symptoms/injuries after inhalation : Irritating to respiratory system.
Symptoms/injuries after skin contact : Slight irritation.
Symptoms/injuries after eye contact : Mild eye irritation.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Harmful to aquatic life.
Ecology - water : Un-burned composition is non-selectively toxic to plants.

Potassium chlorate (3811-04-9)

LC50 fish 1 13500 mg/l (Exposure time: 96 h - Species: Pimephales promelas)
LC50 fish 2 1750 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
Potassium dichromate (7778-50-9)
LC50 fish 1 > 139 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [static])
LC50 fish 2 113.6 - 155.7 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [flow-through])
Phosphorus elemental (7723-14-0)
LC50 fish 1 0.0017 - 0.0035 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [flow-through])
EC50 Daphnia 1 0.03 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC50 fish 2 0.001 - 0.004 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])
EC50 Daphnia 2 0.025 - 0.037 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])

12.2. Persistence and degradability

Safety Matches
Persistence and degradability The product is not biodegradable.

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Safety Matches
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

12.3. Bioaccumulative potential

Safety Matches
Bioaccumulative potential Not established.

Phosphorus elemental (7723-14-0)

BCF fish 1 < 200

12.4. Mobility in soil

No additional information available

12.5. Other adverse effects

Effect on the global warming : No known ecological damage caused by this product.

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Additional information : Hazardous waste due to potential risk of explosion.
Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity.

SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1944 Matches, safety (book, card or strike on box), 4.1, III

UN-No.(DOT) : UN1944
Proper Shipping Name (DOT) : Matches, safety
(book, card or strike on box)
Transport hazard class(es) (DOT) : 4.1 - Class 4.1 - Flammable Solid 49 CFR 173.124
Hazard labels (DOT) : 4.1 - Flammable solid

Packing group (DOT) : III - Minor Danger

DOT Packaging Non Bulk (49 CFR 173.xxx) : 186
DOT Packaging Bulk (49 CFR 173.xxx) : None
DOT Packaging Exceptions (49 CFR 173.xxx) : 186
DOT Quantity Limitations Passenger aircraft/rail : 25 kg
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 100 kg
CFR 175.75)
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.
Other information : No supplementary information available.

TDG
No additional information available

Transport by sea
UN-No. (IMDG) : 1944
Proper Shipping Name (IMDG) : MATCHES, SAFETY
Class (IMDG) : 4.1 - Flammable solids, self-reactive substance and solid desensitized explosives
Packing group (IMDG) : III - substances presenting low danger

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Safety Matches
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Air transport
UN-No. (IATA) : 1944
Proper Shipping Name (IATA) : Matches, safety
Class (IATA) : 4.1 - Flammable solids
Packing group (IATA) : III - Minor Danger

SECTION 15: Regulatory information

15.1. US Federal regulations
Potassium chlorate (3811-04-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Potassium dichromate (7778-50-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
EPA TSCA Regulatory Flag R - R - indicates a substance that is the subject of a Section 6 risk management rule under
TSCA.
Phosphorus elemental (7723-14-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on the United States SARA Section 302
Subject to reporting requirements of United States SARA Section 313
SARA Section 302 Threshold Planning 100 (This material is a reactive solid. The TPQ does not default to 10000 pounds for non-
Quantity (TPQ) powder, non-molten, non-solution form)
SARA Section 313 - Emission Reporting 1.0 % (yellow or white)

15.2. International regulations

CANADA
Potassium chlorate (3811-04-9)
Listed on the Canadian DSL (Domestic Sustances List)
WHMIS Classification Class C - Oxidizing Material
Potassium dichromate (7778-50-9)
Listed on the Canadian DSL (Domestic Sustances List)
WHMIS Classification Class C - Oxidizing Material
Class D Division 1 Subdivision A - Very toxic material causing immediate and serious toxic
effects
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Phosphorus elemental (7723-14-0)
Listed on the Canadian DSL (Domestic Sustances List)
WHMIS Classification Class B Division 4 - Flammable Solid
Class D Division 1 Subdivision A - Very toxic material causing immediate and serious toxic
effects
Class E - Corrosive Material

EU-Regulations
No additional information available

National regulations
Potassium chlorate (3811-04-9)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Japanese Poisonous and Deleterious Substances Control Law
Listed on INSQ (Mexican national Inventory of Chemical Substances)
Listed on Turkish inventory of chemical

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Safety Matches
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Potassium dichromate (7778-50-9)

Listed on IARC (International Agency for Research on Cancer)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Japanese Poisonous and Deleterious Substances Control Law
Japanese Pollutant Release and Transfer Register Law (PRTR Law)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican national Inventory of Chemical Substances)
Phosphorus elemental (7723-14-0)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican national Inventory of Chemical Substances)
Listed on Turkish inventory of chemical

15.3. US State regulations

Potassium chlorate (3811-04-9)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List

Potassium dichromate (7778-50-9)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List

Phosphorus elemental (7723-14-0)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List

SECTION 16: Other information

Other information : None.

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Safety Matches
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Full text of H-phrases:

------ Acute Tox. 1 (Oral) Acute toxicity (oral) Category 1
------ Acute Tox. 2 (Dermal) Acute toxicity (dermal) Category 2
------ Acute Tox. 2 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 2
------ Acute Tox. 2 (Oral) Acute toxicity (oral) Category 2
------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3
------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4
------ Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4
------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1
------ Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1
------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2
------ Carc. 1A Carcinogenicity Category 1A
------ Muta. 1B Germ cell mutagenicity Category 1B
------ Ox. Sol. 1 Oxidizing solids Category 1
------ Ox. Sol. 2 Oxidizing solids Category 2
------ Resp. Sens. 1 Respiratory sensitisation Category 1
------ Skin Corr. 1B Skin corrosion/irritation Category 1B
------ Skin Sens. 1 Skin sensitization Category 1
------ STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
------ H271 May cause fire or explosion; strong oxidizer
------ H272 May intensify fire; oxidizer
------ H300 Fatal if swallowed
------ H301 Toxic if swallowed
------ H302 Harmful if swallowed
------ H310 Fatal in contact with skin
------ H312 Harmful in contact with skin
------ H314 Causes severe skin burns and eye damage
------ H317 May cause an allergic skin reaction
------ H330 Fatal if inhaled
------ H332 Harmful if inhaled
------ H334 May cause allergy or asthma symptoms or breathing difficulties if
inhaled
------ H340 May cause genetic defects
------ H350 May cause cancer
------ H372 Causes damage to organs through prolonged or repeated exposure
------ H400 Very toxic to aquatic life
------ H410 Very toxic to aquatic life with long lasting effects
------ H411 Toxic to aquatic life with long lasting effects

SDS US (GHS HazCom 2012)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product

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