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Blended Cement MSDS August 2009

The document provides a material safety data sheet for a blended cement product, listing its ingredients, potential health effects like skin and eye irritation, and first aid measures for exposure. It identifies the product as a light gray powder containing calcium silicates, gypsum, and trace elements which can cause irritation upon contact with eyes, skin, or inhalation and may require medical attention.

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0% found this document useful (0 votes)
78 views6 pages

Blended Cement MSDS August 2009

The document provides a material safety data sheet for a blended cement product, listing its ingredients, potential health effects like skin and eye irritation, and first aid measures for exposure. It identifies the product as a light gray powder containing calcium silicates, gypsum, and trace elements which can cause irritation upon contact with eyes, skin, or inhalation and may require medical attention.

Uploaded by

Manuel Cardoso
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 6

MATERIAL SAFETY DATA SHEET

Current MSDS may always be viewed at www.inlandcanada.com


SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: InterCem GUb-30F, InterCem HSb-30F, Portland cement clinker/fly ash intergrind

CAS #:

Product Use: Preparation of concrete and mortar.

MSDS Information: This MSDS was produced in August 2009, and replaces any previous versions. This MSDS
covers portland cement clinker/fly ash intergrind at a 70/30 nominal ratio. Individual composition
of constituents will vary within the range shown in Section 2.

Product Code: Not Applicable.

Chemical Family: Calcium compounds. Calcium silicate compounds and other calcium compounds
containing iron and aluminum and silicon make up the majority of this product.

Chemical Name And Synonyms: None.

Formula: This product consists of finely ground portland cement clinker, fly ash
(SiO2:Al2O3:CaO:Fe2O3:Na2O:K2O:MgO) and gypsum.

Supplier/Manufacturer: Lehigh Cement


12640 Inland Way
Edmonton, Alberta, Canada, T5V 1K2 Telephone 780-420-2500

Emergency Contact Information: Lehigh Cement


12640 Inland Way
Edmonton, Alberta, Canada, T5V 1K2 Telephone 780-420-2541

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS

Portland Cement Clinker/Fly Ash ACGIH TLV-TWA 10 mg total dust/m3


Exposure Limits: OSHA PEL-TWA 15 mg total dust/m3
OSHA PEL-TWA 5 mg respirable dust/m3

Portland Cement Clinker/Fly Ash Ingredients & Their Exposure Limits:

Ingredient CAS# % By Weight ACGIH TLV-TWA OSHA PEL-TWA

Calcium Silicates various 30-45% 10 mg total dust/m3 15 mg total dust/m3


5 mg respirable dust/m3

Gypsum 7778-18-9 4-5% 10 mg total dust/m3 15 mg total dust/m3


5 mg respirable dust/m3

Amorphous Silica 6885-54-9 15-18% 10 mg total dust/m3 6 mg total dust/m3

Crystalline Silica 14808-60-7 0.1-2.5% 0.10 mg respirable quartz/m3 (10 mg respirable dust/m3)/(percent silica+2)

NIOSH REL (8-hour TWA) = 0.05 mg respirable quartz dust/m3

Aluminium Oxide 1344-28-1 5-8% 10 mg total dust/m3 15 mg total dust/m3


5 mg respirable dust/m

Magnesium Oxide 1309-48-4 0.5-3% 10 mg total dust/m3 10 mg total dust/m3

Calcium Oxide 1305-78-8 2-4% 2 mg total dust/m3 5 mg total dust/m3

Trace Elements:

Portland cement clinker and flyash are made from materials mined from the earth and are processed using energy provided by fuels. Trace
amounts of chemicals, some of which may be potentially harmful, might be detected during chemical analysis. For example, in addition to
the ingredients listed above, portland cement clinker/fly ash may contain potassium and sodium sulfate compounds, chromium
compounds (including up to 0.003% hexavalent chromium) and nickel compounds.

August 2009 BLENDED CEMENT Page 1 of 6


MATERIAL SAFETY DATA SHEET
Current MSDS may always be viewed at www.inlandcanada.com
SECTION 3 - HAZARDS IDENTIFICATION

Emergency Overview:

Portland cement/flyash intergrind is a light gray powder that poses little immediate hazard. A single short term exposure to the dry
powder is not likely to cause serious harm. However, exposure of sufficient duration to wet portland cement can cause serious,
potentially irreversible tissue (skin or eye) destruction in the form of chemical (caustic) burns, including third degree burns. The same
type of tissue destruction can occur if wet or moist areas of the body are exposed for sufficient duration to dry portland cement.

Potential Health Effects:

• Relevant routes of exposure are:

Eye contact, skin contact, inhalation, and ingestion.

Effects Resulting From EYE CONTACT:

Exposure to airborne dust may cause immediate or delayed irritation or inflammation.

Eye contact by larger amounts of dry powder or splashes of wet portland cement/flyash intergrind may cause effects ranging from
moderate eye irritation to chemical burns and blindness. Such exposures require immediate first aid (see Section 4) and medical
attention to prevent significant damage to the eye.

Effects Resulting From SKIN CONTACT:

Discomfort or pain cannot be relied upon to alert a person to a hazardous skin exposure. Consequently, the only effective means
of avoiding skin injury or illness involves minimizing skin contact, particularly contact with wet cement. Exposed persons may not
feel discomfort until hours after the exposure has ended and significant injury has occurred.

Exposure to dry portland cement/flyash intergrind may cause drying of the skin with consequent mild irritation or more significant
effects attributable to aggravation of other conditions. Dry portland cement/flyash intergrind contacting wet skin or exposure to
moist or wet portland cement/flyash intergrind may cause more severe skin effects including thickening, cracking, or fissuring of
the skin. Prolonged exposure can cause severe skin damage in the form of (caustic) chemical burns.

Some individuals may exhibit an allergic response upon exposure to portland cement/flyash intergrind, possibly due to trace
amounts of chromium. The response may appear in a variety of forms ranging from a mild rash to severe skin ulcers. Persons
already sensitized may react to their first contact with the product. Other persons may first experience this effect after years of
contact with portland cement/flyash intergrind products.

Effects Resulting From INHALATION:

Portland cement/flyash intergrind contains crystalline silica. Prolonged exposure to respirable free crystalline silica may
aggravate other lung conditions. It also may cause delayed lung injury including silicosis, a disabling and potentially fatal lung
disease, and/or other diseases. (Also see “Carcinogenic Potential” below.)

Exposure to portland cement/flyash intergrind may cause irritation to the moist mucous membranes of the nose, throat, and upper
respiratory system. It may also leave unpleasant deposits in the nose.

Effects Resulting From INGESTION:

Although small quantities of dust are not known to be harmful, ill effects are possible if larger quantities are consumed. Portland
cement should not be eaten.

• Carcinogenic Potential:

Portland cement is not listed as a carcinogen by NTP, OSHA, or IARC. It may, however, contain trace amounts of substances
listed as carcinogens by these organizations.

Crystalline silica, a potential trace level contaminant in portland cement/flyash intergrind, is now classified by IARC as a known
human carcinogen (Group 1). NTP has characterized respirable silica as “reasonably anticipated to be [a] carcinogen”.

• Medical Conditions That May Be Aggravated By Inhalation Or Dermal Exposure:

Pre-existing upper respiratory and lung diseases.


Unusual (hyper) sensitivity to hexavalent chromium (chromium+6) salts.

August 2009 BLENDED CEMENT Page 2 of 6


MATERIAL SAFETY DATA SHEET
Current MSDS may always be viewed at www.inlandcanada.com
SECTION 4 - FIRST-AID MEASURES

Eyes:

Immediately flush eyes thoroughly with water. Continue flushing for at least 15 minutes, including under lids, to remove all particles.
Call physician immediately.

Skin:

Wash skin with cool water and pH-neutral soap or a mild detergent intended for use on skin. Seek medical treatment in all cases of
prolonged exposure to wet cement, cement mixtures, liquids from fresh cement products, or prolonged wet skin exposure to dry
cement.

Inhalation Of Airborne Dust:

Remove to fresh air. Seek medical help if coughing and other symptoms do not subside. (“Inhalation” of gross amounts of portland
cement requires immediate medical attention.)

Ingestion:

Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately.

SECTION 5 - FIRE-FIGHTING MEASURES

Flammability: Not Flammable.


Flash Point: Not Applicable.
Lower Explosive Limit: Not Applicable.
Upper Explosive Limit: Not Applicable.
Auto ignition Temperature: Not Applicable.
Sensitivity To Static Discharge: Not Applicable.
Sensitivity To Impact: Not Applicable.
Extinguishing Media: Not Applicable.
Special Fire-Fighting Procedures: None.
Hazardous Combustion Products: Not Applicable.
Unusual Fire And Explosion Hazards: Not Applicable.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Collect dry material using a scoop. Avoid actions that cause dust to become airborne. Avoid inhalation of dust and contact with skin. Wear
appropriate personal protective equipment as described in Section 8.

Scrape up wet material and place in an appropriate container. Allow the material to “dry” before disposal. Do not attempt to wash portland
cement down drains.

Dispose of waste material according to local, provincial, state and federal regulations.

SECTION 7 - HANDLING AND STORAGE

Keep portland cement/flyash intergrind dry until used. Normal temperatures and pressures do not affect the material.

Promptly remove dusty clothing or clothing which is wet with cement fluids and launder before reuse. Wash thoroughly after exposure to
dust or wet cement mixtures or fluids.

August 2009 BLENDED CEMENT Page 3 of 6


MATERIAL SAFETY DATA SHEET
Current MSDS may always be viewed at www.inlandcanada.com
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

Eye Protection:

When engaged in activities where cement dust or wet cement or concrete could contact the eye, wear safety glasses with side shields
or goggles. In extremely dusty environments and unpredictable environments, wear unvented or indirectly vented goggles to avoid eye
irritation or injury. Contact lenses should not be worn when working with portland cement/flyash intergrind or fresh cement products.

Skin Protection:

Prevention is essential to avoiding potentially severe skin injury. Avoid contact with unhardened (wet) portland cement/flyash intergrind
products. If contact occurs, promptly wash affected area with soap and water. Where prolonged exposure to unhardened portland
cement/flyash intergrind products might occur, wear impervious clothing and gloves to eliminate skin contact. Where required, wear
boots that are impervious to water to eliminate foot and ankle exposure.

Do not rely on barrier creams; barrier creams should not be used in place of gloves.

Periodically wash areas contacted by dry portland cement/flyash intergrind or by wet cement or concrete fluids with a pH-neutral soap.
Wash again at the end of work. If irritation occurs, immediately wash the affected area and seek treatment. If clothing becomes
saturated with wet concrete, it should be removed and replaced with clean dry clothing.

Respiratory Protection:

Avoid actions that cause dust to become airborne. Use local or general ventilation to control exposures below applicable exposure
limits.

Use NIOSH/MSHA-approved (under 30 CFR 11) or NIOSH-approved (under 42 CFR 84 after July 10, 1998) respirators in poorly
ventilated areas, if an applicable exposure limit is exceeded, or when dust causes discomfort or irritation.

Ventilation:

Use local exhaust or general dilution ventilation to control exposure within applicable limits.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance: White to gray powder.


Odor: No distinct odor.
Odor Threshold: Not applicable.
Physical State: Solid (powder).
pH (as a solid): Not applicable.
pH (in water) (ASTM D 1293-95): 12 to 13
Solubility In Water: Slightly soluble (0.1 to 1.0 %).
Vapor Pressure: Not applicable.
Vapor Density: Not applicable.
Boiling Point: Not applicable (i.e.,>1000oC).
Freezing Point: Not applicable.
Melting Point: Not applicable.
Specific Gravity (H2O = 1.0): 2.88
Evaporation Rate: Not applicable.
Coeff. Water/Oil Dist.: Not applicable.

SECTION 10 - STABILITY AND REACTIVITY

Stability: Stable
Conditions to avoid: Unintentional contact with water.
Incompatibility: Portland cement reacts with water to produce a caustic solution, pH 12 to pH 13. Wet portland
cement/flyash intergrind is alkaline. As such it is incompatible with acids, ammonium salts and
aluminum metal. Aluminum powder and other alkali and alkaline earth elements will react in wet
mortar or concrete, liberating hydrogen gas. Portland cement dissolves in hydrofluoric acid
producing corrosive silicon tetrafluoride gas. Silicates react with powerful oxidizers such as
fluorine, chlorine, trifluoride and oxygen difluoride.

August 2009 BLENDED CEMENT Page 4 of 6


MATERIAL SAFETY DATA SHEET
Current MSDS may always be viewed at www.inlandcanada.com
SECTION 10 - STABILITY AND REACTIVITY (CONTINUED)

Hazardous Decomposition: Will not spontaneously occur. Adding water results in hydration and produces (caustic)
calcium hydroxide.

Hazardous Polymerization: Will not occur.

SECTION 11 - TOXICOLOGICAL INFORMATION

Effects Of Acute Exposure:

Portland cement and wet portland cement/flyash intergrind mixtures can dry the skin, cause alkali burns and irritate the eyes and upper
respiratory tract. Ingestion can cause irritation of the throat.

Effects Of Chronic Exposure:

Portland cement/flyash intergrind dust can cause inflammation of the tissue lining the interior of the nose and the cornea (white) of the
eye.

SECTION 12 - ECOLOGICAL INFORMATION

Ecotoxicity: No recognized unusual toxicity to plants or animals.


Relevant Physical And Chemical Properties: See Sections 9 and 10.

SECTION 13 - DISPOSAL CONSIDERATIONS

Dispose of waste material according to local, provincial, state and federal regulations. (Since portland cement is stable, uncontaminated
material may be saved for future use.)

Dispose of bags in an approved landfill or incinerator.

SECTION 14 - TRANSPORT INFORMATION

Hazardous materials description/proper shipping name: Portland cement/flyash intergrind is not hazardous under the TDG Act
(Canada) or DOT regulations (USA).
Hazard Class: Not applicable.
Identification Number: Not applicable.
Required Label Text: Not applicable.
Hazardous substances/reportable quantities (RO): Not applicable.

SECTION 15 - REGULATORY INFORMATION

Status under USDOL-OSHA Hazard Communication Rule, 29 CFR 1910.1200:

Portland cement/flyash intergrind is considered a “hazardous chemical” under this regulation, and should be part of any hazard
communication program.

Status under CERCLA/Superfund, 40 CFR 117 and 302:

Not listed.

Hazard Category under SARA (Title III), Sections 311 and 312:

Portland cement/flyash intergrind qualifies as a “hazardous substance” with delayed health effects.

Status under SARA (Title III), Section 313:

Not subject to reporting requirements under Section 313.

August 2009 BLENDED CEMENT Page 5 of 6


MATERIAL SAFETY DATA SHEET
Current MSDS may always be viewed at www.inlandcanada.com
SECTION 15 - REGULATORY INFORMATION (CONTINUED)

Status under TSCA (as of May 1997):

Some substances in portland cement/flyash intergrind are on the TCSA inventory list.

Status under the Federal Hazardous Substances Act:

Portland cement is a “hazardous substance” subject to statutes promulgated under the subject act.

Status under California Proposition 65:

This product contains chemicals (trace metals) known to the State of California to cause cancer, birth defects or other reproductive
harm. California law requires the manufacturer to give the above warning in the absence of definitive testing to prove the defined risks
do not exist.

Status under Canadian Environmental Protection Act:

Not listed.

Status under WHMIS:

Portland cement is considered to be a hazardous material under the Hazardous Products Act as defined by the Controlled Products
Regulations and is therefore subject to the labeling and MSDS requirements of the Workplace Hazardous Materials Information
System (WHMIS).

This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required
by the CPR.

SECTION 16 - OTHER INFORMATION

Prepared By: Lloyd Young


Approved By: Dan Thillman
Approval Date or Revision Date: August 1, 2009
Date of Previous MSDS: May 1, 2006
MSDS Number: Not Applicable

Other Important Information:

Portland cement/flyash intergrind should only be used by knowledgeable persons. A key to using the product safely requires the user
to recognize that portland cement/flyash intergrind chemically reacts with water, and that some of the intermediate products of this
reaction (that is, those present while a portland cement/flyash intergrind product is “setting”) pose a far more severe hazard than does
portland cement/flyash intergrind itself.

While the information provided in this material safety data sheet is believed to provide a useful summary of the hazards of portland
cement/flyash intergrind as it is commonly used, the sheet cannot anticipate and provide all of the information that might be needed in
every situation. Inexperienced product users should obtain proper training before using this product.

In particular, the data furnished in this sheet does not address hazards that may be posed by other materials mixed with portland
cement/flyash intergrind to produce other products. Users should review other relevant material safety data sheets before working with
this portland cement/flyash intergrind or working on other products, for example, portland cement/flyash intergrind concrete.

No representations or warranties with respect to the accuracy or correctness of this information, or of any kind or nature whatsoever
are given, made or intended by Lehigh Cement. No legal responsibility whatsoever is assumed for this information, or for any injuries
or damages, however caused which may result from the use of this information. This information is offered solely for informational
purposes and is subject to your own independent investigation and verification.

August 2009 BLENDED CEMENT Page 6 of 6

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