Preview-9781000854541 A45363271
Preview-9781000854541 A45363271
This book will appeal to chemical, civil, and environmental engineers working on
waste treatment, waste valorization, and pollution control.
Advanced Technologies
for Solid, Liquid, and Gas
Waste Treatment
v
vi Contents
Index���������������������������������������������������������������������������������������������������������������������� 305
Preface
Advanced Technologies for Solid, Liquid, and Gas Waste Treatment has been
prepared to harness significant environmental issues through a comprehensive
up-to-date overview on the recent development of different treatment technol-
ogies. This book is developed not only for practicing environmental and chemical
engineers, but also for civil engineers who are involved in the processes related to
solid, liquid, and gas waste treatment. The book can also be used as a reference
source for undergraduate and postgraduate courses in waste treatments.
This is the first book that is aimed to address the wastes in all three phases,
i.e., solid, liquid, and gas. Statistics released by the BCC Research indicated the
healthy market growth of the treatment technologies in remediating different
wastes. For instance, the global market for scrap tires management and rubber
remediation applications (i.e., solid wastes) will grow from $7.6 billion in 2017
to nearly $9.5 billion by 2022, with a compound annual growth rate (CAGR) of
4.5% for the period of 2017–2022. The global market for wastewater technolo-
gies and air pollution control equipment meanwhile was reported at $64.4 billion
(2018) and $13.3 billion (2015), respectively with a CAGR of at least 5% over the
next 5-year period.
This book contains the chapters that were contributed by well-known scientists/
researchers from different parts of the world and covers many different types of
treatment technologies such as photocatalysis, adsorptive membranes, pyrolysis,
advanced oxidation process, electrocoagulation, and emerging composting methods
for the treatment of agricultural biomass, industrial/domestic solid wastes, waste-
water, and hazardous gas. Other technologies included in this book are related to
artificial intelligence applications, value-added product formation as new energy and
nutrient sources as well as hybrid processes to curb incalcitrant pollutants present in
the environment.
The advances in solid, liquid, and gaseous emission are discussed in breadth and
depth and summarized in 15 chapters. To illustrate waste management through dif-
ferent technologies, individual graphical figures, tables, and diagrams are depicted.
Additional drawings and photographs are included to aid the understanding of the
advanced technologies presented.
To make this book more valuable, discharge from various industries is consid-
ered. These include automotive, agriculture, electronics, food, oil and gas industry,
and pharmaceuticals, just to name a few. These advanced technologies are aimed
not only to reduce negative impacts caused by the wastes on the environment and
humans but also to produce value-added products.
vii
viii Preface
We hope this book will be of great help for practitioners and researchers in the
real-world application – industry.
Editors
Yeek-Chia Ho
Universiti Teknologi PETRONAS, Malaysia
Sudip Chakraborty
University of Calabria, Italy
N. Rajamohan
Sohar University, Oman
Saleh Al Arni
Hail University, Saudi Arabia
Editor biographies
Yeek-Chia Ho (Ph.D.) is Programme Manager for Master in Industrial Environmental
Engineering in Universiti Teknologi PETRONAS. Additionally, she is in the
Leadership Team under the Institute of Self-Sustainable Building (ISB). Also note-
worthy is that she is Secretary in the International Water Association (IWA) for
Design, Operation and Maintenance of Drinking Water Treatment Plants. Her cur-
rent research interest is closely related to environmental engineering, specifically,
Water-Food-Energy nexus. YC is involved in research projects which includes renew-
able energy, microalgae harvesting, water and wastewater treatments, and life cycle
assessment. She has published several works in invited review papers, invited book
chapters, international conference papers and international indexed journal papers.
Also, YC has won a few national awards in publications and international awards for
her research works; two patents and two trademarks have been filed so far. Lastly,
she has been selected to be one of the invited professionals in the Leaders Innovation
Fellowships Programme by the Royal Academy of Engineering, UK.
Woei Jye Lau is currently an associate professor at Faculty of Chemical and Energy
Engineering, Universiti Teknologi Malaysia (UTM). He obtained his Bachelor of
Engineering in Chemical-Gas Engineering and Doctor of Philosophy (Ph.D.) in
Chemical Engineering from UTM. Dr Lau has a very strong research interest in the
field of membrane science and technology for water applications. He has published
more than 250 scientific papers and 30 reviews with a total number of Scopus cita-
tions exceeding 10,000 and h-index of 52. Currently, Dr Lau serves as a subject editor
for Chemical Engineering Research and Design (Elsevier) and associate editor for
Water Reuse (International Water Association). Dr Lau has been named among the
top 2% scientists in the world according to the Stanford Report for 2019 published in
the journal PLOS Biology.
ix
x Editor biographies
several major research grants including the UK-Gulf Institutional Links grant. His
fields of specialization are environmental chemical engineering, heavy metal pol-
lution control, biological treatment of toxic gases and Sustainable technologies. He
has amassed rich research experience over a period of two decades. He was awarded
“Outstanding Achievement in Research and Knowledge Transfer” at his institution
in February 2020.
A. Artola T. Gea
Universitat Autònoma de Barcelona Universitat Autònoma de Barcelona
Bellaterra, Barcelona, Spain Bellaterra, Barcelona, Spain
xi
xii Contributors
N. Rajamohan H. Y. Tey
Sohar University Universiti Teknologi Malaysia
Sohar, Oman Skudai, Johor, Malaysia
CONTENTS
1.1 Introduction........................................................................................................ 1
1.2 Food Waste, Domestic Waste, Organic Fraction of Municipal Solid
Waste or Biowaste?............................................................................................ 3
1.3 Particularities of Food Waste............................................................................. 6
1.3.1 Overall Characteristics........................................................................... 6
1.3.2 Heterogeneity and Seasonality.............................................................. 6
1.3.3 Impurities and Pollutants....................................................................... 6
1.3.4 Microplastics and Microbioplastics....................................................... 7
1.4 Food Waste Composting.................................................................................... 8
1.4.1 Process Conditions................................................................................. 8
1.4.2 Microbiology......................................................................................... 9
1.4.3 Gaseous Emissions.............................................................................. 10
1.5 Food Waste Compost....................................................................................... 11
1.5.1 Stability and Maturity.......................................................................... 11
1.5.2 Pollutants............................................................................................. 12
1.6 Uses of Food Waste Compost.......................................................................... 13
1.6.1 Use as Organic Amendment................................................................ 13
1.6.2 Soil Bioremediation............................................................................. 14
1.6.3 Landfill Cover...................................................................................... 15
1.6.4 Suppressor Effect................................................................................. 16
1.7 Conclusions...................................................................................................... 16
References................................................................................................................. 17
1.1 INTRODUCTION
The global generation of municipal solid wastes (MSW) is 2.01 billion tonnes per
year, and it is expected to increase to approximately 3.40 billion tonnes per year by
2050 [1]. However, per capita generation averages are wide, with calculated rates
varying considerably by region, country, city and even within neighborhoods. MSW
DOI: 10.1201/9781003260738-1 1
2 Advanced Technologies for Solid, Liquid, and Gas Waste Treatment
(a)
(b)
FIGURE 1.1 Pictures of the Organic Fraction of Municipal Solid Waste (OFMSW) a)
OFMSW as received in a composting plant from a source-separated collection
system, b) Details of the entire OFMSW, c) Details of the impurities found in
the OFMSW, d) Compost from the OFMSW (not refined).
(Source: the authors).
Composting of Food Wastes for Soil Amendment 5
(c)
(d)
waste will refer to mainly OFMSW and will include food waste from markets and food
industry for a more general perspective.
The level of impurities can exceed 30% w/w [16, 19] and this fact complicates
the OFMSW management and makes it more expensive. In addition, these non-
compostable materials transfer pollutants into the organic fraction, lowering its qual-
ity as feedstock for composting and eventually contaminating the final compost.
The number of impurities present in OFMSW has been repeatedly linked to
OFMSW selection and collection systems [19–21]. Source-selected OFMSW has
much higher quality than mechanically-sorted OFMSW [8] and is less likely to exceed
the regulatory limits for heavy metal concentration in the compost produced from it.
The type of source-selection systems also affects OFMSW quality. Door-to-door col-
lection systems provide much higher quality OFMSW than anonymous systems based
in street containers, which present a higher non-compostable content (4-fold increase,
according to [16]). The presence of these impurities has serious implications since
they affect the composting process and the quality of the final compost, not only visu-
ally (plastic and glass fragments), but also agronomically (impurities alter porosity
and water holding capacity). In addition, and as mentioned before, they can potentially
transfer chemical pollutants to the organics.
However, chemical pollutants make their way to food and food waste much before
the collection system. In the farm where food is produced, chemical pesticides are
applied and remain in food even at trace level. Later, several opportunities arise for
pollutants to reach food along manufacturing, packaging, and distribution. Isenhour
et al. [22] reflect on the impossible separation of technical and biological cycles and
the consequences for the conceptualization of the circular economy. Besides classical
physical contaminants, heavy metals, and pathogens, some other pollutants are of
arising concern and have been detected in food waste samples [18, 23]. They include
chemicals such as pesticides, halogenated compounds or aromatic hydrocarbons,
antibiotic resistance genes and microplastics. Pesticides and halogenated organics
(i.e., per-and polyfluoroalkyl substances, PFAS) are highly persistent and tend to
accumulate in the environment. When composting food waste, these contaminants
are not degraded and end up in the compost. Antibiotic resistance genes dispersed
in the environment increase risk of gene transfer to human pathogens [23]. Further
research is needed to understand and assess risk related to these pollutants in the
food supply chain to ensure food security [18].
high [35], whereas porosity is not sufficient, which can result in anaerobic zones,
undesirable gaseous emissions, or unpleasant odors. Achieving proper porosity lev-
els ensures correct air circulation through the solid matrix and provides full aerobic
conditions. In general, this issue is approached by composters and researchers by
including a known volumetric ratio of bulking agent to OFMSW to adjust the mois-
ture content, C/N ratio and porosity, although this is not always possible [36, 37].
In OFMSW composting, several bulking agents have been evaluated. Among
them, lignocellulosic waste from agricultural activities, pruning waste, residual pel-
lets and wood chips have resulted in good porosity conditions [35, 38]. Most of the
studies reported an adequate porosity range of 30–50% for OFMSW composting,
expressed as FAS (free air space). However, these values are obtained for the ini-
tial mixture. In general, there is a lack of information about the evolution of poros-
ity during the entire composting process. When using a suitable bulking agent with
enough resistance to compaction, FAS levels are maintained near initial values. It
is also frequent to observe a reduction in FAS in the first days of the process due to
compaction and substrate size reduction due to biodegradation. Later, FAS increases
again as biodegradation proceeds [33, 34]. Yu et al. [39] assessed the effect of poros-
ity during the curing stage by using passive aeration and confirmed and modelled the
direct positive effect of FAS on microbial kinetics. Anyway, lack of FAS could limit
the understanding of the entire process and have a negative impact on the compost
quality.
Another important parameter in any composting process is the C/N ratio. This
variable is critical for several aspects of composting such as ammonia emissions,
but it is particularly crucial for the development of microorganisms during com-
posting because both elements are required for cellular growth. Limiting the content
of nitrogen is undesirable because it generates a reduction in the C consumption
rate, whereas an excess can generate the release of ammonia in gaseous form [40].
The recommended initial C/N ratio at the start of the composting process ranges
from 25–30. However, many other authors have used slightly different C/N ratios
[41, 42], with good results. Regarding C/N ratio, it is important to note that OFMSW
can present slow or non-biodegradable carbon sources depending on the presence of
impurities such as plastics, textiles, wood, etc. In this sense, the use of a ratio based
on the biodegradable organic carbon should be more adequate, as pointed out by
Puyuelo et al. [43].
Other properties have traditionally been used for the monitoring of composting
processes. However, biological and biochemical parameters have been reported as
excellent indicators to know the biological activity of the process [44]. Biological
methods are typically based on respiration activities. Other biologically-related
parameters such as enzymatic activities or maturity tests are also emerging parame-
ters to monitor the composting process [45, 46].
1.4.2 Microbiology
During the last decades, a large variety of mesophilic, thermotolerant and thermo-
philic aerobic microorganisms including bacteria, actinomycetes, yeasts and other
fungi have been extensively reported in compost and composting [47–49]. In fact,
10 Advanced Technologies for Solid, Liquid, and Gas Waste Treatment
1.4.3 Gaseous Emissions
Although composting is generally considered an environmentally friendly tech-
nology, it also has negative environmental impacts. This is the case of atmospheric
emissions, especially in the case of greenhouse gases (GHG) and volatile organic
compounds (VOC).
Among the released GHGs, they can be attributed to energy requirements of the
composting plant operation and to biochemical reactions, which produces carbon
dioxide (CO2), methane (CH4), and nitrous oxide (N2O) in the biodegradation of
organic matter [59–60]. Regarding VOCs, the rates and specific forms of these emis-
sions highly depend on the feedstock materials and composting phases, considering
that aeration of the composting mixture plays a considerable role in releasing these
compounds [61–62].
Undesirable gaseous emissions are formed due to inadequate aerobic conditions
of composting [63]. This results in CH4 emissions, whereas nitrogen transformation
Composting of Food Wastes for Soil Amendment 11
and loss (NH3 and N2O) are related to ammonification, nitrification, and denitrifi-
cation [64]. The rate of gaseous emissions strongly depends on the initial content of
carbon and nitrogen [65]. It is also important to note that the emissions flow is also
influenced by the composting technology [66]. To reduce the impact of gaseous emis-
sions from composting, biofilters effectively reduced ammonia and VOCs emission,
being one of the most extended technologies in composting plants [67].
Finally, when comparing composting with other technologies for the treatment
of organic solid waste, different studies have demonstrated that it has less impact on
global warming, as it produces lower amounts of GHGs. This fact was concluded
and documented by different studies, which emphasized that composting produces
lower amounts of emissions than incineration or landfill in terms of g CO2-eq/ton of
waste [68–69]. The sole exception is vermicomposting, which can be defined as the
process by which worms are used to convert organic materials (usually wastes) into
a humus-like material known as vermicompost. In this case, when composting and
vermicomposting were compared, it was found that the vermicomposting process
caused lower GHG emissions compared to traditional composting [70].
1.5.2 Pollutants
For a long time, the main concern about the use of compost derived from MSW
has been the presence of heavy metals (Cd, Cu, Ni, Pb, Zn, Hg and Cr). However,
the amount of them in compost has been clearly related to the system of collection
[80]. The most effective method of reducing heavy metals in compost is the source
separation of the organic fraction. Nowadays, European regulations only allow food
waste resulting from separate collections at the source as suitable input material to
obtain compost (Regulation (EU) 2019/1009). Mixed municipal waste is excluded.
According to its use as a component of organic fertiliser, soil improver or grow-
ing media, the limits are detailed in the regulation. Also, the content of pathogens
(usually Salmonellas, Salmonella spp. and Escherichia coli or Enterococcaceae) is
usually analyzed and delimited in compost regulations.
Other organic toxins detected in MSW compost have been related to the quality
of the organic fraction, being higher in mixed MSW [79]. Although composting can
be an effective way to reduce levels of these compounds enhancing its degradation
(per example PAHs and short-chain phthalates [81]) their presence is limited when
organic fraction is separately collected. However, there is a rising concern about
the presence of pollutants in compost because some of them can persist in the envi-
ronment and could be accumulated in the food supply chain [18, 23]. More data
is required about the content of microplastics, heavy metals, pesticides, polychlori-
nated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), per- and polyflu-
oroalkyl substances (PFAS), and pathogens in compost and digestates derived from
food waste [18]. It is convenient to know the presence and concentration of toxic and
dangerous compounds to assess the risk that compost handling, treatment, process-
ing, and use can contribute to human health and the environment, helping to prevent
many unwanted risks.
Compost quality also depends on the presence of non-compostable materials.
Especially attention has been paid in the last years to plastic and emerging con-
taminants of plastics impurities [24,25]. In 2022, Edo et al. [21] found that the
concentration of small fragments and fibers (diameter <5 mm) in compost was in
the 5–20 items/g of dry weight. Five polymers represented 94% of the plastic items
found: polyethylene, polystyrene, polyester, polypropylene, polyvinyl chloride.
Composting of Food Wastes for Soil Amendment 13
TABLE 1.1
Stability of OFMSW Compost From Facilities Adopting Different Technologies
OFMSW OFMSW treatment DRI
source technology (g O2 kg-1 TS h-1)
Decomposition phase Maturation Input Output
stage
Street bin Thermophilic anaerobic Static turned 3.4 ± 0.7 0.4 ± 0.1
collection digestion (21days) + windrow
Tunnel (1 week) (1–2 weeks)
Composting tunnel Aerated windrow 3.6 ± 0.1 0.9 ± 0.1
(2 weeks) (8 weeks)
Turned windrow Turned windrow – 1.0 ± 0.1
(2 weeks) (2 months)
Mesophilic anaerobic – 3.0 ± 0.9 0.3 ± 0.1
digestion (22 days) +
Tunnel (3 weeks)
Door to door Home composter – 5.5 ± 1.0 0.1 ± 0.1
collection (3 months)
Aerated module, covered Static windrow 4.8 ± 0.8 1.1 ± 0.2
by a Gore-Tex® layer (4 weeks)
(5 weeks)
Vermicomposting – 3.1 ± 0.2 0.2 ± 0.1
(3 months)
Mechanically Channels – 2.7 ± 0.5 1.6 ± 0.2
separated (4 weeks)
(street bin
mixed waste)
Created by the authors from [28, 44, 76]. OFMSW: organic fraction of municipal solid waste, DRI:
dynamic respiration index, TS: total solids.
Interestingly, the presence of plastic was fewer in compost from simple compost-
ing plants but treating door-to-door collected organic fraction. In that sense, the
use of compostable bioplastics seems to be a useful way to eliminate the presence
of plastic in compost [21].
1.6.2 Soil Bioremediation
As widely known, compost is commonly used as soil fertilizer. However, its role in
soil bioremediation has been discovered in the last few decades as very effective [91].
Contaminated soils normally do not have enough degrading capacity by themselves
since the physicochemical conditions do not allow a satisfactory elimination of the
pollutants. The presence of compost permits the boosting of the biodegrading pro-
cess by providing the system with a satisfactory metabolic activity on one side, and
Composting of Food Wastes for Soil Amendment 15
providing the microbes already present in the soil with nutrients. Hence, it can help
in two soil improvement tasks: bioremediation and soil amendment [92]. Compost
can degrade several organic pollutants normally present in soil coming from very
different sources. Among them, pesticides are the most abundant in soils dedicated
to agriculture, and it becomes essential to degrade these contaminants for the recov-
ery of these soils. Besides pesticides, other usual pollutants can be found in soils,
such as heavy metals and petroleum derivatives, which cause an important damage
in soil in terms of physicochemical and microbiological characteristics [93], signifi-
cantly increasing the interest in the use of compost thanks to its mentioned capacity
to trigger the pollutants biodegradation.
The techniques normally used for the remediation of soils are often expensive,
making compost addition a very promising technique in economic terms [94].
Besides, the bioremediation of soils is an attractive technology that permits the
transformation of contaminants to biomass and innocuous final products [95], which
results in a much more environmentally friendly technique to treat polluted soils.
However, some drawbacks should be considered, for instance, the composition of
compost can vary significantly depending on its origin, which has a very important
influence on the microbial and physical conditions of the compost. Hence, it becomes
important to know if the selected compost can be applied for the degradation of the
contaminants present in the soil to be treated, as some compounds degradation can
result easier than others. In this sense, it is essential that the microbes have an easy
access to contaminants, and the concentration of these should be previously known
as high concentrations could result in toxicity. All these factors make the relationship
between compost amendments and contaminants quite complex, and research is still
needed to clarify this topic [96].
1.6.3 Landfill Cover
It is necessary to apply a daily cover on landfills to reduce their odors and gases
emissions, which generate much inconvenience or are highly pollutant. Landfills
have evolved significantly from being open dumps with no kind of treatment, or
being covered with any type of soil, to modern facilities where a proper and specific
treatment is applied to residues [97]. One of the main problems that landfills present
is that they are considered as one of the great sources of methane emissions nowa-
days, a problem that needs to be addressed urgently due to global warming. Even
though covering landfills with ordinary soils can effectively reduce gases emissions
[98], it results much more useful to use compost as landfill cover in terms of spe-
cific mitigation of methane emissions, since it contains an increased microbiological
activity and diversity. In fact, compost can act both as a biofilter, thanks to its high
capacity to permeate gas flows [99] and as an active source for methane oxidation
[100]. In particular, it has been reported that composts are excellent matrices for the
growth and activity of methanotrophs, which are the bacteria that have the ability to
oxidize methane as their only source of carbon, generating water and carbon dioxide.
Besides, compost contains a high nutrient quantity for the satisfactory development
of these bacteria [101], and it is an economical and environmentally friendly material
to obtain high methane oxidation rates [102]. It has also been described how compost
16 Advanced Technologies for Solid, Liquid, and Gas Waste Treatment
of specific materials can also be used not only in methane mitigation, but also in
reducing landfills emissions of odors, widening its environmental advantages. For
instance, biochar has been reported as a good material for this purpose [103]. Thus,
further research in this field is needed for the development of different types of com-
post materials which may prove very efficient for the reduction of the several species
of gases involved in landfills emissions.
1.6.4 Suppressor Effect
Pest and disease suppression have also been associated with compost application
presumably reducing the need for pesticides [83]. Suppression capacity has been
associated with the microbiota present in compost [104] which interact with the
organic matter already present in soil and the target crops/plants regulates the
rhizosphere microbial community. The mechanisms responsible for the compost
suppressive effects can be found in more detail in the review presented by De
Corato [105] where pros and cons of compost repeated application on soil are
analyzed in terms of enhancement of natural soil suppressiveness. Specifically,
compost from OFMSW can contribute to the control of P. ultimum in cucumber,
Fusarium oxysporum f. sp. basilici in basil or Sclerotinia sclerotiorum in lettuce
[105]. In fact, the influence of raw materials in the suppressive effect of compost
has been reported as well as composting process operation [104]. The type of
bulking agent used and its particle size seem also to play a role in defining final
compost suitability to act on specific soil-borne plant pathogens [106]. Bonanomi
et al. [107] studied data from more than 250 papers to ascertain the key parame-
ters in predicting the beneficial effect of different organic amendments in disease
suppression as results presented lead to inconsistent conclusions depending on
the organic matter used and target plant disease. Microbiological and enzymatic
characteristics were found to provide more information than the physico-chemi-
cal ones. FDA activity, substrate respiration, microbial biomass, total culturable
bacteria, fluorescent Pseudomonas and Trichoderma populations were among the
most useful parameters with not a single variable considered sufficient to deter-
mine disease suppression properties.
1.7 CONCLUSIONS
Composting of the OFMSW, in its different technologies and scales, is a highly valu-
able process for waste management that permits, by means of a biological robust
process, obtaining an end product with a high potential for soil amendment, although
other alternative uses as pathogen suppressor or soil bioremediation enhancer are
being considered in modern literature.
The composting operational conditions must be carefully defined for a successful
process: moisture, biodegradability, C/N ratio and porosity are the main parame-
ters to be adjusted. Particularly, in the composting of the OFMSW the presence of
impurities must be also considered, being plastics (macro and micro) one of the main
problems. These impurities can contaminate the final compost, in which stability and
maturity are also crucial.
Composting of Food Wastes for Soil Amendment 17
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