HeraCeram Zirkonia 750 Application Guide en
HeraCeram Zirkonia 750 Application Guide en
HeraCeram Zirkonia 750 is the perfect choice for framework materials with a CTE of
10.2 to 10.5 μm/mK, e. g. for veneering zirconia and lithium disilicate frameworks. The
Stabilised Leucite Structure protects against crack propagation chipping and fracture, a
recognised problem with some other Zirkonia ceramic systems. Heraceram Zirkonia 750
with it’s SLS formulation gives you proven reliability exactly when and where it’s needed.
Table of contents
Framework preparation Page 08
2
3
HeraCeram®
Natural aesthetics every time.
Ceramics that are perfectly adapted both in terms of their specifically tailored to suit your framework material. At
appearance and their technical properties: that means the same time, every ceramic also offers consistent
simple, reliable and fast processing with unbeatable processing and high aesthetics for perfect results that
aesthetic results. Each HeraCeram ceramic product is you can rely on.
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SLS
The recipe for success.
Leucite is the heart of dental ceramics. Without this silicate In dental ceramics, the leucite acts like a plant that grows
structure derived from mineral classed silicates and after absorbing nutrients. If the constituents are composed
zirconia, metal ceramics as we know them today would with an excess amount of Al2O3 and K 2O, the leucite will
not exist. Leucite is responsible for the thermal expansion continue to increase/grow during multiple firing.
required when bonding ceramic to metal alloys. Adjusting
thermal expansion, however, is not its only function. Leucite In order to solve this problem, Kulzer dental ceramics are
not only increases strength but more importantly reduces manufactured using completely different processing
the bonding material’s susceptibility to stress. methods. All materials are manufactured using precisely
coordinated constituents together with specific processing
The disadvantage of leucite with many metal ceramics is steps. This process, which we term leucite management,
uncontrollable and continual growth of the leucite crystals produces a “Stabilised Leucite Structure” known as SLS
during multiple firings. This leads to an increase in thermal for short. Thanks to this processing method, all Kulzer dental
expansion that can cause unpredictable stress in the frame- ceramics allow you to enjoy the benefits of leucite without
works metal ceramic bond. An uncontrollable increase the worry of adverse effects such as an uncontrollable
in thermal expansion can be attributed to an unsuitable increase in CTE values.
chemical composition and the type of manufacturing
process. For the user, this means maximum reliability and less
stress, with a perfect aesthetic outcome.
HeraCeram Zirkonia
Product A
Product B
Product C
Product D
Product E
0 5 10 15 20
Firing time in minutes
(as recommended by the manufacturers)
Fig. 1 HeraCeram Zirkonia etching micrograph with Fig. 2 Extremely short firing times.
leucite structure.
dL / Lo.10-3
dL / Lo.10-3
3x fired
1x fired
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Ceramic® for all that you do
Perfect frameworks for all requirements.
With HeraCeram ceramics, you can achieve aesthetic Aesthetic veneering: Quite simple with standard materials,
restorations that suit every need in any situation – from highly personalised with a wide range of custom materials
authentic reproduction of everyday A – D shades to or a very natural look with matrix materials. Giving you the
skilful customisation, through to high end complex resto- flexibility you need for your design.
rations with vibrant light dynamics.
Special
Bleach Pressable
Margin set Gingiva set
Special applications Shades*** ceramics****
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Perfectly tailored to your framework.
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HeraCeram® Zirkonia 750
Framework preparation
Preparing the zirconia framework surface
The zirconia frameworks are cleaned with a steam jet. – Sand blasting the framework for
better bonding is not necessary. Zr adhesive 750 can now be applied directly to the
surface of the framework.
pressure and adjusted rotational speed. Please observe the recommendations of the
manufacturer for the rotating instruments.
■■ The minimum thickness required for lithium disilicate frameworks must be maintained.
NOTE: For preparation of the finalised framework, only use instruments which are
recommended by the respective manufacturers e. g. Ivoclar Vivadent for the processing
of lithium disilicate.
Do not sand blast the lithium disilicate surfaces with Al2O3 or glass beads.
Ceramic firing
Instructions for firing HeraCeram Zirkonia 750 can be found at page 31.
VIDEOS: Watch videos about the different layering v ersions of HeraCeram Zirconia 750.
Matrix layering
Start video
kulzer.com/video_HC750_matrix
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Adhesive 750
The adhesive has the ability to fully wet zirconia and lithium
disilicate surfaces perfectly and thus ensure an optimum
bond. The adhesive 750 is fluorescent and provides nature-
like fluorescence from the depth of the restoration.
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HeraCeram® Zirkonia 750
Fig. 8 Slightly glossy adhesive layer on the lithium disilicate surface after firing.
Fig 9 Image at tooth 21: Ideal fluorescence on a ceramic Fig. 10 Image at tooth 21: Ideal fluorescence on a finished
frame. Image at tooth 11: Zero fluorescence after none restoration. Image at tooth 11: Without adhesive 750,
application of Adhesive 750 shine-through on the none fluorescent frame.
PLEASE NOTE: The Adhesive 750 should be applied in a thin, uniform coat to the s urfaces of the framework by
using a HeraCeram opaque paste brush. The firing temperature on zirconia is 800°C and on lithium disilicate is 750 °C,
holdtime is 1 minute. (see the recommended firing cycles at page 31)
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Dentine-enamel build up
HeraCeram Zirkonia 750 dentine and / or chroma dentine can be used for layering of the dentine core.
The dentine is highly transparent. This promotes brilliance but results in the shade of the framework having a stronger influence
on the shade and brightness.
The underlying colour of zirconia frameworks are not standardised and may differ significantly in chroma and brightness from
the desired tooth shade.
Dentine
Ceramic
framework
Increaser
(optional)
Fig. 11 The colour and brightness are very close to that of Fig. 11a In this case, the dentine core can be built up
the desired tooth shade. using dentine material.
Chroma dentine
Ceramic
framework
Increaser
(optional)
Fig.12 This framework differs significantly in colour and Fig.12a The use of chroma dentine is recommended for
brightness from the target shade. build up of the dentine core.
Dentine
Chroma dentine
Ceramic
framework
Increaser
(optional)
Fig. 13 The colour does not correspond to the desired Fig. 13a Depending on the available space, the dentine
shade group. core can be shaped using a combined layering of dentine
and chroma dentine.
Chroma dentine (e. g. CD A3) is the same colour as the corresponding dentine (e. g. D A3). Its high colour density
conceals the framework structures better and thus compensates differences in shade between the framework and the
desired tooth shade. This allows the technician to adapt a preferred layering scheme to suit all indications.
The dentine core can be completely or partially built up with chroma dentine.
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HeraCeram® Zirkonia 750
Everyday layering.
PLEASE NOTE: When grinding ceramic it is essential to wear a mask and safety glasses
and use a dust extractor. Avoid inhaling dust.
Start video
www. kulzer.com/video_HC750_everyday
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Fig. 17 The cut back
comprises the incisal edge
of the dentine and tapers
off towards the lower third
of the tooth.
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HeraCeram® Zirkonia 750
Everyday layering.
Fig. 22 If no further
ceramic needs to be
added, the ceramic should
be ground with diamond
burs to finalise the shape
and surface morphology.
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Glaze firing
HeraCeram stain liquids have the same refractive index as for glaze firing may only be considered as guidelines which
HeraCeram. The layering and shade effects can be made have to be adjusted to the desired outcome. The firing
visible by wetting the ceramic surface with stain liquid. cycle is shown under Glaze
This allows special effects created with glaze and stains to
be evaluated more easily. Firing, see glaze firing programm in capture Firing Pro-
grammes.
The level of glaze and texture of the ceramic surface can
be influenced while firing the glaze by adjusting the HeraCeram Zirkonia 750 can also be polished by hand.
temperature, hold time and final temperature. Further Our Signum HP diamond polishing paste provides an
influencing factors are the type of surface finishing and excellent surface finish.
preparation for glaze firing. Therefore, the settings quoted
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HeraCeram® Zirkonia 750
Everyday layering.
Correction ceramic is for adjustment after the glaze firing, Zirkonia 750 ceramics. Depending on the mixing ratio, the
e. g. building up contact areas – its firing temperature of firing or processing temperature of the correction material
715 °C is well below dentine firing temperature. Correction must be increased (e .g. 1:1 mixture – Firing temperature
material is unshaded and transparent. If the corrections approx. 730 °C).
need shading, it can be mixed with any of the HeraCeram
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HeraCeram® Zirkonia 750
Personalised layering.
Increaser
The use of increasers improves control of the effect of the For distinctive (patient-oriented) characterisations and indi-
shade in all constrained spaces, such as for example, in the vidual modifications, 6 highly chromatised increasers are
cervical region and if the framework shade differs greatly from available in Peach (INP), Solaris (INS), Mango (INM), Orange
the desired target shade. Likewise, excellent harmonisation of (INO), Caramel (INC) and Taiga (INT).
optical differences resulting from very wide variations in layer
thickness, for example, in bridge sections, is possible. A complete list of the colour mapping of the HeraCeram
Zirkonia 750 materials can be found in Section E.
Start video
www.kulzer.com/video_HC750_personalised
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HeraCeram® Zirkonia 750
Personalised layering.
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Enhancer
Enhancers are customised transparent ceramics with which incisors as well as canines to be reproduced easily. Even
the hue or brightness of the layering can be influenced those deviations in shade which cannot be shown on a
slightly but without affecting the character of the shade. shade guide can be achieved in a controlled manner using
This enables the typical shade tones of central and lateral the 6 Enhancers.
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HeraCeram® Zirkonia 750
Personalised layering.
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Mask
Incisal like ceramic with increased opacity, balances the transparency so that on the one
hand, the in-depth effect is retained yet on the other hand the structure of the frame-
works can no longer be perceived. MA bright and MA shadow can also be used to modify
brightness.
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HeraCeram® Zirkonia 750
Personalised layering.
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HeraCeram® Zirkonia 750
Matrix layering.
The ceramic compounds of the Matrix set have remarkable aesthetic properties. With
their easy layering, they make completely natural results possible. The Matrix aesthetic
concept, which is developed in cooperation with MDT Paul A. Fiechter, has a simple
layered structure that is easy to implement.
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HeraCeram® Zirkonia 750
Matrix layering.
Start video
www. kulzer.com/video_HC750_matrix
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Fig. 45 Smooth transitions
are important to avoid
distinct borders between
the value material and base
shade.
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HeraCeram® Zirkonia 750
Matrix layering.
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Glaze firing
Fig. 51 Final stage ready
for glaze and / or polish.
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HeraCeram® Zirkonia 750
Margin
Fig. 55 The shoulder material is mixed with Fig. 56 After adjustment the ceramic
the SM liquid and applied in the cervical shoulder fits perfectly.
area of the crown and fired at 780 °C.
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LM shoulder material (low fusing)
With the LM shoulder materials, the ceramic shoulders temperature of 715 °C, they are also suitable for all other
can be produced after the actual veneering, in other adjustments, e.g. shape corrections or contact point
words, after the glaze firing. With their low processing additions.
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HeraCeram® Zirkonia 750
Colour mapping table.
A1 A2 A3 A3.5 A4 B1 B2 B3 B4 C1 C2 C3 C4 D2 D3 D4
Increaser INA1 INA2 INA3 INA3.5 INA4 INB1 INB2 INB3 INB4 INC1 INC2 INC3 INC4 IND2 IND3 IND4
Increaser INC INC INC INS INS INT INT INT INT INT INT
Dentine DA1 DA2 DA3 DA3.5 DA4 DB1 DB2 DB3 DB4 DC1 DC2 DC3 DC4 DD2 DD3 DD4
Chroma Dentine CDA1 CDA2 CDA3 CDA3,5 CDA4 CDB1 CDB2 CDB3 CDB4 CDC1 CDC2 CDC3 CDC4 CDD2 CDD3 CDD4
Incisal S1 S1 S2 S2 S4 S1 S1 S2 S4 S1 S3 S3 S3 S1 S2 S2
Mamelon,
MD1 MD1 SD2 SD2 SD2 MD2 MD2 MD3 MD3 MD2 SD1 SD2 SD2 MD1 MD3 MD1
Secondary Dentine
Value VL1 VL2 VL3 VL4 VL4 VL1 VL2 VL3 VL4 VL1 VL2 VL3 VL4 VL2 VL3 VL4
Opal Incisal OS1 OS1 OS2 OS2 OS4 OS1 OS1 OS2 OS4 OS1 OS3 OS3 OS3 OS1 OS2 OS2
Margin HM/M 1 1 2 2 6 3 3 4 4 1 1 6 6 1 2 4
All stains and liquids can be used for HeraCeram, HeraCeram Zirkonia
and HeraCeram Zirkonia 750.
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HeraCeram® Zirkonia 750
Firing programmes.
IMPORTANT: The firing temperatures quoted here are guidelines only. Deviations may occur due to differences in
furnace performance and may have to be compensated for if necessary.
*when using Stains and Glaze pastes, starting temperature 600 °C!
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HeraCeram® Zirkonia 750
Firing programmes.
Austromat 3001/Press-i-dent
Adhesive C500 T300•L9 T60 V9 T075•C800 V0 T120 C0 L0 T2 C500
For Zirconiumdioxide-
Austromat M
For Zirconiumdioxide-Frameworks For Lithium-Disilicate-Frameworks
Correction Correction
Adhesive Margin HM Dentine 1 Dentine 2 Glaze Adhesive Margin HM Dentine 1 Dentine 2 Glaze
COR / LM COR / LM
START 500 500 500 500 500* 500 400 400 400 400 400* 400
, 0 0 0 0 0 0 0 0 0 0 0 0
n 5 5 5 5 4 4 5 5 5 5 4 4
, 1 1 1 1 1 1 1 1 1 1 1 1
VAC 9 9 9 9 0 9 9 9 9 9 0 9
°CSmin. 75 60 60 60 60 60 50 50 50 50 60 50
END 800 780 750 745 725 720 750 780 750 745 725 715
, 1:00 1:00 1:00 1:00 0:30–1:00 1:00 1:00 1:00 1:00 1:00 0:30–1:00 1:00
. 0 0 0 0 0 0 0 0 0 0 0 0
. 0 0 0 0 0 0 0 0 0 0 0 0
*when using Stains and Glaze pastes, starting temperature 600 °C!
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IMPORTANT: The firing temperatures quoted here are guidelines only. Deviations may occur due to differences in
furnace performance and may have to be compensated for if necessary.
*when using Stains and Glaze pastes, starting temperature 600 °C!
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HeraCeram® Zirkonia 750
Firing programmes.
Preheat temp. [°C] 500 500 500 500 500* 500 400 400 400 400 400* 400
Drying [min] 5.0 5.0 5.0 5.0 4.0 4.0 5.0 5.0 5.0 5.0 4.0 4.0
Preheating [min] 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0
Vacuum time [°C] 1.0 1.0 1.0 1.0 0 0.1 0.1 0.1 0.1 0.1 0 0.1
Firing time [min] 2.0 2.0 2.0 2.0 0.5–1.0 1.0 1.0 1.0 1.0 1.0 0.5–1.0 1.0
Firing temp. [°C] 800 780 750 745 725 720 750 780 750 745 725 715
Heat rate [°C/min] 75 60 60 60 60 60 50 50 50 50 60 50
Vacuum [hPa] 50 50 50 50 0 50 50 50 50 50 0 50
Standby temp. [°C] 500 500 500 500 500* 500 403 403 403 403 403* 403
Clos. time [min] 6 6 6 6 5 5 6 6 6 6 5 5
Heat rate [°C/min] 75 60 60 60 60 60 50 50 50 50 60 50
Firing temp. [°C] 800 780 750 745 725 720 750 780 750 745 725 715
Holding time [min] 2 1 1 1 0.5–1 1 1 1 1 1 0.5–1 1
Vac. ON [°C] 500 500 500 500 – 500 400 400 400 400 – 400
Vac. OFF [°C] 1° below T 1° below T 1° below T 1° below T – 1° below T 1° below T 1° below T 1° below T 1° below T – 1° below T
Vario 200/300
For Zirconiumdioxide-Frameworks For Lithium-Disilicate-Frameworks
Correction Correction
Adhesive Margin HM Dentine 1 Dentine 2 Glaze Adhesive Margin HM Dentine 1 Dentine 2 Glaze
COR / LM COR / LM
Start temp. [°C] 500 500 500 500 500* 500 400 400 400 400 400* 400
Predrying no no no no no no no no no no no no
Predrying time [min] 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00 00:00
Closing time [min] 05:00 05:00 05:00 05:00 04:00 04:00 05:00 05:00 05:00 05:00 04:00 04:00
Homogenisation [°C] 500 500 500 500 500 500 400 400 400 400 400 400
Homogenisation [min] 01:00 01:00 01:00 01:00 01:00 01:00 01:00 01:00 01:00 01:00 01:00 01:00
Heat rate [°C/min] 75 60 60 60 60 60 50 50 50 50 60 50
Firing temp. [°C] 800 780 750 745 725 720 750 780 750 745 725 715
Holding time [min] 02:00 01:00 01:00 01:00 00:30–01:00 01:00 01:00 01:00 01:00 01:00 00:30–01:00 01:00
Temper [°C] – – – – – – – – – – – –
Temper [min] – – – – – – – – – – – –
Opening temp. [°C] – – – – – – – – – – – –
Opening time [min] – – – – – – – – – – – –
Vacuum yes yes yes yes no yes yes yes yes yes no yes
Vacuum release Heating Heating Heating Heating – Heating Heating Heating Heating Heating – Heating
Vacuum End [°C] 800 780 750 745 – 720 750 780 750 745 – 715
*when using Stains and Glaze pastes, starting temperature 600 °C!
34
IMPORTANT: The firing temperatures quoted here are guidelines only. Deviations may occur due to differences in
furnace performance and may have to be compensated for if necessary.
Vacumat 6000 M
For Zirconiumdioxide-Frameworks For Lithium-Disilicate-Frameworks
Correction Correction
Adhesive Margin HM Dentine 1 Dentine 2 Glaze Adhesive Margin HM Dentine 1 Dentine 2 Glaze
COR / LM COR / LM
Standby temp. [°C] 500 500 500 500 500* 500 400 400 400 400 400* 400
Drying [min] 6 6 6 6 5 5 6 6 6 6 5 5
Heating period [min] 4.00 4.40 4.10 4.05 3.45 3.40 7.00 7.35 7.00 6.54 5.25 6.18
Heat rate [°C/min] 75 60 60 60 60 60 50 50 50 50 60 50
Final temp. [°C] 800 780 750 745 725 720 750 780 750 745 725 715
Holding time [min] 2 1 1 1 0.5–1 1 1 1 1 1 1 0.5–1
Vac. time [min] 4.00 4.40 4.10 4.05 – 3.40 7.00 7.35 7.00 6.54 – 6.18
NOTE: Firing recommendations for additional ceramic kilns are available on our website at kulzer.com/download
*when using Stains and Glaze pastes, starting temperature 600 °C!
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HeraCeram® Stains universal
The range of stains for universal applications
Stain Set, universal. Stain Set, universal, powder.
The Stains universal set includes 22 Stains The Stains universal set includes 22 Stains
(2 ml) and a Glaze paste (2 ml). (3 g) and a Glaze (3 g).
Contents Contents
■■ 17 x 2 ml Individual Stains ■■ 17 x 3 g Individual Stains
■■ 3 x 2 ml Body Stain BS-A; BS-B; BS-C ■■ 3 x 3 g Body Stain BS-A; BS-B; BS-C
■■ 2 x 2 ml Enamels EN Pearl; EN Opal ■■ 2 x 3 g Enamels EN Pearl; EN Opal
■■ 1 x 2 ml Glaze GL ■■ 1 x 3 g Glaze GL
Contact in Germany
Kulzer GmbH
Leipziger Straße 2
63450 Hanau, Germany
[email protected]