NEET / JEE (Medical and Engg.
)
11
Section - B (Chemistry) Marks: 180 Date: 27/ 07 / 2025
Roll No. Test No.
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Topic : Chmical Equilibrium 11th(OLD)
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Note: (1) All questions are compulsory.
(2) Select the most correct answer and darken ( ) the circle ( ) corresponding to correct alternative.
01) The rate at which a substance undergoes 04) Equilibrium concentration of HI, I2 and H2 is
reaction is proportional to 0.7, 0.1 and 0.1 moles/litre. Calculate the equi-
1) mass librium constant for the reaction :
2) mass of solution I2(g) + H2(g) 2HI(g)
*3) active mass of reactants 1) 0.36 2) 36
4) active mass of products *3) 49 4) 0.49
02) For the reaction 05) When the equilibrium is established, there
PCl5(g) PCl3(g) + Cl2(g) occurs :
1) Kp =Kc 2) Kp = Kc (RT)-1 1) Change in concentration of reactants
*3) Kp = Kc(RT) 4) Kp = 2) Change in concentration of the products
Kc(RT) 2
3) Change in concentration of one or more of
Key: 3) n = 2 - 1 = 1 the products
Kp = Kc (RT) *4) None of these
Key: The rate of formation of products becomes equal
03) A reversible reaction is one which : to rate of formation reactants. So, there is no
1) Proceeds in one direction change in concentration of reactants & products.
*2) Proceeds in both directions
3) Proceeds in both directions 06) In a chemical reaction equilibrium is said to have
4) All the statements are wrong been established when :
forward
1) Concentrations of reactants and products are
Key: 2) Reactant Products equal
backward
2) Opposing reactions cease
*3) Velocities of opposing reactions become
equal
4) Temperature of opposing reactions are equal
1
Key: 3) Concentration may or may not become equal 1) Concentration of reactants is changing where
at equilibrium. By saying, reaction attained as concentration of products is constant
equilibrium we mean that, rate of formation of
*2) Concentration of all substances is constant
products becomes equal to rate of formation
reactants. 3) Concentration of reactants is constant where
as concentration of products is changing
4) Concentration of all substances is changing
07) For the reaction
C(s) + CO2(g) 2CO(g) ,
12) A + 2B C + D
the partial pressure of CO2 and CO are 2.0
and 4.0 atm respectively at equilibrium. The the equilibrium constant is
Kp for the reaction is [C][D] [C][D]
1) 0.5 2) 4.0 *1) 2)
[A][B]2 [A ][B]
*3) 8.0 4) 32.0
2 [ A ][ B ]2 [A ][C]
PCO 4x4 3) 4)
Key:- 3) Kp = P = = 8. [ C ][ D ] [B][D]
CO2 2
13) Select the correct expression regarding the
08) In a chemical equilibrium, the equilibrium relation between KP and KC for the reaction
constant is found to be 2.5. If the rate constant aX(g) + bY(g) bZ(g) + aW(g)
of backward reaction is 3.2 × 10–2, the rate
constant of forward reaction is - 1) KP = KC(RT)a+b
*1) 8.0 × 10–2 2) KP = KC(RT)a-b
2) 4.0 × 10–2 3) KP = KC RT
3) 3.5 × 10–2 *4) KP = KC
4) 7.6 × 10–3
14) The equilibrium constant of the reaction
09) For the reaction CO (g) + 3H2(g) CH4(g) + H2O(g) is
10. If rate constant of forward reaction is 1000,
N2(g) + 3H2(g) 2NH3(g), the rate constant of backward reaction is :
the correct expression of equilibrium constant 1) 10 - 3 2) 103
K is *3)102 4) 10 - 4
[NH 3 ]2 [N 2 ][H 2 ]3
*1) K = [N ][H ]3 2) K = [NH ]2 15) When a catalyst is introduced into a reversible
2 2 3
reaction
2[NH 3 ] [N 2 ]x 3[H 2 ] 1) Forward reaction rate increases
3) K= [N ]x 3[H ] 4) K = 2[NH 3 ]
2 2
2) Backward reaction rate increases
3) Equilibrium is not changed
10) The value of KP for the reaction *4) Attains equilibrium quickly
H2(g) + I2(g) 2HI(g)
is 50. What is the value of KC 16) The number of gram molecules (moles) of a
1) 30 2) 40 substance present in unit volume is termed as
*3) 50 4) 70 1) Activity
2) Normal solution
3) active solution
11) In the given reaction
*4) Active mass
N2 + O 2 2NO,,
Key: 4) Active mass
equilibrium means that
2
21) In the reversible reaction
number of gram molecules (moles)
= A+B C + D,
volume
the concentration of each C and D at equilib-
rium are 0.8 mol / L. If the initial moles are 1.
17) According to law of mass action rate of a chemi- Calculate Kc
cal reaction is proportional to
1) 6.4 2) 0.64
1) Concentration of reactants 3) 1.6 4) 16.0
2) Molar concentration of reactants
Key:- 4) Suppose 1 mole of A and B each taken
3) Concentrtation of products then 0.8 mole / litre of C and D each formed
4) Molar concentration of products remaining concentration of A and B will be
Key:- 2) According to low of mass-action, “at a given ( 1- 0.8) = 0.2 mole / litre each.
temperature, the rate of a reaction at a particu-
[C][D] 0.8x 0.8
lar instant is proportional to the product of the Kc = [A ][B] 0.2 x 02 16.0
active masses of the reactants at that instant
raised to powers which are numerically equal
to the numbers of their respective molecules in 22) The rate at which the substance react is directly
the stoichiometric equation describing the re- proportional to
action.”.
1) active mass of any reactant substance
2) active mass of any product substance
18) The equilibrium constant at 298 K for a reaction
*3) active mass of that reactant substance
A+B C + D is 100.
4) active mass of its product substance
If the initial concenttration of all the four species
were 1 M each, the equilibrium concentration of D
(in mol L-1) will be 23) Which one of the following statements is cor-
1) 1.182 2) 0.182 rect ?
3) 0.818 *4) 1.818 *1) Reversible reactions do not proceed to
completion
19) For the system 2) Irreverisble reactions do not proceed to
completion
3A + 2B C,
3) Both reversible and irreversible reactions pro-
the expression for equilibrium constant is ceed to completion
[3A ][2B] [C] 4) Neither reversible nor irreversible reaction
1) 2) [3A ][2B] proceed to completion
C
[A ]3[B]2 [C]
3) 4) [A ]3[B]2 24) The reaction
[C]
A(g) + B(g) C(g) + D(g)
Key: 4) Equilibrium constant for the reaction, proceeds to right hand side upto 99.9%. The
[C] equilibrium constant K for the reaction will be -
3A + 2B C is K= [A ]3[B]2 . 1) 104 2) 105
*3) 106 4) 108
20) The equilibrium constant KC for the decompo-
sition of PCl5 is 0.625 mole / lit at 300ºC. Then 25) On a given condition, the equilibrium concen-
the value of KP is tration of HI, H2 and I2 are 0.80, 0.10 and 0.10
*1) 29.36 atm mole/litre. The equilibrium constant for the re-
action
2) 0.0625 atm
H2 + I2 2HI
3) 6.25 atm
will be
4) 0.00625 atm
1) 64 2) 12
3) 8 4) 0.8
3
2AB A2 + B2, is 49,
Key:- 1)
then the equilibrium constant for reaction
H2 + I2 2HI;
[HI] = 0.80, [H2] = [I2] = 0.10 1 1
AB A2 + B2,
2 2
[HI]2 0.80x 0.80
Kc = [H ][I ] 010
. x 0.10
64 will be
2 2
*1) 7 2) 20
3) 49 4) 21
26) The equilibrium concentration of X, Y and YX2
are 4, 2 and 2 moles respectively for the equi-
31) The equilibrium constant of the reaction
librium
A+B C + D is 10.
2X(g) + Y(g) YX2(g).
The value of KC is If rate constant of forward reaction is 203,
1) 0.625 *2) 0.0625 the rate constant of backward reaction is
3) 6.25 4) 0.00625 *1) 20.3 2) 10.3
3) 2.03 4) 203
27) The KC for the reaction
A + B C + D 32) Which of the following is true for the reaction
is 9. If one mole of each of A and B are CO (g) + 3H2(g) CH4(g) + H2O(g)
mixed and there is no change in volume, 1) It is a homogeneous reaction
the number of moles of C formed is 2) it is a reversible reaction
1) 0.50 *2) 0.75 3) It attends the dynamic equilibrium
3) 0.90 4) 1.5 *4) All of these
28) The rate of forward reaction for the for the re- 33) Unit of equilibrium constant for the reversible
action reaction,
A+B C + D is H2 + I2 2HI
*1) Rf = Kf [A].[B] is
2) Rf = [C].[D] 1) mol-1 litre 2) mol-1
3) Rf = [A].[B] 3) mol litre-1 4) None of these
2) Rf = Kf[A].[C] Key:- 4)
Unit of Kp = (atm) n
29) In a chemical equilibrium A + B C + D, Unit of Kc = (mole / litre) n
when one mole each of the two reactants are =[mole / litre]0
mixed, 0.6 mole each of the products are =0
formed. The equilibrium constant calculated is
1) 1 2) 0.36
34) A homogeneous reaction is one which occurs
3) 9/4 4) 4/9 only in ......... phase.
Key: 3) *1) one 2) two
A+B C=D 3) three 4) four
Initial 1 1 0 0
remaining at eqm 0.4 0.4 0.6 0.6 35) For a hypothetical equilibrium:
[C][D] 0.6x 0.6 36 4A + 5B 4X + 6Y ;
K = [A ][B] 0.4 x 0.4 16 29/4
The equilibrium constant Kc has the unit:
1) mol2 litre–1
30) If equilibrium constant for reaction 2) litre mol–1
4
3) litre2 mol–2
*4) mol litre–1 40) 4 moles of A are mixed with 4 moles of B. At
equilibrium for the reaction
36) The change in ........ of the substances in unit A+B C + D,
time is known as rate of reaction. 2 moles of C and D are formed. The equilibrium
1) mass 2) volume constant for the reaction will be
*3) concentration 4) density 1 1
1) 2)
4 2
37) A sample of HI(g) is placed in a flask at a pres- 3) 1 4) 4
sure of 0.2 atm. At equilibrium partial pressure
Key: 3) A + B C + D
of HI(g) is 0.04 atm. What is Kp for the given
equilibrium? Initial conc. 4 4 0 0
2HI(g) H2(g) + I2(g) After T time (4 - 2) (4 - 2) 2 2
1) 6 2) 4 conc.
3) 8 4) 2 [C][D] 2x2
Equilibrium constant = [A ][B] 2 x 2 1
Sol: 2) pHI = 0.04 atm,
pH2 = 0.08 atm;
pI2 = 0.08 atm 41) In which of the following reaction, the value of
KP will be equal to KC
2HI(g) H2(g) + I2(g) *1) N2(g) + O2(g) 2NO(g)
2) PCl5 (g) PCl3 (g) + Cl2(g)
pH 2 pI 2
Kp = 2
3) 2NH3 (g) N2(g) + 3H2(g)
PHI
4) 2SO2 (g) + O2(g) 2SO3 (g)
0.08 atm 0.08 atm
Kp = 0.04 atm 0.04 atm
42) We know that the relationship between Kc and
= 4.0 Kp is
Kp = Kc (RT)n
38) In the reaction
What would be the value of n for the reaction
C2H4(g) + H2(g) C2H6(g),
NH4Cl(s) NH3(g) + HCl(g)?
the equilibrium constant can be expressed in
units of - 1) 1 2) 0.5
3) 1.5 4) 2
1) litre–1 mol–1
2) mol2 litre–2 Sol : 4) : n n p nr = 2 - 0 = 2
*3) litre mol–1
4) mol litre–1 43) At 700 K, equilibrium constant for the reaction
:
39) For hypothetical reactions, the equilibrium H2(g) + I2(g) 2HI(g) is 54.8.
constant (k) values are given If 0.5 mol L of HI(g) is present at equilibrium at
-1
A B; K1 = 2.0 700 K, what are the concentration of H2(g) and
I2(g) assuming that we initially started with HI(g)
B C; K2 = 4.0
and allowed it to reach equilibrium at 700 K?
C D; K3 = 3.0
1) 0.068 mol litre-1
The equilibrium constant for reaction
2) 1 mol litre-1
A D is
3) 2.5 mol litre-1
1) 48 2) 6
4) 68 mol litre-1
3) 2.7 *4) 24
5
Sol : H2(g) + I2(g) 2HI(g) ; K1 = 54.8.
By starting with HI
2HI(g) H2(g) + I2(g) ; K2 = ?
2HI(g) H2(g) + I2(g)
Initial concentration a 0 0
At equilibrium 0.5 x x
H 2 I 2
K2 = HI 2
1 xx 1
= 0.52 K 2
54.8 K1
2 0.25
x
54.8
x = 0.068
[H2] = [I2] = 0.068 mol litre
e-1
44) For the reaction
3
Fe2N(s) + H (g) 2Fe(s) + NH3(g)
2 2
1) KC = KP (RT)1/2
2) KC = KP(RT)
3) KC = Kp (RT)3/2
4) KC = KP(RT)- 1/2
n
KEY: 1) KP = KC (RT) g
= KC(RT)1 - 3 / 2
= KC(RT) - 1/2
KC = KP(RT)1/2
45) 4 moles of A are mixed with 4 moles of B. At
equilibrium for the reaction
A+B C+D,
2 moles of C and D are formed. The equilibrium
constant for the reaction will be
1 1
1) 2)
4 2
3) 1 4) 4
KEY: 3)
A+B C+D
Initial conc. 4, 4 0 0
After T time conc. (4-2)(4-2) 2 2
[C][D] 2 x 2
Equilibrium constnat = 1
[A ][B] 2 x 2
