NEET

KATTAR NEET (2026)

CHEMISTRY
Structure of Atom

Q1 Penetration power of proton is Q6 The de-Broglie wavelength associated with a

(A) More than electron material particle is
(B) Less than electron (A) Directly proportional to its energy
(C) More than neutron (B) Directly proportional to its momentum
(D) Equal to electron (C) Inversely proportional to its energy
(D) Inversely proportional to its momentum
Q2 The mass number of an element is double than
its atomic number. If there are four electrons in Q7 The uncertainty in momentum of an electron is
p-orbitals, the element is 1 × 10
−5
kg − m/s . The uncertainty in its
(A) C (B) N position will be:
(C) O (D) Na (h = 6. 62 × 10
−34 2
kg − m /s )
(A) 1. 05 × 10
−28
m
Q3 Orbital is a
(B) 1. 05 × 10 −26
m
(A) Circular path around the nucleus in which the
(C) 5. 27 × 10 −30
m
electron revolves
(D) 5. 25 × 10 −28
m
(B) Space around the nucleus where the
probability of finding the electron is Q8 Principal quantum number of an atom represents
maximum (A) Size of the orbital
(C) Amplitude of electrons wave (B) Spin angular momentum
(D) Number of electron wave (C) Shape of orbital
(D) Space orientation of the orbital
Q4 Rutherford's experiment on scattering of
particles showed for the first time that the atom Q9 In a given atom no two electrons can have the
has; same values for all the four quantum numbers;
(A) Electrons (B) Protons This is called
(C) Nucleus (D) Neutrons (A) Hund's rule
(B) Aufbau's principle
Q5 Which one of the following is not the
(C) Uncertainty principle
characteristic of Planck's quantum theory of
(D) Pauli's exclusion principle
radiation?
(A) The energy is not absorbed or emitted in Q10 Which of the following graphs of radial part of
whole number or multiple of quantum wave-function (ψ) versus distance from nucleus
(B) Radiation is associated with energy is/are incorrectly labeled?
(C) Radiation energy is not emitted or absorbed (A)
continuously but in the form of small packets
called quanta
(D) Magnitude of energy associated with a
quantum is proportional to its frequency

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(B) Radius of nth Inversely

(D) (IV)
orbit proportional to n2
(A) (A)- I; (B)- II; (C)- IV (D)- III
(B) (A)- IV; (B)- III; (C)- I (D)- II
(C) (A)- III; (B)- II; (C)- IV (D)- I
(D) (A)- IV; (B)- I; (C)- II (D)- III
(C)
Q13 If the value of azimuthal quantum number is 3,
the possible values of magnetic quantum
number would be;
(A) 0, 1, 2, 3
(B) 0, – 1, – 2, – 3
(C) 0, ± 1, ± 2, ± 3

(D) (D) ±1, ± 2, ± 3

Q14 The electronic configuration 1s2 2s2 2p1x 2p1y 2p1z

belongs to
(A) Oxygen (B) Nitrogen
(C) Hydrogen (D) Fluorine

Q15 The energy of the electron in the first orbit of

He
+
is −871. 6 × 10−20 J. The energy of the
Q11 Which of the following statements are true:
electron in the first orbit of hydrogen would be:
(A) ‘3s’ orbital is spherically symmetrical with two
(A) −871. 6 × 10−20 J
nodes
(B) −435. 8 × 10−20 J
(B) dx 2
−y
2 has lobes of electron density in XY (C) −217. 9 × 10−20 J
plane along X and Y axis.
(D) −108. 9 × 10−20 J
(C) The radial probability curves of 1s, 3p and 5d
have one, two and three peaks respectively. Q16 Given below are two statements: one is labelled
(D) 3dz has zero electron density in XY plane
2
as Assertion A and the other is labelled as
(A) A, B, D only (B) A, B, C only Reason R:
(C) B, C, D only (D) A, C, D only Assertion A: Two electrons in an atom can have
the same values of three quantum numbers.
Q12 Match the Column – I with Column – II.
Reason R:Two electrons in an atom can be
present in the same shell, sub-shell and orbital
Column I Column II
and have the same spin
In the light of the above statements, choose the
Time period 3

(A) (I) Proportional to

n
correct answer from the options given below:
electron z
2

(A) A is true but R is false.

Velocity of Inversely (B) A is false but R is true.
(B) (II)
electron proportional to n (C) Both A and R are true and R is the correct
explanation of A.
Energy of
(C) (III) Proportional to n2 (D) Both A and R are true but R is NOT the
electron
correct explanation of A.

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Q17 An electron in a hydrogen atom in its ground (A) (B)

2 2
h h
2 2 2 2
4π ma 16π ma
state absorbs energy equal to the ionization
0 0

(C) (D)
2 2
h h

energy of Li+2. The wavelength of the emitted 32π

2
ma
2
0
64π
2
ma
2
0

electron is:
Q22 The wavelength of a spectral line for an
(A) 3.32
−10
× 10 m
electronic transition is inversely related to
(B) 1. 17Å
(A) Number of electrons undergoing transition
(C) 2.32
−9
× 10 m
(B) The number of nutrons in the atom.
(D) 3.33 pm
(C) Velocity of an electron undergoing transition
Q18 The wavelength of the radiation emitted, when a (D) The difference in the energy levels involved
hydrogen atom electron falls from infinity to in the transition
stationary state 1, would be nearly (Rydberg
Q23 The velocity of electron moving in 3rd orbit of
constant = )
7 −1
1. 097 × 10 m
He+ is v. The velocity of electron moving in 2nd
(A) 406 nm
orbit of Li+2 is
(B) 192 nm
(A) 9
v (B) 4
v
(C) 91 nm 4 9

(C) v (D) 2
v
(D) 9.1 × 10−8 nm 3

Q24 The momentum of a particle which has a de

Q19 Calculate the wavelength associated with a
Broglie wavelength of 0.1 nm is (h = 6.6 ×10-34Js)
proton moving at 1.0 × 103 ms−1 (Mass of proton =
(A) 3. 2 × 10−24 −1

1.67 × 10−27 kg and h = 6.63 × 10−34 Js):

Kg ms

(B) 4. 3 × 10−22 Kg ms
−1

(A) 0.032 nm (B) 0.40 nm

(C) 5. 3 × 10−22 Kg ms
−1

(C) 2.5 nm (D) 14.0 nm

(D) 6. 6 × 10−24 Kg ms
−1

Q20 Given below are two statements:

Q25 With increasing principal quantum number, the
Statement I: Emitted radiations will fall in the
energy difference between adjacent energy
visible range when an electron jumps from higher
levels in atoms
level to n = 2 in Li+2 ion.
(A) Decreases
Statement II: Balmer series radiations belong to
(B) Increases
visible range in all H-like atoms.
In the light of the above statements, choose the (C) Remains constant
(D) Decreases for low Z and increases for high Z
most appropriate answer from the options given
below: Q26 'The electron identified by quantum numbers n
(A) Statement I is correct but Statement II is and I
incorrect. (i) n = 4, l = 1 (ii) n = 4, l = 0
(B) Statement I is incorrect but Statement II is (iii) n = 3, l = 0 (iv) n = 3, l = 1
correct. Can be placed in order of increasing energy
(C) Both Statement I and Statement II are (A) (iii) < (iv) < (i) < (ii)
correct. (B) (iii) < (iv) < (ii) < (i)
(D) Both Statement I and Statement II are (C) (i) < (iii) < (ii) < (iv)
incorrect. (D) (iii) < (i) < (iv) < (ii)

Q21 The kinetic energy of an electron in the second Q27 Which of the following has the same number of
Bohr orbit of a hydrogen atom is [a is Bohr 0
s-electrons as the d-electrons in Fe2+?
radius] (A) Li (B) Ca

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(C) N (D) P Q32 In an atom, the total number of electrons having

quantrm numbers n = 4, |m l | = 2 ` and
Q28 Match the column-I with column-II.
is;
1
ms = +
2
Column II
Column I (A) 6 (B) 4
(Nature and no. of
(Orbitals) (C) 8 (D) 2
nodes)
(A) 4d xy (I) One spherical node Q33 Among the following, the energy of 2s orbital is

(B) 3s (II) One nodal plane maximum in;

(A) H (B) Li
Two spherical
(C) 2p x (III) (C) Na (D) K
nodes
(D) 3dxy (IV) Two nodal planes Q34 If the de-Broglie wavelength of an electron in nth
Choose the correct answer from the options Bohr orbit of hydrogen atom is 2πa 0 (a0 is Bohr
given below. radius), then value of n is;
(A) A-III, B-I, C-IV, D-II (A) 2 (B) 3
(B) A-I, B-III, C-II, D-IV (C) 4 (D) 1
(C) A-II, B-III, C-IV, D-I
Q35 The extra stability of Half filled and completely
(D) A-II, B-IV, C-I, D-III
filled subshells is due to
Q29 Given below are two statement: one is labelled (I) Relatively small shielding
as Assertion A and the other is labelled as (II) Smaller coulombic repulsion energy
Reason R: (III) Larger exchange energy
Assertion (A): Wavelength of the first line of the (A) I and II only
Balmer series is more than the first line of Lyman (B) II and III only
series in H-atom. (C) I and III only
Reason (R): ΔE =
hc
(D) I, II and III
λ

In the light of the above statements, choose the

Q36 Which of the following graphs is incorrect
correct answer from the options given below:
regarding photoelectrinc effect?
(A) A is true but R is false.
(A)
(B) A is false but R is true.
(C) Both A and R are true and R is the correct
explanation of A.
(D) Both A and R are true but R is NOT the
correct explanation of A.

Q30 What is the de-Broglie wavelength associated

(B)
with the hydrogen electron in its third orbit.
(A) 9. 96 × 10−10 cm

(B) 9. 96 × 10 −8
cm

(C) 9. 96 × 10 4
cm

(D) 9. 96 × 10 8
cm

Q31 The energy of second excited state of He+ ion is (C)

(A) –6.04 eV (B) –13.6 eV
(C) –3.4 eV (D) –54.4 eV

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(A) 5 (B) 8
(C) 10 (D) 7

Q41 An electron in an atom is moving with a speed of

662 ms–1 with an accuracy of 0.001%. The
certainity with which the position of electron in
(D) atom can be located is; (Given : me = 9.1 × 10–31kg
h = 6.62 × 10–34Js)
(A) 2.45 × 10–4 m
(B) 4.21 × 10–3 m
(C) 8.62 × 10–4 m
(D) 8.74 × 10–3 m

Q37 The wave number for the shortest wavelength Q42 The correct set of quantum numbers for the
transition in the Lyman series of atomic hydrogen outermost electron of Cr (Z = 24) atom is;
is; (A) n = 3, l = 2 , m = –2, s = +
1

(A) R cm –1 (B) n = 4, l = 0 , m = 0, s =–
1

(B) 3R
cm
–1 (C) n = 3, l = 2, m = +2, s =–
1

2
4

(C) 2
cm
–1 (D) n = 4, l = 1, m = –2, s = +
1

2
3R

(D) 4
cm
–1

3R Q43 The increasing order of magnitude of [ Charge(e) ]

mass (m)

Q38 Given below are two statement: one is labelled for the given particles is;
as Assertion A and the other is labelled as (A) n, p, α, e
Reason R: (B) n, α, p, e
Assertion A: For H-atom, energy of 2s and 2p (C) n, p, e, α
orbitals are different. (D) e, p, n, α
Reason R: Shape of 2s and 2p orbitals are
different Q44 Number of photons emitted ber second from a
In the light of the above statements, choose the 33.1 wath hight source (50% effciency) who emits
correct answer from the options given below: light of 300 nm wavelength is;
(A) A is true but R is false. (A) 2.5 × 1019
(B) A is false but R is true. (B) 3.5 × 1020
(C) Both A and R are true and R is the correct (C) 3.5 × 1018
explanation of A. (D) 2.5 × 1021
(D) Both A and R are true but R is not the correct
Q45 Which of the following arrangement is incorrect
explanation of A.
according to pauli's exclusion principle?
Q39 Maximum number of spectral lines possible for a (A) ↑↓ ↑ ↑ ↑

sample containg only two atoms of hydrogen in ns np

(B)
which electron is present is 4th shell is; ↑ ↑ ↑ ↑

ns np
(A) 1 (B) 2
(C) ↑↓ ↑ ↓ ↑
(C) 3 (D) 4
ns np

Q40 Maximum possible ways of exchange for nd5 (D) ↑↓ ↑↓ ↑↓ ↑

configuration is; ns np

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Q46 Given below are two statements: (C) 1 and 1 (D) 2 and 2
Statement (I): splitting of a spectral lines in
Q49 The given graph is corresponds to;
presence of magnetic field is known as zeeman
effect
Statement (II): Boundary surface diagram for a
s-orbital in two dimensions encloses a region in
which probability of finding the electron is about
100%.
In the light of the above statements, choose the
most appropriate answer from the options given (A) 2p-orbital (B) 1s-orbital
below: (C) 3p-orbital (D) 2s-orbital
(A) Statement I is correct but Statement II is
incorrect. Q50 Number of de-Broglie wave made by a bohr
(B) Statement I is incorrect but Statement II is electron in an orbit having maxium magnetic
correct. quantum number +2 is;
(C) Both Statement I and Statement II are correct. (A) 4 (B) 3
(D) Both Statement I and Statement II are (C) 2 (D) 1
incorrect.
Q51 If kinetic energy of a microscopic particle is
Q47 According to Bohr's theory : halved its de-broglie wavelength becomes
–
En = total energy (A) 2 times (B) √2 times
Kn = kinetic energy (C) 4 times (D) 1
times
√2

Vn = poterntial energy
rn = radius Q52 Given below are two statement: one is labelled
as Assertion A and the other is labelled as
List-I List-II
Reason R:
Vn
(A) Kn
=? (I) 0 Assertion: Spin quantum numbers are obtained
by solving schrodinger wave equation.
If r n ∝ En ,
x

(B) (II) –1 Reason: For an atom whose energy does not

x =?
change with time, the schrodinger equation is
If
1 y
∝ z ,
(C) rn
(III) –2 ˆ
Hψ = Eψ
y = ?
In the light of the above statements choose the
angular
correct answer from the options given below:
(D) momentum (IV) 1
(A) A is true but R is false.
in 1s orbital
(B) A is false but R is true.
Choose the correct answer from the options (C) Both A and R are true and R is the correct
given below: explanation of A.
(A) A-III, B-II, C-IV, D-I (D) Both A and R are true but R is not the correct
(B) A-II, B-III, C-IV, D-I explanation of A.
(C) A-II, B-I, C-IV, D-III
(D) A-II, B-III, C-I, D-IV Q53 The angular momentum of an electon in
∘

hydrogen atom, which is at a distance of 4.768 A

Q48 The number of radial nodes in 2s and 3p orbital
for nuculeus is;
respectively are;
(A) h
(B) h

(A) 1 and 0 (B) 2 and 1 2π π

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(C) 3h

2π
(D) 2h

π
(III) line spectra of hydrogen
(IV) Diffraction
Q54 Given below are two statements: (A) I, II and III (B) I, II and IV
Statement (I): With the increasing principal (C) II, III and IV (D) I, III and IV
quantum number, the energy difference between
adjcent energy levels in H-atom increases. Q59 The nucleus of an imaginary ion 48
22
y
3–
contains
Statement (II): The quantum numbers +
1
and x% more neutrons than the number of electrons
2

–
1
for the electron spin represents rotation of in the ion. The value of x in nearly;
2

the electron in clockwise and anticlockwise (A) 6 (B) 4

directions repectively (C) 5 (D) 3
In the light of the above statements, choose the
Q60 Given below are two statement: one is labelled
most appropriate answer from the options given
as Assertion A and the other is labelled as
below:
Reason R:
(A) Statement I is correct but Statement II is
Assertion A : Of all the elements, hydrogen atom
incorrect.
has the simplest line spectrum.
(B) Statement I is incorrect but Statement II is
Reason R : Hydrogen atom has only one
correct.
electron.
(C) Both Statement I and Statement II are correct.
In the light of the above statements, choose the
(D) Both Statement I and Statement II are
correct answer from the options given below:
incorrect.
(A) A is true but R is false.
Q55 The electronic configuration 1s7 is not observed (B) A is false but R is true.
for nitrogen atom because it violates; (C) Both A and R are true and R is the correct
(A) Hund's rule explanation of A.
(B) Aufbou principle (D) Both A and R are true but R is not the correct
(C) Heisenberg uncertainity principle explanation of A.
(D) Pauli's exclusion principle

Q56 The visible spectrum wavelength range is around;

(A) 400 nm to 750 nm.
(B) 100 nm to 350 nm.
(C) 500 nm to 950 nm.
(D) 200 nm to 550 nm.

Q57 The ratio of time periods in second orbit of He+

ion to third orbit of H-atom is;
(A) 2

27
(B) 27

(C) 27
(D) 7

27
4

Q58 Which of the following phenomenon can not be

exsplained by wave nature of electromagnetic
radiation?
(I) Black body radiation.
(II) Variation of heat capacity of solids as a
function of temperature

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Answer Key
Q1 (B) Q31 (A)

Q2 (C) Q32 (B)

Q3 (B) Q33 (A)

Q4 (C) Q34 (D)

Q5 (A) Q35 (D)

Q6 (D) Q36 (D)

Q7 (C) Q37 (A)

Q8 (A) Q38 (B)

Q9 (D) Q39 (D)

Q10 (D) Q40 (C)

Q11 (B) Q41 (D)

Q12 (A) Q42 (B)

Q13 (C) Q43 (B)

Q14 (B) Q44 (A)

Q15 (C) Q45 (C)

Q16 (A) Q46 (A)

Q17 (B) Q47 (A)

Q18 (C) Q48 (C)

Q19 (B) Q49 (D)

Q20 (B) Q50 (B)

Q21 (C) Q51 (B)

Q22 (D) Q52 (B)

Q23 (A) Q53 (C)

Q24 (D) Q54 (D)

Q25 (A) Q55 (D)

Q26 (B) Q56 (A)

Q27 (D) Q57 (A)

Q28 (B) Q58 (A)

Q29 (C) Q59 (B)

Q30 (B) Q60 (C)

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Hints & Solutions

Q1 Text Solution: A. Number of node = n-1
Proton is 1837 times heavier than an electron. B.
Penetration power ∝
1

mass

Q2 Text Solution:
16 2 2 4
O = 1s 2s 2p
8

Q3 Text Solution:
An orbital is a region in space around the nucleus
where the probability of finding an electron is
high (typically ≥ 90%). C.

Q4 Text Solution:
Rutherford's scattering experiment showed that
atom has nucleus.

Q5 Text Solution:
Energy is always absorbed or emitted in whole Q12 Text Solution:
number or multiples of quantum. n
3

T ∝ (A) → I
2
z

Q6 Text Solution: z
v ∝ (B) → II
de-Broglie equation is λ
h n
=
p
2
z
En ∝ (C) → IV
Q7 Text Solution: n
2

(C) r ∝
n
2

(D) → III
z
According to Δx
h
× Δp =
4π

h 6.62×10
−34 Q13 Text Solution:
Δx = =
When l then
−5
Δp×4π 1×10 ×4×3.14 = 3
−30
= 5.27 × 10 m
m = −3, − 2, − 1, 0, + 1, + 2, + 3
.
m = −l to +l including zero.
Q8 Text Solution:
Q14 Text Solution:
Principal quantum no. tells about the size of the 14 2 2 1 1 1
N = 1s 2s 2p x 2p y 2p z
7
orbital.
Q15 Text Solution:
Q9 Text Solution: 2
E + = E1 H
× z
1 He
Pauli's exclusion principle −20
− 871. 6 × 10 = E1H × 4
Q10 Text Solution: −20
E1 H
= −217. 9 × 10 J

Q16 Text Solution:

We know from the Pauli exclusion principle, that
no two electrons in the same atom can not have
same value of all four quantum numbers. This
means each electron in an atom has only one set
of values for n, l, m and s. A is true but R is false..

Q17 Text Solution:

Q11 Text Solution:
(B)

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2
1 2 1 1 a 0 ×n
= RH × Z [ − ] r = = 4a 0
λ 2 2 1
n n
1 2

912 Å 1
2
2 h
2

⇒ λ = KE = m( )
1 1
2 2 2 2
9[ − ] 4π m ×(4a 0 )
2 2
1 ∞
2
h
∴ E = 13. 6 × 9 eV KE =
2 2
32π ma

Ionisation energy of H = 13.6 eV

0

KE of e− = 13.6 × 8 eV
λ =
h
=
h Q22 Text Solution:
mv √2 mkE 1
ΔE ∝
−34
λ
6.6×10
=
√ 2×9.1×10 −31 ×13.6×8×1.6×10 −19 Q23 Text Solution:
−34

=
6.6×10
−24
1. 17 Å
6×10

Q18 Text Solution:

(C)
1 1 1
= R[ − ]
2 2
λ n n
1 2

1 7 −1 1 1
= 1.097 × 10 m [ − ]
2 2
λ 1 ∞

−9
∴ l = 91. 15 × 10

We know,
−9
10 = 1 nm

S o, λ = 91 nm

Q19 Text Solution:

(B)
As, Q24 Text Solution:
−34
h 6.63×10 −10m −9
λ = = = 3. 97 × 10 λ = 0. 1 × 10 m
mυ −27 3
1.67×10 ×1×10
−9 −34
= 0. 397 × 10 m = 0. 40 nm h = 6. 6 × 10

h h
Q20 Text Solution: λ =
mv
=
p

(B) −10 6.6×10

−34

∴ 10 =
2+
In Li , if n1 = 2, and n2 > 2, then the line may p

−24 −1
not be in visible region, as energy of that line is 9 p = 6. 6 × 10 Kg ms

times the corresponding line H atom (which is in Q25 Text Solution:

visible region). Since,
2
Z
Q21 Text Solution: En = −13.6
n
2

As per Bohr’s postulate, E2 − E1 > E3 − E2 > E4 − E3

nh
mvr =
2π Q26 Text Solution:
So, v =
nh
Higher the value of (n +l) more will be energy.
2πmr

1 2 If (n +l) value is same, more than value of n, more

KE = mv
will energy.
2

2
1 nh
So, KE = m( )
2 2πmr
Q27 Text Solution:
2

Fe2+ has 6 d-electrons. P also has 6s-electrons.

a 0 ×n
Since, r =
z

So, for 2nd Bohr orbit of H-atom P(Z=15):1s22s22p63s23p3

Q28 Text Solution:

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A. 4dxy ⇒ n = 4 l = 2 λ is the de Broglie wavelength

Radial node = 4 - 2 -1 = 1 rn ​is the radius of the nth orbit
Angular node = l = 2 n is the orbit number (given as 3)
So, 1 spherical node and 2 Nodal planes
The Bohr radius of hydrogen atom’s first orbit:
B. 3s = n = 3 l = 0 −8
r 1 = 0. 529 × 10 cm
Radial node = 3 - 0 - 1 = 2
Radius of the n-th orbit:
Angular node = 0 2 2 −8
rn = n . r1 = 3 ⋅ 0.529 × 10
⇒ 2 spherical node −8 −8
= 9 ⋅ 0.529 × 10 = 4.761 × 10 cm
C. 2Px
Now, plug into the de Broglie formula:
n = 2, l = 1 2πrn 2π.4.761×10
−8

λ = =
Radial node ⇒ 2 -1 -1 = 0 n 3

−8

Angular node ⇒l = 1 λ =
29.91×10

3
= 9. 97 × 10
−8
cm

⇒ 1 nodal plane Rounded: λ = 9. 96 × 10

−8
cm
D. 3dxy
Q31 Text Solution:
n = 3, l = 2
(A)
Radial nodes = 3 - 2 - 1 = 0 2

En = –13.6 Z eV
Angular nodes = l = 2 n
2

⇒ 2 nodal planes for He+, z = 2

for second excited state : n = 3
Q29 Text Solution: 2
2

E3 = – 13. 6 × =– 6. 04 eV
- It is found that for Balmer series is: 3
2

ΔE1 = E3 − E2 Q32 Text Solution:

- And for lyman series change in energy can be (B)
given as: |m l | = 2 means ml = +2 or –2
ΔE = E2 − E1 ml

- Hence, we can see here that ∴ 4d : –2 –1 0 +1 +2

ΔE > ΔE1
ml

because energy is inversaly proportional to wave

4f : –3 –2 –1 0 +1 +2 +3
length .
for ms only 4 electrons are possible.
1
= + ,
- That is the change in the energy level for the 2

lyman series is greater than that for the change Q33 Text Solution:
in energy level for the Balmer series. (A)
- we know that energy is inversely proportional Energies of the orbitals in the same subshell
to the wavelength, therefore wavelength of decrease with increase in the atomic number
Balmer series is greater than that of Iyman series (Zeff)
(λlyman < λ Balmer ) Q34 Text Solution:
- Hence, option (A), Both A and R are true and R (D)
is the correct explanation of A. is correct . 2πr = nλ
2
Q30 Text Solution: 2π a 0 n = nλ
λ 2πa 0
The de Broglie wavelength λ of an electron in a n =
2πa 0
=
2πa 0
= 1

hydrogen atom’s orbit can be calculated using:

2πrn
Q35 Text Solution:
λ =
n (D)
Where:

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The extra stability of Half filled and completely Q41 Text Solution:
filled subshells is due to relatively small shielding, (D)
smaller coulombic repulsion energy and larger Δx × Δp ⩾
h

4π

exchange energy. Δx × 9. 1 × 10
–31
× 662 ×
0.001

100

Q36 Text Solution: ≥

6.62×10
–34

4×3.14
(D) Δx ⩾ 8. 74 × 10
–3
m
KE = W0 – hv0
Q42 Text Solution:
(B)
Cr(z = 24) : [Ar]3d54s1
for outermost electron (4s1):
n = 4, l = 0, m = 0, s or –
1 1
= +
2 2

Q43 Text Solution:

Q37 Text Solution: (B)
(A) ⋅ for neutron, e = 0 so, m
e
= 0 (minimum)
1 2 1 1 ⋅ for electron, m is minimum so, m
e
is maximum
ν̄ = = RZ ( – )
q
for proton,
2 2 e
λ n1 n2
⋅ =
Z = 1, n1 = 1, n2 = ∞
m M
2q q
for α,
e
⋅ = =
2 1 1 m 4M 2M
ν̄ = R(1) ( – )
Q44 Text Solution:
2 2
1 ∞

= R cm–1
(A)
Q38 Text Solution: E = x hv
(B) 33. 1 ×
50
=
x×6.62×10
–34
×3×10
8

100 300×10
–9

Energy of orbitals for H-atom:

x = 2.5 × 1019
1s < 2s = 2p < 3s = 3p = 3d
s-orbital : spherical Q45 Text Solution:

p-orbital : Dumb-bell (C)

Pauli exclusion principle can also be stated as :
Q39 Text Solution:
only two electrons may exist in the same orbital
(D)
and these electrons must have opposite spin".

Q46 Text Solution:

(A)
Boundary surface diagram for a s-orbital in two
dimensions encloses a region in which probability
Maximum spectral lines = 3 + 1 = 4 of finding the elctron is about 90%
Q40 Text Solution: Q47 Text Solution:
(C) (A)
If Kn = E
then, Vn = –2E
En = – E
Vn 2E
∴ =– =– 2
Kn E
2 2
z –z
rn α , En α
2 2
n n
2 2
rn z –n
∴ α ×
En 2 2
n z

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r n α– En
–1
mechanical spin states which have no classical
∴ x = –1 analogous.
2
n
rn α
z Q55 Text Solution:
1 z
∴
rn
α
n
2 (D)
∴ y = 1 Pauli's exclusion principle : No two electrons in an
angular momument for 1s-orbital atom cam have the same set of for quantum
−− −−−−
numbers.
h
= √l(l + 1) = 0
2π

Q48 Text Solution: Q56 Text Solution:

(C) (A)
radial node = n-l-1 Visible spectrum wavelength range is around
for 2s orbital, radial node = 2-0-1=1 400 nm to 750 nm
for 3p orbital, radial node = 3-1-1=1 Q57 Text Solution:
Q49 Text Solution: (A)
(D)
3

Time period (T) α

n
2
z

2s-orbital has one node. T1

=
2
3

×
1
3

=
2

T2 2 3 27
2 3

Q50 Text Solution:

Q58 Text Solution:
(B)
(A)
for l = 2, ml (maximum) = 2
Diffraction and interference can be explained by
for l = 2, n = 3
wave nature of electromagnetic radiations.
∴ No of de-Broglie wave = n = 3
Q59 Text Solution:
Q51 Text Solution:
(B)
(B)
h
No. of neutrons = 48 –22 = 26
λ =
√2m KE No. of electrons = 22 + 3 = 25
−−− −−−−
λ2 KE 1 –
% of extra neutrons =
K 26−25
= √ = = √2 × 100 = 4%
λ1 KE 2 √ K
25
( )
2

Q60 Text Solution:

Q52 Text Solution:
(C)
(B)
Both A and R are true and R is the correct
Solution of schrodinger wave equation gives only
explanation of A.
n, l and m.

Q53 Text Solution:

(C)
2

r = 0.529 × n

z
A°
2

4.768 = 0.529 × n

n=3
angular momentum = nh

2π
=
3h

2π

Q54 Text Solution:

(D)
⋅ for H-atom : E2-E1 > E3-E2 > E4-E3...
⋅ The quantum numbers +
1

2
and –
1

2
for the
electron spin represents two quantum

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