4 ch0 1c_msc_20151501

Mark Scheme (Results)
January 2015
Pearson Edexcel International GCSE in
Chemistry (4CHO) Paper 1C
Pearson Edexcel Certificate in
Chemistry (KCH0) Paper 1C

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January 2015
Publications Code UG040479
All the material in this publication is copyright
© Pearson Education Ltd 2015

General Marking Guidance
 All candidates must receive the same treatment. Examiners must mark
the first candidate in exactly the same way as they mark the last.
 Mark schemes should be applied positively. Candidates must be rewarded
for what they have shown they can do rather than penalised for
omissions.
 Examiners should mark according to the mark scheme not according to
their perception of where the grade boundaries may lie.
 There is no ceiling on achievement. All marks on the mark scheme should
be used appropriately.
 All the marks on the mark scheme are designed to be awarded.
Examiners should always award full marks if deserved, i.e. if the answer
matches the mark scheme. Examiners should also be prepared to award
zero marks if the candidate’s response is not worthy of credit according to
the mark scheme.
 Where some judgement is required, mark schemes will provide the
principles by which marks will be awarded and exemplification may be
limited.
 When examiners are in doubt regarding the application of the mark
scheme to a candidate’s response, the team leader must be consulted.
 Crossed out work should be marked UNLESS the candidate has replaced
it with an alternative response.

Question
number
Answer Notes Marks
1 a 1
b i A (an electron) 1
ii B (a neutron) 1
iii B (electrons and protons) 1
c isotopes
3atomic numbers
mass numbers
Total 7 marks

Question
number
Answer Notes Marks
2 a i tick for P = chromatography 1
tick for Q = fractional distillation 1
tick for R = filtration 1
tick for S = simple distillation 1
ii R Accept (sand from a mixture of) sand and water 1
b M1 for B in first box AND D in last box
M2 for A in box 3 AND C in box 4
1
M2 dependent on M1 correct 1
Total 7 marks

Question
number
Answer Notes Marks
3 a burns with a pop/squeak
OR
use burning/lit splint/flame to see if pop/squeak
Must be reference to test and result
Reference to splint/match with no indication of flame
is not enough
Ignore flame extinguished
Reject reference to glowing splint
Squeaky pop test on its own is not enough
1
b i anhydrous/white copper sulfate Ignore colourless
Accept correct formula
Incorrect formula (eg CuSO) counts as near miss
2
turns blue
OR
anhydrous/blue cobalt chloride Accept correct formula
Incorrect formula (eg CoCl) counts as near miss
turns pink
M2 DEP on M1 or near miss
ii measure boiling point / freezing point Accept boil it / freeze it
Ignore heat
2
100 (°C) / O (°C) Value must match property
Ignore units
Answers such as boils/distils at 100 °C
/ freezes at 0 °C score M2 only

Question
number
Answer Notes Marks
3 b iii cross by
carbon dioxide from the air reacts to cause the
cloudiness
If 3 boxes crossed then max 1
If 4 or more boxes crossed then 0
2
cross by
the cloudiness is caused by the formation of a
white precipitate
Total 7 marks

Question
number
Answer Notes Marks
4 a i reactants labelled wrong way round / OWTTE Accept manganese(IV) oxide is the solid OR
hydrogen peroxide is the liquid
Ignore just manganese(IV) oxide/hydrogen
peroxide is wrongly labelled
1
ii bung / cork Accept stopper
Ignore plug
1
iii to prevent oxygen/gas from escaping
OR
(without a bung), oxygen/gas would
escape/could not be collected
Do not penalise wrong gas, such as
hydrogen
1
b use a (gas) syringe Accept collect in gas jar by displacement of
air in place of syringe
1
c 2 2 (1) Accept multiples and fractions 1

Question
number
Answer Notes Marks
4 d (a substance that) increases rate of reaction /
speeds up reaction / decreases time of reaction
Ignore change/decrease in rate
Ignore references to element / compound
1
is (chemically) unchanged (at the end)
OR
mass does not change
Accept is not used up / does not change
Accept reference to lowering activation
energy
Ignore reference to alternative route
Ignore references to yield
Ignore reference to not reacting or taking
part in reaction
Ignore refs to being physically unchanged
Ignore references to starting reaction
Reject reference to providing/increasing
energy for M2
Reject reference to incorrect statement
such as removes impurities for M2
1
e (approximately) vertical line between hydrogen
peroxide and top of curve
AND
labelled activation energy / Ea
ignore arrowheads on vertical line 1
curve starting from hydrogen peroxide line and
ending at water + oxygen line
AND
peak below peak of original curve
Accept near misses, such to and from
words
Accept curve leaving or joining original
curve
Do not penalise more than one peak
1
Total 9 marks

Question
number
Answer Notes Marks
5 a i 4 1
ii B (hydrated) 1
b i aluminium hydroxide AND sodium sulfate Accept in either order
Ignore formulae / oxidation numbers
1
ii smothers/blankets the fuel/fire
/ sinks onto to fuel/fire
Accept high density / higher density than
air/oxygen
Ignore heavier than air/oxygen
1
(therefore) prevents oxygen/air from reaching
the fuel/fire
Accept does not support combustion
Ignore carbon dioxide does not burn
1
c i Al(OH)3 has (s) / is solid /is insoluble / its ions
not free / its ions not released
1
H2SO4 has (aq) / is a solution
AND (H+
) ions are released
1
ii B (5.5) 1
Total 8 marks

Question
number
Answer Notes Marks
6 a C (diffusion) 1
b ammonia (moves more quickly)
AND
it travels further /white solid is close(r) to the
HCl end / further from the NH3 end
Ignore reference to solution
Ignore reverse argument for HCl
Ignore references to reacting more quickly
1
c i sodium hydroxide / NaOH Accept other suitable alkalis 1
ammonia / NH3 Reject ammonium 1
blue Reject all other colours
M3 DEP on M2 or near miss
1
ii to remove carbonate (ions)/sulfite (ions) Accept to prevent other ions interfering / to
prevent other precipitates from forming
Ignore to make sure other reactions do not
occur
1
iii silver nitrate / AgNO3 1
silver chloride / AgCl 1
If both name and formula given, both must
be correct
Total 8 marks

Question
number
Answer Notes Marks
7 a fractional distillation/fractionating
column/tower
Reference to fractional / fractionating
needed
Ignore references to fracking
4
(crude oil) heated/vaporised / boiled
cooler at top/hotter at bottom/idea of
temperature gradient
fractions condense /separate at different
heights/levels
Accept components / hydrocarbons /
compounds / gases
fractions have different boiling points/ranges Accept separate at different temperatures
Ignore references to melting point
Any four for 1 mark each
If any reference to cracking, MAX 2
M1 - M4 can be scored from suitably
labelled diagram

Question
number
Answer Notes Marks
7 b i CnH2n+2 Do not penalise inappropriate spaces or
failure to show 2 and n as subscripts
1
ii same/similar chemical
properties/reactions/behaviour/characteristics
Ignore specific examples such as react with
oxygen
Ignore similar (type of) reactivity
Do not penalise reference to trends
2
gradation / gradual change / trend / increase /
decrease of physical properties
Accept reference to specific property, eg
boiling point
Reject same / similar physical properties
Ignore variable physical properties
same functional group Ignore reference to specific group
(neighbouring) members differ by CH2
Any two for 1 each
Accept two answers on one answer line
Ignore any reference to properties not
specified as physical or chemical
c (1) 5 3 4 Accept multiples and fractions 1
d i carbon monoxide / CO 1
ii reduces capacity of blood to carry oxygen /
OWTTE
Accept correct explanation involving
haemoglobin
Ignore references to carbon monoxide
reacting with blood / red blood cells
1
iii nitrogen/N2 AND oxygen/O2 Accept in either order
Ignore N and O
1

Question
number
Answer Notes Marks
7 e 1
1
Penalise missing H atoms once only
provided all bonds are correctly shown
Penalise missing bonds in both structures

Question
number
Answer Notes Marks
7 f i setting out correct division of each % by Ar
OR
4.4, 11.1 and 1.1
Award 0/3 if division by any atomic
numbers / wrong way up / multiplication
used / wrong atomic mass (eg 16 for C)
Do not penalise roundings and minor
misreads of % values, eg 11 for H and 36.5
for S
If molecular mass used for H, no M1, but
can award M2 and M3
but no CQ in ii
Using 2 for H gives C4H5S
Working required for this answer
1
division by smallest /ratio of 4 : 10 : 1 M2 subsumes M1 1
C4H10S(1) Accept elements in any order
Award 3 for correct final answer with no
working
No ECF from M2
1
Accept use of 90 from ii,
i.e. 90 × 0.533 = 48 etc scores M1
ratio scores M2, answer scores M3
ii C4H10S(1) Accept elements in any order
No other answer acceptable
1
Total 17 marks

Question
number
Answer Notes Marks
8 a hydrogen / H2 Ignore H 1
b only single bonds (between carbon atoms)
/single bond(s) between carbon atoms
ignore between C and H
Accept no double bond(s) / no multiple
bond(s)
Ignore answers that refer to numbers of
hydrogens
1
c i Accept Br atoms in any position provided one
on each carbon
1
ii C (the product of the reaction is colourless) 1
d M1 for 4 × C AND 6 × H and 2 × CH3
M2 for extension bonds and two CH3 groups
on alternate carbon atoms (can be both above
or both below carbon chain)
M2 DEP on M1
Do not penalise bonds to H of CH3
Ignore brackets and subscripted n
If any double bond shown, then 0/2
2
e Reject any extension bonds
Ignore bond angles
Do not penalise more than one correct
structure
1

Question
number
Answer Notes Marks
8 f i (polymer) breaks down / decomposes /
decays
Do not penalise compound / object /
molecule / substance in place of polymer
Reject element in place of polymer
Ignore rots / degrades / digests /
disintegrate
If reference to not breaking down etc, only
M2 can be awarded
1
by bacteria / microbes / microorganisms Ignore naturally / enzymes 1
ii inert / unreactive / OWTTE Ignore do not react with named chemical
Ignore references to bond strengths / bond
breaking
1
Total 10 marks

Question
number
Answer Notes Marks
9 a C (lithium reacts with water to form an alkali) 1
b A (have the same number of outer shell electrons) 1
c (similar)
bubbles / fizzing / effervescence
OR
moves / darts / floats
OR
gets smaller / disappears
Accept gas given off
/evolved/formed/produced
Accept hydrogen gas
Ignore identity of gas
Accept dissolves
1
potassium shows a flame / sparks / explodes
OR
potassium melts / forms ball
Accept reverse arguments for lithium 1
d K2O Accept K2O2 and KO2
Reject KO
1
KCl 1
If formula shown as product of an
equation, ignore reactants and
balancing
Ignore coefficients
e s l aq g 1
f 85 AND 87 calculated (even if not identified) Accept 37+48 and 37+50 1
(85 × 0.72) + (87 × 0.28) = 85.6 Correct final answer = 2 marks
85.5 or 85.56 = 1 mark
1
No ECF from incorrect mass numbers
Ignore units
Total 9 marks

Question
number
Answer Notes Marks
10 a mix / add / react (the two) solutions / salts
together
Ignore references to volumes
4stir Accept swirl
filter Accept description of filtration
wash (with water)
suitable method of drying eg warm / heat / place in oven / leave on
window ledge / leave to dry / dry with filter
paper or kitchen towel
Not just dry
Any four above for 1 mark each
If M3 not scored then M4 and M5 cannot be
awarded
If description of evaporation of solution, then
M4 and M5 cannot be awarded
identifying two suitable pieces of apparatus Any two of
 beaker / flask / test tube (for mixing)
 (glass) rod (for stirring)
 (filter) funnel/paper (for separation)
1
Reference to filter paper or filter funnel scores
M3 and counts as one of M6
If any other substance added, then MAX 4

Question
number
Answer Notes Marks
10 b i B (the products are both elements) 1
ii electrons on wrong side / should be on right
/should be – 2e–
Accept + in front of electrons (should be —) 1
2Br should be Br2 Accept product is shown as a bromine atom
/ should be shown as a bromine molecule
1
Equation correctly rewritten scores both marks
iii ions stop moving / ions not free to move
OR
electrons stop moving (through wires)
Ignore liquid becomes solid / no free ions
Accept electric current in place of electrons
Reject implication that electrons stop flowing
through liquid
1
Total 9 marks

Question
number
Answer Notes Marks
11 a i pipette 1
ii pink Ignore purple
Accept red
1
colourless Ignore clear
Ignore white
1
Award 1 mark for both colours correct in wrong order
b (after) 23.15 1
(before) 1.40 1
(added) 21.75 CQ on before and after readings 1
Award 1 mark for both readings correct but in wrong
order
All values must be to 2 dp
Penalise answers to other than 2 dp once only
c i ticks in columns 3 and 4 1
ii 21.10 + 21.20
2
CQ on any combination of ticked results
If no results ticked, award M1 if only columns 3 and 4
averaged
If only 1 result ticked, then no marks can be awarded in
(c)
1
21.15 CQ on results averaged - see separate table
Answer should be to 2 dp, except that trailing zero not
needed
Correct final answer without working scores 2
1

Question
number
Answer Notes Marks
11 d i 0.300 × 200
1000
1
0.06(00) (mol) Correct final answer scores 2 marks 1
60 scores 1 mark in di
No marks for answers such as 0.6 / 6 / 600
clip
ii di ÷ 2 / 0.03(00) (mol) 1
clip
iii Mr = 98 Award 1 mark for 98 anywhere in iii 1
2.94 (g) ECF from incorrect Mr
Moles CQ on ii
Must be 2 or more sig figs
1
Total 14 marks

Question
number
Answer Notes Marks
12 a mass / amount Accept weight
Ignore number of marble chips
1
surface area / size / volume Ignore length / width / height / thickness /
shape / type
1
Ignore temperature / purity / density
b gas/carbon dioxide escapes / OWTTE Ignore references to solid dissolving
Ignore references to acid spray / vapour
Do not penalise incorrectly named gas (eg
hydrogen)
1
c prevents loss of acid (spray)/liquid Ignore references to evaporation / water vapour
/ spilling of liquid
Reject references to stopping gases/marble
chips escaping
1
d i 210 (s) 1
some indication of mark on curve
OR
vertical line from 50% / horizontal line
from 210 s
Mark M1 and M2 independently 1
ii B (the loss of mass was greater than 1.0g 1
e 1 ÷ 210 Accept any time value in range 200 - 210 1
evaluation of M1 / 0.00476 Accept answer in range 0.004- 0.005
Accept any number of sig fig
1

Question
number
Answer Notes Marks
12 f
all five points plotted to nearest gridline
Deduct 1 mark for each error up to max
2
2
straight line of best fit Line need not be extrapolated to origin
If line not extrapolated, it should go to
the origin if extrapolated
Must be drawn with a ruler
CQ on candidate’s plotted points
1

Question
number
Answer Notes Marks
12 g more particles (in a given volume) Accept ions
Reject atoms / molecules
Accept quantitative answer such as twice as
many particles when concentration doubles
1
more collisions (between particles) /
OWTTE
1
per unit time / OWTTE more frequent collisions scores M2 and M3
Ignore greater chance/likelihood of collisions
1
Accept reverse argument if clear that decreasing
concentration is being considered
MAX 1 if any reference to particles moving faster
/ having more energy
Total 15 marks

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4 ch0 1c_msc_20151501

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