DR.S.BLESSED SINGH
PROFESSOR & HOD
Introduction
 We could live about a month without food. We could
even live for several days without water. But without
air, we cannot live more than a few minutes.
 We might foul the air so badly in some places that it
could become unfit to breath. In some areas, the air
is so bad that people become sick from breathing it,
and some even die because of it.
 The World Health Organization estimates that a
billion people live in places where the air is
substandard and that air pollution kills 8,000 people
a day worldwide. About 90% of the deaths occur in
developing countries.
What is air pollution?
What is air pollution?
 Air pollution is the contamination of air by the
discharge of harmful substances.
Indoor Pollutions
There are many sources of
indoor air pollution.
 Tobacco smoke
 cooking
 heating appliances
 vapors from building
materials, paints,
furniture
 other materials within
the home that emit
unhealthy chemicals
Explanation
 While air pollution is thought to be a problem related
to outdoor air, the same pollutants can be found
indoors. We spend up to 60% of our time indoors and
our homes are not always the safe places we would
like them to be.
 These chemicals, some of which are called volatile
organic compounds (VOC) can cause ill health and
they are found in carpets, chipboard, furnishing
fabrics, clothing pesticides, cleaning products,
toiletries, cosmetics and hobby products.
Outdoor Pollutions
 automobile exhaust
 industrial emissions
Natural Pollution
 Wildfires
 Windblown dust
 Volcanic eruptions
 Burning of fossil
fuels (Chemistry
Book)
Explanation-Cars
 Cars are wonderful things. You can go where you want and when. You can
travel with friends or family in a weatherproof lounge-room on wheels that
whisks you along far faster than you could run. But they do create air pollution.
 Lead in petrol
 Photochemical smog
 discomfort.
 Catalytic converters
 But as more and more cars take to the road, even these much cleaner cars are
still a major source of pollution. Also, using a precious metal like platinum
makes the converters very expensive to produce.
Explanation-Natural Pollution
 Even before there were people, there were air
pollution. Wildfires, windblown dust, and volcanic
eruptions added pollutants to the atmosphere, and
they still do so. Volcanoes spew ash and poisonous
gases into the atmosphere.
 Dust storms, especially in arid regions, add massive
amounts of particulate matter to the atmosphere.
Explanation-Burning of Coal
 Air Pollution in China
 As China strives to become an industrial power, its people are paying a
heavy price in pollution. Coal burning supplies about ¾ of China’s
commercial energy needs. The coal has a high sulfur content, and
emission controls are often inadequate. As a result, levels of sulfur
dioxide and particulate matter are among the highest in the world.
About half of China’s largest cities have SO2 levels above the WHO
guidelines. Some cities, such as Lanzhou and Taiyuan, have levels
almost 10 times the WHO standard. All but 2 of 82 cities monitored
exceeded WHO guidelines for particular matter.
 China’s growing fleet of motor vehicles also contributes to air pollution
problems. Most vehicles are operated in large cities, and because few
have effective emission controls, they contribute heavily to the smog in
these cities.
 China is beginning to attack the problem by closing heavily polluting
factories in some larger metropolitan areas. The Chinese government
has also invested in gas and in cleaner, more efficient briquettes as
replacements for raw coal as a fuel for domestic cooking and heating.
Major Air Pollutants
 Carbon Monoxide (CO) CO Carbon Dioxide
(CO2)
 Chlorofluorocarbons (CFCs)
 Hazardous Air Pollutants (HAPs)
 Ozone (O3 )
 Nitrogen Oxide (NOx)
 Atmosphere as a Resource
 Types and Sources of Air Pollution
 Major Classes of Air Pollutants
 Sources of Outdoor Air Pollutants
 Urban Air Pollution
 Effects of Air Pollution
 Controlling Air Pollution in the US
Atmosphere as a Resource
 Atmospheric
Composition
 Nitrogen 78.08%
 Oxygen 20.95%
 Argon 0.93%
 Carbon dioxide 0.04%
 Ecosystem services
 Blocks UV radiation
 Moderates the climate
 Redistributes water in
the hydrologic cycle
Types and Sources of Air Pollution
 Air Pollution
 Chemicals added to the atmosphere by natural
events or human activities in high enough
concentrations to be harmful
 Two categories
 Primary Air Pollutant
 Harmful substance that is emitted directly into the
atmosphere
 Secondary Air Pollutant
 Harmful substance formed in the atmosphere when a
primary air pollutant reacts with substances normally
found in the atmosphere or with other air pollutants
Major Air Pollutants
AIR POLLUTION. of community  health nursing II
Particulate Material
 Thousands of different solid or liquid particles
suspended in air
 Includes: soil particles, soot, lead, asbestos, sea
salt, and sulfuric acid droplets
 Dangerous for 2 reasons
 May contain materials with toxic or carcinogenic
effects
 Extremely small particles can become lodged in
lungs
Nitrogen and Sulfur Oxides
 Nitrogen Oxides
 Gases produced by the chemical interactions
between atmospheric nitrogen and oxygen at high
temperature
 Problems
 Greenhouse gases
 Cause difficulty breathing
 Sulfur Oxides
 Gases produced by the chemical interactions
between sulfur and oxygen
 Causes acid precipitation
Carbon Oxides and Hydrocarbons
 Carbon Oxides
 Gases carbon monoxide (CO) and carbon dioxide
(CO2)
 Greenhouse gases
 Hydrocarbons
 Diverse group of organic compounds that contain
only hydrogen and carbon (ex: CH4- methane)
 Some are related to photochemical smog and
greenhouse gases
Ozone
 Tropospheric Ozone
 Man- made pollutant in the lower atmosphere
 Secondary air pollutant
 Component of photochemical smog
 Stratospheric Ozone
 Essential component that screens out UV radiation
in the upper atmosphere
 Man- made pollutants (ex: CFCs) can destroy it
Sources of Outdoor Air Pollution
 Two main sources
 Transportation
 Industry
 Intentional forest
fires is also high
Causes of Air Pollution
Asthma and Air Pollution
Urban Air Pollution
 Photochemical Smog (ex: Los Angeles below)
 Brownish-orange haze formed by chemical reactions
involving sunlight, nitrogen oxide, and hydrocarbons
Formation of Photochemical Smog
Sources of Smog in Los Angeles
Case-In-Point Air Pollution in Beijing and
Mexico City
 Beijing (left)
 Mexico City (above)
Effects of Air Pollution
 Low level exposure
 Irritates eyes
 Causes inflammation of respiratory tract
 Can develop into chronic respiratory diseases
Health Effects of Air Pollution
 Sulfur Dioxide and Particulate material
 Irritate respiratory tract and impair ability of
lungs to exchange gases
 Nitrogen Dioxides
 Causes airway restriction
 Carbon monoxide
 Binds with iron in blood hemoglobin
 Causes headache, fatigue, drowsiness, death
 Ozone
 Causes burning eyes, coughing, and chest
discomfort
Effects of Air Pollution
Effects of Air Pollution
 Global Warming– the increased concentration of
carbon dioxide and other greenhouse gases in the
atmosphere lead to rise in earth’s average
temperature.
 Ozone
 Greenhouse Effect
 Acid Rain comes mainly from sulfur dioxide emitted
from power plants and smelters and from nitrogen
oxides discharges from power plant and
automobiles. These acids are often carried far before
falling as rain or snow. Acids corrode metals and
even erode stone buildings and statues.
Children and Air Pollution
 Greater health threat to children than adults
 Air pollution can restrict lung development
 Children breath more often than adults
 Children who live in high ozone areas are more
likely to develop asthma
Controlling Air Pollution in US
 Smokestacks with
electrostatic precipitator
(right)
Without Electrostatic
Without Electrostatic
precipitator
precipitator
With Electrostatic
With Electrostatic
precipitator
precipitator
Controlling Air Pollution in
the US
 Smokestacks with scrubbers
(right)
 Particulate material can also
be controlled by proper
excavating techniques
Controlling Air Pollution in the US
 Phase I Vapor Recovery System for gasoline
The Clean Air Act
 Authorizes EPA to set
limits on amount of
specific air pollutants
permitted
 Focuses on 6 pollutants:
 lead, particulate matter,
sulfur dioxide, carbon
monoxide, nitrogen
oxides, and ozone
 Act has led to decreases!
AIR POLLUTION. of community  health nursing II
Ozone Depletion in Stratosphere
 Ozone thinning/hole
 First identified in 1985 over
Antarctica
 Caused by
 human-produced bromine
and chlorine containing
chemicals
 Ex: CFCs
Ozone Depletion in Stratosphere
 Hole over Antarctica requires two conditions:
 Sunlight just returning to polar region
 Circumpolar vortex- a mass of cold air that
circulates around the southern polar region
 Isolates it from the warmer air in the rest of the planet
 Polar stratospheric clouds form
 Enables Cl and Br to destroy ozone
Effects of Ozone Depletion
 Higher levels of UV-
radiation hitting the
earth
 Eye cataracts
 Skin cancer (right)
 Weakened immunity
 May disrupt ecosystems
 May damage crops and
forests
Recovery of Ozone Layer
 Montreal Protocol (1987)
 Reduction of CFCs
 Started using HCFCs (greenhouse gas)
 Phase out of all ozone destroying chemicals is
underway globally
 Satellite pictures in 2000 indicated that ozone
layer was recovering
 Full recovery will not occur until 2050
Acid Deposition
 Sulfur dioxide and nitrogen dioxide emissions
react with water vapor in the atmosphere and
form acids that return to the surface as either
dry or wet deposition
 pH scale
How Acid Deposition Develops
Effects of Acid Deposition
 Declining Aquatic Animal
Populations
 Thin-shelled eggs prevent
bird reproduction
 Because calcium is
unavailable in acidic soil
 Forest decline
 Ex: Black forest in
Germany (50% is
destroyed)
Acid Deposition and Forest Decline
Air Pollution Around the World
 Air quality is deteriorating
rapidly in developing countries
 Shenyang, China
 Residents only see sunlight a few
weeks each year
 Developing countries have older
cars
 Still use leaded gasoline
 5 worst cities in world
 Beijing, China; Mexico City, Mexico;
Shanghai, China; Tehran, Iran; and
Calcutta, India
Long Distance Transport of Air Pollutants
Indoor Air
Pollution
 Pollutants can be
5-100X greater
than outdoors
 Most common:
 Radon, cigarette
smoke, carbon
monoxide,
nitrogen dioxide,
formaldehyde
pesticides, lead,
cleaning solvents,
ozone, and
asbestos
Indoor Air Pollution - Radon
WHO Global Urban Ambient Air Pollution Database (update 2016)
 More than 80% of people living in urban areas that monitor air
pollution are exposed to air quality levels that exceed the World Health
Organization (WHO) limits. While all regions of the world are affected,
populations in low-income cities are the most impacted.
 According to the latest urban air quality database, 98% of cities in low-
and middle income countries with more than 100 000 inhabitants do
not meet WHO air quality guidelines. However, in high-income
countries, that percentage decreases to 56%.
 In the past two years, the database – now covering 3000 cities in 103
countries – has nearly doubled, with more cities measuring air
pollution levels and recognizing the associated health impacts.
 As urban air quality declines, the risk of stroke, heart disease, lung
cancer, and chronic and acute respiratory diseases, including asthma,
increases for the people who live in them.
The WHO urban air quality database is currently being updated. If you are an official air quality data
provider either at country or city level, please use this template to submit the data.
Emissions to air
Emissions to air and noise emissions arise during the manufacture of cement.
Furthermore with regard to the use of waste, odors can arise, e.g. from the storage
and handling of waste. In this section, ranges of air pollutant emissions are
presented for the process of cement production, including other process steps, such
as the storage and handling of, e.g. raw materials, additives and fuels including
waste fuels. The IPPC Directive [7] includes a general indicative list of the main air-
polluting substances to be taken into account, if they are relevant for fixing
emission limit values. Relevant to cement manufacture including the use of waste
are: · oxides of nitrogen (NOx) and other nitrogen compounds, · sulphur dioxide
(SO2) and other sulphur compounds dust, · total organic compounds (TOC)
including volatile organic compounds (VOC), · polychlorinated dibenzo-p-dioxins
and dibenzofurans (PCDDs and PCDFs), · metals and their compounds, · hydrogen
fluoride (HF), · hydrogen chloride (HCl), · carbon monoxide (CO). Not mentioned on
the list, but considered to be relevant for cement production is carbon dioxide
(CO2). Furthermore, emissions of NH3 may be considered to be relevant, especially
when using secondary measures/techniques for NOx reduction. The main emissions
from the production of cement are emissions to air from the kiln system. The main
constituents of the exit gases from a cement kiln are nitrogen from the combustion
air; CO2 from calcination of CaCO3 and combustion of fuel; water vapour from the
combustion process and from the raw materials; and excess oxygen.
Dioxin Facts
 Dioxins and furans are the most toxic chemicals
known to science
 Dioxins cause infertility, learning disabilities,
endometriosis, birth defects, sexual reproductive
disorders, damage to the immune system, cancer
and more.
 93% of dioxin exposure is from eating meat and
dairy products.
Pollutants Released by Cement
Kilns
 Carbon dioxide (global warming gas)
 Acid Gases, Nitrogen Oxides, Sulfur Dioxide,
Particulate Matter
 19 heavy metals, including lead, mercury,
cadmium and chromium VI
 Products of Incomplete Combustion (PICs),
including dioxins, furans and Polycyclic
Aromatic Hydrocarbons (PAHs)
What’s in Cement Kiln Dust?
 Calcium Oxide
 Toxic metals: Arsenic, Chromium, Cadmium,
Antimony, Barium, Beryllium, Lead, Silver,
Mercury, Thallium, Selenium, Nickel
 Dioxin, Furans
 Cement Kiln Dust More Toxic when Burning
Hazardous Waste
Hazardous Waste Fuels vs. Traditional Fuels
 Hazardous Waste either emitted into air,
absorbed into CKD, or into clinker (final
product)
 Using hazardous waste produces 104% more
cement kiln dust by volume
 Lead concentrations 250% higher
 Cadmium concentrations 150% higher
 Chromium concentrations 50% higher
 Selenium concentrations 100% higher
 700 times more dioxin
AIR POLLUTION. of community  health nursing II
AIR POLLUTION. of community  health nursing II
AIR POLLUTION. of community  health nursing II
AIR POLLUTION. of community  health nursing II

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AIR POLLUTION. of community health nursing II

  • 2. Introduction  We could live about a month without food. We could even live for several days without water. But without air, we cannot live more than a few minutes.  We might foul the air so badly in some places that it could become unfit to breath. In some areas, the air is so bad that people become sick from breathing it, and some even die because of it.  The World Health Organization estimates that a billion people live in places where the air is substandard and that air pollution kills 8,000 people a day worldwide. About 90% of the deaths occur in developing countries.
  • 3. What is air pollution?
  • 4. What is air pollution?  Air pollution is the contamination of air by the discharge of harmful substances.
  • 5. Indoor Pollutions There are many sources of indoor air pollution.  Tobacco smoke  cooking  heating appliances  vapors from building materials, paints, furniture  other materials within the home that emit unhealthy chemicals
  • 6. Explanation  While air pollution is thought to be a problem related to outdoor air, the same pollutants can be found indoors. We spend up to 60% of our time indoors and our homes are not always the safe places we would like them to be.  These chemicals, some of which are called volatile organic compounds (VOC) can cause ill health and they are found in carpets, chipboard, furnishing fabrics, clothing pesticides, cleaning products, toiletries, cosmetics and hobby products.
  • 7. Outdoor Pollutions  automobile exhaust  industrial emissions Natural Pollution  Wildfires  Windblown dust  Volcanic eruptions  Burning of fossil fuels (Chemistry Book)
  • 8. Explanation-Cars  Cars are wonderful things. You can go where you want and when. You can travel with friends or family in a weatherproof lounge-room on wheels that whisks you along far faster than you could run. But they do create air pollution.  Lead in petrol  Photochemical smog  discomfort.  Catalytic converters  But as more and more cars take to the road, even these much cleaner cars are still a major source of pollution. Also, using a precious metal like platinum makes the converters very expensive to produce.
  • 9. Explanation-Natural Pollution  Even before there were people, there were air pollution. Wildfires, windblown dust, and volcanic eruptions added pollutants to the atmosphere, and they still do so. Volcanoes spew ash and poisonous gases into the atmosphere.  Dust storms, especially in arid regions, add massive amounts of particulate matter to the atmosphere.
  • 10. Explanation-Burning of Coal  Air Pollution in China  As China strives to become an industrial power, its people are paying a heavy price in pollution. Coal burning supplies about ¾ of China’s commercial energy needs. The coal has a high sulfur content, and emission controls are often inadequate. As a result, levels of sulfur dioxide and particulate matter are among the highest in the world. About half of China’s largest cities have SO2 levels above the WHO guidelines. Some cities, such as Lanzhou and Taiyuan, have levels almost 10 times the WHO standard. All but 2 of 82 cities monitored exceeded WHO guidelines for particular matter.  China’s growing fleet of motor vehicles also contributes to air pollution problems. Most vehicles are operated in large cities, and because few have effective emission controls, they contribute heavily to the smog in these cities.  China is beginning to attack the problem by closing heavily polluting factories in some larger metropolitan areas. The Chinese government has also invested in gas and in cleaner, more efficient briquettes as replacements for raw coal as a fuel for domestic cooking and heating.
  • 11. Major Air Pollutants  Carbon Monoxide (CO) CO Carbon Dioxide (CO2)  Chlorofluorocarbons (CFCs)  Hazardous Air Pollutants (HAPs)  Ozone (O3 )  Nitrogen Oxide (NOx)
  • 12.  Atmosphere as a Resource  Types and Sources of Air Pollution  Major Classes of Air Pollutants  Sources of Outdoor Air Pollutants  Urban Air Pollution  Effects of Air Pollution  Controlling Air Pollution in the US
  • 13. Atmosphere as a Resource  Atmospheric Composition  Nitrogen 78.08%  Oxygen 20.95%  Argon 0.93%  Carbon dioxide 0.04%  Ecosystem services  Blocks UV radiation  Moderates the climate  Redistributes water in the hydrologic cycle
  • 14. Types and Sources of Air Pollution  Air Pollution  Chemicals added to the atmosphere by natural events or human activities in high enough concentrations to be harmful  Two categories  Primary Air Pollutant  Harmful substance that is emitted directly into the atmosphere  Secondary Air Pollutant  Harmful substance formed in the atmosphere when a primary air pollutant reacts with substances normally found in the atmosphere or with other air pollutants
  • 17. Particulate Material  Thousands of different solid or liquid particles suspended in air  Includes: soil particles, soot, lead, asbestos, sea salt, and sulfuric acid droplets  Dangerous for 2 reasons  May contain materials with toxic or carcinogenic effects  Extremely small particles can become lodged in lungs
  • 18. Nitrogen and Sulfur Oxides  Nitrogen Oxides  Gases produced by the chemical interactions between atmospheric nitrogen and oxygen at high temperature  Problems  Greenhouse gases  Cause difficulty breathing  Sulfur Oxides  Gases produced by the chemical interactions between sulfur and oxygen  Causes acid precipitation
  • 19. Carbon Oxides and Hydrocarbons  Carbon Oxides  Gases carbon monoxide (CO) and carbon dioxide (CO2)  Greenhouse gases  Hydrocarbons  Diverse group of organic compounds that contain only hydrogen and carbon (ex: CH4- methane)  Some are related to photochemical smog and greenhouse gases
  • 20. Ozone  Tropospheric Ozone  Man- made pollutant in the lower atmosphere  Secondary air pollutant  Component of photochemical smog  Stratospheric Ozone  Essential component that screens out UV radiation in the upper atmosphere  Man- made pollutants (ex: CFCs) can destroy it
  • 21. Sources of Outdoor Air Pollution  Two main sources  Transportation  Industry  Intentional forest fires is also high
  • 22. Causes of Air Pollution
  • 23. Asthma and Air Pollution
  • 24. Urban Air Pollution  Photochemical Smog (ex: Los Angeles below)  Brownish-orange haze formed by chemical reactions involving sunlight, nitrogen oxide, and hydrocarbons
  • 26. Sources of Smog in Los Angeles
  • 27. Case-In-Point Air Pollution in Beijing and Mexico City  Beijing (left)  Mexico City (above)
  • 28. Effects of Air Pollution  Low level exposure  Irritates eyes  Causes inflammation of respiratory tract  Can develop into chronic respiratory diseases
  • 29. Health Effects of Air Pollution  Sulfur Dioxide and Particulate material  Irritate respiratory tract and impair ability of lungs to exchange gases  Nitrogen Dioxides  Causes airway restriction  Carbon monoxide  Binds with iron in blood hemoglobin  Causes headache, fatigue, drowsiness, death  Ozone  Causes burning eyes, coughing, and chest discomfort
  • 30. Effects of Air Pollution
  • 31. Effects of Air Pollution  Global Warming– the increased concentration of carbon dioxide and other greenhouse gases in the atmosphere lead to rise in earth’s average temperature.  Ozone  Greenhouse Effect  Acid Rain comes mainly from sulfur dioxide emitted from power plants and smelters and from nitrogen oxides discharges from power plant and automobiles. These acids are often carried far before falling as rain or snow. Acids corrode metals and even erode stone buildings and statues.
  • 32. Children and Air Pollution  Greater health threat to children than adults  Air pollution can restrict lung development  Children breath more often than adults  Children who live in high ozone areas are more likely to develop asthma
  • 33. Controlling Air Pollution in US  Smokestacks with electrostatic precipitator (right) Without Electrostatic Without Electrostatic precipitator precipitator With Electrostatic With Electrostatic precipitator precipitator
  • 34. Controlling Air Pollution in the US  Smokestacks with scrubbers (right)  Particulate material can also be controlled by proper excavating techniques
  • 35. Controlling Air Pollution in the US  Phase I Vapor Recovery System for gasoline
  • 36. The Clean Air Act  Authorizes EPA to set limits on amount of specific air pollutants permitted  Focuses on 6 pollutants:  lead, particulate matter, sulfur dioxide, carbon monoxide, nitrogen oxides, and ozone  Act has led to decreases!
  • 38. Ozone Depletion in Stratosphere  Ozone thinning/hole  First identified in 1985 over Antarctica  Caused by  human-produced bromine and chlorine containing chemicals  Ex: CFCs
  • 39. Ozone Depletion in Stratosphere  Hole over Antarctica requires two conditions:  Sunlight just returning to polar region  Circumpolar vortex- a mass of cold air that circulates around the southern polar region  Isolates it from the warmer air in the rest of the planet  Polar stratospheric clouds form  Enables Cl and Br to destroy ozone
  • 40. Effects of Ozone Depletion  Higher levels of UV- radiation hitting the earth  Eye cataracts  Skin cancer (right)  Weakened immunity  May disrupt ecosystems  May damage crops and forests
  • 41. Recovery of Ozone Layer  Montreal Protocol (1987)  Reduction of CFCs  Started using HCFCs (greenhouse gas)  Phase out of all ozone destroying chemicals is underway globally  Satellite pictures in 2000 indicated that ozone layer was recovering  Full recovery will not occur until 2050
  • 42. Acid Deposition  Sulfur dioxide and nitrogen dioxide emissions react with water vapor in the atmosphere and form acids that return to the surface as either dry or wet deposition  pH scale
  • 44. Effects of Acid Deposition  Declining Aquatic Animal Populations  Thin-shelled eggs prevent bird reproduction  Because calcium is unavailable in acidic soil  Forest decline  Ex: Black forest in Germany (50% is destroyed)
  • 45. Acid Deposition and Forest Decline
  • 46. Air Pollution Around the World  Air quality is deteriorating rapidly in developing countries  Shenyang, China  Residents only see sunlight a few weeks each year  Developing countries have older cars  Still use leaded gasoline  5 worst cities in world  Beijing, China; Mexico City, Mexico; Shanghai, China; Tehran, Iran; and Calcutta, India
  • 47. Long Distance Transport of Air Pollutants
  • 48. Indoor Air Pollution  Pollutants can be 5-100X greater than outdoors  Most common:  Radon, cigarette smoke, carbon monoxide, nitrogen dioxide, formaldehyde pesticides, lead, cleaning solvents, ozone, and asbestos
  • 50. WHO Global Urban Ambient Air Pollution Database (update 2016)  More than 80% of people living in urban areas that monitor air pollution are exposed to air quality levels that exceed the World Health Organization (WHO) limits. While all regions of the world are affected, populations in low-income cities are the most impacted.  According to the latest urban air quality database, 98% of cities in low- and middle income countries with more than 100 000 inhabitants do not meet WHO air quality guidelines. However, in high-income countries, that percentage decreases to 56%.  In the past two years, the database – now covering 3000 cities in 103 countries – has nearly doubled, with more cities measuring air pollution levels and recognizing the associated health impacts.  As urban air quality declines, the risk of stroke, heart disease, lung cancer, and chronic and acute respiratory diseases, including asthma, increases for the people who live in them.
  • 51. The WHO urban air quality database is currently being updated. If you are an official air quality data provider either at country or city level, please use this template to submit the data.
  • 52. Emissions to air Emissions to air and noise emissions arise during the manufacture of cement. Furthermore with regard to the use of waste, odors can arise, e.g. from the storage and handling of waste. In this section, ranges of air pollutant emissions are presented for the process of cement production, including other process steps, such as the storage and handling of, e.g. raw materials, additives and fuels including waste fuels. The IPPC Directive [7] includes a general indicative list of the main air- polluting substances to be taken into account, if they are relevant for fixing emission limit values. Relevant to cement manufacture including the use of waste are: · oxides of nitrogen (NOx) and other nitrogen compounds, · sulphur dioxide (SO2) and other sulphur compounds dust, · total organic compounds (TOC) including volatile organic compounds (VOC), · polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDDs and PCDFs), · metals and their compounds, · hydrogen fluoride (HF), · hydrogen chloride (HCl), · carbon monoxide (CO). Not mentioned on the list, but considered to be relevant for cement production is carbon dioxide (CO2). Furthermore, emissions of NH3 may be considered to be relevant, especially when using secondary measures/techniques for NOx reduction. The main emissions from the production of cement are emissions to air from the kiln system. The main constituents of the exit gases from a cement kiln are nitrogen from the combustion air; CO2 from calcination of CaCO3 and combustion of fuel; water vapour from the combustion process and from the raw materials; and excess oxygen.
  • 53. Dioxin Facts  Dioxins and furans are the most toxic chemicals known to science  Dioxins cause infertility, learning disabilities, endometriosis, birth defects, sexual reproductive disorders, damage to the immune system, cancer and more.  93% of dioxin exposure is from eating meat and dairy products.
  • 54. Pollutants Released by Cement Kilns  Carbon dioxide (global warming gas)  Acid Gases, Nitrogen Oxides, Sulfur Dioxide, Particulate Matter  19 heavy metals, including lead, mercury, cadmium and chromium VI  Products of Incomplete Combustion (PICs), including dioxins, furans and Polycyclic Aromatic Hydrocarbons (PAHs)
  • 55. What’s in Cement Kiln Dust?  Calcium Oxide  Toxic metals: Arsenic, Chromium, Cadmium, Antimony, Barium, Beryllium, Lead, Silver, Mercury, Thallium, Selenium, Nickel  Dioxin, Furans  Cement Kiln Dust More Toxic when Burning Hazardous Waste
  • 56. Hazardous Waste Fuels vs. Traditional Fuels  Hazardous Waste either emitted into air, absorbed into CKD, or into clinker (final product)  Using hazardous waste produces 104% more cement kiln dust by volume  Lead concentrations 250% higher  Cadmium concentrations 150% higher  Chromium concentrations 50% higher  Selenium concentrations 100% higher  700 times more dioxin