CERAMICS Carasco, Allan Gabriel Doliente, Lorenzo Miguel Jacinto, Stephanie Villanueva, Von Kirby
Ceramics One of the largest groups of materials with the properties of nonmetals and all are made by firing or burning, often including silicates and metal oxides. Greek term  Keramos , meaning "a potter" or "pottery”.
Ceramic materials are attractive for several reasons : Cheap in terms of its starting materials. Compared to metals, lightweight and retain their strength up to 1000 ˚C where metals tends to fail. They have electrical, optical, and magnetic properties of value in the computer and electronic industries.
History The art of making pottery by forming and burning clay has been practiced from the earliest civilizations. Burnt clayware has been found dating from about 15,000 B.C. and as well developed as an industrial product in Egypt by about 5000 B.C.  Formed glass dates from the period 7000-5000 B.C. and was a stable industry in Egypt by about 1500 B.C.
Ceramics Industry An important characteristic of the ceramics industry is that it is basic to the successful operation of many other industries. In the Philippines, smuggled ceramics has cause severe effect on the ceramic industry locally. But exporting of ceramic materials is significantly increasing.
Uses of Ceramics The ceramics industry is divided in the manufacture of the ff. products: Structural Clay Products Whitewares Refractories Glasses Abrasives Cements Advance Ceramics -Structural -Electrical -Coating
Classifications of the  Ceramics Traditional Ceramics New Ceramics
Ceramic Tile Processes Raw Material Weighing Ball Milling Vibrating Screen and HomoTank Spray Dryer Powder Storage (SILO) Dry Pressing Horizontal Dryer Glazing Silk Screen Printing Roller Heart Kiln
Raw Materials The traditional ceramics industry is largely based on various combinations of clay minerals, feldspar and silica. The mineral raw materials used in the ceramic industry are mainly inorganic, nonmetallic, crystalline solids formed by complex geologic processes.
Raw Materials Oxygen, silicon, and aluminum together account for 90% of the elements in the earth’s crust , These, together with other minerals compounds of oxygen, constitute the greatest bulk of naturally occurring ceramic raw materials.
Raw Materials Clay Minerals Talc and Related Minerals Silica and Silicate Minerals Feldspars and related minerals.  Refractory Raw Materials Talc Silica Clay
Common Types of Clay Kaolin or China Clay  Ball Clays Fire Clays Flint Clays Pottery Clay Shale Vitrifying Clays Brick Clays Slip Clays
Important Characteristics of Clays in Ceramic Bodies Clays have the ability to form clay-water composition and to maintain their shape and strength during drying and firing  They fuse over a temperature range depending on their composition in such a way as to become dense and strong without losing their shape
Talc and Related Minerals Talc is a hydrous magnesium silicate which has a layer structure similar to that of the clay minerals.  It is an important ceramic raw material for the manufacture of electrical and electronic components
Talc and Related Minerals Pyrophyllite  Block talc  Asbestos
Silica and Silicate Minerals Silica is a major ingredient in glass, glazes, enamels, refractories, abrasives, and whiteware compositions.  It is widely used because it is inexpensive, hard, chemically stable
Silica and Silicate Minerals The major source of silica for the ceramic industry is sandstone, consisting of lightly bonded quartz grains.  The sand is frequently mined by loosening the quarts grains with a stream of high-pressure water.
Feldspars and Related Minerals   Feldspar are anhydrous aluminosilicates containing K+, Na+, and Ca2.; they are present in virtually all igneous rocks.  Most production comes from pegmatites which are coarsely crystalline rock formed in the later stages of crystallization of a magma
Feldspars and Related Minerals Nepheline syenite Wollastonite Sillimanite  Sillimanite Wollastonite Nepheline syenite
Refractory Raw Materials   Alumina Magnesia Dolomite Chrome Ore  Alumina Dolomite Chrome Ore Magnesia
Other Raw Materials Soda ash Borate minerals Fluorspar Phosphate minerals  Abrasive raw materials  Soda Ash Borate Minerals Flourspar
Ball Milling Spheres mixed with the stock to be comminuted are rotated inside a large cylindrical container. These operations are often carried out with water
Ball Milling Stock Balls Drive rolls Container
Spray Dryer Characterized by atominization of a solution or suspension into droplets, followed by drying.
Spray Dryer Schematic Diagram of Spray Dryer Particle Trajectory
Dry Pressing Forming of the “greenware” tile body. Non-clumping granulates are compressed in steel dies designed appropriately for the part to be manufactured.
Glazing The application of glassy coatings on ceramic wares to give them decorative finishes and to make them impervious to moisture
Roller Hearth Kiln A roller tunnel kiln for firing a drying refractory material advanced along the refractory rotatable rollers includes an upper section comprising a prefiring zone, a firing zone, a first forced cooling zone, a natural cooling zone and a second forced cooling zone.
Roller Hearth Kiln Firing zone  Gear system Entrance
Traditional Ceramic  Processes Preparation of Raw Materials Crushing Types of Equipments Used Jaw Crushers Gyratory Crushers Roll Crushers Hammer Mills
Crushing Jaw Crusher Gyratory Crusher Roll Crusher Hammer Mill
Traditional Ceramic  Processes Grinding Types of Equipments Used Ball mill Roller mill Impact grinding
Grinding Ball Mill Roller Mill Impact Grinding
Traditional Ceramic  Processes B. Shaping Processes Slip Casting Drain Casting Solid Casting Plastic Forming Manual Forming Hand modeling Hand molding Hand throwing
Drain Casting
Traditional Ceramic  Processes Mechanized Jiggering Plastic pressing Extrusion Semi-dry Pressing Dry Pressing
Semidry Pressing
Traditional Ceramic  Processes Drying Firing Glazing
New Ceramic  Processes Preparation of Raw Materials Freeze Drying Precipitation from solution Shaping Hot pressing Isostatic pressing Doctor-blade process Injection molding
New Ceramic  Processes Sintering To bond individual grains into a solid mass To increase density To reduce or eliminate porosity Finishing To increase dimensional accuracy To improve surface finish To make minor changes in part geometry
New Ceramic  Processes Doctor blade Process
Factors Affecting Ceramic Process Oxidation Decomposition Reactions Phase Transformations Trapped Gases Non uniform Mixing Over firing Hot Pressing
Common Errors in Ceramic Process Firing Shrinkage Warping

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Ceramics

  • 1. CERAMICS Carasco, Allan Gabriel Doliente, Lorenzo Miguel Jacinto, Stephanie Villanueva, Von Kirby
  • 2. Ceramics One of the largest groups of materials with the properties of nonmetals and all are made by firing or burning, often including silicates and metal oxides. Greek term Keramos , meaning "a potter" or "pottery”.
  • 3. Ceramic materials are attractive for several reasons : Cheap in terms of its starting materials. Compared to metals, lightweight and retain their strength up to 1000 ˚C where metals tends to fail. They have electrical, optical, and magnetic properties of value in the computer and electronic industries.
  • 4. History The art of making pottery by forming and burning clay has been practiced from the earliest civilizations. Burnt clayware has been found dating from about 15,000 B.C. and as well developed as an industrial product in Egypt by about 5000 B.C. Formed glass dates from the period 7000-5000 B.C. and was a stable industry in Egypt by about 1500 B.C.
  • 5. Ceramics Industry An important characteristic of the ceramics industry is that it is basic to the successful operation of many other industries. In the Philippines, smuggled ceramics has cause severe effect on the ceramic industry locally. But exporting of ceramic materials is significantly increasing.
  • 6. Uses of Ceramics The ceramics industry is divided in the manufacture of the ff. products: Structural Clay Products Whitewares Refractories Glasses Abrasives Cements Advance Ceramics -Structural -Electrical -Coating
  • 7. Classifications of the Ceramics Traditional Ceramics New Ceramics
  • 8. Ceramic Tile Processes Raw Material Weighing Ball Milling Vibrating Screen and HomoTank Spray Dryer Powder Storage (SILO) Dry Pressing Horizontal Dryer Glazing Silk Screen Printing Roller Heart Kiln
  • 9. Raw Materials The traditional ceramics industry is largely based on various combinations of clay minerals, feldspar and silica. The mineral raw materials used in the ceramic industry are mainly inorganic, nonmetallic, crystalline solids formed by complex geologic processes.
  • 10. Raw Materials Oxygen, silicon, and aluminum together account for 90% of the elements in the earth’s crust , These, together with other minerals compounds of oxygen, constitute the greatest bulk of naturally occurring ceramic raw materials.
  • 11. Raw Materials Clay Minerals Talc and Related Minerals Silica and Silicate Minerals Feldspars and related minerals. Refractory Raw Materials Talc Silica Clay
  • 12. Common Types of Clay Kaolin or China Clay Ball Clays Fire Clays Flint Clays Pottery Clay Shale Vitrifying Clays Brick Clays Slip Clays
  • 13. Important Characteristics of Clays in Ceramic Bodies Clays have the ability to form clay-water composition and to maintain their shape and strength during drying and firing They fuse over a temperature range depending on their composition in such a way as to become dense and strong without losing their shape
  • 14. Talc and Related Minerals Talc is a hydrous magnesium silicate which has a layer structure similar to that of the clay minerals. It is an important ceramic raw material for the manufacture of electrical and electronic components
  • 15. Talc and Related Minerals Pyrophyllite Block talc Asbestos
  • 16. Silica and Silicate Minerals Silica is a major ingredient in glass, glazes, enamels, refractories, abrasives, and whiteware compositions. It is widely used because it is inexpensive, hard, chemically stable
  • 17. Silica and Silicate Minerals The major source of silica for the ceramic industry is sandstone, consisting of lightly bonded quartz grains. The sand is frequently mined by loosening the quarts grains with a stream of high-pressure water.
  • 18. Feldspars and Related Minerals Feldspar are anhydrous aluminosilicates containing K+, Na+, and Ca2.; they are present in virtually all igneous rocks. Most production comes from pegmatites which are coarsely crystalline rock formed in the later stages of crystallization of a magma
  • 19. Feldspars and Related Minerals Nepheline syenite Wollastonite Sillimanite Sillimanite Wollastonite Nepheline syenite
  • 20. Refractory Raw Materials Alumina Magnesia Dolomite Chrome Ore Alumina Dolomite Chrome Ore Magnesia
  • 21. Other Raw Materials Soda ash Borate minerals Fluorspar Phosphate minerals Abrasive raw materials Soda Ash Borate Minerals Flourspar
  • 22. Ball Milling Spheres mixed with the stock to be comminuted are rotated inside a large cylindrical container. These operations are often carried out with water
  • 23. Ball Milling Stock Balls Drive rolls Container
  • 24. Spray Dryer Characterized by atominization of a solution or suspension into droplets, followed by drying.
  • 25. Spray Dryer Schematic Diagram of Spray Dryer Particle Trajectory
  • 26. Dry Pressing Forming of the “greenware” tile body. Non-clumping granulates are compressed in steel dies designed appropriately for the part to be manufactured.
  • 27. Glazing The application of glassy coatings on ceramic wares to give them decorative finishes and to make them impervious to moisture
  • 28. Roller Hearth Kiln A roller tunnel kiln for firing a drying refractory material advanced along the refractory rotatable rollers includes an upper section comprising a prefiring zone, a firing zone, a first forced cooling zone, a natural cooling zone and a second forced cooling zone.
  • 29. Roller Hearth Kiln Firing zone Gear system Entrance
  • 30. Traditional Ceramic Processes Preparation of Raw Materials Crushing Types of Equipments Used Jaw Crushers Gyratory Crushers Roll Crushers Hammer Mills
  • 31. Crushing Jaw Crusher Gyratory Crusher Roll Crusher Hammer Mill
  • 32. Traditional Ceramic Processes Grinding Types of Equipments Used Ball mill Roller mill Impact grinding
  • 33. Grinding Ball Mill Roller Mill Impact Grinding
  • 34. Traditional Ceramic Processes B. Shaping Processes Slip Casting Drain Casting Solid Casting Plastic Forming Manual Forming Hand modeling Hand molding Hand throwing
  • 36. Traditional Ceramic Processes Mechanized Jiggering Plastic pressing Extrusion Semi-dry Pressing Dry Pressing
  • 38. Traditional Ceramic Processes Drying Firing Glazing
  • 39. New Ceramic Processes Preparation of Raw Materials Freeze Drying Precipitation from solution Shaping Hot pressing Isostatic pressing Doctor-blade process Injection molding
  • 40. New Ceramic Processes Sintering To bond individual grains into a solid mass To increase density To reduce or eliminate porosity Finishing To increase dimensional accuracy To improve surface finish To make minor changes in part geometry
  • 41. New Ceramic Processes Doctor blade Process
  • 42. Factors Affecting Ceramic Process Oxidation Decomposition Reactions Phase Transformations Trapped Gases Non uniform Mixing Over firing Hot Pressing
  • 43. Common Errors in Ceramic Process Firing Shrinkage Warping