The workshop, led by DevOps engineer Ahmed Abouzaid, covers 18 best practices for effective Docker usage, organized into four categories: essential practices, image practices, security practices, and miscellaneous practices. Aimed at attendees with a basic knowledge of Docker, it includes hands-on experience applying the practices discussed and emphasizes the importance of using proper Dockerfile syntax, optimizing image size, ensuring security, and maintaining best practices in configuration. Key takeaways include using trusted images, avoiding unnecessary files, utilizing Docker build cache, and implementing a non-root user to enhance security.