ESSENTIAL ELEMENTS/NUTRIENTS: FUNCTIONS AND DEFICIENCIES
Dr. K. Vanangamudi
Formerly Dean (Agriculture),
Dean Adhiparasakthi Agricultural College,
Professor & Head,
Seed Science & Technology, TNAU, Coimbatore.
1. Classification of essential nutrients
1.1. Based on the amount required by the plant
 Major nutrients – required in large quantities eg. N, P, K.
 Secondary nutrients – required in lesser quantities compared to major nutrients eg. Ca,
Mg, S.
 Micronutrients – required in trace quantities eg. Fe, Mn, Zn, Cu, B, Mo.
1.2. Classification based on the role of element in plant system (according to TRUOc,
1954)
 Accessor structural elements: N, P, S
 Regulator and carriers: K, Ca, Mg
 Catalyst and activators: Fe, Mn, Zn, Cu, Mo, Cl, B.
 Seventeen elements are considered essential to plant growth.
 Carbon (C), hydrogen (H) and oxygen (O) are the most abundant elements in plants.
 Carbon, H and O are not considered as mineral nutrients.
2. Essential nutrients and their principal forms for uptake
Nutrient Chemical symbol Principal forms for uptake
Carbon C CO2
Hydrogen H H2O
Oxygen O H2O.O2
Nitrogen N NH+4
.NO-3
Phosphorus P H2PO-4
, HPO2
-4
Potassium K K+
Calcium Ca Ca2+
Magnesium Mg Mg2+
Sulphur S SO2
-4
, SO2
Iron Fe Fe2+,
Fe3+
Manganese Mn Mn2+
Boron B H3BO3
Zinc Zn Zn2+
Copper Cu Cu2+
Molybdenum Mo MoO2
-4
Chlorine Cl Cl-
Nickel
3. Functions of essential nutrients in plants
Nutrient Function
Carbon (C)  Basic molecular component of carbohydrates, proteins, lipids
and nucleic acids
Oxygen (O)  Occurs in all organic compounds of living organisms
Hydrogen (H)  Hydrogen plays a central role in plant metabolism.
 Important in ionic balance and as main reducing agent.
 Plays a key role in energy relations of cells.
Nitrogen (N)  Component of proteins to nucleic acids and chlorophyll.
 Essential role in plant growth.
 Also foods in soils.
Phosphorus (P)  Central role in plants is in energy transfer during respiration
ADP + Pi → ATP and protein metabolism.
 Root growth and photosynthesis.
Potassium (K)  Helps in osmotic and ionic regulation.
 Cofactor or activator for many enzymes of carbohydrate and
protein metabolism.
 Resistance to cold, disease and insects.
Calcium (Ca)  Involved in cell division and maintenance of membrane
integrity.
 Signal transduction pathway.
Magnesium (Mg)  Component of chlorophyll.
 Cofactor for many enzymatic reactions.
Sulphur (S)  Involved in plant cell energy.
Iron (Fe)  Essential component of many heme and nonheme Fe enzymes.
 Involved in key metabolic function such as N fixation,
photosynthesis and electron transfer.
 Chlorophyll production.
Zinc (Zn)  Essential component of several dehydrogenases and peptidases,
including carbonic anhydrase, alcohol dehydrogenase, glutamic
dehydrogenase and malic dehydrogenase.
 Synthesis of protein, hormones, enzymes.
Manganese (Mn)  Involved in the O2 – evolving system of photosynthesis.
 Component of the enzymes arginase and phosphortransferases.
 Chlorophyll production.
Copper (Cu)  Constituent of enzymes like cytochrome oxidase, ascorbic acid
oxidase and laccase.
Boron (B)  Involved in carbohydrate metabolism and synthesis of cell wall
components.
 Pollen production, fertility and fruit formation.
Molybdenum (Mo)  Required for the normal assimilation of N in plants.
 Essential component of nitrate reductase as well as nitrogenase
(N2 fixation enzymes).
Chlorine (Cl)  Essential for photosynthesis and as an activator of enzymes
involved in splitting water.
 Involved osmoregulation of plants growing on saline soils.
Nickel (Ni) Involves in N metabolism and nitrogen fixation
4. Deficiency symptoms of nutrients
4.1. Nitrogen (N)
 Promotes rapid vegetative growth
 Gives plants healthy green colour
 Deficiency:
 Stimulated growth, pale yellowish colour.
 Burning tips and margins of leaves starting at the bottom of the plant.
4.2. Phosphorus (P)
 Stimulates early growth and root formation.
 Hastens maturity.
 Promotes seed production.
 Makes plants hardy.
 Deficiency:
 Small root growth, spindly stalk, delayed maturity.
 Purplish discoloration of leaves.
 Dying of tips of older leaves, poor fruit and seed development.
4.3. Potassium (K)
 Improves plant ability to resist disease and cold.
 Aids in the production of carbohydrates.
 Deficiency:
 Slow growth.
 Margin on leaves develop a scorched effect on the older leaves.
 Weak stalk, shriveled seed and fruits.
4.4. Calcium
 Absorbed by plants as Ca2+
and concentration in plant ranges from 0.2 to 1.0%.
 Deficiency:
 Young leaves of terminal buds dieback at the tip and margins.
 Root may become short, stubby and brown.
 Causes acidity of soil.
 Cell may become rigid and brittle.
 Young leaves of cereals remain folded
4.5. Magnesium
 Absorbed as Mg2+
and concentration in plant varies between 0.1 and 0.6%.
 Deficiency:
 Interveinal chlorosis.
 Stiff brittle, twisted, wrinkled and distortion of leaves.
 Cotton – lower leaves develop a reddish purple finally nicrotic (Redding of
leaves).
 In brassica, chlorosis with interveinal mottling uniformly distributed in older
leaves and other vascular tissues remain green called Puckering.
4.6. Sulphur
 Absorbed by plant roots as SO4
2-
ions.
 Concentration in plants ranges between 0.1 and 0.4%.
 Deficiency:
 Stunted growth, pale green to yellow colour.
 Immobile in plants and plants symptoms start first at younger leaves.
 Poor seed set in rapeseed.
 Tea –tea yellows.
4.7. Iron
 Absorbed by plants roots as Fe2+
, Fe3+
.
 Concentration in plant tissue is 50-250 ppm.
 Deficiency:
 Occurs in younger leaves since Fe is immobile element.
 Occurs in calcareous or alkaline soils and poorly drained water logged soils.
 Younger leaves develop interveinal chlorosis.
 Entire leaf turns yellow colour.
4.8. Manganese
 Mn concentration in plant ranges from 20 to 500 ppm.
 Deficiency:
 Immobile in plant and deficiency starts in the younger leaves.
 Interveinal chlorosis occurs.
 Oats - gray specks / streaks
 Peas - marsh spot
 Sugarbeet - speckled yellow
 Sugarcane - pahala blight
4.9. Zinc
 Normal concentration in plant is 25 to 150 ppm.
 Deficiency:
 Light yellow or white areas between the veins of older leaves.
 Death of tissue, discoloured.
 Malformation of fruits.
 Cotton : White bud (or) little leaf
 Citrus : Mottle leaf
 Potato : Fern leaf
 Fruit trees : Rosette (Upnormal growth)
 Paddy : Khaira
4.10. Copper
 Absorbed Cu2+
.
 Normal concentration in plants is 5-20 ppm.
 Deficiency:
 Chlorosis, withering and distortion of terminal buds.
 Guava - cracking of fruits and terminal bud dieback.
4.11. Boron
 Since it is immobile, deficiency occurs in terminal bud growth.
 Poor pollen production and fertility.
 Restricted flowering, fruit development and fruit set.
 Sterility and mal formation of reproductive organs.
 Discolouration, cracking or rotting of fruit, tubers or roots.
 In apple, Internal cracking.
 Break down of internal tissue in root crops gives rise to darkened areas - brown heart /
black heart.
 Cotton - weeping disease.
4.12. Molybdenum
 Absorbed as molybdate (MoO4).
 Plant contains <1 ppm Mo.
 Deficiency:
 Inhibits flower formation.
 Whiptail in cauliflower.
4.13. Chlorine
 Absorbed by plants as Cl-
through roots and aerial parts.
 Normal concentration in plant is 0.2-2.0%.
 Deficiency:
 Partial wilting and loss of turgidity.
 Necrosis, leaf bronzing and reduction in growth.
4.14. Nickel
 Content in plant is 0.1 - 1.0 ppm.
 Legumes: whole leaf chlorosis along with necrotic leaf tips in cowpea.

ESSENTIAL ELEMENTS/NUTRIENTS - FUNCTIONS AND DEFICIENCIES

  • 1.
    ESSENTIAL ELEMENTS/NUTRIENTS: FUNCTIONSAND DEFICIENCIES Dr. K. Vanangamudi Formerly Dean (Agriculture), Dean Adhiparasakthi Agricultural College, Professor & Head, Seed Science & Technology, TNAU, Coimbatore. 1. Classification of essential nutrients 1.1. Based on the amount required by the plant  Major nutrients – required in large quantities eg. N, P, K.  Secondary nutrients – required in lesser quantities compared to major nutrients eg. Ca, Mg, S.  Micronutrients – required in trace quantities eg. Fe, Mn, Zn, Cu, B, Mo. 1.2. Classification based on the role of element in plant system (according to TRUOc, 1954)  Accessor structural elements: N, P, S  Regulator and carriers: K, Ca, Mg  Catalyst and activators: Fe, Mn, Zn, Cu, Mo, Cl, B.  Seventeen elements are considered essential to plant growth.  Carbon (C), hydrogen (H) and oxygen (O) are the most abundant elements in plants.  Carbon, H and O are not considered as mineral nutrients. 2. Essential nutrients and their principal forms for uptake Nutrient Chemical symbol Principal forms for uptake Carbon C CO2 Hydrogen H H2O Oxygen O H2O.O2 Nitrogen N NH+4 .NO-3 Phosphorus P H2PO-4 , HPO2 -4 Potassium K K+ Calcium Ca Ca2+ Magnesium Mg Mg2+ Sulphur S SO2 -4 , SO2 Iron Fe Fe2+, Fe3+ Manganese Mn Mn2+ Boron B H3BO3 Zinc Zn Zn2+ Copper Cu Cu2+ Molybdenum Mo MoO2 -4 Chlorine Cl Cl-
  • 2.
    Nickel 3. Functions ofessential nutrients in plants Nutrient Function Carbon (C)  Basic molecular component of carbohydrates, proteins, lipids and nucleic acids Oxygen (O)  Occurs in all organic compounds of living organisms Hydrogen (H)  Hydrogen plays a central role in plant metabolism.  Important in ionic balance and as main reducing agent.  Plays a key role in energy relations of cells. Nitrogen (N)  Component of proteins to nucleic acids and chlorophyll.  Essential role in plant growth.  Also foods in soils. Phosphorus (P)  Central role in plants is in energy transfer during respiration ADP + Pi → ATP and protein metabolism.  Root growth and photosynthesis. Potassium (K)  Helps in osmotic and ionic regulation.  Cofactor or activator for many enzymes of carbohydrate and protein metabolism.  Resistance to cold, disease and insects. Calcium (Ca)  Involved in cell division and maintenance of membrane integrity.  Signal transduction pathway. Magnesium (Mg)  Component of chlorophyll.  Cofactor for many enzymatic reactions. Sulphur (S)  Involved in plant cell energy. Iron (Fe)  Essential component of many heme and nonheme Fe enzymes.  Involved in key metabolic function such as N fixation, photosynthesis and electron transfer.  Chlorophyll production. Zinc (Zn)  Essential component of several dehydrogenases and peptidases, including carbonic anhydrase, alcohol dehydrogenase, glutamic dehydrogenase and malic dehydrogenase.  Synthesis of protein, hormones, enzymes. Manganese (Mn)  Involved in the O2 – evolving system of photosynthesis.  Component of the enzymes arginase and phosphortransferases.  Chlorophyll production. Copper (Cu)  Constituent of enzymes like cytochrome oxidase, ascorbic acid oxidase and laccase. Boron (B)  Involved in carbohydrate metabolism and synthesis of cell wall components.  Pollen production, fertility and fruit formation. Molybdenum (Mo)  Required for the normal assimilation of N in plants.  Essential component of nitrate reductase as well as nitrogenase (N2 fixation enzymes). Chlorine (Cl)  Essential for photosynthesis and as an activator of enzymes involved in splitting water.  Involved osmoregulation of plants growing on saline soils.
  • 3.
    Nickel (Ni) Involvesin N metabolism and nitrogen fixation 4. Deficiency symptoms of nutrients 4.1. Nitrogen (N)  Promotes rapid vegetative growth  Gives plants healthy green colour  Deficiency:  Stimulated growth, pale yellowish colour.  Burning tips and margins of leaves starting at the bottom of the plant. 4.2. Phosphorus (P)  Stimulates early growth and root formation.  Hastens maturity.  Promotes seed production.  Makes plants hardy.  Deficiency:  Small root growth, spindly stalk, delayed maturity.  Purplish discoloration of leaves.  Dying of tips of older leaves, poor fruit and seed development. 4.3. Potassium (K)  Improves plant ability to resist disease and cold.  Aids in the production of carbohydrates.  Deficiency:  Slow growth.  Margin on leaves develop a scorched effect on the older leaves.  Weak stalk, shriveled seed and fruits. 4.4. Calcium  Absorbed by plants as Ca2+ and concentration in plant ranges from 0.2 to 1.0%.  Deficiency:  Young leaves of terminal buds dieback at the tip and margins.  Root may become short, stubby and brown.  Causes acidity of soil.  Cell may become rigid and brittle.  Young leaves of cereals remain folded
  • 4.
    4.5. Magnesium  Absorbedas Mg2+ and concentration in plant varies between 0.1 and 0.6%.  Deficiency:  Interveinal chlorosis.  Stiff brittle, twisted, wrinkled and distortion of leaves.  Cotton – lower leaves develop a reddish purple finally nicrotic (Redding of leaves).  In brassica, chlorosis with interveinal mottling uniformly distributed in older leaves and other vascular tissues remain green called Puckering. 4.6. Sulphur  Absorbed by plant roots as SO4 2- ions.  Concentration in plants ranges between 0.1 and 0.4%.  Deficiency:  Stunted growth, pale green to yellow colour.  Immobile in plants and plants symptoms start first at younger leaves.  Poor seed set in rapeseed.  Tea –tea yellows. 4.7. Iron  Absorbed by plants roots as Fe2+ , Fe3+ .  Concentration in plant tissue is 50-250 ppm.  Deficiency:  Occurs in younger leaves since Fe is immobile element.  Occurs in calcareous or alkaline soils and poorly drained water logged soils.  Younger leaves develop interveinal chlorosis.  Entire leaf turns yellow colour. 4.8. Manganese  Mn concentration in plant ranges from 20 to 500 ppm.  Deficiency:  Immobile in plant and deficiency starts in the younger leaves.  Interveinal chlorosis occurs.  Oats - gray specks / streaks  Peas - marsh spot  Sugarbeet - speckled yellow
  • 5.
     Sugarcane -pahala blight 4.9. Zinc  Normal concentration in plant is 25 to 150 ppm.  Deficiency:  Light yellow or white areas between the veins of older leaves.  Death of tissue, discoloured.  Malformation of fruits.  Cotton : White bud (or) little leaf  Citrus : Mottle leaf  Potato : Fern leaf  Fruit trees : Rosette (Upnormal growth)  Paddy : Khaira 4.10. Copper  Absorbed Cu2+ .  Normal concentration in plants is 5-20 ppm.  Deficiency:  Chlorosis, withering and distortion of terminal buds.  Guava - cracking of fruits and terminal bud dieback. 4.11. Boron  Since it is immobile, deficiency occurs in terminal bud growth.  Poor pollen production and fertility.  Restricted flowering, fruit development and fruit set.  Sterility and mal formation of reproductive organs.  Discolouration, cracking or rotting of fruit, tubers or roots.  In apple, Internal cracking.  Break down of internal tissue in root crops gives rise to darkened areas - brown heart / black heart.  Cotton - weeping disease. 4.12. Molybdenum  Absorbed as molybdate (MoO4).  Plant contains <1 ppm Mo.  Deficiency:
  • 6.
     Inhibits flowerformation.  Whiptail in cauliflower. 4.13. Chlorine  Absorbed by plants as Cl- through roots and aerial parts.  Normal concentration in plant is 0.2-2.0%.  Deficiency:  Partial wilting and loss of turgidity.  Necrosis, leaf bronzing and reduction in growth. 4.14. Nickel  Content in plant is 0.1 - 1.0 ppm.  Legumes: whole leaf chlorosis along with necrotic leaf tips in cowpea.