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Vol.6 No.8, 2014 
Greywater Disinfection by SolarReactor in Baghdad 
SeroorAtallahKhaleefa Ali 
College of Engineering Environmental Department Al Mustanseriya University 
Mob:+9647901442796 Email: seroor909@yahoo.com 
Abstract 
Solar disinfection is an efficient method for greywater treatment where it is exposed to solar radiation to 
inactivate pathogenic organisms.Solar disinfection is affected by numerous variables which include the 
wavelengths of solar radiation, water temperature, turbidity, and reactor selection. A Laborotary model of solar 
reacter has been designed and constructed at Environmental Hydraulic in Mustansiriya University/College of 
Engineering. The model consists of four independent Acrylic reactors of 100mm diameter and 1300mm length, 
filled with different materials for filtration and disinfection including (sand, Black granite, Granular activated 
carbón, and Mixture of granular activated carbonated black granite). 
Thesolardisinfectiontreatmentwas experimented bya8 L multistage contiuous flow with recycling ratio 4 .The 
treatmentprocesses still incomplete wherethe tertiarytreatmentisnotapplied in many treatment plants in 
Iraq.Thissituationcouldcompromisetheplannedwastewater reuseregardingespecially themicrobialquality. 
KeyWord: Solar Energy, Disinfection, Greywater, Multi Stage reactor 
1-Introduction 
Greywater can be contaminated by activities such as bathing and clothes washing. Disease-causing organisms in 
greywater are principally transmitted through ingestion of greywater via contaminated hands, aerosols from 
spray irrigation (usually only allowed for use with suitably treated greywater), or indirectly through contact with 
contaminated items such as grass, soil, toys and garden implements. (Dheyaa et. al, 2013) 
Inaridareas of Baghdad, water conservation and reuse are issues that receive a great deal of public attention in 
the last decade. The search for way store sponsibly use and reuse water is vital to the sustainability of the water 
supply and thus the future of the seregions Treated grey water in house scanbere used fortoilet flushing, outdoor 
irrigationandspraying water evaporation cooling of selected apartments building located in Baghdad. Treated 
wastewateralsocanbeusedforirrigationandstreetscleaningbymunicipalinstitutes.Several experiments in Baghdad 
have been achieved for small scale to reuse greywaterfor toilet flushing, irrigation, outside housecleaning and 
evaporative cooling. Baghdad's Water demand is estimated to 3.2Millionm3/sec, the quantity of produce 
dwateris (66%)of the required needs (Dheyaa et.al, 2014) 
Untreated greywater is not considered suitable for spray irrigation and human contact should be avoided if 
bucketing or maintaining greywater diversion or irrigation systems ( Table 1 ). (Dheyaa et.al, 2014) 
Table 1: International Criteria for Reuse, Surendran and Wheatley, 1998 
20 
Faecal 
coliforms 
cfu/100ml 
Total coliforms 
cfu/100 ml 
BOD 
mg/l 
Turbidity 
NTU 
TSS 
(mg/l) 
DO% 
% saturation 
PH 
Cl2 
Residual 
mg/l 
US EPA (g) 14 for any sample 
0 for 90% samples 
10 2 6-9 1 
Florida (m) 25 for any sample 
0 for 75% samples 
20 5 1 
Texas (m) 75 (m) 5 3 
Germany (g) 100 (g) 500 (g) 20 (g) 1-2 (m) 30 80-120 6-9 
Japan (m) 10 for any sample 10 10 5 6-9 
South Africa (g) 0 (g) 
WHO Iawn 
200 (g) 
irrigation 
1000 (m) 
EC bathing water 100 (g) 
2000 (m) 
500 (g) 
10000 (m) 
2 m (g) 
1 m (m) 
80-120 6-9 
UK (BSRIA) 
Proposed (g) 
14 for any sample 
0 for 90% 
A study which aimed at evaluating the amount of grey water generation in the city of Baghdad has been carried 
out by Dheyaaetal.(2009). The study showed that the water consumption in Baghdad in August averaged 138
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Vol.6 No.8, 2014 
Liters per capita per day (120-200Lpcd); while the water consumption in Baghdad in December averaged 75 
Liters per capita per day (58-100Lpcd). 
Greywaterrepresenta an incontestable release source of many chemicals, physical and biological compounds 
which may havean impact on the environment and human health. Water disinfection methods can be divided into 
two categories. The first category is chemical disinfection. Which includes methods such as chlorination and 
iodine treatment.However. The other catogary physical treatment methods such as boiling water and UV 
treatment which is only effective for low turbid water and therefore pretreatment such as filtering is required for 
poor water quality sources 
Solar water disinfection is a type of portable water purification that uses solar energy, in one or more ways, to 
make contaminated water safe to drink by ridding it of infectious disease-causing biological agents such as 
bacteria, viruses, protozoa and worms. However, disinfection may not make all kinds of water safe to drink due 
to non-biological agents such as toxic chemicals or heavy metals. Consequently, additional steps beyond 
disinfection may be necessary to make water clean to drink. . 
Solar thermal water disinfection uses heat from the sun to heat water to 70C-100oC for a short period of time. A 
number of approaches exist here. Solar heat collectors can have lenses in front of them, or use reflectors. They 
may also use varying levels of insulation or glazing. In addition, some solar thermal water disinfection processes 
are batch-based, while others (through-flow solar thermal disinfection) operate almost continuously while the 
sun shines. Water heated to temperatures below 100C is generally referred to as Pasteurized water (SANDEC, 
2010). . 
UV radiation is subdivided into UVA (400–320nm)which constitutes94%’sUV radiation. The rest is constitutes 
by UVB(320–290nm) and UVC (290–200nm) (Meierhofer R, 2002). 
In the disinfection technologies, UV radiation is used because it induces harmful photo biological effects. The 
researches improvement all owed their successful application against all water borne pathogens (Hijnenet al. 
(2006). 
Comparatively to UVB and UVC, UVA radiation is more abundant in the solar spectrum but induces the lower 
photo biological effects. The wave lengths radiations inferior to 320 nmare more active which induces the 
subdivision of UVA into UVAI (400–340nm) and UVAII (340–320 nm) (Meierhofer R, 2002) 
Direct UV radiation use (photolysis) remains less effective by themselves, the combination of UV and semi-conductors 
metals (photocatalysis) as TiO2;ZnO, Ag…records better results in water-and air-purification and 
several antibacterial products (Fujishima et al.(2000) 
Many several studies advised UV disinfection for its efficiency and safe use especially for the wastewater 
treatment intended for the reuse (Adam Jokerst , 2012). 
The objective of this research is to test the inactivation of different bacteria by solar disinfection using multi 
stage of Solar Reacter. The variables tested have to be water , turbidity, and exposure time. The inactivation of E. 
coli in the samples is quantified over time. 
2- Material and Methodlogy 
A Laborotary Models of Solar Reacter has been designed and constructed at Environmental Hydraulic in 
Mustansiriya University/College of Engineering as shown in plate (1) and fig.(1) The model consists of four 
independent acrylic reactors of 100mm diameter and 1300mm length ,filled with different materials biofiltration 
and disinfection, as shown in table (1). 
Measurments were achieved during period from Febreuary to December 2013 in Baghdad 
Table (1 ) Types of reactors and media used 
Type of reactor Type of media effective size mm Uniformity factor 
1st reactor Sand of effective grain size 0.7 1.4 
2nd reactor Black granite 1.2 1.8 
3rd reactor Granular activated carbon 2.2 2.4 
4th reactor Mixture of granular activated 
21 
carbonated black granite 
1.2 2.4 
Tests includ : PH,TDS,TSS,BOD5,COD,Cl, E. Coli, Faecal Coliforms.
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Vol.6 No.8, 2014 
3. Results 
3.1. Metrology Measurements: 
Efficiency oftheSolar Reactor process is dependent on theamountofsunlightavailable a nd solarradiation, 
however, is unevenly distributed and varies in intensity from one geographical location to another depending on 
latitude, season and the time of the day Baghdad forSolar Collector which is locatedLatitude33 Over 90% of the 
sunlight touch the earth as direct radiation due to the limited cloud cover and rainfall (less than 250mm rain and 
usually more than 3350 hours of sunshine annually). The date of hourly solar energy, air temperatura, relative 
humidity, wind speed are graphed in figuers (2) to (7) can therefore rely as an energy source for solar 
disinfection of drinking water 
. 
22 
Water tank 
Solar collector 
Pressure Guage 
Panel inclined angle=300 
Flow meter panel 
fig(1 ) plate (1) 
1400 
1200 
1000 
800 
600 
400 
200 
0 
march 
january 
february 
april 
may 
june 
october 
november 
july 
august 
september 
december 
Date , Month 
Fig. (3): The Monthly variation of solar radiation in 
Baghdad city 
Solar Radiation W/m2 
AVG max min 
60 
50 
40 
30 
20 
10 
0 
march 
january 
february 
april 
may 
june 
july 
august 
september 
october 
november 
december 
Time , Month 
Temperature, 0C 
avg max min 
Fig. (2): The Monthly variation of air temperature in 
Baghdad city
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Vol.6 No.8, 2014 
2.5 
2 
1.5 
1 
0.5 
march 
February 
April 
May 
June 
July 
August 
September 
October 
November 
December 
Date, Months 
70 
60 
50 
40 
30 
20 
10 
october 
november 
october 
november 
120 
100 
80 
60 
40 
20 
BOD5 mg/L-COD mg/L- TDS mg/L-Tss mg/L – Turbidity NTU 
3.2. Physiochemical Properties of Greywater 
The physical and chemical properties of Greywater are highly variable depending on the source, and are 
influenced by many factors including the number of household occupants, types of cleaners and personal care 
products used, grooming and hygiene habits, and sink waste disposal practices (Eriksson et al., 2002). 
Concentration ranges for common water quality constituents compiled from three studies are listed in Table (2) 
to (3). The values presented Eriksson et al. are for low-load Greywater only derived from bathroom sinks, 
showers, and baths. The values 8 from Rose et al. (1991) are in reference to Greywater not including kitchen 
sources composited in a storage tank. The values from Gross et al. (2007b) refer to Greywater mixed artificially 
23 
0 
january 
february 
april 
may 
june 
july 
august 
september 
october 
november 
december 
month 
log reduction 
0.2 
0.18 
0.16 
0.14 
0.12 
0.1 
0.08 
0.06 
0.04 
0.02 
0 
Fig (4) : The Monthly UV dose in Baghdad city Fig (5) : The Monthly UV dose exposure in Baghdad city 
UV Dose 
avg max min 
0 
january 
february 
march 
april 
may 
june 
july 
august 
september 
december 
months 
Wind Speed (m/s) 
avg max min 
120 
100 
80 
60 
40 
20 
0 
january 
february 
march 
april 
may 
june 
july 
august 
september 
december 
Months 
Relative Humidity % 
avg max min 
Fig.(6): The monthly variation of relative humidity in Baghdad 
city 
Fig.(7): The monthly variation of wind speed 
in Baghdad city 
different average Parameters with time 
500 
450 
400 
350 
300 
250 
200 
150 
100 
50 
0 
August September October November December 
months 
parameters 
BOD5 COD TDS TSS turbidity 
y = 147.67e-0.0255x 
R2 = 0.9882 
0 
0 20 40 60 80 100 120 
Turbidity ( NTU ) 
Disinfection effeciency % 
Fig (8 ): Different average parameters with time in Baghdad city Fig (9): Disinfection Effeciency with turbidity
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Vol.6 No.8, 2014 
to replicate Greywater from mixed sources. 
To study the effects of solar radiation and heating on the inactivation of E. coli, experiments are conducted from 
Febreuary to December 2013. For each experiment, the test reactors are prepared and spiked with E. coli in the 
laboratory. The initial temperature and turbidity of each test is recorded and samples must be taken to enumerate 
the starting concentration of bacteria. The test are then exposes to sunlight and samples have to be collected at 
predetermined intervals to determine the bacteria concentration. During each sampling time, air temperature, 
water temperature, and solar irradiance are measured and the log inactivation of bacteria is calculated over time. 
The results of the solar radiation and heating experiments are then analyzed and compared to the results of the 
heating only experiments. 
The greywater characteristics in this study were measured in table( 2) figure (8 ) 
Table(2) :Quantity of Pollutants Loading (minimum and maximum value ) Measure dinmgper Liter for sixty one 
samples for period from August to December 2010. 
Parameter August September October November December 
BOD5(mg/l) 158-187 119-169 105-164 91-158 89-132 
COD(mg/l) 287-390 267-313 123-240 144-180 156-230 
pH 8.6-9.5 7.7-7.9 7.9-8.3 7.6-8.2 7.4-7.8 
SuspendedSolid(mg/l) 88-137 42-76 37-65 36-45 39-76 
TotalSolid(mg/l) 345-546 322-418 296-396 287-354 234-344 
TotalPhosphorus(mg/l) 7-9 8- 
24 
11 
7-13 9-12 9-13 
PresumptiveFaecal 2.50E+05 8.00E+05 8.00E+03 6.00E+03 5.00E+03 
Coliforms 0. 
6 
0. 
3 
0.3 0.4 0.4 
NitrateN(mg/l) 0.07 0.0 
3 
0.02 0.008 0.03 
Nitrite N(mg/l) 2 
3 
3 
6 
34 2 
7 
28 
TurbidityNTU 44-78 34-62 28-47 29-43 23-46 
Lead(mg/l) 4 1 
1 
7 1 
5 
16 
Zinc(mg/l) 6 
7 
7 
6 
43 5 
6 
81 
Copper(mg/l) 9 
7 
11 
2 
108 132 107 
The basic treatment has been achieved using biological treatment for 6 hrs to make dissolved oxygen of 3 to 
4 mg/l 
Table(3): Average Values of Composition of grey water from different sources in Baghdad households based on 
measurements of 50 to 118 for each parameter compared to the concentration of domestic black water. 
Greywater from 
bathtubs,showers and 
hand basins 
Greywater from 
bathtubs, showers, hand basins 
and washing machine 
(including baby diaper) 
Greywater from bathtubs, 
showers, hand basins, 
washing machines 
and kitchen 
Domestic 
wastewater 
(black water) 
BOD5 (mg/l) 113 193 372 281 
COD (mg/l) 234 354 546 567 
TSS (mg/l) 46 n/a n/a 224 
Ptotal 1.8 n/a 6.2 17 
Ntotal 11.8 n/a 15.6 73 
Total coliforms 
(MPN/ml) 105 104 104 106 
E. coli 
(MPN/ml) 104 104 105 106 
pH 7, 7 n/a 7.4 6.7
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3.3.Microbiologic analysis 
The UV disinfection efficiency was evaluated by the enumeration of the live pathogenic colonies after each 
experiment. The MPN method (most probable number) was followed to enumerate total and fecalcoliforms, 
streptococci, staphylococci, sulphite-reducing sporesand fungi. 
Thesampleswerefilteredby0.45micrometerthenseedinginselectiveculturemediaduring 
48hours. The number of microorganisms was plotted as CFU(Colony forming units)/100ml and the 
disinfection result is plotted in Logreduction as follows: 
25 
Log reduction = log C0 ……………….. (1) 
where: C 
C0: number of survival pathogenic before treatment. 
C: number of survival pathogenic after treatment. 
For grey water with turbidity less than 30 NTU the disinfection resultsachieved2.5 Log-reduction of total 
coliforms,3.4 Log reduction off ecalcoliforms, where 2.72-Logreductionofstreptococci,3.2- 
Logreductionofstaphylococci,0.07-logreduction of yeasts, 0.18- Log reduction of molds and 1.17-logreduction of 
sulphite-reducing spores. 
The disinfection effeciency reduced extremely when grey water turbidity is more tan( 60 NTU ). 
3.3.1. Effect of Solar reactor on pathogens 
Human pathogens are adapted to live in the human intestines, where they find a dark, humid environment and 
temperatures ranging between 36°C and 37°C. Once the pathogens are discharged into the environment, they 
are very sensitive to the harsh conditions outside the human body. They are not able to resist increased 
temperatures and they do not have any protection mechanisms against UV radiation. Therefore, temperature and 
UV radiation can be used to inactivate the pathogens. 
The solar energy required will vary according to type and concentration of pathogen and greywatercharacterstics 
such as turbidity fig.(9), and pH fig ( ), oxygen content, mineral salts, humic substances, colour, and other 
factors, solar reaction design such as the diameter (depth) of water, type of backing (reflective, absorptive), 
shape of container, material composition, etc. Bacteria and most viruses are relatively easy to destroy, while 
bacterial spores, and parasitic eggs, cysts or oocysts, are relatively difficult. The most UV resistant organism is 
the Ascaris egg, which, due likely to the protein cost, requires a fluence of 8 KJ/m2. However, this pathogen is 
not normally water borne. The most difficult water borne organism to destroy is the Bacillus subtilis spore15, 
which required a fluence of 2.22 KJ/cm2These energies refer to UVC radiation, typically at 253.7 nm, which is 
not available in natural solar radiation. 
Natural solar radiation available at ground level includes: UVA (280-320nm) , UVB (320-400nm), Visible light 
(400-700nm), and Infrared (700-14,000nm) 
120 
100 
80 
60 
40 
20 
Fig.(10): Monthly Percentage of Graywater Samples 
Positive for Fecal Coliforms and E. coli 
Fig. (11) : Mean values of pH and Feacl Coliforms in 
greywater in Baghdad 
0 
1/12013 
14/01/2013 
02/01/2013 
02/01/2013 
04/01/2013 
05/01/2013 
14/05/2013 
01/06/2013 
01/07/2013 
01/08/2013 
14/08/2013 
Date 
Percentage of Greywater 
Samples Positive for Fecal 
Coliforms 
coliforms E. coli
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Vol.6 No.8, 2014 
1000000 
100000 
10000 
1000 
100 
10 
may 
june 
1000000 
100000 
10000 
1000 
100 
10 
Fig(13): The monthly Fecal Coliform in Baghdad Fig(14): Fecal Coliform in Baghdad city 
june 
3.4. Effects of UV-radiation 
Solar radiation in to three ranges of wave length: UV radiation, visible light and infrared radiation. UV 
radiation is a very aggressive radiation that can cause severe damage to the skin and eyes and destroys living 
cells.Luckily most of the UV-Cand UV-Blight in the range of 200 to 320nm is absorbed by the ozone 
(O3)layer in the atmosphere which protects the earth from radiation coming from space. Only a higher fraction 
of UV-Aradiation in the wave length range of 320nm–400nm, near the visible violet light, reaches the surface 
of the earth. 
The solar UV-Aintensity shows both seasonal and daily variations. 
The seasonal variation depends on the latitude and is mainly responsible for the climate in that region. In 
Baghdad for example(latitude:33°N),the UV-A radiationintensityreachesapeaklevelof0.19 KW/m2 in May, July 
0,16 KW/m2 and decreases to 0.05 KW/m2in December, while UV- A radiation intensity reaches a peak level of 
0.16 Kw/m2 
The sola radiation intensity is also subject to daily variations. With increasing cloudiness, less radiation energy 
is available. During completely montor days the UV-Aradiation intensity is reduced to 30% of the intensity 
recorded during a cloudy day. 
During very cloudy days, the Solar Collector have to be exposed for two consecutive days toreach the required 
radiation dose and to ensure the complete inactivation of the pathogens 
1200 
1000 
800 
600 
400 
200 
0 
Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 
Months 
Solar Rate W/m2 
UV-Alighthasalethaleffectonhumanpathogenspresentin water.Thesepathogensarenotwelladaptedtoaggressive 
environmentalconditionsastheyfindtheirspecificliving conditionsinthehumangastrointestinaltract.Therefore,they 
aremoresensitivetosunlightthanorganismscommonly abundant in the environment. 
Three effects of solar radiation are believed to contribute to the inactivation of pathogenic organisms 
· UV-A interferes directly with the metabolism and destroys cell structures of bacteria. 
· UV-A (wavelength 320–400 nm) reacts with oxygen dissolved in the water and produces highly 
26 
1 
january 
february 
july 
october 
january 
february 
july 
Months 
Geometric mean (CFU/100ml) 
1 
january 
june 
february 
july 
april 
august 
may 
june 
january 
march 
august 
september 
july 
april 
september 
november 
november 
december 
december 
Months 
Fcal Colform 
Fig (15) : The monthly Solar Rate Fig (14): The monthly solar radiationo of sun exposure in Baghdad in Baghdad city 
city
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Vol.6 No.8, 2014 
reactive forms of oxygen (oxygen free radicals and hydrogen peroxides) that are believed to also 
damage pathogens. 
· Cumulative solar energy (including the infrared radiation component) heats the water. If the water 
temperatures rises above 50 °C (122 °F), the disinfection process is three times faster. 
At a water temperature of about 30 °C (86 °F), a threshold solar irradiance of at least 500 W/m2 (all spectral 
light) is required for about 5 hours for SODIS to be efficient. This dose contains energy of 555 Wh/m2 in the 
range of UV-A and violet light, 350–450 nm, corresponding to about 6 hours of mid-latitude midday summer 
sunshine.At water temperature higher than 450C (113 0F), synergistics effects of UV radiation and temperature 
further enhance the disinfection efficiency (more than 30 NTU and distillation ability decreases extremely. 
Greywaterfilteration is very important before solar disinfection when the turbidity is more than 30 NTU and 
distillation ability decreases extremely 
27 
Conclusions 
Solar disinfection of greywater using multi-stage solar collector has been conducted and tested during period 
( Febreuary 2013 to December 2013).The basic conclusions can be: 
1- The solar reactor performance depends on sunlight available , solar radiation, turbidity and water 
temperature, air temperature, relative humidity and sun shine duration. 
2- The disinfection effeciency of multi stage solar reactors reduced extremely when greywater turbidity 
more that 60 NTU, and increased with significant rate for greywater turbidity less than 30 NTU. 
3- At water temperatures higher than 45 °C (113 °F), synergistic effects of UV radiation and temperature 
further enhance the disinfection efficiency. More than 98% for turbidity less than (30 NTU). 
4- Theseasonaldifferencesofsolarradiationareimportant fortheapplicabilityofsolarwaterdisinfection.Atotal 
solar radiation intensity of at least 0.5 KW/m2 is required for approximately 6 hours for Solar reactor 
to be effective. 
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Greywater disinfection by solar reactor in baghdad

  • 1. Chemistry and Materials Research www.iiste.org ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online) Vol.6 No.8, 2014 Greywater Disinfection by SolarReactor in Baghdad SeroorAtallahKhaleefa Ali College of Engineering Environmental Department Al Mustanseriya University Mob:+9647901442796 Email: [email protected] Abstract Solar disinfection is an efficient method for greywater treatment where it is exposed to solar radiation to inactivate pathogenic organisms.Solar disinfection is affected by numerous variables which include the wavelengths of solar radiation, water temperature, turbidity, and reactor selection. A Laborotary model of solar reacter has been designed and constructed at Environmental Hydraulic in Mustansiriya University/College of Engineering. The model consists of four independent Acrylic reactors of 100mm diameter and 1300mm length, filled with different materials for filtration and disinfection including (sand, Black granite, Granular activated carbón, and Mixture of granular activated carbonated black granite). Thesolardisinfectiontreatmentwas experimented bya8 L multistage contiuous flow with recycling ratio 4 .The treatmentprocesses still incomplete wherethe tertiarytreatmentisnotapplied in many treatment plants in Iraq.Thissituationcouldcompromisetheplannedwastewater reuseregardingespecially themicrobialquality. KeyWord: Solar Energy, Disinfection, Greywater, Multi Stage reactor 1-Introduction Greywater can be contaminated by activities such as bathing and clothes washing. Disease-causing organisms in greywater are principally transmitted through ingestion of greywater via contaminated hands, aerosols from spray irrigation (usually only allowed for use with suitably treated greywater), or indirectly through contact with contaminated items such as grass, soil, toys and garden implements. (Dheyaa et. al, 2013) Inaridareas of Baghdad, water conservation and reuse are issues that receive a great deal of public attention in the last decade. The search for way store sponsibly use and reuse water is vital to the sustainability of the water supply and thus the future of the seregions Treated grey water in house scanbere used fortoilet flushing, outdoor irrigationandspraying water evaporation cooling of selected apartments building located in Baghdad. Treated wastewateralsocanbeusedforirrigationandstreetscleaningbymunicipalinstitutes.Several experiments in Baghdad have been achieved for small scale to reuse greywaterfor toilet flushing, irrigation, outside housecleaning and evaporative cooling. Baghdad's Water demand is estimated to 3.2Millionm3/sec, the quantity of produce dwateris (66%)of the required needs (Dheyaa et.al, 2014) Untreated greywater is not considered suitable for spray irrigation and human contact should be avoided if bucketing or maintaining greywater diversion or irrigation systems ( Table 1 ). (Dheyaa et.al, 2014) Table 1: International Criteria for Reuse, Surendran and Wheatley, 1998 20 Faecal coliforms cfu/100ml Total coliforms cfu/100 ml BOD mg/l Turbidity NTU TSS (mg/l) DO% % saturation PH Cl2 Residual mg/l US EPA (g) 14 for any sample 0 for 90% samples 10 2 6-9 1 Florida (m) 25 for any sample 0 for 75% samples 20 5 1 Texas (m) 75 (m) 5 3 Germany (g) 100 (g) 500 (g) 20 (g) 1-2 (m) 30 80-120 6-9 Japan (m) 10 for any sample 10 10 5 6-9 South Africa (g) 0 (g) WHO Iawn 200 (g) irrigation 1000 (m) EC bathing water 100 (g) 2000 (m) 500 (g) 10000 (m) 2 m (g) 1 m (m) 80-120 6-9 UK (BSRIA) Proposed (g) 14 for any sample 0 for 90% A study which aimed at evaluating the amount of grey water generation in the city of Baghdad has been carried out by Dheyaaetal.(2009). The study showed that the water consumption in Baghdad in August averaged 138
  • 2. Chemistry and Materials Research www.iiste.org ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online) Vol.6 No.8, 2014 Liters per capita per day (120-200Lpcd); while the water consumption in Baghdad in December averaged 75 Liters per capita per day (58-100Lpcd). Greywaterrepresenta an incontestable release source of many chemicals, physical and biological compounds which may havean impact on the environment and human health. Water disinfection methods can be divided into two categories. The first category is chemical disinfection. Which includes methods such as chlorination and iodine treatment.However. The other catogary physical treatment methods such as boiling water and UV treatment which is only effective for low turbid water and therefore pretreatment such as filtering is required for poor water quality sources Solar water disinfection is a type of portable water purification that uses solar energy, in one or more ways, to make contaminated water safe to drink by ridding it of infectious disease-causing biological agents such as bacteria, viruses, protozoa and worms. However, disinfection may not make all kinds of water safe to drink due to non-biological agents such as toxic chemicals or heavy metals. Consequently, additional steps beyond disinfection may be necessary to make water clean to drink. . Solar thermal water disinfection uses heat from the sun to heat water to 70C-100oC for a short period of time. A number of approaches exist here. Solar heat collectors can have lenses in front of them, or use reflectors. They may also use varying levels of insulation or glazing. In addition, some solar thermal water disinfection processes are batch-based, while others (through-flow solar thermal disinfection) operate almost continuously while the sun shines. Water heated to temperatures below 100C is generally referred to as Pasteurized water (SANDEC, 2010). . UV radiation is subdivided into UVA (400–320nm)which constitutes94%’sUV radiation. The rest is constitutes by UVB(320–290nm) and UVC (290–200nm) (Meierhofer R, 2002). In the disinfection technologies, UV radiation is used because it induces harmful photo biological effects. The researches improvement all owed their successful application against all water borne pathogens (Hijnenet al. (2006). Comparatively to UVB and UVC, UVA radiation is more abundant in the solar spectrum but induces the lower photo biological effects. The wave lengths radiations inferior to 320 nmare more active which induces the subdivision of UVA into UVAI (400–340nm) and UVAII (340–320 nm) (Meierhofer R, 2002) Direct UV radiation use (photolysis) remains less effective by themselves, the combination of UV and semi-conductors metals (photocatalysis) as TiO2;ZnO, Ag…records better results in water-and air-purification and several antibacterial products (Fujishima et al.(2000) Many several studies advised UV disinfection for its efficiency and safe use especially for the wastewater treatment intended for the reuse (Adam Jokerst , 2012). The objective of this research is to test the inactivation of different bacteria by solar disinfection using multi stage of Solar Reacter. The variables tested have to be water , turbidity, and exposure time. The inactivation of E. coli in the samples is quantified over time. 2- Material and Methodlogy A Laborotary Models of Solar Reacter has been designed and constructed at Environmental Hydraulic in Mustansiriya University/College of Engineering as shown in plate (1) and fig.(1) The model consists of four independent acrylic reactors of 100mm diameter and 1300mm length ,filled with different materials biofiltration and disinfection, as shown in table (1). Measurments were achieved during period from Febreuary to December 2013 in Baghdad Table (1 ) Types of reactors and media used Type of reactor Type of media effective size mm Uniformity factor 1st reactor Sand of effective grain size 0.7 1.4 2nd reactor Black granite 1.2 1.8 3rd reactor Granular activated carbon 2.2 2.4 4th reactor Mixture of granular activated 21 carbonated black granite 1.2 2.4 Tests includ : PH,TDS,TSS,BOD5,COD,Cl, E. Coli, Faecal Coliforms.
  • 3. Chemistry and Materials Research www.iiste.org ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online) Vol.6 No.8, 2014 3. Results 3.1. Metrology Measurements: Efficiency oftheSolar Reactor process is dependent on theamountofsunlightavailable a nd solarradiation, however, is unevenly distributed and varies in intensity from one geographical location to another depending on latitude, season and the time of the day Baghdad forSolar Collector which is locatedLatitude33 Over 90% of the sunlight touch the earth as direct radiation due to the limited cloud cover and rainfall (less than 250mm rain and usually more than 3350 hours of sunshine annually). The date of hourly solar energy, air temperatura, relative humidity, wind speed are graphed in figuers (2) to (7) can therefore rely as an energy source for solar disinfection of drinking water . 22 Water tank Solar collector Pressure Guage Panel inclined angle=300 Flow meter panel fig(1 ) plate (1) 1400 1200 1000 800 600 400 200 0 march january february april may june october november july august september december Date , Month Fig. (3): The Monthly variation of solar radiation in Baghdad city Solar Radiation W/m2 AVG max min 60 50 40 30 20 10 0 march january february april may june july august september october november december Time , Month Temperature, 0C avg max min Fig. (2): The Monthly variation of air temperature in Baghdad city
  • 4. Chemistry and Materials Research www.iiste.org ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online) Vol.6 No.8, 2014 2.5 2 1.5 1 0.5 march February April May June July August September October November December Date, Months 70 60 50 40 30 20 10 october november october november 120 100 80 60 40 20 BOD5 mg/L-COD mg/L- TDS mg/L-Tss mg/L – Turbidity NTU 3.2. Physiochemical Properties of Greywater The physical and chemical properties of Greywater are highly variable depending on the source, and are influenced by many factors including the number of household occupants, types of cleaners and personal care products used, grooming and hygiene habits, and sink waste disposal practices (Eriksson et al., 2002). Concentration ranges for common water quality constituents compiled from three studies are listed in Table (2) to (3). The values presented Eriksson et al. are for low-load Greywater only derived from bathroom sinks, showers, and baths. The values 8 from Rose et al. (1991) are in reference to Greywater not including kitchen sources composited in a storage tank. The values from Gross et al. (2007b) refer to Greywater mixed artificially 23 0 january february april may june july august september october november december month log reduction 0.2 0.18 0.16 0.14 0.12 0.1 0.08 0.06 0.04 0.02 0 Fig (4) : The Monthly UV dose in Baghdad city Fig (5) : The Monthly UV dose exposure in Baghdad city UV Dose avg max min 0 january february march april may june july august september december months Wind Speed (m/s) avg max min 120 100 80 60 40 20 0 january february march april may june july august september december Months Relative Humidity % avg max min Fig.(6): The monthly variation of relative humidity in Baghdad city Fig.(7): The monthly variation of wind speed in Baghdad city different average Parameters with time 500 450 400 350 300 250 200 150 100 50 0 August September October November December months parameters BOD5 COD TDS TSS turbidity y = 147.67e-0.0255x R2 = 0.9882 0 0 20 40 60 80 100 120 Turbidity ( NTU ) Disinfection effeciency % Fig (8 ): Different average parameters with time in Baghdad city Fig (9): Disinfection Effeciency with turbidity
  • 5. Chemistry and Materials Research www.iiste.org ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online) Vol.6 No.8, 2014 to replicate Greywater from mixed sources. To study the effects of solar radiation and heating on the inactivation of E. coli, experiments are conducted from Febreuary to December 2013. For each experiment, the test reactors are prepared and spiked with E. coli in the laboratory. The initial temperature and turbidity of each test is recorded and samples must be taken to enumerate the starting concentration of bacteria. The test are then exposes to sunlight and samples have to be collected at predetermined intervals to determine the bacteria concentration. During each sampling time, air temperature, water temperature, and solar irradiance are measured and the log inactivation of bacteria is calculated over time. The results of the solar radiation and heating experiments are then analyzed and compared to the results of the heating only experiments. The greywater characteristics in this study were measured in table( 2) figure (8 ) Table(2) :Quantity of Pollutants Loading (minimum and maximum value ) Measure dinmgper Liter for sixty one samples for period from August to December 2010. Parameter August September October November December BOD5(mg/l) 158-187 119-169 105-164 91-158 89-132 COD(mg/l) 287-390 267-313 123-240 144-180 156-230 pH 8.6-9.5 7.7-7.9 7.9-8.3 7.6-8.2 7.4-7.8 SuspendedSolid(mg/l) 88-137 42-76 37-65 36-45 39-76 TotalSolid(mg/l) 345-546 322-418 296-396 287-354 234-344 TotalPhosphorus(mg/l) 7-9 8- 24 11 7-13 9-12 9-13 PresumptiveFaecal 2.50E+05 8.00E+05 8.00E+03 6.00E+03 5.00E+03 Coliforms 0. 6 0. 3 0.3 0.4 0.4 NitrateN(mg/l) 0.07 0.0 3 0.02 0.008 0.03 Nitrite N(mg/l) 2 3 3 6 34 2 7 28 TurbidityNTU 44-78 34-62 28-47 29-43 23-46 Lead(mg/l) 4 1 1 7 1 5 16 Zinc(mg/l) 6 7 7 6 43 5 6 81 Copper(mg/l) 9 7 11 2 108 132 107 The basic treatment has been achieved using biological treatment for 6 hrs to make dissolved oxygen of 3 to 4 mg/l Table(3): Average Values of Composition of grey water from different sources in Baghdad households based on measurements of 50 to 118 for each parameter compared to the concentration of domestic black water. Greywater from bathtubs,showers and hand basins Greywater from bathtubs, showers, hand basins and washing machine (including baby diaper) Greywater from bathtubs, showers, hand basins, washing machines and kitchen Domestic wastewater (black water) BOD5 (mg/l) 113 193 372 281 COD (mg/l) 234 354 546 567 TSS (mg/l) 46 n/a n/a 224 Ptotal 1.8 n/a 6.2 17 Ntotal 11.8 n/a 15.6 73 Total coliforms (MPN/ml) 105 104 104 106 E. coli (MPN/ml) 104 104 105 106 pH 7, 7 n/a 7.4 6.7
  • 6. Chemistry and Materials Research www.iiste.org ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online) Vol.6 No.8, 2014 3.3.Microbiologic analysis The UV disinfection efficiency was evaluated by the enumeration of the live pathogenic colonies after each experiment. The MPN method (most probable number) was followed to enumerate total and fecalcoliforms, streptococci, staphylococci, sulphite-reducing sporesand fungi. Thesampleswerefilteredby0.45micrometerthenseedinginselectiveculturemediaduring 48hours. The number of microorganisms was plotted as CFU(Colony forming units)/100ml and the disinfection result is plotted in Logreduction as follows: 25 Log reduction = log C0 ……………….. (1) where: C C0: number of survival pathogenic before treatment. C: number of survival pathogenic after treatment. For grey water with turbidity less than 30 NTU the disinfection resultsachieved2.5 Log-reduction of total coliforms,3.4 Log reduction off ecalcoliforms, where 2.72-Logreductionofstreptococci,3.2- Logreductionofstaphylococci,0.07-logreduction of yeasts, 0.18- Log reduction of molds and 1.17-logreduction of sulphite-reducing spores. The disinfection effeciency reduced extremely when grey water turbidity is more tan( 60 NTU ). 3.3.1. Effect of Solar reactor on pathogens Human pathogens are adapted to live in the human intestines, where they find a dark, humid environment and temperatures ranging between 36°C and 37°C. Once the pathogens are discharged into the environment, they are very sensitive to the harsh conditions outside the human body. They are not able to resist increased temperatures and they do not have any protection mechanisms against UV radiation. Therefore, temperature and UV radiation can be used to inactivate the pathogens. The solar energy required will vary according to type and concentration of pathogen and greywatercharacterstics such as turbidity fig.(9), and pH fig ( ), oxygen content, mineral salts, humic substances, colour, and other factors, solar reaction design such as the diameter (depth) of water, type of backing (reflective, absorptive), shape of container, material composition, etc. Bacteria and most viruses are relatively easy to destroy, while bacterial spores, and parasitic eggs, cysts or oocysts, are relatively difficult. The most UV resistant organism is the Ascaris egg, which, due likely to the protein cost, requires a fluence of 8 KJ/m2. However, this pathogen is not normally water borne. The most difficult water borne organism to destroy is the Bacillus subtilis spore15, which required a fluence of 2.22 KJ/cm2These energies refer to UVC radiation, typically at 253.7 nm, which is not available in natural solar radiation. Natural solar radiation available at ground level includes: UVA (280-320nm) , UVB (320-400nm), Visible light (400-700nm), and Infrared (700-14,000nm) 120 100 80 60 40 20 Fig.(10): Monthly Percentage of Graywater Samples Positive for Fecal Coliforms and E. coli Fig. (11) : Mean values of pH and Feacl Coliforms in greywater in Baghdad 0 1/12013 14/01/2013 02/01/2013 02/01/2013 04/01/2013 05/01/2013 14/05/2013 01/06/2013 01/07/2013 01/08/2013 14/08/2013 Date Percentage of Greywater Samples Positive for Fecal Coliforms coliforms E. coli
  • 7. Chemistry and Materials Research www.iiste.org ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online) Vol.6 No.8, 2014 1000000 100000 10000 1000 100 10 may june 1000000 100000 10000 1000 100 10 Fig(13): The monthly Fecal Coliform in Baghdad Fig(14): Fecal Coliform in Baghdad city june 3.4. Effects of UV-radiation Solar radiation in to three ranges of wave length: UV radiation, visible light and infrared radiation. UV radiation is a very aggressive radiation that can cause severe damage to the skin and eyes and destroys living cells.Luckily most of the UV-Cand UV-Blight in the range of 200 to 320nm is absorbed by the ozone (O3)layer in the atmosphere which protects the earth from radiation coming from space. Only a higher fraction of UV-Aradiation in the wave length range of 320nm–400nm, near the visible violet light, reaches the surface of the earth. The solar UV-Aintensity shows both seasonal and daily variations. The seasonal variation depends on the latitude and is mainly responsible for the climate in that region. In Baghdad for example(latitude:33°N),the UV-A radiationintensityreachesapeaklevelof0.19 KW/m2 in May, July 0,16 KW/m2 and decreases to 0.05 KW/m2in December, while UV- A radiation intensity reaches a peak level of 0.16 Kw/m2 The sola radiation intensity is also subject to daily variations. With increasing cloudiness, less radiation energy is available. During completely montor days the UV-Aradiation intensity is reduced to 30% of the intensity recorded during a cloudy day. During very cloudy days, the Solar Collector have to be exposed for two consecutive days toreach the required radiation dose and to ensure the complete inactivation of the pathogens 1200 1000 800 600 400 200 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Months Solar Rate W/m2 UV-Alighthasalethaleffectonhumanpathogenspresentin water.Thesepathogensarenotwelladaptedtoaggressive environmentalconditionsastheyfindtheirspecificliving conditionsinthehumangastrointestinaltract.Therefore,they aremoresensitivetosunlightthanorganismscommonly abundant in the environment. Three effects of solar radiation are believed to contribute to the inactivation of pathogenic organisms · UV-A interferes directly with the metabolism and destroys cell structures of bacteria. · UV-A (wavelength 320–400 nm) reacts with oxygen dissolved in the water and produces highly 26 1 january february july october january february july Months Geometric mean (CFU/100ml) 1 january june february july april august may june january march august september july april september november november december december Months Fcal Colform Fig (15) : The monthly Solar Rate Fig (14): The monthly solar radiationo of sun exposure in Baghdad in Baghdad city city
  • 8. Chemistry and Materials Research www.iiste.org ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online) Vol.6 No.8, 2014 reactive forms of oxygen (oxygen free radicals and hydrogen peroxides) that are believed to also damage pathogens. · Cumulative solar energy (including the infrared radiation component) heats the water. If the water temperatures rises above 50 °C (122 °F), the disinfection process is three times faster. At a water temperature of about 30 °C (86 °F), a threshold solar irradiance of at least 500 W/m2 (all spectral light) is required for about 5 hours for SODIS to be efficient. This dose contains energy of 555 Wh/m2 in the range of UV-A and violet light, 350–450 nm, corresponding to about 6 hours of mid-latitude midday summer sunshine.At water temperature higher than 450C (113 0F), synergistics effects of UV radiation and temperature further enhance the disinfection efficiency (more than 30 NTU and distillation ability decreases extremely. Greywaterfilteration is very important before solar disinfection when the turbidity is more than 30 NTU and distillation ability decreases extremely 27 Conclusions Solar disinfection of greywater using multi-stage solar collector has been conducted and tested during period ( Febreuary 2013 to December 2013).The basic conclusions can be: 1- The solar reactor performance depends on sunlight available , solar radiation, turbidity and water temperature, air temperature, relative humidity and sun shine duration. 2- The disinfection effeciency of multi stage solar reactors reduced extremely when greywater turbidity more that 60 NTU, and increased with significant rate for greywater turbidity less than 30 NTU. 3- At water temperatures higher than 45 °C (113 °F), synergistic effects of UV radiation and temperature further enhance the disinfection efficiency. More than 98% for turbidity less than (30 NTU). 4- Theseasonaldifferencesofsolarradiationareimportant fortheapplicabilityofsolarwaterdisinfection.Atotal solar radiation intensity of at least 0.5 KW/m2 is required for approximately 6 hours for Solar reactor to be effective. References 1- Acra,A.etal.(1980).DisinfectionofOralRehydrationSolutionsbySunlight.The Lancet 2:1257-1258. 2- Dheyaa, WajidAbbod et al, Water Status in Baghdad, Journal of Environmental Science and Engineering B, volume 1, Number 5, May 2012 ( seial number 5) 3- Dheyaa, WajidAbbod, AyadSliebi, Dheyaa, SeroorAtallahKhaleefa Ali, social Investigation of Greywater Reuse in Baghdad,Civil and Environmental Resrarch, 2014. 4- Dheyaa, WajidAbbod, SeroorAtallahKhaleefa Ali, SuhaAnwer, Greywater Reuse Assessments on Different Soil, Journal of Environmental Science and Engineering, USA, 2014 5- Household water treatment and safe storage". World Health Organization. Retrieved 30 November 2010. 6- Training material". Swiss Federal Institute of Environmental Science and Technology (EAWAG) Department of Water and Sanitation in Developing Countries (SANDEC). Retrieved 1 February 2010. 7- Meierhofer R, Wegelin M (October 2002). Solar water disinfection — A guide for the application of SODIS. Swiss Federal Institute of Environmental Science and Technology (EAWAG) Department of Water and Sanitation in Developing Countries (SANDEC). ISBN 3-906484-24-6. 8- Greywater Treatment Using Constructed Wetlands, EPA/600/R-12/684 | October 2012 | www.epa.gov/gateway/scienceGreywater Treatment Using Constructed Wetlands by Adam Jokerst1, Meg Hollowed1, Sybil Sharvelle1, Larry Roesner (retired)1, A. Charles Rowney2 9- Resources and nutrients oriented greywater treatment for non-potable reuses Fangyue Li, Joachim Behrendt, Knut Wichmann and Ralf Otterpo, WA Publishing 2008 10- Water Science & Technology—WST 57.12 2008 11- Resources and nutrients oriented greywater treatment for non-potable reuses Fangyue Li, Joachim Behrendt, Knut Wichmann and Ralf Otterpohl 12- Water Quality: Guidelines, Standards and Health, 2012. 13- Eriksson, E., Auffarth, K., Henze, M., and Ledin,A.(2002) Characteristics of grey waste water. Urban Water,4(1),85. 14- Dheyaa, W.A.(2009)Saving Water and Energy Consumption in Baghdad.(2009), Baghdad, Water
  • 9. Chemistry and Materials Research www.iiste.org ISSN 2224- 3224 (Print) ISSN 2225- 0956 (Online) Vol.6 No.8, 2014 consumption problem in Baghdad symposium, Baghdad government .Baghdad ,Iraq. 15- Erikkson,E.,Auffarth,K.,Henze,M.andLedin,A.2002.Characteristics of Grey Wastewater, Urban Water 28 (4):85-104. 16- Rose, Joan. The Application of a Risk Assessment Model for Pathogenic Microorganisms in Sludge: A Case History of Risk from Sludge Treated Playing Fields (unpublished). 17- Household Water Treatment Options in Developing Countries: CDC, Solar Disinfection (SODIS) , January 2008 18- Brian L.B.L. Diffey, Sources and measurement of ultra violet radiation, Academic press, Methods 28 (2002)4-13. 19- Ultra violet disinfection guidance manual, Office of water, United State Environmental Protection Agency EPA (2007)815-D-03-007. 20- Xiaoxu Zhao, Tatsushi Toyooka, YukoIbuki, Synergistic bactericidal effectby combined exposure to Agnanoparticles and UVA, Science of the Total Environment 458-460 (2013) 54-62. 21- Serkan Evcimeand Aslihan Kerc, Applicarion of UV disinfection in municipal wastewater treatment plants for agriculture use of reclaimed waste water in Turkey, Desal. Wat. Treat.,26 (2011) 39-44. 22- C. Hallmich, R. Gehr, Effect of pre- and post-UV disinfection conditions on Photo reactivation of ecalcoliforms in waste water effluents,Wat.Res.,44(2010)2885-2893. 23- M. Guo, M. Hu, J. R. Olton, J.R., M. and Gamal El-Din, Comparison of low-and medium-pressure ultraviolet lamps: photo reactivation of Escherichiacoli and total coliformsin secondary effluents of municipal waste water treatment plants,Wat.Res.,43 (3)(2009),815-820 24- Dheyaa Waiid Abbood, Ayad Sleibi Mustafa and Rasha Azeez Jouda. Modification of Grey water Treatment Using Cmbination of Gascade Aeration and Biofiltrstion(2013). Journal of Environmental Science annd Engineering B, Volume 2, No. 8, August 2013. 25- W.A. Dheyaa. Improvement of Greywater treatment using combination of trickling biofiltration and ozonation. 9th Canada- France-Japan-Korea Joint Conferenceon GE. Geo-rnvironmental Engineering. University of British Columbia. Vanouver British Columbia. Canada, 2009. 26- W. A. Dheyaa Water war in Baghdad, in 19th AnualConfrence of International Environmetrics Society Kelowna, Canada, June-8-13, 2008.
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