Impact of Biofield Treatment on Atomic and Structural Characteristics of Barium Titanate Powder

Research Article Open Access
Industrial Engineering & Management
Trivedi et al., Ind Eng Manage 2015, 4:3
http://dx.doi.org/10.4172/2169-0316.1000166
Volume 4 • Issue 3 • 1000166Ind Eng Manage
ISSN: 2169-0316, IEM an open access journal
Keywords: Biofield treatment; Barium titanate; Fourier transform
infrared; X-Ray diffraction; Electron spin resonance
Introduction
Piezoelectric materials are commonly used in optoelectronic
industries in fabricating sensor, capacitor, and actuator owing to their
piezoelectricity and wide range of dielectric constant. In these materials
a strong relationship exists between mechanical displacements and
electric field i.e. it induce electric polarization in response to applied
stress and strained in response to applied electric fields. The perovskite
structure, ABO3
type material usually exhibits spontaneous
polarizations in response to mechanical stress [1]. Additionally, this
perovskite structure is promising in positive coefficient (PCT) resistors,
light-emission devices, and field emission displays (FEDs) [2]. The
perovskite, barium titanate (BaTiO3
) has recently gain significant
attention due to its demand for lead-free piezoelectric materials in
several industries. In addition to that, the perovskite structure of
BaTiO3
attracted significant attention due to its exceptional dielectric,
piezoelectric, and electro optic properties [3]. These exceptional
properties make it a promising material for other applications
such as multilayer ceramic capacitors (MLCCs), dynamic random
access ferroelectric memories (DRAMs) [4]. This material requires
non-centrosymmetric crystal structure to behave as piezoelectric,
because its centrosymmetric cubic crystal structure doesn’t show
piezoelectricity, whereas hexagonal, tetragonal, orthorhombic, and
rhombohedral shows due to their non-centrosymmetric structure
[1]. In BaTiO3
the piezoelectricity is highly depends upon its crystal
structure, lattice vibration, and grain size etc. Furthermore, in order
to alter its piezoelectric and ferroelectric properties, many researchers
have used various doping methods to modify the dielectric and
piezoelectric properties [5,6]. Recently, it was reported that distortion
in perovskite BatiO3
reduced symmetry, which enhanced its magnetic
and electrical properties [7]. Moreover, Chernova et al. demonstrated
that strain induced in BaTiO3
unit cell enhanced its ferroelectric
polarizations [8]. Thus, after considering the vast importance of
BatiO3
and its crystal structure in several applications, authors wish to
investigate an approach that could be beneficial to modify the atomic
Impact of Biofield Treatment on Atomic and Structural Characteristics of
Barium Titanate Powder
Trivedi MK1
, Nayak G1
, Patil S1
, Tallapragada RM1
, Latiyal O2
and Jana S2
*
1
Trivedi Global Inc., 10624 S Eastern Avenue Suite A-969, Henderson, NV 89052, USA
2
Trivedi Science Research Laboratory Pvt. Ltd., Hall-A, Chinar Mega Mall, Chinar Fortune City, Hoshangabad Rd., Bhopal- 462026 Madhya Pradesh, India
Abstract
Barium titanate, perovskite structure is known for its high dielectric constant and piezoelectric properties, which
makes it interesting material for fabricating capacitors, transducer, actuator, and sensors. The perovskite crystal
structure and lattice vibrations play a crucial role in its piezoelectric and ferroelectric behavior. In the present study, the
barium titanate powder was subjected to biofield treatment. Further, the control and treated samples were characterized
using X-ray diffraction (XRD) and Fourier transform infrared spectrometer (FT-IR) and Electron spin resonance (ESR).
The XRD analysis showed the permanent compressive strain of 0.45% in treated barium titanate powder as compared
to control. Furthermore, the biofield treatment has enhanced the density upto 1.38% in barium titanate as compared to
control. The FT-IR spectra showed that the stretching and bending vibrations of Ti-O bond in treated BaTiO3
were shifted
towards lower frequency as compared to control. The bond length was substantially increased by 0.72 % in treated
BaTiO3
as compared to control. The ESR spectra of control and treated BaTiO3
sample showed the g-factor of 2.0;
and biofield treatment has substantially changed the width and height of ESR signal in treated BaTiO3
as compared to
control. These observations revealed that biofield treatment has significantly altered the crystal structure, lattice strain,
and bond vibration of barium titanate.
*Corresponding author: Snehasis Jana, Trivedi Science Research Laboratory
Pvt. Ltd., Hall-A, Chinar Mega Mall, Chinar Fortune City, Hoshangabad Rd.,
Bhopal- 462026, Madhya Pradesh, India, Tel: +91-755-6660006; E-mail:
publication@trivedisrl.com
Received June 22, 2015; Accepted August 04, 2015; Published August 06, 2015
Citation: Trivedi MK, Nayak G, Patil S, Tallapragada RM, Latiyal O, et al. (2015)
Impact of Biofield Treatment on Atomic and Structural Characteristics of Barium
Titanate Powder. Ind Eng Manage 4: 166. doi:10.4172/2169-0316.1000166
Copyright: © 2015 Trivedi MK, et al. This is an open-access article distributed
under the terms of the Creative Commons Attribution License, which permits
unrestricted use, distribution, and reproduction in any medium, provided the
original author and source are credited.
and structural properties of BatiO3
powder.
William Tiller, a physicist, reported that the existence of a new force
related to human body, in addition to four well known fundamental
forces of physics such as gravitational force, strong force, weak force,
and electromagnetic force [9]. Biophysicist Fritz-Albert Popp et al.
reported that human physiology shows a high degree of order and
stability due to their coherent dynamic states [10-13]. This coherent
dynamic state of human body emits the electromagnetic waves in form
of bio-photons, which surrounds the body and it is known as biofield.
Therefore, the biofield consisting of electromagnetic field, generated
by moving electrically charged particles (ions, cell, molecule etc.)
inside the human body. Furthermore, a human has ability to harness
the energy from environment/universe and can transmit into any
object (living or non-living) around the Globe. The object(s) always
receive the energy and responded into useful way that is called
biofield energy. This process is termed as biofield treatment. Mr.
Trivedi’s unique biofield treatment is known as The Trivedi effect®
.
Mr. Trivedi’s biofield treatment is known to alter the crystal structure
and atomic level changes in various ceramics and metals [14-21].
Additionally, the biofield treatment has also transformed the molecular
and cellular properties in agriculture [22-24], microbiology [25-27]
and biotechnology [28,29]. Recently, it was reported that biofield
treatment had increased the particle size by six fold and enhanced
the crystallite size by two fold in zinc powder [14]. In another report,

Citation: Trivedi MK, Nayak G, Patil S, Tallapragada RM, Latiyal O, et al. (2015) Impact of Biofield Treatment on Atomic and Structural Characteristics
of Barium Titanate Powder. Ind Eng Manage 4: 166. doi:10.4172/2169-0316.1000166
Page 2 of 6
biofield treatment has shown the significant effect in carbon allotropes,
where the unit cell volume was decrease by 1% and crystallite size
was increased by 100% [15]. To the best of our knowledge, this is the
first report to evaluate the impact of biofield treatment on atomic and
structural characteristics of BaTiO3
powder.
Materials and Methods
BaTiO3
powder was procured from the Sigma-Aldrich (MA, USA).
The powder sample was divided into two equal groups i.e. control and
treatment. The control group was remained as untreated and treatment
group was subjected to biofield treatment.
Biofield treatment
The treatment group was handed over in sealed pack to Mr. Trivedi
for biofield treatment under standard laboratory condition. Mr. Trivedi
provided this treatment through his energy transmission process to the
treatment group without touching the samples. After that, both control
and treated samples were characterized using X-ray diffraction (XRD),
Fourier-transform infrared spectrometer (FT-IR) and Electron spin
resonance (ESR).
X-ray diffraction study
For XRD analysis, treated sample was further divided into two
parts as T1 and T2. XRD analysis was carried out using a Phillips,
Holland PW 1710 XRD system, which had a copper cathode with
nickel filter. The wavelength of X-ray radiation used was 1⋅54056 Å.
The data obtained from the XRD was in the form of chart of intensity
vs.2θ° with a detailed table containing d value (Å), number of peaks,
peak width 2θ°, peak count, and relative intensity of peaks, etc. The
lattice parameter and unit cell volume were computed using Powder
X software. The molecular weight was calculated as the sum of atomic
weight of all the atoms present in a molecule. The atomic weight
was calculated as the sum of the weight of all protons, neutrons and
electrons present in the atom. The weight of the unit cell was calculated
as: atomic weight multiplied by the number of atoms present in a unit
cell. The density of the unit cell was computed as ratio of unit cell weight
to unit cell volume. The percentage change in the unit cell volume was
calculated using the following equation:
% change in unit cell volume: (ΔV/Vc) × 100.
Here, ΔV=(Vt-Vc)/Vc where Vt and Vc are the unit cell volume
of treated and control samples, respectively. The percent change in
all other parameters such as density, molecular weight, and lattice
parameter were calculated in the similar way.
Fourier transform infrared spectroscopy
Both, control and treated BaTiO3
were characterized using
Shimadzu, Fourier transform infrared (FT-IR) spectrometer with
frequency range of 300-4000/cm.
Electron spin resonance spectroscopy
ESR analysis of control and treated BaTiO3
samples were carried
out on E-112 ESR spectrometer of Varian USA of X-band microwave
frequency (9.5 GHz), which had sensitivity of 5 × 1010
, ΔH spins was
used to analyze the electron spin properties.
Results and Discussion
X-ray diffraction study
XRD pattern of control and treated BaTiO3
are shown in Figure
1. The peaks were observed at 2θ=22.0°, 31.3°, 38.70°, 45.11°, 50.72°,
55.97°, and 65.8° in control Figure 1a, which indexed for tetragonal
crystal structure of BaTiO3 as per Joint Committee on Powder
Diffraction Standards (JCPDS) 05-0626. Furthermore, diffraction
peaks were observed at 2θ=22.13°, 23.9°, 31.5°, 38.9°, 45.2°, 50.8°, 56.1°,
and 65.8° in T1 (Figure 1b), and 22.0°, 23.9°, 31.5°, 38.8°, 45.2°, 50.9°,
56.2°, 65.8° in T2 (Figure 1c). In addition, lattice parameter and unit cell
volume of control and treated samples were computed using Powder
X software and result are presented in Table 1. It was found that the
Figure 1a: XRD pattern of control barium titanate powder.
Figure 1b: XRD pattern of biofield treated barium titanate powder sample (T1).
Figure 1c: XRD pattern of biofield treated barium titanate powder sample (T2).

Page 3 of 6
to its original shape and become unstrained [30]. On the contrary, in
this experiment the lattice strain was permanent, i.e. the unit cell was
permanently distorted after biofield treatment. Thus, it is postulated
that biofield treatment acting at atomic level to induce this permanent
strain in BaTiO3
. Additionally, it was also observed that the molecular
weight was reduced upto 1.36% after the treatment, which indicates
that the biofield treatment possibly acting at nuclear level to cause these
changes. Furthermore, Y. Tanaka et al. demonstrated that compressive
strain in BaTiO3
increased the remnant polarization and reduced the
dielectric permittivity that enhanced the piezoelectric coefficient [31].
In addition to that, this compressive strain found in treated BaTiO3
may lead to reduce the symmetry of the crystal structure. The reduction
in symmetry probably enhanced the piezoelectric properties in treated
BaTiO3
as compared to control [8,9].
Fourier transform infrared spectroscopy
FT-IR of BaTiO3
control and treated samples are presented in
Figure 4 and 5, respectively. FT-IR spectra displayed two strong
absorption peaks at 441/cm and 563/cm in control (Figure 4); and 430/
cm and 557/cm in treated samples (Figure 5). The former peaks (441/
cm and 430/cm) were assigned to Ti-O bending vibrations along the
polar axis whereas the latter peaks (563/cm and 557/cm) were assigned
to Ti-O stretching vibrations as shown in Figure 6. These peaks suggest
that both treated and control sample had pure tetragonal phase [32].
The comparative result analysis of Ti-O bond vibrations is presented
in Table 2 and Figure 7. It was observed that the absorption peak
frequency of Ti-O bond stretching and bending vibrations were shifted
toward lower frequency by 1.06 and 2.49% respectively in treated
BaTiO3
as compared to control sample (Figure 7). Further, the peaks
at 868 /cm in control and treated were assigned to stretching vibrations
of metal-oxygen. The peaks displayed at 1724 and 3429 /cm, in control
and treated samples were attributed to moisture absorption by samples.
Additionally, the bond force constant (k) and bond length for Ti-O
bond were calculated using following equations [33]:
lattice parameter of the unit cell was reduced from 4.03 Å (control)
to 4.01 Å (treated) after biofield treatment that resulted into negative
lattice strain of 0.45% in BaTiO3
unit cell. Further, this compressive
strain led to reduce the volume of the unit cell upto 1.36 and 1.29% in
treated samples T1 and T2, respectively (Figure 2). This reduced unit
cell volume caused an increase in density by 1.38 and 1.30% in treated
T1 and T2, respectively as compared to control (Figure 3). It is well
known that BaTiO3
shows piezoelectric and converse piezoelectric
effect [1]. In converse piezoelectric effect, the BaTiO3
unit cell responds
to applied electric field that results into mechanical strain. Besides this,
the unit cell parameter of BaTiO3
was strained upto -0.45% that might
be due to electric field required by converse piezoelectric behavior of
BaTiO3
. It is hypothesized that the induced strain in treated sample
may be due to electric field supplied through biofield treatment.
Further, when electric field supplied through biofield treatment the
negative ions (O2-
) tend to move toward the positive electric field
whereas the positive ions (Ti+4
) moved toward negative side. Due to
movement of these ions toward each other, this compressive strain
may be induced in BaTiO3
unit cell. However, when electric field
supply turned off in piezoelectric materials, the unit cell comes back
Lattice parameter (Å) % change Unit cell volume (cm3
) % change Density (g/cc) % change Mol. Wt. (g/Mol) % change
Control 4.030 6.55 × 10-23
5.954 235.01
Treated T1 4.010 -0.45 6.46 × 10-23
-1.36 6.036 1.38 231.82 -1.36
Treated T2 4.015 -0.43 6.47 × 10-23
-1.29 6.032 1.30 231.98 -1.29
Table 1: X-ray diffraction analysis result of barium titanate powder.
Figure 2: Effect of biofield treatment on the lattice parameter and unit cell
volume of barium titanate powder.
Figure 3: Effect of biofield treatment of density and molecular weight of barium
titanate powder.
Figure 4: FT-IR spectrum of controlbarium titanate sample.

Page 4 of 6
1
2 c µ
ν =
π
k
(1)
Where, c= speed of light (cm/s), μ=effective mass of Titanium and
oxygen, which can be calculated as given below
( )
( )
µ
×
=
+
Ti O
Ti O
M M
M M
(2)
Where, MTi
=Atomic mass of titanium (Kg), MO
=Atomic mass of
oxygen (Kg), ν=IR wavenumber (/cm).
The bond force constant (k) is related to average bond length (r) by
following equation [34]:
k=17/r3 (3)
The bond length and force constant were calculated using equations
(1) and (3), respectively, which are illustrated in Figure 8. Data showed
that bond force constant was reduced from 2.24 N/cm (control) to
2.19 N/cm (treated) after biofield treatment. It suggest that bond force
constant of Ti-O was significantly decreased by 2.12% in treated BaTiO3
as compared to control (Figure 9). Furthermore, bond length of Ti-O
Figure 5: FT-IR spectrum of biofield treated barium titanate powder.
Figure 6: Strecthing and bending vibrations of Ti-Obonds in BaTiO3
.
Figure 7: Effect of biofield treatment on the strecthing and bending vibration
frequency of Ti-O bond of barium titanate powder.
Figure 8: Bond force constant and bond length result of Ti-O bond in control
and biofield treated barium titanate powder.
Figure 9: Effect of biofield treatment on bond force constant and bond length
of Ti-O in barium titanate powder.
IR Absorption Peaks (cm-1
)
Stretching Vibration (Ti-O) Bending Vibration (Ti-O)
Control 563 441
Treated 557 430
Table 2: FT-IR Strecthing and bending vibration frequency of Ti-O bond in barium
titanate powder.

Page 5 of 6
was increased in treated (1.979Å) as compared to control (1.965Å).
This indicates that the Ti-O bond length was increased by 0.72% after
biofield treatment (Figure 9). Additionally, the shifting of bending
vibrational frequency from 441/cm (control) to 430/cm (treated)
might be due to distortion of BaTiO3
unit cell after biofield treatment
[35]. These findings suggest that biofield treatment has significantly
altered the bond properties and vibrations of crystal lattice possibly
through the electric and magnetic fields. Sun et al. demonstrated that
the vibrations of crystal lattice of BaTiO3
had significant effect on its
Ferro-electricity and piezoelectricity [35].
Electron spin resonance spectroscopy
The ESR spectroscopic data are presented in Figure 10 and
11.The g-factors computed from ESR spectra were 2.0035 and 2.0011
for control and treated BaTiO3
, respectively (Figure 10). The signal
for g-factor at 2.00035 and 2.0011 were probably originated due to
titanium vacancy with unpaired electron spin [36]. It was also observed
that ESR signal height was reduced by 85.71%; and width was increased
by 300% as compared to control (Figure 11). The decrease in intensity
and broadening of ESR signal implies that the particle size probably
reduced after treatment [37]. It is postulated that during biofield
treatment, the energy has been transferred to BaTiO3
powder sample
in form of electric and magnetic field, which may induced high energy
milling and resulted into smaller particle size.
Conclusion
In summary, the biofield treatment has induced the permanent
compressive lattice strain in tetragonal crystal structure of BaTiO3
,
which may occur due to electromagnetic field transferred through
biofield treatment. This permanently strained crystal structure of
BaTiO3
led to alter its piezoelectric behavior. The FT-IR analysis result
revealed that Ti-O bond length in BaTiO3
was increased by 0.72% after
biofield treatment as compared to control. Therefore, these findings
indicate that biofield treatment may be acting at atomic level of BaTiO3
to cause these modifications. Furthermore, the variation observed in
width and height of ESR spectra, which suggest that particle size of
treated BaTiO3
might be altered through high energy milling process.
Hence, it is hypothesized that biofield treatment has induced the electric
and magnetic field that can affect the BaTiO3
powder at electronic and
atomic level. To conclude, the biofield treatment could be applied to
alter the crystal structure and piezoelectricity of BaTiO3
powder.
Acknowledgment
Authors gratefully acknowledged to Dr. Cheng Dong of NLSC, Institute of
Physics, and Chinese academy of Sciences for providing the facilities to use
PowderX software for analyzing XRD data. Authors also would like to thank Trivedi
Science, Trivedi master wellness and Trivedi testimonials for their support during
the work.
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Citation: Trivedi MK, Nayak G, Patil S, Tallapragada RM, Latiyal O, et al.
(2015) Impact of Biofield Treatment on Atomic and Structural Characteristics
of Barium Titanate Powder. Ind Eng Manage 4: 166. doi:10.4172/2169-
0316.1000166

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