Chillers 
Data Centers 
Hospitals 
Water Efficiency 
and You
Executive Summary 
Water Misalignment 
• Current Water Practices are 
unsustainable 
• We face 
– Epic Drought 
– Pressure like never before on water 
• Current WT industries method of 
delivery sets incorrect incentives 
– Maximize 
• the sale of high margin “Specialty “ 
product 
– Minimize 
• “Service “ Time 
– Almost Ignore 
• Water and energy use 
In the end, the current services delivery 
method simply ignores the key issues and 
costs customers more to operate chiller 
system than should be the case 
Resources Wasted 
• Water 
– Excessive Water 
• Make up 
• Bleed 
– Excessive & Dangerous Chemical 
• Antiscale 
• Biocide 
• Acids 
– Excessive Utility Use 
• Electrical Use 
– Chiller inefficient Kw / Tn 
• Process management 
– Staff assigned no / low value activities 
• Daily water testing 
– Important information not communicated 
• H/E 
– Approach, Heat Flux, Etc 
• Tower efficiency 
• Atmospheric conditions 
– Wet bulb, dew point, humidity 
– Out of spec conditions not reported until 
damage is done vs with in seconds
Getting Started 
• No Cost to Client 
– Water Samples provided to SWS LLC 
• City & Tower 
– System Information 
• Cost 
– Water, Sewer, Power, Descaling 
– Tns total system design 
– % Load On Line 
» Fall, Winter, Spring, Summer 
» Days in each season 
• Output with in 2 weeks 
– Savings available, Cap Ex, Op Ex 
• Pilot is available 
• Process guarantee 
– $ savings will be delivered 
– Water will be saved 
– System will operate with less scale than is currently the case 
– System will operate with less corrosion than is currently the case 
– System will operate with less energy than is currently the case
Preface - Drought 
Houston – We Have A Problem
Preface - Inefficiency
No Water 
From Water Project 
Preface – Surface Water 
Reservoirs are Drying Up
Preface – Ground Water
Preface - Food Prices
Preface 
People, Food, Energy – All Need H2O
Preface – Energy Cost Up
Executive Summary 
Too Many Big Straws in The Milkshake
Help Do Your Part to Help Us Help You 
Save 1,000,000,000 GPY
The Data on Water 
• As data centers get larger, they are getting 
thirstier as well. The enormous volume of 
water required to cool high-density cloud 
computing server farms is making water 
management a growing priority for data 
center operators. A 15-megawatt data center 
can use up to 360,000 gallons of water a 
day, according to James Hamilton, a data 
center designer and researcher at 
Amazon.com.
The Data on Water 
• Hospitals on average use 136,000 
gallons of water / year / bed for cooling
Get the Water Chemistry Right 
Proper Water Chemistry Allows Higher Cycles 
Annual Water Use 
14,000,000 
12,000,000 
10,000,000 
8,000,000 
6,000,000 
4,000,000 
2,000,000 
- 
500 Tn Chiller 
2 4 6 8
Carbonate Based Scales 
• 6/18 of common scales in cooling applications 
are associated with Carbonate / BiCarbonate 
– Calcite 
– Aragonite 
– Witherite 
– Strontianite 
– Calcium Oxalate 
– Stederite 
• Eliminate this with H+ 
In the past Today 
danger 
Condensafe II 
0 
CO3-2 + 2H+= CO2 + H20 0 0
Carbonate Based Scales 
• 4/18 of common scales in 
cooling applications are 
associated with Sulfate 
– Anhydrite 
– Gypsum 
– Barite 
– Celestite 
• Eliminate this by not feeding 
H2SO4 
In the past Today 
danger 
Condensafe II 
0 
CO3-2 + 2H+= CO2 + H20 0 0
Condensafe II 
• Synthetic 
• Functional replacement for H2SO4 
• On June 18, 2008 
– Dr. Robert Scheuplein, Toxicologist and Veteran Director of the Office of 
Toxicology Sciences at FDA’s Center for Food Safety and Applied Nutrition. 
• Dr. Scheuplein has assessed that the active ingreadient in Condensafe II is “Generally Recognized as Safe 
(GRAS) in accordance with FDA assessment guidelines. 
• Condensafe product formulations 
– carry a triple zero Hazardous Materials Information System Score 
– An A rating with regards to required PPE 
– Are 100% biodegradable in 30 days or less per EPA, Design for the Environment, 
– OECD and Hach Reactor method guidelines and meet or exceed stringent Direct Release Guidelines for 10 day 
bio-degradation. 
– The entire family of SAFE products 
• are non-regulated by the 
– US D.O.T., 
– CANADIAN TDG, IMO and IATA. 
• are classified as non-voc, non-corrosive, non-mutagenic, and non-toxic. 
• show no potential for the generation of carbon dioxide under NIOSH 7903, OSHA & ACGIH testing protocols.
All Good Cooling Inhibitors Contain Common 
Building Blocks 
– BZT 
• BZT is a corrosion inhibitor and/or yellow metal deactivator based on 1,2,3- 
benzotrizole. 
– BZT prevents corrosion of yellow metals such as copper, copper alloys, bronze, and other 
metals. 
– BZT inhibits the corrosion of steel, cast iron, cadmium and nickel alloys under certain 
conditions. 
– BZT reduces the corrosive influence of copper ions on various metals. 
– HEDP 
• HEDP is an organophosphoric acid corrosion / scale inhibitor. 
– HEDP can chelate with Fe, Cu, and Zn ions to form stable chelating compounds. 
– HEDP shows excellent scale and corrosion inhibition effects under temperature 250℃. 
– HEDP has good chemical stability under high pH value, hard to be hydrolyzed, and hard to be 
decomposed under ordinary light and heat conditions. 
– HEDP acid/alkali and chlorine oxidation tolerance are better than that of other 
organophosphoric acids (salt). 
– HEDP can react with metal ions in water systems to form hexa-element chelating complex, 
with calcium ion in particular. 
– PBTC 
• PBTC acts as a crystal modifying agent and threshold inhibitor for calcium and other 
metal salts. 
– PBTC is widely used in industry as a sequestering agent and calcium carbonate scale inhibitor. 
– In systems that utilize oxidizing microbiocides, such as bromine, PBTC exhibits superior 
stability under oxidizing conditions compared to other organophosphonate compounds. 
– Silica Control Polymer 
• ACUMER 5000 is a proprietary multifunctional polymer with a molecular weight of 
5000 that provides outstanding silica and magnesium silicate scale inhibition. 
– ACUMER 5000 prevents silica-based scale formation by dispersing colloidal silica and by 
preventing magnesium silicate scale formation at heat transfer surfaces
Alternatives 
• Do Nothing 
• Dolphin and or Magnets 
– Relies on Low Cycles 
• Wastes Water 
• Deposits 
• Corrosion 
• Softeners 
– Improper water chemistry results in corrosion 
• Other Water Treatment Companies 
– Low degree of monitoring 
– Disincentive to provide service
Traditional Water Treatment 
• Monitored 
– Conductivity 
– pH 
• Controlled 
– pH 
– Conductivity 
– Antiscale pump on and off
Dolphin 
• Controls nothing 
• Tower is bled to keep 
– Cycles Low 
– Water Use High 
• Essentially once through cooling
Softeners 
Softeners are not recommended for galvanized towers 
• Historically, maximum service life was obtained by maintaining the chemistry of 
the circulating water at an essentially neutral state (pH of 6.5 to 9.0) and 
allowing the natural formation of a protective, light crystalline film on the zinc 
surface which retarded the formation of white rust. 
• While there is still some disagreement on the actual cause of the recent increase 
in reported cases of "white rust", various water treatment experts are concluding 
that some of the newer, higher alkaline, treatment chemistries actually inhibit the 
formation of protective films on the galvanized surface and thus allow the 
development of white rust. 
• There are also indications that soft water (less than 30 ppm total hardness), 
when combined with these high pH conditions, can exacerbate the problem.
We Use Water More Effectively
Nereus On Line Chemistry 
• Conductivity 
– Controls cycles of concentration 
• pH 
– Controls alkalinity / LSI / Scale 
• ORP 
– Controls biocide feed 
– Biological control 
• Antiscalant 
– Controls scale 
• Ca 
• Si 
• Fe
Nereus On Line Meters 
• Make Up 
– Water Use and cost 
• Bleed 
– Sewer discharge and cost 
• Recirculation 
– Supply to Heat Exchangers 
• Temperature 
– Air Dry 
– Air Wet bulb 
– Heat exchanger supply water 
– Heat exchanger return water 
– Refrigerant condensing temperature 
• Chemical inventory levels 
• Chemical feed rate
Nereus Auxilary 
• Corrosion coupons 
– System metallurgy 
• Biological Testing 
– Total Aerobic Count 
– Sulfate Reducing Bacteria 
– Mold 
– Fungus
Nereus Calculations 
• Tower 
– Efficiency and efficiency vs design 
– Approach and approach vs design 
– Delta T and delta T vs design 
• Heat Exchanger 
– Approach and approach vs design 
– Heat Flux in BTU / Sq. Ft. / Hr. and Heat flux vs 
design 
– $ lost due to fouling 
• Today / this Month / YTD 
• Yr over Yr 
• Water 
– $ / Day, Month, Yr 
– $ vs budget Day / Month / Yr 
– Yr over Yr 
• Sewer 
– $ / Day, Month, Yr 
– $ vs budget Day / Month / Yr 
– Yr over Yr 
• Chemical 
– % Tank level 
– $ / Day, Month, Yr 
– $ vs budget Day / Month / Yr 
– Yr over Yr
Nereus Calculations 
• Refrigeration tns on line 
• Refrigeration as a % of design max 
• Cost / Tn of refrigeration for 
– Water actual / actual vs budget / Yr vs Yr 
– Sewer actual / actual vs budget / Yr vs Yr 
– Chemical actual / actual vs budget / Yr vs Yr 
– Power actual / actual vs budget / Yr vs Yr 
• Refrigeration Efficiency 
– Kw / Tn refrigeration actual / actual vs budget / Yr vs Yr
Nereus vs Old School
We Use Water More Effectively
Getting Started 
• No Cost to Client 
– Water Samples provided to SWS LLC 
• City & Tower 
– System Information 
• Cost 
– Water, Sewer, Power, Descaling 
– Tns total system design 
– % Load On Line 
» Fall, Winter, Spring, Summer 
» Days in each season 
• Output with in 2 weeks 
– Savings available, Cap Ex, Op Ex 
• Process guarantee 
– $ savings will be delivered 
– System will operate with less scale than is currently the case 
– System will operate with less corrosion than is currently the case 
– System will operate with less energy than is currently the case
Appendix 
• Chiller Facts 
• Measuring 
• Definitions 
• Chillers 
• Fouling 
• Chiller Efficiency 
• Improving Chiller Efficiency 
• Typical Water Treatment Problems 
• Pitting
Chiller Facts 
This article has been published in Maintenance Technology and Hotel Engineer Magazines. 
• Chillers are the single largest energy-using component in most facilities, and can 
typically consume over 50% of the electrical usage. 
• Chillers use approximately 20% of the total electrical power generated in North America 
• U.S. Department of Energy estimates that chillers expend up to 30% in additional 
energy through inefficiency. 
• With over 100,000 chillers in the United States alone, inefficiency costs industry billions 
of dollars in energy annually. 
• Chillers running inefficiently also result in decreased equipment reliability, increased 
maintenance intervals and shortened lifespan. The slightest decrease in chiller 
performance can have a major impact on efficiency. 
• For instance, every 1°F increase in condenser water temperature above full load 
design can decrease chiller efficiency by 1% to 2%. 
• A failing or neglected water treatment program can reduce efficiency 10% to 35% or 
more in extreme cases.
Measuring 
• The metric for water usage in the data center is defined at a 
high level as Water Usage Effectiveness or WUE 
Annual Water Usage 
IT Equipment Energy 
• The units of WUE are liters/kilowatt-hour (L/kWh). 
• IT Equipment Energy. This includes the load associated with all 
of the IT equipment, including computer, storage, and network 
equipment, along with supplemental equipment such as KVM 
switches, monitors, and workstations/laptops used to monitor 
or otherwise control the data center 
• “We think that 0.22 L/kWh is a great result, but it should be 
noted that the WUE concept is fairly new and, to our 
knowledge, no one else has publicly reported WUE yet,” writes 
Facebook’s Daniel Lee. “
Definitions 
• 1 ppm 
– 1 Lb. of something / 1,000,000 Lbs. of something 
– Ex 1 pounds antiscale / 1,000,000 Lbs water 
– 10 pounds antiscale / 1,000,000 Lbs water 
– Our Dose of antiscale 
• 100 – 200 pounds antiscale / 1,000,000 Lbs water 
• 10 – 20 / 100,000 
• 1 - 2/ 10,000 
• 2 – 4 / 20,000 Find 2 guys at an average a’s game 
• Q or Heat Flux = BTU / Sq. Ft. / Hr 
• 1 Tn Refrigeration = 12,000 BTU / Hr rejected 
• Cycles = How many times a feed water is concentrated up 
• Bleed = water removed from the system to control cycles
Definitions 
• Heat exchangers were initially developed to use plain (or 
smooth) heat transfer surfaces. 
– An Enhanced heat transfer surface has a special surface geometry 
that provides a higher thermal performance, per unit base surface 
area than a plain surface. 
Internal Enhancement External Enhancement
Chillers 
• What is a Chiller? 
– A chiller is a water-cooled air conditioning system that cools inside air, creating a 
more comfortable and productive environment. 
– Chillers are also used in the manufacturing environment to provide "process" 
cooling to equipment in an effort to maximize productivity. 
• With large facilities, such as commercial buildings, hospitals, universities, 
government facilities and theme parks, the cost of energy to generate 
cooling in excess of 50 tons is cost prohibitive with air-cooled units. 
• Water-cooled chillers produce higher tonnage at lower costs per ton, 
creating greater energy efficiency. 
• Typical Home 
– has 3-5 tons of cooling capacity. 
• Typical Data Center 
– has 300 – 1000 + tns cooling 
– Older = smaller 
– Newer = larger 
• Typical Hospital 
– has 2 – 5 tns / bed
Chillers 
• How a Complete Chiller System 
Works 
– Chillers circulate chilled water to 
air-handlers in order to transfer 
heat from air to water. 
– This water then returns to the 
evaporator side of the chiller 
where the heat is passed from the 
water to a liquid refrigerant (freon). 
– The refrigerant leaves the 
evaporator as a cold vapor and 
enters the compressor where it is 
compressed into a hot vapor. 
– Upon leaving the compressor, the 
vapor enters the condenser side of 
the chiller where heat is 
transferred from the refrigerant to 
the water side of the condenser 
where it is circulated to an open 
cooling tower for the final removal 
of heat via evaporation in the 
cooling tower. 
Closed Chilled Water Loop Open Tower Water Loop 
Potential Fouling Points 
On Water Side
Fouling 
• 240 ton chiller 
– Greg Bush Regional Services Lead for Americas 
• SAP GFM Data Center Services 
• Regional Energy Manager for Americas 
– In the case of SAP at $0.15 kWH 
– $5,600.00 a year in wasted electricity per degree approach 
fowling. This is a meter verified number. 
• Chiller in study has efficiency of .65 Kw per ton annualized. 
EPA statement said a 1000 ton chiller at 
$0.11 per kWH is $10,000.00 a year of 
wasted energy per degree fouling
Chiller Efficiency 
• Chiller efficiency is the amount of energy (electricity) it takes to produce a "ton" of 
cooling. It is expressed as kw/ton. 
– All chillers have a designed kw/ton efficiency that was established when the chiller was 
commissioned. 
– Plant design, water treatment, maintenance practices, chiller age, cooling tower design, 
cooling load and plant operations dramatically effect chiller operating efficiency and 
operating costs. 
• A chiller "operator" is known by several titles, including Stationary Engineer, HVAC 
Engineer and Service Technician. 
– Operation and maintenance includes collecting and logging data from various gauges, 
controls and meters located on or near the chiller. 
• There are essentially three types of maintenance performed on chillers; 
– Water chemistry is maintained to keep proper balance and minimize the effects of scale, 
corrosion and micro-biological / debris fouling. 
– Mechanical maintenance includes proper lubrication, adequate liquid refrigerant, oil levels 
and pump curve tests. 
– Operational procedures include eddy-current tests, oil analysis, calibration of gauges and 
meters and other various tests.
Improving Chiller Efficiency 
• The best way to provide precise data, obtain concrete results and minimize problems 
is to verify flow rates to the chiller for tonnage measurements and other 
calculations to determine efficiency. 
Four methods for determining flow are 
inline flow meter, external flow meter, delta pressure and delta temperature. 
• The use of delta temperature along with a flow meter or delta pressure gauge creates a powerful 
diagnostic tool that can detect problems affecting efficiency in the chiller system. 
• Increase the Chill Water Temperature and Lower the Entering Condenser Water Temperature For 
constant speed chillers, every 1°F increase in chill water temperature can increase chiller energy 
efficiency 1 to 2%. For variable speed chillers, every 1°F increase in chill water temperature can result in 
a 2 to 4% efficiency increase. 
• Take advantage of wet bulb conditions in the cooling tower system to lower the chiller's entering 
condenser water temperature. This can result in a 1 to 1.5% efficiency improvement for every 1°F below 
the chiller full load design.
Improving Chiller Efficiency 
• A good water treatment program is a necessity for efficiency. Maintaining the proper 
water treatment will prevent costly problems. 
– If a problem(s) already exists, take the necessary steps to correct it immediately. 
• Biocide and Scale/Corrosion Protection 
– A water treatment program provides a biocide program that minimizes microbiological 
growth along with excellent scale/corrosion protection. 
– Microbes, if not properly controlled, can cause numerous problems, such as forming sticky 
slime deposits in the tube bundle of a chiller, possibly reducing heat transfer efficiency 15% 
or more. 
– The situation can be compounded by the formation of permanent scale or iron deposits on 
the sticky site. If this occurs, an additional 10 to 20% loss in heat transfer efficiency may 
result.
Typical Problems Encountered 
• Tower Basin 
– Calcium deposits 
– Corrosion Tubercle 
• Tubercle removed 
• Under Deposit Corrosion 
• Corrosion Perforation 
– Under Deposit Corrosion
Pitting 
• All forms of corrosion, with the exception of some types of high-temperature 
corrosion, occur through the action of the electrochemical 
cell. 
• The elements that are common to all corrosion cells are: 
– An anode where oxidation and metal loss occur, 
– A cathode where reduction and protective effects occur, 
– Metallic and electrolytic ( system water ) paths between the anode and 
cathode through which electronic and ionic current flows, 
– A potential difference that drives the cell. 
• The driving potential may be the result of differences between the characteristics of 
dissimilar metals, surface conditions, and the environment, including chemical 
concentrations.
Pitting 
• Pitting corrosion is a localized form of corrosion by which cavities or 
"holes" are produced in the material. 
• Pitting is considered to be more dangerous than uniform corrosion 
damage because it is more difficult to detect, predict and design against. 
• Corrosion products often cover the pits. 
– A small, narrow pit with minimal overall metal loss can lead to the failure of an entire 
engineering system. 
– Pitting corrosion, which, for example, is almost a common denominator of all types of 
localized corrosion attack, may assume different shapes. 
• Pitting is initiated by: 
– Localized chemical or mechanical damage to the protective oxide film; water chemistry 
factors which can cause breakdown of a passive film are acidity, low dissolved oxygen 
concentrations (which tend to render a protective oxide film less stable) and high 
concentrations of chloride (as in seawater) 
– Localized damage to, or poor application of, a protective coating 
– The presence of non-uniformities in the metal structure of the component, e.g. nonmetallic 
inclusions. 
• Theoretically, a local cell that leads to the initiation of a pit can be caused 
by 
– an abnormal anodic site ( under a deposit ) surrounded by normal surface which acts as a 
cathode, 
– or by the presence of an abnormal cathodic site surrounded by a normal surface in which a 
pit will have disappeared due to corrosion.
Theory 
• Water Chemistry 
– Lack of proper water treatment chemistry allows deposits to occur 
– Ca, Mg, Fe 
– Deposits cause corrosion 
– Corrosion products cause more deposits / corrosion with out proper treatment
Observations 
• Corrosion 
• Corrosion Products 
• Corrosion products covered with 
scale 
• Scale is chips off and anode is 
formed 
• Small anode 
• Combined with large cathode 
• Pitting is expected

Introducing nereus for cooling 09112014 gn (2)

  • 1.
    Chillers Data Centers Hospitals Water Efficiency and You
  • 2.
    Executive Summary WaterMisalignment • Current Water Practices are unsustainable • We face – Epic Drought – Pressure like never before on water • Current WT industries method of delivery sets incorrect incentives – Maximize • the sale of high margin “Specialty “ product – Minimize • “Service “ Time – Almost Ignore • Water and energy use In the end, the current services delivery method simply ignores the key issues and costs customers more to operate chiller system than should be the case Resources Wasted • Water – Excessive Water • Make up • Bleed – Excessive & Dangerous Chemical • Antiscale • Biocide • Acids – Excessive Utility Use • Electrical Use – Chiller inefficient Kw / Tn • Process management – Staff assigned no / low value activities • Daily water testing – Important information not communicated • H/E – Approach, Heat Flux, Etc • Tower efficiency • Atmospheric conditions – Wet bulb, dew point, humidity – Out of spec conditions not reported until damage is done vs with in seconds
  • 3.
    Getting Started •No Cost to Client – Water Samples provided to SWS LLC • City & Tower – System Information • Cost – Water, Sewer, Power, Descaling – Tns total system design – % Load On Line » Fall, Winter, Spring, Summer » Days in each season • Output with in 2 weeks – Savings available, Cap Ex, Op Ex • Pilot is available • Process guarantee – $ savings will be delivered – Water will be saved – System will operate with less scale than is currently the case – System will operate with less corrosion than is currently the case – System will operate with less energy than is currently the case
  • 4.
    Preface - Drought Houston – We Have A Problem
  • 5.
  • 6.
    No Water FromWater Project Preface – Surface Water Reservoirs are Drying Up
  • 7.
  • 8.
  • 9.
    Preface People, Food,Energy – All Need H2O
  • 10.
  • 11.
    Executive Summary TooMany Big Straws in The Milkshake
  • 12.
    Help Do YourPart to Help Us Help You Save 1,000,000,000 GPY
  • 13.
    The Data onWater • As data centers get larger, they are getting thirstier as well. The enormous volume of water required to cool high-density cloud computing server farms is making water management a growing priority for data center operators. A 15-megawatt data center can use up to 360,000 gallons of water a day, according to James Hamilton, a data center designer and researcher at Amazon.com.
  • 14.
    The Data onWater • Hospitals on average use 136,000 gallons of water / year / bed for cooling
  • 15.
    Get the WaterChemistry Right Proper Water Chemistry Allows Higher Cycles Annual Water Use 14,000,000 12,000,000 10,000,000 8,000,000 6,000,000 4,000,000 2,000,000 - 500 Tn Chiller 2 4 6 8
  • 16.
    Carbonate Based Scales • 6/18 of common scales in cooling applications are associated with Carbonate / BiCarbonate – Calcite – Aragonite – Witherite – Strontianite – Calcium Oxalate – Stederite • Eliminate this with H+ In the past Today danger Condensafe II 0 CO3-2 + 2H+= CO2 + H20 0 0
  • 17.
    Carbonate Based Scales • 4/18 of common scales in cooling applications are associated with Sulfate – Anhydrite – Gypsum – Barite – Celestite • Eliminate this by not feeding H2SO4 In the past Today danger Condensafe II 0 CO3-2 + 2H+= CO2 + H20 0 0
  • 18.
    Condensafe II •Synthetic • Functional replacement for H2SO4 • On June 18, 2008 – Dr. Robert Scheuplein, Toxicologist and Veteran Director of the Office of Toxicology Sciences at FDA’s Center for Food Safety and Applied Nutrition. • Dr. Scheuplein has assessed that the active ingreadient in Condensafe II is “Generally Recognized as Safe (GRAS) in accordance with FDA assessment guidelines. • Condensafe product formulations – carry a triple zero Hazardous Materials Information System Score – An A rating with regards to required PPE – Are 100% biodegradable in 30 days or less per EPA, Design for the Environment, – OECD and Hach Reactor method guidelines and meet or exceed stringent Direct Release Guidelines for 10 day bio-degradation. – The entire family of SAFE products • are non-regulated by the – US D.O.T., – CANADIAN TDG, IMO and IATA. • are classified as non-voc, non-corrosive, non-mutagenic, and non-toxic. • show no potential for the generation of carbon dioxide under NIOSH 7903, OSHA & ACGIH testing protocols.
  • 19.
    All Good CoolingInhibitors Contain Common Building Blocks – BZT • BZT is a corrosion inhibitor and/or yellow metal deactivator based on 1,2,3- benzotrizole. – BZT prevents corrosion of yellow metals such as copper, copper alloys, bronze, and other metals. – BZT inhibits the corrosion of steel, cast iron, cadmium and nickel alloys under certain conditions. – BZT reduces the corrosive influence of copper ions on various metals. – HEDP • HEDP is an organophosphoric acid corrosion / scale inhibitor. – HEDP can chelate with Fe, Cu, and Zn ions to form stable chelating compounds. – HEDP shows excellent scale and corrosion inhibition effects under temperature 250℃. – HEDP has good chemical stability under high pH value, hard to be hydrolyzed, and hard to be decomposed under ordinary light and heat conditions. – HEDP acid/alkali and chlorine oxidation tolerance are better than that of other organophosphoric acids (salt). – HEDP can react with metal ions in water systems to form hexa-element chelating complex, with calcium ion in particular. – PBTC • PBTC acts as a crystal modifying agent and threshold inhibitor for calcium and other metal salts. – PBTC is widely used in industry as a sequestering agent and calcium carbonate scale inhibitor. – In systems that utilize oxidizing microbiocides, such as bromine, PBTC exhibits superior stability under oxidizing conditions compared to other organophosphonate compounds. – Silica Control Polymer • ACUMER 5000 is a proprietary multifunctional polymer with a molecular weight of 5000 that provides outstanding silica and magnesium silicate scale inhibition. – ACUMER 5000 prevents silica-based scale formation by dispersing colloidal silica and by preventing magnesium silicate scale formation at heat transfer surfaces
  • 20.
    Alternatives • DoNothing • Dolphin and or Magnets – Relies on Low Cycles • Wastes Water • Deposits • Corrosion • Softeners – Improper water chemistry results in corrosion • Other Water Treatment Companies – Low degree of monitoring – Disincentive to provide service
  • 21.
    Traditional Water Treatment • Monitored – Conductivity – pH • Controlled – pH – Conductivity – Antiscale pump on and off
  • 22.
    Dolphin • Controlsnothing • Tower is bled to keep – Cycles Low – Water Use High • Essentially once through cooling
  • 23.
    Softeners Softeners arenot recommended for galvanized towers • Historically, maximum service life was obtained by maintaining the chemistry of the circulating water at an essentially neutral state (pH of 6.5 to 9.0) and allowing the natural formation of a protective, light crystalline film on the zinc surface which retarded the formation of white rust. • While there is still some disagreement on the actual cause of the recent increase in reported cases of "white rust", various water treatment experts are concluding that some of the newer, higher alkaline, treatment chemistries actually inhibit the formation of protective films on the galvanized surface and thus allow the development of white rust. • There are also indications that soft water (less than 30 ppm total hardness), when combined with these high pH conditions, can exacerbate the problem.
  • 24.
    We Use WaterMore Effectively
  • 26.
    Nereus On LineChemistry • Conductivity – Controls cycles of concentration • pH – Controls alkalinity / LSI / Scale • ORP – Controls biocide feed – Biological control • Antiscalant – Controls scale • Ca • Si • Fe
  • 27.
    Nereus On LineMeters • Make Up – Water Use and cost • Bleed – Sewer discharge and cost • Recirculation – Supply to Heat Exchangers • Temperature – Air Dry – Air Wet bulb – Heat exchanger supply water – Heat exchanger return water – Refrigerant condensing temperature • Chemical inventory levels • Chemical feed rate
  • 28.
    Nereus Auxilary •Corrosion coupons – System metallurgy • Biological Testing – Total Aerobic Count – Sulfate Reducing Bacteria – Mold – Fungus
  • 29.
    Nereus Calculations •Tower – Efficiency and efficiency vs design – Approach and approach vs design – Delta T and delta T vs design • Heat Exchanger – Approach and approach vs design – Heat Flux in BTU / Sq. Ft. / Hr. and Heat flux vs design – $ lost due to fouling • Today / this Month / YTD • Yr over Yr • Water – $ / Day, Month, Yr – $ vs budget Day / Month / Yr – Yr over Yr • Sewer – $ / Day, Month, Yr – $ vs budget Day / Month / Yr – Yr over Yr • Chemical – % Tank level – $ / Day, Month, Yr – $ vs budget Day / Month / Yr – Yr over Yr
  • 30.
    Nereus Calculations •Refrigeration tns on line • Refrigeration as a % of design max • Cost / Tn of refrigeration for – Water actual / actual vs budget / Yr vs Yr – Sewer actual / actual vs budget / Yr vs Yr – Chemical actual / actual vs budget / Yr vs Yr – Power actual / actual vs budget / Yr vs Yr • Refrigeration Efficiency – Kw / Tn refrigeration actual / actual vs budget / Yr vs Yr
  • 31.
  • 32.
    We Use WaterMore Effectively
  • 33.
    Getting Started •No Cost to Client – Water Samples provided to SWS LLC • City & Tower – System Information • Cost – Water, Sewer, Power, Descaling – Tns total system design – % Load On Line » Fall, Winter, Spring, Summer » Days in each season • Output with in 2 weeks – Savings available, Cap Ex, Op Ex • Process guarantee – $ savings will be delivered – System will operate with less scale than is currently the case – System will operate with less corrosion than is currently the case – System will operate with less energy than is currently the case
  • 34.
    Appendix • ChillerFacts • Measuring • Definitions • Chillers • Fouling • Chiller Efficiency • Improving Chiller Efficiency • Typical Water Treatment Problems • Pitting
  • 35.
    Chiller Facts Thisarticle has been published in Maintenance Technology and Hotel Engineer Magazines. • Chillers are the single largest energy-using component in most facilities, and can typically consume over 50% of the electrical usage. • Chillers use approximately 20% of the total electrical power generated in North America • U.S. Department of Energy estimates that chillers expend up to 30% in additional energy through inefficiency. • With over 100,000 chillers in the United States alone, inefficiency costs industry billions of dollars in energy annually. • Chillers running inefficiently also result in decreased equipment reliability, increased maintenance intervals and shortened lifespan. The slightest decrease in chiller performance can have a major impact on efficiency. • For instance, every 1°F increase in condenser water temperature above full load design can decrease chiller efficiency by 1% to 2%. • A failing or neglected water treatment program can reduce efficiency 10% to 35% or more in extreme cases.
  • 36.
    Measuring • Themetric for water usage in the data center is defined at a high level as Water Usage Effectiveness or WUE Annual Water Usage IT Equipment Energy • The units of WUE are liters/kilowatt-hour (L/kWh). • IT Equipment Energy. This includes the load associated with all of the IT equipment, including computer, storage, and network equipment, along with supplemental equipment such as KVM switches, monitors, and workstations/laptops used to monitor or otherwise control the data center • “We think that 0.22 L/kWh is a great result, but it should be noted that the WUE concept is fairly new and, to our knowledge, no one else has publicly reported WUE yet,” writes Facebook’s Daniel Lee. “
  • 37.
    Definitions • 1ppm – 1 Lb. of something / 1,000,000 Lbs. of something – Ex 1 pounds antiscale / 1,000,000 Lbs water – 10 pounds antiscale / 1,000,000 Lbs water – Our Dose of antiscale • 100 – 200 pounds antiscale / 1,000,000 Lbs water • 10 – 20 / 100,000 • 1 - 2/ 10,000 • 2 – 4 / 20,000 Find 2 guys at an average a’s game • Q or Heat Flux = BTU / Sq. Ft. / Hr • 1 Tn Refrigeration = 12,000 BTU / Hr rejected • Cycles = How many times a feed water is concentrated up • Bleed = water removed from the system to control cycles
  • 38.
    Definitions • Heatexchangers were initially developed to use plain (or smooth) heat transfer surfaces. – An Enhanced heat transfer surface has a special surface geometry that provides a higher thermal performance, per unit base surface area than a plain surface. Internal Enhancement External Enhancement
  • 39.
    Chillers • Whatis a Chiller? – A chiller is a water-cooled air conditioning system that cools inside air, creating a more comfortable and productive environment. – Chillers are also used in the manufacturing environment to provide "process" cooling to equipment in an effort to maximize productivity. • With large facilities, such as commercial buildings, hospitals, universities, government facilities and theme parks, the cost of energy to generate cooling in excess of 50 tons is cost prohibitive with air-cooled units. • Water-cooled chillers produce higher tonnage at lower costs per ton, creating greater energy efficiency. • Typical Home – has 3-5 tons of cooling capacity. • Typical Data Center – has 300 – 1000 + tns cooling – Older = smaller – Newer = larger • Typical Hospital – has 2 – 5 tns / bed
  • 40.
    Chillers • Howa Complete Chiller System Works – Chillers circulate chilled water to air-handlers in order to transfer heat from air to water. – This water then returns to the evaporator side of the chiller where the heat is passed from the water to a liquid refrigerant (freon). – The refrigerant leaves the evaporator as a cold vapor and enters the compressor where it is compressed into a hot vapor. – Upon leaving the compressor, the vapor enters the condenser side of the chiller where heat is transferred from the refrigerant to the water side of the condenser where it is circulated to an open cooling tower for the final removal of heat via evaporation in the cooling tower. Closed Chilled Water Loop Open Tower Water Loop Potential Fouling Points On Water Side
  • 41.
    Fouling • 240ton chiller – Greg Bush Regional Services Lead for Americas • SAP GFM Data Center Services • Regional Energy Manager for Americas – In the case of SAP at $0.15 kWH – $5,600.00 a year in wasted electricity per degree approach fowling. This is a meter verified number. • Chiller in study has efficiency of .65 Kw per ton annualized. EPA statement said a 1000 ton chiller at $0.11 per kWH is $10,000.00 a year of wasted energy per degree fouling
  • 42.
    Chiller Efficiency •Chiller efficiency is the amount of energy (electricity) it takes to produce a "ton" of cooling. It is expressed as kw/ton. – All chillers have a designed kw/ton efficiency that was established when the chiller was commissioned. – Plant design, water treatment, maintenance practices, chiller age, cooling tower design, cooling load and plant operations dramatically effect chiller operating efficiency and operating costs. • A chiller "operator" is known by several titles, including Stationary Engineer, HVAC Engineer and Service Technician. – Operation and maintenance includes collecting and logging data from various gauges, controls and meters located on or near the chiller. • There are essentially three types of maintenance performed on chillers; – Water chemistry is maintained to keep proper balance and minimize the effects of scale, corrosion and micro-biological / debris fouling. – Mechanical maintenance includes proper lubrication, adequate liquid refrigerant, oil levels and pump curve tests. – Operational procedures include eddy-current tests, oil analysis, calibration of gauges and meters and other various tests.
  • 43.
    Improving Chiller Efficiency • The best way to provide precise data, obtain concrete results and minimize problems is to verify flow rates to the chiller for tonnage measurements and other calculations to determine efficiency. Four methods for determining flow are inline flow meter, external flow meter, delta pressure and delta temperature. • The use of delta temperature along with a flow meter or delta pressure gauge creates a powerful diagnostic tool that can detect problems affecting efficiency in the chiller system. • Increase the Chill Water Temperature and Lower the Entering Condenser Water Temperature For constant speed chillers, every 1°F increase in chill water temperature can increase chiller energy efficiency 1 to 2%. For variable speed chillers, every 1°F increase in chill water temperature can result in a 2 to 4% efficiency increase. • Take advantage of wet bulb conditions in the cooling tower system to lower the chiller's entering condenser water temperature. This can result in a 1 to 1.5% efficiency improvement for every 1°F below the chiller full load design.
  • 44.
    Improving Chiller Efficiency • A good water treatment program is a necessity for efficiency. Maintaining the proper water treatment will prevent costly problems. – If a problem(s) already exists, take the necessary steps to correct it immediately. • Biocide and Scale/Corrosion Protection – A water treatment program provides a biocide program that minimizes microbiological growth along with excellent scale/corrosion protection. – Microbes, if not properly controlled, can cause numerous problems, such as forming sticky slime deposits in the tube bundle of a chiller, possibly reducing heat transfer efficiency 15% or more. – The situation can be compounded by the formation of permanent scale or iron deposits on the sticky site. If this occurs, an additional 10 to 20% loss in heat transfer efficiency may result.
  • 45.
    Typical Problems Encountered • Tower Basin – Calcium deposits – Corrosion Tubercle • Tubercle removed • Under Deposit Corrosion • Corrosion Perforation – Under Deposit Corrosion
  • 46.
    Pitting • Allforms of corrosion, with the exception of some types of high-temperature corrosion, occur through the action of the electrochemical cell. • The elements that are common to all corrosion cells are: – An anode where oxidation and metal loss occur, – A cathode where reduction and protective effects occur, – Metallic and electrolytic ( system water ) paths between the anode and cathode through which electronic and ionic current flows, – A potential difference that drives the cell. • The driving potential may be the result of differences between the characteristics of dissimilar metals, surface conditions, and the environment, including chemical concentrations.
  • 47.
    Pitting • Pittingcorrosion is a localized form of corrosion by which cavities or "holes" are produced in the material. • Pitting is considered to be more dangerous than uniform corrosion damage because it is more difficult to detect, predict and design against. • Corrosion products often cover the pits. – A small, narrow pit with minimal overall metal loss can lead to the failure of an entire engineering system. – Pitting corrosion, which, for example, is almost a common denominator of all types of localized corrosion attack, may assume different shapes. • Pitting is initiated by: – Localized chemical or mechanical damage to the protective oxide film; water chemistry factors which can cause breakdown of a passive film are acidity, low dissolved oxygen concentrations (which tend to render a protective oxide film less stable) and high concentrations of chloride (as in seawater) – Localized damage to, or poor application of, a protective coating – The presence of non-uniformities in the metal structure of the component, e.g. nonmetallic inclusions. • Theoretically, a local cell that leads to the initiation of a pit can be caused by – an abnormal anodic site ( under a deposit ) surrounded by normal surface which acts as a cathode, – or by the presence of an abnormal cathodic site surrounded by a normal surface in which a pit will have disappeared due to corrosion.
  • 48.
    Theory • WaterChemistry – Lack of proper water treatment chemistry allows deposits to occur – Ca, Mg, Fe – Deposits cause corrosion – Corrosion products cause more deposits / corrosion with out proper treatment
  • 49.
    Observations • Corrosion • Corrosion Products • Corrosion products covered with scale • Scale is chips off and anode is formed • Small anode • Combined with large cathode • Pitting is expected