Environmental Engineering
Engr. Lorenz Esperon Borromeo
lorenz.borromeo@upd.edu.ph
Environmental Engineering
Environmental Engineering is manifest by sound engineering thought and practice in the
solution of problems of environmental sanitation, notably in the provision of safe, palatable and
ample public water supplies; the proper disposal of or recycle of wastewater and solid wastes;
the adequate drainaige of urban and rural areas for proper sanitation; and the control of water,
soil and atmospheric pollution, and the social and environmental impact of these solutions
(ASCE,1977)
Fields of Environmental Engineering
Environmental Impact Assessment
The process of predicting the likely environmental consequences of implementing a project &
designing appropriate preventive mitigating & enhancement measures as an input to decision
making.
Water Supply and Transport
Develop a systems to store, treat, convey water for various uses
Wastewater Conveyance and Treatment
Develop collection and treatment systems to carry this waste material away from where people
live and produce the waste and discharge it into the environment
Fields of Environmental Engineering
Air Quality Management
Design of manufacturing and combustion processes to reduce air pollutant emissions to
acceptable levels
Water Quality
Management
Water Classification
Depends on the uses of water, namely for domestic, industrial,
irrigation, transportation, habitat for marine life etc.
Streams are classified according to the highest beneficial use that can
be obtained from them.
*Revised Water Usage and Classification- DENR Administrative Order
No. 34 Series of 1990.
*Revised Effluent Regulations of 1990- DENR Administrative Order
No. 35 Series of 1990
*DAO 2016-08. For key changes, refer to the handout.
Characteristics of Wastewater
A. Physical Characteristics
Color
Odor
Turbidity
Temperature
Total Solids
B. Chemical Characteristics
pH Phenols
Hardness Pesticides and Agri Chemicals
Nutrients
Trace Metals
Proteins
Carbohydrates
Oils, Fats and Greases
Surfactants
Characteristics of Wastewater
C. Biological Characteristics
Measures of Oxygen Demand
◦ DO
◦ ThOD
◦ BOD
◦ COD
Kinetics of BOD
Color
Varies according to the type of industry.
It is generally an indication of its age.
Color
Color is measured by comparison with standards using:
Visual Comparison Method
Nessler Tubes/Nessler Cylinders – Standardized glass tubes for filling with standard solution
colors for visual color comparison with similar tubes filled with solution samples.
Photoelectric Colorimeters/Spectrophotometers - Colorimeter that uses a phototube or
photocell, a set of color filters, an amplifier, and an indicating meter for quantitative
determination of color.
Odor
Odors are usually caused by gases produced by the decomposition of organic matter or by the
substances added to the wastewater.
Odor
Olfactometer - device used to measure odour intensity, and concentrations of volatile organic
compounds, by means of their smell.
Turbidity
A measure of the light-transmitting properties of water, is another test used to indicate the
quality of wastewater discharges and natural waters with respect to colloidal and residual
suspended matter.
Nephelometer – measures the intensity of light scattered at 90 degrees as a beam of light passes
through a water sample.
Turbidity
Secchi Disk Depth – circular disk used to measure water transparency in oceans and lakes.
Units in turbidity; JTU, FTU, NTU
Temperature
High temperatures lower the solubility of oxygen in water and increase the rate at which
oxygen-consuming microbes attack organic waste.
Solids
0.45-2 micrometer filter
Drying at
103-105
deg C
Drying at
103-105
deg C
Ignition to high
temperatures
(500°C to 600°C)
Ignition to high
temperatures
(500°C to 600°C)
SS = Settleable Solids
TSS = Total Suspended Solids
TDS = Total Dissolved Solids
VSS = Volatile Suspended Solids
FSS = Fixed Suspended Solids
VDS = Volatile Dissolved Solids
FDS = Fixed Dissolved Solids
TVS = Total Volatile Solids
TFS = Total Fixed Solids
TS = Total Solids
pH
The term pH is used to describe the acid or base properties of water solutions.
Trace Metals
Heavy metals which are toxic even in small concentrations.
Mercury – causes minamata disease which is a neurological disease characterized by trembling,
inability to walk and speak and even serious convulsions that can lead to death.
Cadmium – responsible for the Itai-itai disease; an extremely painful disease that causes
disintegration of the bones.
Silver – causes argyria, the blue-gray discoloration of the skin and mucous membrane.
Arsenic – recognized poison; carcinogenic
Chromium – causes neurological disease
Lead – leads to fetal malformation, mental disability, irritability, loss of appetite, and reduction
of sex drive.
Dissolved Oxygen
Quantity of free molecular oxygen dissolved in the water.
Factors affecting DO:
Temperature
Surface Area
Velocity
Theoretical Oxygen Demand
Measure of the amount of oxygen needed to oxidize completely and organic matter whose
chemical formula is known.
Biological Oxygen Demand
Measure of the amount of oxygen needed by microorganism to decompose biodegradable
organics at a specified time (5 days), temperature (20 deg C) and pH 7.
Chemical Oxygen Demand
Measure of the amount of oxygen needed to oxidize organics using strong oxidizing agents,
usually KMnO4 or K2Cr2O7 in acid media.
Reflux for 2 hours at 150 deg C
Kinetics of BOD
Oxygen Cocn
Time
Lt
Lo-Lt
BODt
Lo
BOD
BODt=Lo(1-e-kt
)
At different temperatures:
kt=k20(Ɵ)(T-20)
Ɵ = 1.056 (20-30)
Ɵ = 1.135 (<20)
Ɵ = 1.047 (>30)
Sample k
Raw Sewage 0.35-0.70
Well-treated sewage 0.12-0.23
Factors affecting k:
1. Nature of the waste
2. Temperature
3. Ability of the organisms in the system
to utilize the waste
Wastewater Treatment
Methods
Types of Wastes
Oxygen Demanding Wastes
Inorganic Wastes
Synthetic Organic Wastes
Nutrients
Pathogenic Wastes
Radioactive Wastes
Thermal Wastes
Why do we treat wastes?
To remove organic matter from the sewage which causes pollution
To remove pathogens (disease causing organisms) which pose serious health risk
Pre-treatment
Pre-treatment process has a little effect in BOD reduction.
Bar Racks- to remove large objects that would damage or foul pumps, valves and other
mechanical equipment.
Grit Chambers- tanks used to remove grits. Grits are inert dense materials such as sand, broken
glass, silt and pebbles. (Type I Sedimentation-Dilutes, non-flocculent, free-settling)
Comminutors/Macerators- used to macerate wastewater solids by revolving cutting bars.
Equalization Basins-not a treatment method but a technique to improve the effectiveness of
both secondary and advanced wastewater treatment. Purpose is to dampen variations so that
the wastewater can be treated at a nearby constant flow thus reducing the size and cost of
treatment units.
Primary Treatment
Primary Sedimentation Basins- removal of raw sludge by gravity settling. Overflow rate is the
controlling parameter and hydraulic detention time.
Type II Sedimentation-Dilute, flocculent (particles can flocculate as they settle).
FACTORS AFFECTING SEDIMENTATION
•PARTICLE SIZE
The size and type of particles to be removed have a significant effect on the operation of the
sedimentation tank.
•WATER TEMPERATURE
Another factor to consider in the operation of a sedimentation basin is the temperature of the
water being treated. When the temperature decreases, the rate of settling becomes slower.
Primary Treatment
Secondary Treatment (Biological)
Secondary treatment process removes soluble BOD that escapes the primary treatment.
Aerobic Decomposition
molecular oxygen is the terminal electron acceptor.
products of decomposition: carbon dioxide, water and new cell material (more stable products)
large amount of energy released therefore high growth rates. Consequently, large production
of new cells. (More biological sludge)
decomposition is rapid, efficient, low odor potential
Anaerobic Decomposition
molecular oxygen and nitrate must not be present as terminal electron acceptors.
sulfates, carbon dioxide and other organic compounds can serve as T.E.A.
decomposition products: ammonia, hydrogen sulfides, methane, mercaptans etc
energy released is low, thus sludge production is low.
3 Step Process:
1. Hydrolysis- breakdown of high molecular weight organic compounds into a smaller chained
compounds.
2. Acidogenesis-formation of low molecular weight fatty acids
3. Methanogenesis- formation of methane from organic fatty acids.
Secondary Treatment (Biological)
Secondary Treatment (Biological)
Anoxic Decomposition
nitrate ion is the terminal electron acceptor.
oxidation by this route is called denitrification.
decomposition products: nitrogen gas, carbon dioxide, water and new cell material
Activated Sludge Process
Activated Sludge Process
Aerated for 6-8 hrs (8 cubic meters/cubic meter wastewater)
as the microorganisms grow and are mixed by the agitation of the air, they clump together
forming biological floc (activated sludge).
some of the settled sludge is return to the aeration tank (return sludge) to maintain the high
population of microbes that permits rapid breakdown. (20-30%)
amount of time that microorganisms are kept in the system is called mean cell residence time,
solids retention time or sludge age.
Trickling Filters
consists of bed of coarse material, such as stones or plastic materials (media) over which
wastewater is applied.
provide large amounts of surface area where the microorganisms cling and grow in a slime on
the rocks. (attached growth process)
Trickling Filters
Trickling Filters
Filter Media:
Crushed rock
Plastic media
Rotating Biological Contactors (RBC)
Provide media for the buildup of attached microbial growth.
Bring growth into contact with the wastewater.
Aerate the wastewater and the suspended microbial growth in the reservoir.
Secondary Treatment (Chemical)
Chemical Precipitation
In current practice, chemical precipitation is used for the removal of phosphorus and for the
removal of heavy metals.
Common Precipitants:
•Lime
•Ferric Chloride
•Soda Ash
•Ferric Sulfate
•Alum
Secondary Treatment (Chemical)
Chemical Coagulation
An electrochemical process used in the removal of colloidal matter in wastewater through the
addition of coagulating agents which reduce the electrostatic chargers surrounding colloidal
matter.
Common Coagulants:
•Alum
•Copperas
Secondary Treatment (Chemical)
Chemical Flocculation
A physico-chemical process used in the removal of finely divided solids, a polyelectrolyte is
added to wastewater which can form bridges that will join together the solids.
Common Flocculants
•Anionic Polyacrylamide
•Alginates
•Sodium Aluminate
•Sodium Silicate
Tertiary Treatment
Disinfection
refers to the destruction of pathogenic microorganisms for the sole purpose of preventing
transmission of disease through water.
Sterilization
killing of ALL microorganisms present in water
Tertiary Treatment
Chlorination
Chlorine is used to disinfect wastewater in either gaseous form (Cl2), or as hypochlorite salts. All
forms of chlorine react with water to produce hypochlorous acid (HOCl), which rapidly
dissociates to form the hypochlorite ion according to the following reaction:
Cl2 +H2O ↔ HOCl + H+
+Cl-
HOCl ↔ OCl-
+ H+
Tertiary Treatment
Ozonation
Disinfection by ozonation is achieved using the formation of free radicals as oxidizing agents.
Ozonation is more effective against viruses and bacteria than chlorination, yet problems with
effective bactericidal action occur when conditions are not ideal.
Tertiary Treatment
Ultraviolet radiation
A physical process that principally involves passing a film of wastewater within close proximity
of a UV source (lamp). The efficiency of UV disinfection depends on the physical and chemical
water quality characteristics of the wastewater prior to disinfection.
Advanced Treatment Process
Carbon Adsorption
Reverse Osmosis
Micro, Nano and Ultrafiltration;
Electrodialysis
Ion-exchange
Solid Waste
Management
Integrated Solid Waste Management
The selection and application of suitable techniques, technologies and management programs
to achieve specific waste management objectives.
Includes factor like: frequency of collection, types of wastes collected, location of disposal site
and environmental acceptability of disposal system and level of satisfaction to customers.
Hierarchy of SWM
Prevention
Reduction
Recycling
Treatment
Dis
pos
al
Hierarchy of SWM
Reduce and Reuse
• Replacing raw materials (e.g. bioplastics-
replacing petroleum based plastics)
•Economic instruments to reduce waste
generation (Polluter pays principle)
Waste minimization
•Consumer behavior and ordinances
•Redesigning manufacturing process to reduce
waste
Hierarchy of SWM
Treatment
•Anaerobic Digestion-biological process that
occurs when organic matter is decomposed by
bacteria in the absence of oxygen. As the
bacteria decompose the organic matter, biogas
is released and captured.
•Biogas consists of approximately 60% methane
and 40% carbon dioxide.
•By-product is called Digestate and is low in
odor and nutritious.
Hierarchy of SWM
Treatment
•Composting-aerobic method of decomposing
organic solid wastes.
•The process involves decomposition of organic
material into a humus-like material, known as
compost, which is a good fertilizer for plants.
•Composting requires the following three
components: human management, aerobic
conditions, development of internal biological
heat.
Hierarchy of SWM
Treatment
•Incineration with energy recovery
•”Banned” in the Philippines.
•May emit dioxins and furans
•Volume reduction of 70%
•Capital intensive and needs constant feedstock
Treatment Technologies
Functional Elements of SWM
Generation
Amount of waste generated depends on the level of economic activity.
Storage
Trash bins/trash cans
Onsite Collection
Must isolate waste from the environment to prevent health hazard.
Collection
Accounts for significant portion of total cost
Functional Elements of SWM
Transfer/Transport
Direct or by transfer stations
Treatment
Recycling, Composting or Incineration
Disposal
Controlled dumpsite/Sanitary Landfill
Landfill Planning Considerations
Required Capacity
Area and volume required for MSW disposal
Depends on: Projected waste generation, rate of population growth, density to which waste is
compacted at landfill
NIMBY (Not in my backyard mentality)
Resident concerns: health and environmental risks, negative impact on aesthetics in the area,
lowering of property values
Hydro-geology
presence of water table, hydrological conductivity of the soil, annual precipitation, degree of
seismic activity in the area
Landfill Components and Configuration
Air Quality Management
Air Pollution
Alteration of the physical, chemical and biological properties of the atmosphere that is likely to
create harmful effects on public health, safety, and welfare
Different Air Pollutants
COx
CH 4
NO x
VOC
SO X
PM 10
Air Pollutant Classifications
Primary Pollutant
emitted by an identifiable source (e.g. CO,NOx,COx,SOx)
Secondary Pollutant
formed by the chemical reactions of the primary pollutants (e.g. acid rain)
Criteria Pollutant
6 criteria pollutants; CO,Pb,NO2,O3,PM and SO2
Non-criteria Pollutant
other than criteria pollutants
Air Pollution
Mobile sources generated the largest share of carbon monoxide in the metropolis at 99.21%
followed by the total organic gases at 93.5%, NOx at 82.86%, PM10 at 16.36%, SOx at 11.75%
and PM at 10.59% (EMB-DENR, 1999).
Major Air Pollutants
Carbon Dioxide
Main product of fossil fuel combustion; major greenhouse gas when it displaces oxygen in the air
causing suffocation due to binomia.
CO
Product of incomplete combustion; causes anoxicity where CO reacts with hemoglobin forming
carboxyhemoglobin
SOx
Acid rain precursors
NOx
Formed mainly during high temperature combustion of fuel in cars; causes reddish-brown haze in city
air; contributor to the formation of ground level bad ozone (tropospheric ozone)
Major Air Pollutants
Chlorofluorocarbons (CFCs)
Artificial gases used as coolants in refrigerators and air conditioners
Non-toxic, non-flammable, non-biodegradable, non-water soluble
Stable and can reach the stratosphere
Particulate Matter (PM)
Contribute to urban haze, cause visibility reduction
Air Pollution Control Equipment
Settling Chambers
Particulate removal is by gravity; recommended for particulate sizes in the range of 50 microns
or higher.
Cyclone Collector
Dirty gas is fed peripherally into the device. Particulate removal is by centrifugal impaction on
the cyclone wall from where it falls to the bottom; recommended for particulates of 20 to 45
microns in size.
Venturi Scrubbers
Uses water to effect particulate separation from the gas stream; recommended for particulates
of 5 to 20 microns and should have high affinity for water.
Air Pollution Control Equipment
Filters
Separates the particulates from the main stream by direct interception; filter medium is cloth or
acetate membrane filters
Electrostatic Precipitators
Most efficient method; recommended for all sizes if particulates especially those below 1 to 10
microns; gas is given an electrical charge as it enters the device.
Philippine Environmental Laws
RA 6969 – Toxic Substances and Hazardous and Nuclear Wastes Control Act of 1990
RA 8749 – Philippine Clean Air Act of 1999
RA 9003 – Ecological Solid Waste Management Act of 2000
RA 9275 – Philippine Clean Water Act of 2004
PD 1151 – Philippine Environmental Policy
PD 1152 – Philippine Environmental Code
List of International Agreements
Atmosphere
Framework Convention on Climate Change (UNFCC), New York, 1992
Kyoto Protocol, Japan 1997
Vienna Convention for the Protection of the Ozone Layer, Vienna, 1985
Montreal Protocol on Substances the Deplete the Ozone Layer, Montreal, 1987
List of International Agreements
Hazardous Substances
Convention on the Control of Transboundary Movements of Hazardous Wastes and their
Disposal, Basel, 1989
Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and
Pesticides in International Trade, Rotterdam, 1998
Minamata Convention on Mercury, Minamata 2013
Stockholm Convention Stockholm Convention on Persistent Organic Pollutants Stockholm, 2001
List of International Agreements
Nature Conservation and Terrestrial Living Resources
Ramsar Convention Convention on Wetlands of International Importance, especially as
Waterfowl Habitat, Ramsar, 1971
Nuclear Safety
Comprehensive Test Ban Treaty 1996
Convention on Early Notification of a Nuclear Accident (Notification Convention), Vienna, 1986

Introduction to Environmental Engineering.pptx

  • 1.
  • 2.
    Environmental Engineering Environmental Engineeringis manifest by sound engineering thought and practice in the solution of problems of environmental sanitation, notably in the provision of safe, palatable and ample public water supplies; the proper disposal of or recycle of wastewater and solid wastes; the adequate drainaige of urban and rural areas for proper sanitation; and the control of water, soil and atmospheric pollution, and the social and environmental impact of these solutions (ASCE,1977)
  • 3.
    Fields of EnvironmentalEngineering Environmental Impact Assessment The process of predicting the likely environmental consequences of implementing a project & designing appropriate preventive mitigating & enhancement measures as an input to decision making. Water Supply and Transport Develop a systems to store, treat, convey water for various uses Wastewater Conveyance and Treatment Develop collection and treatment systems to carry this waste material away from where people live and produce the waste and discharge it into the environment
  • 4.
    Fields of EnvironmentalEngineering Air Quality Management Design of manufacturing and combustion processes to reduce air pollutant emissions to acceptable levels
  • 5.
  • 6.
    Water Classification Depends onthe uses of water, namely for domestic, industrial, irrigation, transportation, habitat for marine life etc. Streams are classified according to the highest beneficial use that can be obtained from them. *Revised Water Usage and Classification- DENR Administrative Order No. 34 Series of 1990. *Revised Effluent Regulations of 1990- DENR Administrative Order No. 35 Series of 1990 *DAO 2016-08. For key changes, refer to the handout.
  • 7.
    Characteristics of Wastewater A.Physical Characteristics Color Odor Turbidity Temperature Total Solids B. Chemical Characteristics pH Phenols Hardness Pesticides and Agri Chemicals Nutrients Trace Metals Proteins Carbohydrates Oils, Fats and Greases Surfactants
  • 8.
    Characteristics of Wastewater C.Biological Characteristics Measures of Oxygen Demand ◦ DO ◦ ThOD ◦ BOD ◦ COD Kinetics of BOD
  • 9.
    Color Varies according tothe type of industry. It is generally an indication of its age.
  • 10.
    Color Color is measuredby comparison with standards using: Visual Comparison Method Nessler Tubes/Nessler Cylinders – Standardized glass tubes for filling with standard solution colors for visual color comparison with similar tubes filled with solution samples. Photoelectric Colorimeters/Spectrophotometers - Colorimeter that uses a phototube or photocell, a set of color filters, an amplifier, and an indicating meter for quantitative determination of color.
  • 11.
    Odor Odors are usuallycaused by gases produced by the decomposition of organic matter or by the substances added to the wastewater.
  • 12.
    Odor Olfactometer - deviceused to measure odour intensity, and concentrations of volatile organic compounds, by means of their smell.
  • 13.
    Turbidity A measure ofthe light-transmitting properties of water, is another test used to indicate the quality of wastewater discharges and natural waters with respect to colloidal and residual suspended matter. Nephelometer – measures the intensity of light scattered at 90 degrees as a beam of light passes through a water sample.
  • 14.
    Turbidity Secchi Disk Depth– circular disk used to measure water transparency in oceans and lakes. Units in turbidity; JTU, FTU, NTU
  • 15.
    Temperature High temperatures lowerthe solubility of oxygen in water and increase the rate at which oxygen-consuming microbes attack organic waste.
  • 16.
    Solids 0.45-2 micrometer filter Dryingat 103-105 deg C Drying at 103-105 deg C Ignition to high temperatures (500°C to 600°C) Ignition to high temperatures (500°C to 600°C) SS = Settleable Solids TSS = Total Suspended Solids TDS = Total Dissolved Solids VSS = Volatile Suspended Solids FSS = Fixed Suspended Solids VDS = Volatile Dissolved Solids FDS = Fixed Dissolved Solids TVS = Total Volatile Solids TFS = Total Fixed Solids TS = Total Solids
  • 17.
    pH The term pHis used to describe the acid or base properties of water solutions.
  • 18.
    Trace Metals Heavy metalswhich are toxic even in small concentrations. Mercury – causes minamata disease which is a neurological disease characterized by trembling, inability to walk and speak and even serious convulsions that can lead to death. Cadmium – responsible for the Itai-itai disease; an extremely painful disease that causes disintegration of the bones. Silver – causes argyria, the blue-gray discoloration of the skin and mucous membrane. Arsenic – recognized poison; carcinogenic Chromium – causes neurological disease Lead – leads to fetal malformation, mental disability, irritability, loss of appetite, and reduction of sex drive.
  • 19.
    Dissolved Oxygen Quantity offree molecular oxygen dissolved in the water. Factors affecting DO: Temperature Surface Area Velocity
  • 20.
    Theoretical Oxygen Demand Measureof the amount of oxygen needed to oxidize completely and organic matter whose chemical formula is known.
  • 21.
    Biological Oxygen Demand Measureof the amount of oxygen needed by microorganism to decompose biodegradable organics at a specified time (5 days), temperature (20 deg C) and pH 7.
  • 22.
    Chemical Oxygen Demand Measureof the amount of oxygen needed to oxidize organics using strong oxidizing agents, usually KMnO4 or K2Cr2O7 in acid media. Reflux for 2 hours at 150 deg C
  • 23.
    Kinetics of BOD OxygenCocn Time Lt Lo-Lt BODt Lo BOD BODt=Lo(1-e-kt ) At different temperatures: kt=k20(Ɵ)(T-20) Ɵ = 1.056 (20-30) Ɵ = 1.135 (<20) Ɵ = 1.047 (>30) Sample k Raw Sewage 0.35-0.70 Well-treated sewage 0.12-0.23 Factors affecting k: 1. Nature of the waste 2. Temperature 3. Ability of the organisms in the system to utilize the waste
  • 24.
  • 25.
    Types of Wastes OxygenDemanding Wastes Inorganic Wastes Synthetic Organic Wastes Nutrients Pathogenic Wastes Radioactive Wastes Thermal Wastes
  • 26.
    Why do wetreat wastes? To remove organic matter from the sewage which causes pollution To remove pathogens (disease causing organisms) which pose serious health risk
  • 27.
    Pre-treatment Pre-treatment process hasa little effect in BOD reduction. Bar Racks- to remove large objects that would damage or foul pumps, valves and other mechanical equipment. Grit Chambers- tanks used to remove grits. Grits are inert dense materials such as sand, broken glass, silt and pebbles. (Type I Sedimentation-Dilutes, non-flocculent, free-settling) Comminutors/Macerators- used to macerate wastewater solids by revolving cutting bars. Equalization Basins-not a treatment method but a technique to improve the effectiveness of both secondary and advanced wastewater treatment. Purpose is to dampen variations so that the wastewater can be treated at a nearby constant flow thus reducing the size and cost of treatment units.
  • 30.
    Primary Treatment Primary SedimentationBasins- removal of raw sludge by gravity settling. Overflow rate is the controlling parameter and hydraulic detention time. Type II Sedimentation-Dilute, flocculent (particles can flocculate as they settle).
  • 31.
    FACTORS AFFECTING SEDIMENTATION •PARTICLESIZE The size and type of particles to be removed have a significant effect on the operation of the sedimentation tank. •WATER TEMPERATURE Another factor to consider in the operation of a sedimentation basin is the temperature of the water being treated. When the temperature decreases, the rate of settling becomes slower. Primary Treatment
  • 32.
    Secondary Treatment (Biological) Secondarytreatment process removes soluble BOD that escapes the primary treatment. Aerobic Decomposition molecular oxygen is the terminal electron acceptor. products of decomposition: carbon dioxide, water and new cell material (more stable products) large amount of energy released therefore high growth rates. Consequently, large production of new cells. (More biological sludge) decomposition is rapid, efficient, low odor potential
  • 33.
    Anaerobic Decomposition molecular oxygenand nitrate must not be present as terminal electron acceptors. sulfates, carbon dioxide and other organic compounds can serve as T.E.A. decomposition products: ammonia, hydrogen sulfides, methane, mercaptans etc energy released is low, thus sludge production is low. 3 Step Process: 1. Hydrolysis- breakdown of high molecular weight organic compounds into a smaller chained compounds. 2. Acidogenesis-formation of low molecular weight fatty acids 3. Methanogenesis- formation of methane from organic fatty acids. Secondary Treatment (Biological)
  • 34.
    Secondary Treatment (Biological) AnoxicDecomposition nitrate ion is the terminal electron acceptor. oxidation by this route is called denitrification. decomposition products: nitrogen gas, carbon dioxide, water and new cell material
  • 35.
  • 36.
    Activated Sludge Process Aeratedfor 6-8 hrs (8 cubic meters/cubic meter wastewater) as the microorganisms grow and are mixed by the agitation of the air, they clump together forming biological floc (activated sludge). some of the settled sludge is return to the aeration tank (return sludge) to maintain the high population of microbes that permits rapid breakdown. (20-30%) amount of time that microorganisms are kept in the system is called mean cell residence time, solids retention time or sludge age.
  • 37.
    Trickling Filters consists ofbed of coarse material, such as stones or plastic materials (media) over which wastewater is applied. provide large amounts of surface area where the microorganisms cling and grow in a slime on the rocks. (attached growth process)
  • 38.
  • 40.
  • 41.
    Rotating Biological Contactors(RBC) Provide media for the buildup of attached microbial growth. Bring growth into contact with the wastewater. Aerate the wastewater and the suspended microbial growth in the reservoir.
  • 43.
    Secondary Treatment (Chemical) ChemicalPrecipitation In current practice, chemical precipitation is used for the removal of phosphorus and for the removal of heavy metals. Common Precipitants: •Lime •Ferric Chloride •Soda Ash •Ferric Sulfate •Alum
  • 44.
    Secondary Treatment (Chemical) ChemicalCoagulation An electrochemical process used in the removal of colloidal matter in wastewater through the addition of coagulating agents which reduce the electrostatic chargers surrounding colloidal matter. Common Coagulants: •Alum •Copperas
  • 45.
    Secondary Treatment (Chemical) ChemicalFlocculation A physico-chemical process used in the removal of finely divided solids, a polyelectrolyte is added to wastewater which can form bridges that will join together the solids. Common Flocculants •Anionic Polyacrylamide •Alginates •Sodium Aluminate •Sodium Silicate
  • 46.
    Tertiary Treatment Disinfection refers tothe destruction of pathogenic microorganisms for the sole purpose of preventing transmission of disease through water. Sterilization killing of ALL microorganisms present in water
  • 47.
    Tertiary Treatment Chlorination Chlorine isused to disinfect wastewater in either gaseous form (Cl2), or as hypochlorite salts. All forms of chlorine react with water to produce hypochlorous acid (HOCl), which rapidly dissociates to form the hypochlorite ion according to the following reaction: Cl2 +H2O ↔ HOCl + H+ +Cl- HOCl ↔ OCl- + H+
  • 48.
    Tertiary Treatment Ozonation Disinfection byozonation is achieved using the formation of free radicals as oxidizing agents. Ozonation is more effective against viruses and bacteria than chlorination, yet problems with effective bactericidal action occur when conditions are not ideal.
  • 49.
    Tertiary Treatment Ultraviolet radiation Aphysical process that principally involves passing a film of wastewater within close proximity of a UV source (lamp). The efficiency of UV disinfection depends on the physical and chemical water quality characteristics of the wastewater prior to disinfection.
  • 50.
    Advanced Treatment Process CarbonAdsorption Reverse Osmosis Micro, Nano and Ultrafiltration; Electrodialysis Ion-exchange
  • 51.
  • 52.
    Integrated Solid WasteManagement The selection and application of suitable techniques, technologies and management programs to achieve specific waste management objectives. Includes factor like: frequency of collection, types of wastes collected, location of disposal site and environmental acceptability of disposal system and level of satisfaction to customers.
  • 53.
  • 54.
    Hierarchy of SWM Reduceand Reuse • Replacing raw materials (e.g. bioplastics- replacing petroleum based plastics) •Economic instruments to reduce waste generation (Polluter pays principle) Waste minimization •Consumer behavior and ordinances •Redesigning manufacturing process to reduce waste
  • 56.
    Hierarchy of SWM Treatment •AnaerobicDigestion-biological process that occurs when organic matter is decomposed by bacteria in the absence of oxygen. As the bacteria decompose the organic matter, biogas is released and captured. •Biogas consists of approximately 60% methane and 40% carbon dioxide. •By-product is called Digestate and is low in odor and nutritious.
  • 57.
    Hierarchy of SWM Treatment •Composting-aerobicmethod of decomposing organic solid wastes. •The process involves decomposition of organic material into a humus-like material, known as compost, which is a good fertilizer for plants. •Composting requires the following three components: human management, aerobic conditions, development of internal biological heat.
  • 58.
    Hierarchy of SWM Treatment •Incinerationwith energy recovery •”Banned” in the Philippines. •May emit dioxins and furans •Volume reduction of 70% •Capital intensive and needs constant feedstock
  • 59.
  • 60.
    Functional Elements ofSWM Generation Amount of waste generated depends on the level of economic activity. Storage Trash bins/trash cans Onsite Collection Must isolate waste from the environment to prevent health hazard. Collection Accounts for significant portion of total cost
  • 61.
    Functional Elements ofSWM Transfer/Transport Direct or by transfer stations Treatment Recycling, Composting or Incineration Disposal Controlled dumpsite/Sanitary Landfill
  • 62.
    Landfill Planning Considerations RequiredCapacity Area and volume required for MSW disposal Depends on: Projected waste generation, rate of population growth, density to which waste is compacted at landfill NIMBY (Not in my backyard mentality) Resident concerns: health and environmental risks, negative impact on aesthetics in the area, lowering of property values Hydro-geology presence of water table, hydrological conductivity of the soil, annual precipitation, degree of seismic activity in the area
  • 63.
  • 64.
  • 65.
    Air Pollution Alteration ofthe physical, chemical and biological properties of the atmosphere that is likely to create harmful effects on public health, safety, and welfare Different Air Pollutants COx CH 4 NO x VOC SO X PM 10
  • 66.
    Air Pollutant Classifications PrimaryPollutant emitted by an identifiable source (e.g. CO,NOx,COx,SOx) Secondary Pollutant formed by the chemical reactions of the primary pollutants (e.g. acid rain) Criteria Pollutant 6 criteria pollutants; CO,Pb,NO2,O3,PM and SO2 Non-criteria Pollutant other than criteria pollutants
  • 67.
    Air Pollution Mobile sourcesgenerated the largest share of carbon monoxide in the metropolis at 99.21% followed by the total organic gases at 93.5%, NOx at 82.86%, PM10 at 16.36%, SOx at 11.75% and PM at 10.59% (EMB-DENR, 1999).
  • 68.
    Major Air Pollutants CarbonDioxide Main product of fossil fuel combustion; major greenhouse gas when it displaces oxygen in the air causing suffocation due to binomia. CO Product of incomplete combustion; causes anoxicity where CO reacts with hemoglobin forming carboxyhemoglobin SOx Acid rain precursors NOx Formed mainly during high temperature combustion of fuel in cars; causes reddish-brown haze in city air; contributor to the formation of ground level bad ozone (tropospheric ozone)
  • 69.
    Major Air Pollutants Chlorofluorocarbons(CFCs) Artificial gases used as coolants in refrigerators and air conditioners Non-toxic, non-flammable, non-biodegradable, non-water soluble Stable and can reach the stratosphere Particulate Matter (PM) Contribute to urban haze, cause visibility reduction
  • 70.
    Air Pollution ControlEquipment Settling Chambers Particulate removal is by gravity; recommended for particulate sizes in the range of 50 microns or higher. Cyclone Collector Dirty gas is fed peripherally into the device. Particulate removal is by centrifugal impaction on the cyclone wall from where it falls to the bottom; recommended for particulates of 20 to 45 microns in size. Venturi Scrubbers Uses water to effect particulate separation from the gas stream; recommended for particulates of 5 to 20 microns and should have high affinity for water.
  • 71.
    Air Pollution ControlEquipment Filters Separates the particulates from the main stream by direct interception; filter medium is cloth or acetate membrane filters Electrostatic Precipitators Most efficient method; recommended for all sizes if particulates especially those below 1 to 10 microns; gas is given an electrical charge as it enters the device.
  • 72.
    Philippine Environmental Laws RA6969 – Toxic Substances and Hazardous and Nuclear Wastes Control Act of 1990 RA 8749 – Philippine Clean Air Act of 1999 RA 9003 – Ecological Solid Waste Management Act of 2000 RA 9275 – Philippine Clean Water Act of 2004 PD 1151 – Philippine Environmental Policy PD 1152 – Philippine Environmental Code
  • 73.
    List of InternationalAgreements Atmosphere Framework Convention on Climate Change (UNFCC), New York, 1992 Kyoto Protocol, Japan 1997 Vienna Convention for the Protection of the Ozone Layer, Vienna, 1985 Montreal Protocol on Substances the Deplete the Ozone Layer, Montreal, 1987
  • 74.
    List of InternationalAgreements Hazardous Substances Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal, Basel, 1989 Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade, Rotterdam, 1998 Minamata Convention on Mercury, Minamata 2013 Stockholm Convention Stockholm Convention on Persistent Organic Pollutants Stockholm, 2001
  • 75.
    List of InternationalAgreements Nature Conservation and Terrestrial Living Resources Ramsar Convention Convention on Wetlands of International Importance, especially as Waterfowl Habitat, Ramsar, 1971 Nuclear Safety Comprehensive Test Ban Treaty 1996 Convention on Early Notification of a Nuclear Accident (Notification Convention), Vienna, 1986