L-35
Ambient air quality monitoring and
High volume sampler
Unit-V
Instruments needed for
sampling
Sr.
No

Parameter Instrument
used

Measuring unit

1

Temperature Thermometer

0C

2

Wind speed Anemometer

m/sec

3

Relative
humidity
Arm.
pressure

No unit (Expressed
in percentage)
Millibars or mm of
Hg

4

Page 2

Hygrometer
Barometer

15-10-2013
The Aim of Sampling:
•The principal requirement of a
sampling system is to obtain a sample
that
is
representative
of
the
atmosphere at a particular place and
time and that can be evaluated as a
mass or volume concentration.
•The sampling system should not alter
the
chemical
or
physical
characteristics of the sample in an
undesirable manner.
The major components of most
sampling systems are:
1) An inlet manifold
2) An Air mover (Blower)
3) A collection medium
4 ) Flow measurement device
(1)The

inlet

manifold

transports

the

material from the ambient atmosphere to
the collection medium or analytical
device in an unaltered condition, all inlet
of ambient air must be rainproof.
(2)The air mover (Blower) provides the force
to create a vacuum or lower pressure at
the end of the sampling system (pumps).
(3) The collecting medium, may be
solid

or

liquid

sorbent

for

dissolving gases a filter surface for
collecting particles.
(4)The flow device measures the
volume of air associated with the
sampling system.
PARTICULATE SAMPLING
METHODS
Page 7

15-10-2013
• Gravitational method
• For collecting dust particles of 1µ

(micron) or larger 40 µ (micron ) in
the atmosphere, clean glass jars are kept
in the area where dust fall is to be
determined and after a few hours or days,
the dust is collected from each jar and
then weighed.
• The average weight of dust in each jar
is estimated and the dust fall is
expressed as weight of dust per unit
area per unit time.
Page 8

15-10-2013
• Containers, generally conical plastic jars,

10-15 cm in diameter, open at the top
are used.
• The jars are kept in strategic locations
throughout a community or in the vicinity
of particulate sources under study.
• Grit and dust fall into the jars which
sometimes have water to hold the dust.
After a one month exposure, the jars are
collected and brought into the laboratory
where their contents are analysed.
Page 9

15-10-2013
• In most cases only the total

particulate matter is determined, and
the results are expressed in terms of
tons per square kilometer per
month or g/sq. m / month.
• Monthly isopleth maps can be
constructed showing the variation of
dust fall throughout the area.

Page 10

15-10-2013
Page 11

15-10-2013
Dust
fall
jar

Page 12

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Dust
depositor

Page 13

15-10-2013
Filtration
• A fibrous filter which is woven with randomly

oriented fibers acts as a target for the
collection of fine particles. When airborne
particles enter a filter and flow around the
fibers, they are subjected to aerodynamic
forces which result in their collection on the
fibers.
• The principal mechanisms operating are
gravitation, inertia, interception and diffusion.
Page 14

15-10-2013
• Many types of filters are available for

removal of particulate matter from gas
streams.
• The chief variations are in the filter media
material and in the shape of the
membrane.
• One common type is the thimble filter
shown diagrammatically.
• The filter paper thimble is filled with wellfluffed cotton which operates at a
sampling rate of 2 cf/min.
Page 15

15-10-2013
• By determining the change in

weight of the dried filter after
exposure, dust concentration in the
gas stream is determined.
• The paper thimble cannot be used
with high temperature gases; an
alundum thimble is useful in this
case.

Page 16

15-10-2013
Page 17

15-10-2013
Cyclones
• Cyclones are a special type of impactors where

the impaction (on the side walls of the cyclone)
is combined with the gravitational settling of
the large particles.
• The effect is that the large particles will get
trapped before they reach the collecting filter
and thus giving a cut off size dependent of the
size, geometry and air flow velocity through the
cyclone.
• Cyclones (often) have the advantage of being
both small and cheap but still accurate enough
for most modern requirements.
Page 18
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Page 19

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Page 20

15-10-2013
Cascade Impactors
• Cascade impactors are consists of a

number of impactor stages connected
in series with smaller and smaller cutoff diameter.
• The cut-off diameter in each stage
depends on the air velocity and
geometry of the stage (i.e. the
distance from the nozzle to the
impaction plate).
Page 21

15-10-2013
• Cascade impactors often have up to

some ten stages ranging from a
cut-off diameter on the first stage
of 10 – 30 m to a diameter of 0.1
m or lower on the backup filter in
the end.
• This gives the opportunity to
analyse (e.g. chemical or
gravimetrical) a number of small
size intervals.
Page 22

15-10-2013
• Some drawbacks are the risk of bounce off

from one stage to the next (i.e. particles of
wrong size at some of the stages) as well as
the problem of obtaining sharp cut-off
diameters in the last stages (cut-off diameter
less than 0.1 – 0.2 m).
• Coating the impaction plates with oil or some
other sticky substance, which catches the
particles more effectively, can reduce the risk
of bounce of.
• This will then prevent or severely complicate
direct mass concentration calculations of the
different stages.
Page 23
15-10-2013
Page 24

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Page 25

15-10-2013
Electrostatic precipitators
• An electrostatic precipitator consists of an

ionizing electrode charged with a high negative
potential and a collector to be maintained at
positive potential produced by a special
transformer and rectifier.
• A known volume of air is allowed to pass
through the precipitator where the incoming
particles become negatively charged by the
electrode and adhere to the positively charged
collecting tube.
Page 26

15-10-2013
• The collected particles are weighed and

their number can also be counted
accurately by using a microscope.
• This method of collection of particulate
matter is very efficient as high flow
rates with small pressure drops can be
used.
Page 27

15-10-2013
Thermal precipitator
• In thermal precipitators the particles in the

sampled stream move past a very hot wire
and are repulsed to the nearby cold plate
where they are collected.
• However, it can operate only at very low
sampling rates-approximately 50 mililitres
per minute and is useful only for R&D work.
Figure shows a thermal precipitator of the
type supplied by Casella Company Ltd.,
London, England.
Page 28

15-10-2013
Page 29

15-10-2013
L-36
High Volume Sampler

Page 30

15-10-2013
Page 31

15-10-2013
INTRODUCTION
• High Volume Samplers are the basic

instruments used to monitor Ambient Air
Quality.
• They are in widespread use all over the
world to measure air pollution in industrial
areas, urban areas, on the shop floor,
near monuments and other sensitive
areas.
Page 32

15-10-2013
• The High Volume Sampler is a vital tool

for studies relating to impact of
industrialisation to the air analysis, and
for work related diseases of the
respiratory system to air pollution.
• These are very much essential for
various Environmental Impact
Assessment studies

Page 33

15-10-2013
Components of HVS
• Heavy Duty Blower,
• Orifice flow meter- measures flow,
• Time Totaliser-records time,
• Programmable Timer- measures time,
• Instrument Cabinet- acts as protection,
• Filter Holder assembly- holds the filter in

position,
• Voltage Stabiliser- guards against
voltage fluctuation,
• Detachable Gable roof- allows passage of
air and protects filter.
Page 34
15-10-2013
PRINCIPLE OF OPERATION
• In these samplers, air-borne suspended

particulates (SPM) are measured by passing air
at a high flow-rate of 1.1 to 1.7 cubic meters
per minute through a high efficiency filter
paper which retains the particles.
• The instrument measures the volume of air
sampled, while the amount of particulates
collected is determined by measuring the
change in weight of the filter paper as a
consequence of the sampling.
Page 35

15-10-2013
• The passage for air reaching the filter is

designed to prevent heavier settleable dust
particles from reaching the filter (by provision
of cyclone) thus measuring the concentration of
Suspended Particulate Matter (SPM) in
atmospheric air.

Page 36

15-10-2013
• In high volume sampler provisions have

been made for simultaneous sampling of
gaseous pollutants.
• Here the air is passed through suitable
reagents that would absorb specific gases
where gaseous pollutants like SO2, NOx,
Cl2, H2S, CS2, NH3, etc. are analysed
subsequently by simple wet chemistry
method to determine the concentration of
specific pollutant.
Page 37

15-10-2013
Page 38

15-10-2013
Page 39

15-10-2013
Page 40

15-10-2013
Page 41

15-10-2013
Applications of HVS
• Routine Monitoring by air monitoring

networks
• Open Spaces like forests and national park
air monitoring.
• Monitoring around ecologically sensitive
monuments
•

Page 42

15-10-2013
• Data reporting for monthly and

•
•
•
•

yearly averages by local area air
quality networks.
Site Monitoring by industries.
Evaluative Studies
Lab Applications
Research Studies
Page 43

15-10-2013
Calculation of SPM concentration

Page 44

15-10-2013
Theory Questions
Q1. State principles used for sampling of
particulate matter. Explain any one in detail.

(Nov 2008, May 2009, 8 marks)
Q2. Explain working of high volume sampler with
sketch. (May 2011, 8 marks).
Q3. Explain various principles used in particulate
matter sampling. (May 2011, 8 marks)

Q4. Explain procedure for determining
concentration of SPM in ambient air.
Page 45

15-10-2013

L 35 final

  • 1.
    L-35 Ambient air qualitymonitoring and High volume sampler Unit-V
  • 2.
    Instruments needed for sampling Sr. No ParameterInstrument used Measuring unit 1 Temperature Thermometer 0C 2 Wind speed Anemometer m/sec 3 Relative humidity Arm. pressure No unit (Expressed in percentage) Millibars or mm of Hg 4 Page 2 Hygrometer Barometer 15-10-2013
  • 3.
    The Aim ofSampling: •The principal requirement of a sampling system is to obtain a sample that is representative of the atmosphere at a particular place and time and that can be evaluated as a mass or volume concentration. •The sampling system should not alter the chemical or physical characteristics of the sample in an undesirable manner.
  • 4.
    The major componentsof most sampling systems are: 1) An inlet manifold 2) An Air mover (Blower) 3) A collection medium 4 ) Flow measurement device
  • 5.
    (1)The inlet manifold transports the material from theambient atmosphere to the collection medium or analytical device in an unaltered condition, all inlet of ambient air must be rainproof. (2)The air mover (Blower) provides the force to create a vacuum or lower pressure at the end of the sampling system (pumps).
  • 6.
    (3) The collectingmedium, may be solid or liquid sorbent for dissolving gases a filter surface for collecting particles. (4)The flow device measures the volume of air associated with the sampling system.
  • 7.
  • 8.
    • Gravitational method •For collecting dust particles of 1µ (micron) or larger 40 µ (micron ) in the atmosphere, clean glass jars are kept in the area where dust fall is to be determined and after a few hours or days, the dust is collected from each jar and then weighed. • The average weight of dust in each jar is estimated and the dust fall is expressed as weight of dust per unit area per unit time. Page 8 15-10-2013
  • 9.
    • Containers, generallyconical plastic jars, 10-15 cm in diameter, open at the top are used. • The jars are kept in strategic locations throughout a community or in the vicinity of particulate sources under study. • Grit and dust fall into the jars which sometimes have water to hold the dust. After a one month exposure, the jars are collected and brought into the laboratory where their contents are analysed. Page 9 15-10-2013
  • 10.
    • In mostcases only the total particulate matter is determined, and the results are expressed in terms of tons per square kilometer per month or g/sq. m / month. • Monthly isopleth maps can be constructed showing the variation of dust fall throughout the area. Page 10 15-10-2013
  • 11.
  • 12.
  • 13.
  • 14.
    Filtration • A fibrousfilter which is woven with randomly oriented fibers acts as a target for the collection of fine particles. When airborne particles enter a filter and flow around the fibers, they are subjected to aerodynamic forces which result in their collection on the fibers. • The principal mechanisms operating are gravitation, inertia, interception and diffusion. Page 14 15-10-2013
  • 15.
    • Many typesof filters are available for removal of particulate matter from gas streams. • The chief variations are in the filter media material and in the shape of the membrane. • One common type is the thimble filter shown diagrammatically. • The filter paper thimble is filled with wellfluffed cotton which operates at a sampling rate of 2 cf/min. Page 15 15-10-2013
  • 16.
    • By determiningthe change in weight of the dried filter after exposure, dust concentration in the gas stream is determined. • The paper thimble cannot be used with high temperature gases; an alundum thimble is useful in this case. Page 16 15-10-2013
  • 17.
  • 18.
    Cyclones • Cyclones area special type of impactors where the impaction (on the side walls of the cyclone) is combined with the gravitational settling of the large particles. • The effect is that the large particles will get trapped before they reach the collecting filter and thus giving a cut off size dependent of the size, geometry and air flow velocity through the cyclone. • Cyclones (often) have the advantage of being both small and cheap but still accurate enough for most modern requirements. Page 18 15-10-2013
  • 19.
  • 20.
  • 21.
    Cascade Impactors • Cascadeimpactors are consists of a number of impactor stages connected in series with smaller and smaller cutoff diameter. • The cut-off diameter in each stage depends on the air velocity and geometry of the stage (i.e. the distance from the nozzle to the impaction plate). Page 21 15-10-2013
  • 22.
    • Cascade impactorsoften have up to some ten stages ranging from a cut-off diameter on the first stage of 10 – 30 m to a diameter of 0.1 m or lower on the backup filter in the end. • This gives the opportunity to analyse (e.g. chemical or gravimetrical) a number of small size intervals. Page 22 15-10-2013
  • 23.
    • Some drawbacksare the risk of bounce off from one stage to the next (i.e. particles of wrong size at some of the stages) as well as the problem of obtaining sharp cut-off diameters in the last stages (cut-off diameter less than 0.1 – 0.2 m). • Coating the impaction plates with oil or some other sticky substance, which catches the particles more effectively, can reduce the risk of bounce of. • This will then prevent or severely complicate direct mass concentration calculations of the different stages. Page 23 15-10-2013
  • 24.
  • 25.
  • 26.
    Electrostatic precipitators • Anelectrostatic precipitator consists of an ionizing electrode charged with a high negative potential and a collector to be maintained at positive potential produced by a special transformer and rectifier. • A known volume of air is allowed to pass through the precipitator where the incoming particles become negatively charged by the electrode and adhere to the positively charged collecting tube. Page 26 15-10-2013
  • 27.
    • The collectedparticles are weighed and their number can also be counted accurately by using a microscope. • This method of collection of particulate matter is very efficient as high flow rates with small pressure drops can be used. Page 27 15-10-2013
  • 28.
    Thermal precipitator • Inthermal precipitators the particles in the sampled stream move past a very hot wire and are repulsed to the nearby cold plate where they are collected. • However, it can operate only at very low sampling rates-approximately 50 mililitres per minute and is useful only for R&D work. Figure shows a thermal precipitator of the type supplied by Casella Company Ltd., London, England. Page 28 15-10-2013
  • 29.
  • 30.
  • 31.
  • 32.
    INTRODUCTION • High VolumeSamplers are the basic instruments used to monitor Ambient Air Quality. • They are in widespread use all over the world to measure air pollution in industrial areas, urban areas, on the shop floor, near monuments and other sensitive areas. Page 32 15-10-2013
  • 33.
    • The HighVolume Sampler is a vital tool for studies relating to impact of industrialisation to the air analysis, and for work related diseases of the respiratory system to air pollution. • These are very much essential for various Environmental Impact Assessment studies Page 33 15-10-2013
  • 34.
    Components of HVS •Heavy Duty Blower, • Orifice flow meter- measures flow, • Time Totaliser-records time, • Programmable Timer- measures time, • Instrument Cabinet- acts as protection, • Filter Holder assembly- holds the filter in position, • Voltage Stabiliser- guards against voltage fluctuation, • Detachable Gable roof- allows passage of air and protects filter. Page 34 15-10-2013
  • 35.
    PRINCIPLE OF OPERATION •In these samplers, air-borne suspended particulates (SPM) are measured by passing air at a high flow-rate of 1.1 to 1.7 cubic meters per minute through a high efficiency filter paper which retains the particles. • The instrument measures the volume of air sampled, while the amount of particulates collected is determined by measuring the change in weight of the filter paper as a consequence of the sampling. Page 35 15-10-2013
  • 36.
    • The passagefor air reaching the filter is designed to prevent heavier settleable dust particles from reaching the filter (by provision of cyclone) thus measuring the concentration of Suspended Particulate Matter (SPM) in atmospheric air. Page 36 15-10-2013
  • 37.
    • In highvolume sampler provisions have been made for simultaneous sampling of gaseous pollutants. • Here the air is passed through suitable reagents that would absorb specific gases where gaseous pollutants like SO2, NOx, Cl2, H2S, CS2, NH3, etc. are analysed subsequently by simple wet chemistry method to determine the concentration of specific pollutant. Page 37 15-10-2013
  • 38.
  • 39.
  • 40.
  • 41.
  • 42.
    Applications of HVS •Routine Monitoring by air monitoring networks • Open Spaces like forests and national park air monitoring. • Monitoring around ecologically sensitive monuments • Page 42 15-10-2013
  • 43.
    • Data reportingfor monthly and • • • • yearly averages by local area air quality networks. Site Monitoring by industries. Evaluative Studies Lab Applications Research Studies Page 43 15-10-2013
  • 44.
    Calculation of SPMconcentration Page 44 15-10-2013
  • 45.
    Theory Questions Q1. Stateprinciples used for sampling of particulate matter. Explain any one in detail. (Nov 2008, May 2009, 8 marks) Q2. Explain working of high volume sampler with sketch. (May 2011, 8 marks). Q3. Explain various principles used in particulate matter sampling. (May 2011, 8 marks) Q4. Explain procedure for determining concentration of SPM in ambient air. Page 45 15-10-2013