Today we will discuss about
Introduction
BASIT ALI KHAN (2012-IM-124)
PRESENTED BY
OUTLINES of our Presentation
We have features for every step of the way
Introduction
to Processes
Mechanism/
Procedure
Example &
Applications
ADVANTAGES &
DISADVANTAGES
Introduction
Introduction
Both Processes are Anti-wear
Heat treatments.
Nitriding
&
Carbonitriding
NITRIDING
Nitriding is a heat treating process that
diffuses nitrogen into the surface of a metal to
create a case hardened surface.
 Nitriding of steels produces less distortion
and deformation than either carburizing or
conventional hardening.
NITRIDING
 These processes are most commonly used on
low-carbon, low-alloy steels.
However they are also used on medium and
high-carbon steels, titanium, aluminum and
molybdenum.
Carbonitriding
CARBONITRIDING
 Carbonitriding is a metallurgical surface modification
technique that is used to increase the surface
hardness of a metal, thereby reducing wear.
 In carbonitriding , atoms of carbon and nitrogen
diffuse interstitially into the metal, creating barriers
to slip, increasing the hardness and modulus near
the surface.
MECHANISMPROCEDURE
 Carbonitriding is often applied to inexpensive, easily
machined low carbon steel to impart the surface
properties of more expensive and difficult to work
grades of steel.
 Surface hardness of carbonitrided parts ranges from
55 to 62 HRC.
Carbonitriding
Nitriding and carbonitriding   copy
Introduction
NITRIDING
MECHANISM / PROCEDURE
MECHANISM OF NITRIDING
NITRIDING.
• Case-hardening process.
• Solid ferrous alloy.
• Diffuse nitrogen.
• At some suitable temperature.
MEHANISM OF NITRIDING
gas nitriding .
Salt bath nitriding.
plasma nitriding.
MEHANISM OF NITRIDING
•Gas Nitriding
•Case-Hardening Process
•Nitrogen Introduction
•Surface of a Solid Ferrous Alloy
•Nitrogenous Gas
•Ammonia
 Chemical Reaction
•Nitrogen & Iron
•Core Properties Not Effected
 Temperature Range
•495 - 565 ºC
•Below Tempering Temperature
 White Layer By-Product
•Thin
•Hard Iron Nitride
• Chemical Reaction
Nitriding and carbonitriding   copy
MEHANISM OF NITRIDING
•Salt bath NITRIDING
•Thermo-chemical Diffusion Treatment
•Hardening Components With
Repeatability.
•Use salt nitrogen-containing
•Salt Bath, at sub-Critical Temperatures.
•Higher diffusion nitrogen
•Corrosion Protection
Nitriding and carbonitriding   copy
MEHANISM OF NITRIDING
•Vacuum Chamber
•Pressure = 0.64 Pa
•Pre-Heat Cycle
•Surface Cleaning
•Intense electric field.
•Control Gas Flow
•N, H, CH4
•Ionization by Voltage
•Blue-Violet Glow
•Wear Resistant Layer
•PLASMA NITRIDING
Nitriding and carbonitriding   copy
MEHANISM OF NITRIDING
Introduction
CARBONITRIDING
MECHANISM / PROCEDURE
 Carbonitriding is similar to gas carburization
with the addition of ammonia to the
carburizing atmosphere, which provides a
source of nitrogen.
 Nascent nitrogen forms at the work
surface by the dissociation of ammonia in
the furnace atmosphere; the nitrogen
diffuses into the steel simultaneously
with carbon.
 Typically, carbonitriding is carried out at
a lower temperature and for a shorter
time than is gas carburizing, producing a
shallower case than is usual in production
carburizing.
CARBONITRIDING IN FC-35
ATMOSPHERE
Ammonia and CO2 flows are
maintained constant through out the
process during Carbonitriding in the
FC35 process.
A typical Carbonitriding process cycle
using the FC35
Nitriding/CarbonitridingFurnace
 Carbonitriding (around 850 °C / 1550 °F) is carried
out at temperatures substantially higher than plain
nitriding (around 530 °C / 990 °F) but slightly
lower than those used for carburizing (around 950
°C / 1700 °F) and for shorter times.
A typical Carbonitriding process cycle using the
FC35
 Carbonitriding forms a hard, wear-resistant case, is
typically 0.07mm to 0.5mm thick.
 Maximum case depth is typically restricted to
0.75mm; case depths greater than this take too long
to diffuse to be economical.
 Its carried out in a salt bath or in a furnace gas
atmosphere.
Nitriding and carbonitriding   copy
Aircraft Industry
Aircraft Industry
 Military technology
 Military technology
Automotive Industry
Internal combustion engines
Compressors
Crank Shafts, Cam shafts, Gears etc.
Tools & Dies
Nitriding and carbonitriding   copy
 It gives high surface hardness.
 Nitriding increase wear resistance.
 It increase the tensile strength and
yield point.
 Improves fatigue life by 30% to 100%.
 It is good for high temperature
applications.
ADVANTAGES
 It has a greater resistance to softening
during Tempering.
 The carbonitrided case has better wear
and temper resistance than a straight
carburized case.
 It is carried out at a lower temperature
and for a shorter time than is gas
carburizing.
 Reduced distortion due to lower
temperature.
ADVANTAGES
 Since nitrided parts are not quenched,
this minimizes distortion or cracking.
 Whereas in a carburized part, hardness
begins to fall at about 200°C, a nitrided
part retains hardness up to 500°C.
 No machining is required after nitriding.
 Some complex parts which are not
carburized satisfactorily, can be nitrided
without difficulty.
ADVANTAGES
DISADVANTAGES
 Asymmetric products could buckle due
to unequal cooling effects
 Maximum dimensions are determined
by the furnace dimensions
 Blind holes cannot be treated during
plasma - nitriding.
 Toughness and impact resistance
decrease
DISADVANTAGES
 It produces shallower cases.
 It is not possible to obtain higher core
hardness and deeper case depths.
 Only useful for Plain carbon steel or
Low alloy Steel.
 Ammonia can produce harmful effects.
 Long cycle times (40 to 100 hours).
DISADVANTAGES
 The brittle case formed is Brittle.
 Only special alloy steels (containing Al, Cr
and V) can be satisfactorily treated.
 High cost of the nitriding process.
 Technical control required.
 If a nitrided component is accidentally
overheated, the surface hardness will be lost
completely and the component must be
nitrided again.
?
Scratch your mind!
THANK YOU
!

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Nitriding and carbonitriding copy

  • 1. Today we will discuss about
  • 2. Introduction BASIT ALI KHAN (2012-IM-124) PRESENTED BY
  • 3. OUTLINES of our Presentation We have features for every step of the way Introduction to Processes Mechanism/ Procedure Example & Applications ADVANTAGES & DISADVANTAGES
  • 5. Introduction Both Processes are Anti-wear Heat treatments. Nitriding & Carbonitriding
  • 6. NITRIDING Nitriding is a heat treating process that diffuses nitrogen into the surface of a metal to create a case hardened surface.  Nitriding of steels produces less distortion and deformation than either carburizing or conventional hardening.
  • 7. NITRIDING  These processes are most commonly used on low-carbon, low-alloy steels. However they are also used on medium and high-carbon steels, titanium, aluminum and molybdenum.
  • 8. Carbonitriding CARBONITRIDING  Carbonitriding is a metallurgical surface modification technique that is used to increase the surface hardness of a metal, thereby reducing wear.  In carbonitriding , atoms of carbon and nitrogen diffuse interstitially into the metal, creating barriers to slip, increasing the hardness and modulus near the surface.
  • 9. MECHANISMPROCEDURE  Carbonitriding is often applied to inexpensive, easily machined low carbon steel to impart the surface properties of more expensive and difficult to work grades of steel.  Surface hardness of carbonitrided parts ranges from 55 to 62 HRC. Carbonitriding
  • 12. MECHANISM OF NITRIDING NITRIDING. • Case-hardening process. • Solid ferrous alloy. • Diffuse nitrogen. • At some suitable temperature.
  • 13. MEHANISM OF NITRIDING gas nitriding . Salt bath nitriding. plasma nitriding.
  • 14. MEHANISM OF NITRIDING •Gas Nitriding •Case-Hardening Process •Nitrogen Introduction •Surface of a Solid Ferrous Alloy •Nitrogenous Gas •Ammonia  Chemical Reaction •Nitrogen & Iron •Core Properties Not Effected  Temperature Range •495 - 565 ºC •Below Tempering Temperature  White Layer By-Product •Thin •Hard Iron Nitride
  • 17. MEHANISM OF NITRIDING •Salt bath NITRIDING •Thermo-chemical Diffusion Treatment •Hardening Components With Repeatability. •Use salt nitrogen-containing •Salt Bath, at sub-Critical Temperatures. •Higher diffusion nitrogen •Corrosion Protection
  • 19. MEHANISM OF NITRIDING •Vacuum Chamber •Pressure = 0.64 Pa •Pre-Heat Cycle •Surface Cleaning •Intense electric field. •Control Gas Flow •N, H, CH4 •Ionization by Voltage •Blue-Violet Glow •Wear Resistant Layer •PLASMA NITRIDING
  • 23.  Carbonitriding is similar to gas carburization with the addition of ammonia to the carburizing atmosphere, which provides a source of nitrogen.
  • 24.  Nascent nitrogen forms at the work surface by the dissociation of ammonia in the furnace atmosphere; the nitrogen diffuses into the steel simultaneously with carbon.
  • 25.  Typically, carbonitriding is carried out at a lower temperature and for a shorter time than is gas carburizing, producing a shallower case than is usual in production carburizing.
  • 26. CARBONITRIDING IN FC-35 ATMOSPHERE Ammonia and CO2 flows are maintained constant through out the process during Carbonitriding in the FC35 process. A typical Carbonitriding process cycle using the FC35
  • 28.  Carbonitriding (around 850 °C / 1550 °F) is carried out at temperatures substantially higher than plain nitriding (around 530 °C / 990 °F) but slightly lower than those used for carburizing (around 950 °C / 1700 °F) and for shorter times. A typical Carbonitriding process cycle using the FC35
  • 29.  Carbonitriding forms a hard, wear-resistant case, is typically 0.07mm to 0.5mm thick.  Maximum case depth is typically restricted to 0.75mm; case depths greater than this take too long to diffuse to be economical.  Its carried out in a salt bath or in a furnace gas atmosphere.
  • 37. Crank Shafts, Cam shafts, Gears etc.
  • 40.  It gives high surface hardness.  Nitriding increase wear resistance.  It increase the tensile strength and yield point.  Improves fatigue life by 30% to 100%.  It is good for high temperature applications. ADVANTAGES
  • 41.  It has a greater resistance to softening during Tempering.  The carbonitrided case has better wear and temper resistance than a straight carburized case.  It is carried out at a lower temperature and for a shorter time than is gas carburizing.  Reduced distortion due to lower temperature. ADVANTAGES
  • 42.  Since nitrided parts are not quenched, this minimizes distortion or cracking.  Whereas in a carburized part, hardness begins to fall at about 200°C, a nitrided part retains hardness up to 500°C.  No machining is required after nitriding.  Some complex parts which are not carburized satisfactorily, can be nitrided without difficulty. ADVANTAGES
  • 43. DISADVANTAGES  Asymmetric products could buckle due to unequal cooling effects  Maximum dimensions are determined by the furnace dimensions  Blind holes cannot be treated during plasma - nitriding.  Toughness and impact resistance decrease
  • 44. DISADVANTAGES  It produces shallower cases.  It is not possible to obtain higher core hardness and deeper case depths.  Only useful for Plain carbon steel or Low alloy Steel.  Ammonia can produce harmful effects.  Long cycle times (40 to 100 hours).
  • 45. DISADVANTAGES  The brittle case formed is Brittle.  Only special alloy steels (containing Al, Cr and V) can be satisfactorily treated.  High cost of the nitriding process.  Technical control required.  If a nitrided component is accidentally overheated, the surface hardness will be lost completely and the component must be nitrided again.

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