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Liottite
A valid IMA mineral species
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About Liottite
Formula:
(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4
Colour:
Colourless
Hardness:
5
Specific Gravity:
2.56
Crystal System:
Hexagonal
Member of:
Name:
Named in 1977 by S. Merlino and P. Orlandi in honor of Luciano Liotti (1932 - 2006), a mineral collector who donated the material in which liottite was first found.
Type Locality:
This page provides mineralogical data about Liottite.
Unique Identifiers
Mindat ID:
2411
Long-form identifier:
mindat:1:1:2411:8
Similar Names
| Latite | A rock classification type | |
| Lautite | A valid IMA mineral species - grandfathered | CuAsS |
| Leiteite | A valid IMA mineral species | Zn(As2O4) |
| Leyteite | A variety of 'Bitumen' ['Petroleum'] | |
| Lutite | A synonym of 'Mudstone' |
IMA Classification of Liottite
Approved
IMA Formula:
Na16Ca8Si18Al18O72(S6+O4)5Cl4
Approval year:
1975
First published:
1977
Classification of Liottite
9.FB.05
9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.5.9
76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.10.5
17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate
17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Lio | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Liottite
Colour:
Colourless
Streak:
White
Hardness:
5 on Mohs scale
Density:
2.56(2) g/cm3 (Measured) 2.61 g/cm3 (Calculated)
Comment:
Measured in a mixture of bromoform and acetone.
Optical Data of Liottite
Type:
Uniaxial (-)
RI values:
nω = 1.53 nε = 1.528
Max. Birefringence:
δ = 0.002
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic
(convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis
centred and vertical. The coloured rings are isochromatics, computed with the
same physics as the Michel-Lévy bar above; the dark cross is the isogyre.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Chemistry of Liottite
Mindat Formula:
(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4
Element Weights:
Common Impurities:
Fe
Crystallography of Liottite
Crystal System:
Hexagonal
Class (H-M):
6 - Trigonal Dipyramidal
Space Group:
P6
Cell Parameters:
a = 12.870(1) Å, c = 16.096(2) Å
Ratio:
a:c = 1 : 1.251
Unit Cell V:
2,308.90 ų (Calculated from Unit Cell)
Morphology:
{001}, {100}, {110}, {101}, {102}, {103}, {104}, {203}, {111}, and minor forms {120}, {121}, {112}, {113}.
Comment:
Cell parameters from Ballirano et al. (1996).
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0005509 | Liottite | Ballirano P, Merlino S, Bonaccorsi E, Maras A (1996) The crystal structure of liottite, a six-layer member of the cancrinite group The Canadian Mineralogist 34 1021-1030 | ![]() | 1996 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.715 Å | (100) |
| 3.315 Å | (75) |
| 4.84 Å | (36) |
| 2.141 Å | (24) |
| 2.686 Å | (10) |
| 2.471 Å | (10) |
| 1.801 Å | (10) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 31 : Thermally altered carbonate, phosphate, and iron formations | |
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Liottite
General Appearance of Type Material:
Flattened hexagonal prisms up to 1 cm in diameter.
Place of Conservation of Type Material:
University of Pisa, Pisa, Italy, 3209.
University of Modena, Modena, Italy.
University of Modena, Modena, Italy.
Geological Setting of Type Material:
In cavities of ejected blocks in a pumice deposit.
Associated Minerals at Type Locality:
Synonyms of Liottite
Other Language Names for Liottite
Relationship of Liottite to other Species
Member of:
Other Members of Cancrinite Group:
| Afghanite | (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 | Trig. 3m : P31c |
| Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 | Trig. 3m : P31c |
| Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) | Hex. 6 : P63 |
| Betzite | Na6Ca2(Al6Si6O24)Cl4 | Hex. 6 : P63 |
| Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O | Trig. 3 : P3 |
| Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl | Trig. 3m : P31c |
| Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O | Hex. 6 : P63 |
| Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O | Hex. 6mm : P63mc |
| Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O | Trig. 3m : P31c |
| Davyne | (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 | Hex. 6/m : P63/m |
| Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) | Hex. 6 : P63 |
| Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O | Trig. 3 : R3 |
| Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O | Hex. 6/m : P63/m |
| Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O | Hex. |
| Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 | Trig. 3m : P31c |
| Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O | Hex. 6 : P63 |
| Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O | Trig. 32 : R32 |
| Kyanoxalite | Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) | Hex. 6 : P63 |
| Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O | Trig. 3m : P31c |
| Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 | Hex. 622 : P6322 |
| Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O | Hex. 6 : P63 |
| Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 | Hex. 6/m : P63/m |
| Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O | Hex. |
| Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O | Hex. 6m2 : P62c |
| Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) | Trig. 3m : P31c |
| Tounkite | (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O | Hex. 622 : P6222 |
| 'UM2004-48-SiO:AlClCaNaS' | (Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3 | |
| 'UM2009-23-SiO:AlCCaClHKNaS' | (Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2O | Trig. 3 : P3 |
| Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O | Hex. 6 : P63 |
Common Associates
Associations Based on Photo Data:
| 7 photos of Liottite associated with Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
| 7 photos of Liottite associated with 'Melanite' | Ca3Fe3+2(SiO4)3 |
| 5 photos of Liottite associated with Andradite | Ca3Fe3+2(SiO4)3 |
| 4 photos of Liottite associated with Sanidine | K(AlSi3O8) |
| 2 photos of Liottite associated with Titanite | CaTiO(SiO4) |
| 2 photos of Liottite associated with Grossular | Ca3Al2(SiO4)3 |
| 1 photo of Liottite associated with Magnetite | Fe2+Fe3+2O4 |
| 1 photo of Liottite associated with Augite | (CaxMgyFez)(Mgy1Fez1)Si2O6 |
| 1 photo of Liottite associated with Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 |
| 1 photo of Liottite associated with Biotite | K(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2 |
Related Minerals - Strunz-mindat Grouping
| 9.FB. | Perchukite-(Y) | PbYAsSi2O8 |
| 9.FB. | Åsgruvanite-(Ce) | Ce16Ca5Al(SiO4)6(AsO3)8(CO3)2Cl4F3(OH)2 |
| 9.FB. | Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O |
| 9.FB. | Wenlanzhangite-(Y) | Y2V3+2V4+2(SiO4)2O4(OH)4 |
| 9.FB. | Slyudyankaite | Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O |
| 9.FB. | Bolotinaite | (Na7◻)(Al6Si6O24)F · 4H2O |
| 9.FB. | Sapozhnikovite | Na8(Al6Si6O24)(HS)2 |
| 9.FB. | Betzite | Na6Ca2(Al6Si6O24)Cl4 |
| 9.FB.05 | Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 |
| 9.FB.05 | Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) |
| 9.FB.05 | Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O |
| 9.FB.05 | Afghanite | (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 |
| 9.FB.05 | Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl |
| 9.FB.05 | Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O |
| 9.FB.05 | Kyanoxalite | Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) |
| 9.FB.05 | Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O |
| 9.FB.05 | Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O |
| 9.FB.05 | Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 |
| 9.FB.05 | Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5) |
| 9.FB.05 | Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O |
| 9.FB.05 | Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O |
| 9.FB.05 | Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O |
| 9.FB.05 | Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O |
| 9.FB.05 | Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O |
| 9.FB.05 | Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 |
| 9.FB.05 | Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O |
| 9.FB.05 | Tounkite | (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O |
| 9.FB.05 | Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) |
| 9.FB.05 | Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 |
| 9.FB.05 | Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O |
| 9.FB.05 | Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O |
| 9.FB.05 | Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O |
| 9.FB.05 | Davyne | (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 |
| 9.FB.10 | Haüyne | Na3Ca(Si3Al3)O12(SO4) |
| 9.FB.10 | Lazurite | Na7Ca(Al6Si6O24)(SO4)(S3) · H2O |
| 9.FB.10 | Danalite | Be3Fe2+4(SiO4)3S |
| 9.FB.10 | Helvine | Be3Mn2+4(SiO4)3S |
| 9.FB.10 | Kamaishilite | Ca2(Al2SiO6)(OH)2 |
| 9.FB.10 | Sodalite | Na4(Si3Al3)O12Cl |
| 9.FB.10 | Nosean | Na8(Al6Si6O24)(SO4) · H2O |
| 9.FB.10 | Genthelvite | Be3Zn4(SiO4)3S |
| 9.FB.10 | Bicchulite | Ca2(Al2SiO6)(OH)2 |
| 9.FB.10 | Tsaregorodtsevite | (N(CH3)4)(AlSi5O12) |
| 9.FB.10 | Vladimirivanovite | Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O |
| 9.FB.10 | Tugtupite | (BeAlSi)Na4(SiO4)3Cl |
| 9.FB.15 | Marialite | Na4Al3Si9O24Cl |
| 9.FB.15 | Meionite | Ca4Al6Si6O24CO3 |
| 9.FB.15 | Silvialite | (Ca,Na)4(Al6Si6O24)(SO4,CO3) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Liottite
mindat.org URL:
https://www.mindat.org/min-2411.html
Please feel free to link to this page.
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References for Liottite
Reference List:
Merlino, Stefano, Orlandi, Paolo (1977) Liottite, a new mineral in the cancrinite-davyne group. American Mineralogist, 62 (3-4) 321-326
Rinaldi, R., Wenk, H. R. (1979) Stacking variations in cancrinite minerals. Acta Crystallographica Section A: Crystal Physics, Diffraction, Theoretical and General Crystallography, 35 (5). 825-828 doi:10.1107/s0567739479001868
Hassan, I., Grundy, H. D. (1984) The crystal structures of sodalite-group minerals. Acta Crystallographica Section B Structural Science, 40 (1) 6-13 doi:10.1107/s0108768184001683
Localities for Liottite
Showing 9 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Italy | |
| www.geocities.com/gmgn/n1_96-4.htm +2 other references |
| Russo (2010) | |
| in the collection of Luigi Mattei | |
| Liotti L. and Tealdi E. (1983) |
| Chukanov et al. (2022) |
| Stoppani et al. (1982) |
| Cresta et al. (2002) |
| Collected & analyzed by Rossano Carlini |
| Merlino et al. (1977) |
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The
Montenero Quarry, Onano, Viterbo Province, Lazio, Italy