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Liottite

A valid IMA mineral species
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About LiottiteHide

09676490017271924881179.jpg
Luciano Liotti
Formula:
(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4
Colour:
Colourless
Hardness:
5
Specific Gravity:
2.56
Crystal System:
Hexagonal
Name:
Named in 1977 by S. Merlino and P. Orlandi in honor of Luciano Liotti (1932 - 2006), a mineral collector who donated the material in which liottite was first found.
This page provides mineralogical data about Liottite.


Unique IdentifiersHide

Mindat ID:
2411
Long-form identifier:
mindat:1:1:2411:8

Similar NamesHide

LatiteA rock classification type
LautiteA valid IMA mineral species - grandfatheredCuAsS
LeiteiteA valid IMA mineral speciesZn(As2O4)
LeyteiteA variety of 'Bitumen' ['Petroleum']
LutiteA synonym of 'Mudstone'

IMA Classification of LiottiteHide

Approved
IMA Formula:
Na16Ca8Si18Al18O72(S6+O4)5Cl4
Approval year:
1975
First published:
1977

Classification of LiottiteHide

9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.5.9

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.10.5

17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
LioIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LiottiteHide

Colour:
Colourless
Streak:
White
Hardness:
Density:
2.56(2) g/cm3 (Measured)    2.61 g/cm3 (Calculated)
Comment:
Measured in a mixture of bromoform and acetone.

Optical Data of LiottiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.53 nε = 1.528
Max. Birefringence:
δ = 0.002
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of LiottiteHide

Mindat Formula:
(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4
Element Weights:
Element% weight
O42.619 %
Si14.637 %
Al14.062 %
Na10.650 %
Ca9.283 %
S4.642 %
Cl4.106 %

Calculated from ideal end-member formula.
O
Si
Al
Na
Ca
S
Cl
Common Impurities:
Fe

Crystallography of LiottiteHide

Crystal System:
Hexagonal
Class (H-M):
6 - Trigonal Dipyramidal
Space Group:
P6
Cell Parameters:
a = 12.870(1) Å, c = 16.096(2) Å
Ratio:
a:c = 1 : 1.251
Unit Cell V:
2,308.90 ų (Calculated from Unit Cell)
Morphology:
{001}, {100}, {110}, {101}, {102}, {103}, {104}, {203}, {111}, and minor forms {120}, {121}, {112}, {113}.
Comment:
Cell parameters from Ballirano et al. (1996).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005509LiottiteBallirano P, Merlino S, Bonaccorsi E, Maras A (1996) The crystal structure of liottite, a six-layer member of the cancrinite group The Canadian Mineralogist 34 1021-103019960293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.715 Å(100)
3.315 Å(75)
4.84 Å(36)
2.141 Å(24)
2.686 Å(10)
2.471 Å(10)
1.801 Å(10)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of LiottiteHide

General Appearance of Type Material:
Flattened hexagonal prisms up to 1 cm in diameter.
Place of Conservation of Type Material:
University of Pisa, Pisa, Italy, 3209.
University of Modena, Modena, Italy.
Geological Setting of Type Material:
In cavities of ejected blocks in a pumice deposit.
Associated Minerals at Type Locality:

Synonyms of LiottiteHide

Other Language Names for LiottiteHide

Dutch:Liottiet
German:Liottit
Spanish:Liottita

Relationship of Liottite to other SpeciesHide

Other Members of Cancrinite Group:
Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P31c
Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P31c
Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P31c
Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P31c
Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5)Hex. 6 : P63
Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P31c
HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 32 : R32
KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P31c
MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 622 : P6322
PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6m2 : P62c
SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P31c
Tounkite(Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2OHex. 622 : P6222
'UM2004-48-SiO:AlClCaNaS'(Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3
'UM2009-23-SiO:AlCCaClHKNaS'(Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2OTrig. 3 : P3
Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63

Common AssociatesHide

Associations Based on Photo Data:
7 photos of Liottite associated with VesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9
7 photos of Liottite associated with 'Melanite'Ca3Fe3+2(SiO4)3
5 photos of Liottite associated with AndraditeCa3Fe3+2(SiO4)3
4 photos of Liottite associated with SanidineK(AlSi3O8)
2 photos of Liottite associated with TitaniteCaTiO(SiO4)
2 photos of Liottite associated with GrossularCa3Al2(SiO4)3
1 photo of Liottite associated with MagnetiteFe2+Fe3+2O4
1 photo of Liottite associated with Augite(CaxMgyFez)(Mgy1Fez1)Si2O6
1 photo of Liottite associated with Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2
1 photo of Liottite associated with BiotiteK(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2

Related Minerals - Strunz-mindat GroupingHide

9.FB.Perchukite-(Y)PbYAsSi2O8Mon. 2/m : B2/b
9.FB.Åsgruvanite-(Ce)Ce16Ca5Al(SiO4)6(AsO3)8(CO3)2Cl4F3(OH)2Trig. 3m(32/m) : P3m1
9.FB.SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6m2 : P62c
9.FB.Wenlanzhangite-(Y)Y2V3+2V4+2(SiO4)2O4(OH)4Tric. 1 : P1
9.FB.SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
9.FB.Bolotinaite(Na7◻)(Al6Si6O24)F · 4H2OIso. 43m : I43m
9.FB.SapozhnikoviteNa8(Al6Si6O24)(HS)2Iso. 43m : P43n
9.FB.BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
9.FB.05Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
9.FB.05SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P31c
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P31c
9.FB.05Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P31c
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P31c
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P31c
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5)Hex. 6 : P63
9.FB.05Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
9.FB.05Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P31c
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 622 : P6322
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
9.FB.05Tounkite(Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2OHex. 622 : P6222
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P31c
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 32 : R32
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
9.FB.05Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
9.FB.10HaüyneNa3Ca(Si3Al3)O12(SO4)Iso. 43m : P43n
9.FB.10LazuriteNa7Ca(Al6Si6O24)(SO4)(S3) · H2OIso. 43m : P43n
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 43m : P43n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 43m : P43n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10SodaliteNa4(Si3Al3)O12ClIso. 43m : P43n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 43m : P43n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 43m : P43n
9.FB.10BicchuliteCa2(Al2SiO6)(OH)2Iso. 43m : I43m
9.FB.10Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth. 222 : I222
9.FB.10VladimirivanoviteNa6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2OOrth. mmm(2/m2/m2/m)
9.FB.10Tugtupite(BeAlSi)Na4(SiO4)3ClTet. 4 : I4
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LiottiteHide

References for LiottiteHide

Localities for LiottiteHide

Showing 9 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy
 
  • Campania
    • Metropolitan City of Naples
      • Bacoli
www.geocities.com/gmgn/n1_96-4.htm +2 other references
Russo (2010)
in the collection of Luigi Mattei
  • Lazio
    • Metropolitan City of Rome Capital
      • Magliano Romano
Liotti L. and Tealdi E. (1983)
      • Sacrofano
Chukanov et al. (2022)
    • Viterbo Province
Stoppani et al. (1982)
      • Onano
Cresta et al. (2002)
      • Valentano
Collected & analyzed by Rossano Carlini
  • Tuscany
    • Grosseto Province
      • Pitigliano
Merlino et al. (1977)
 
and/or  
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