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Pradetite

A valid IMA mineral species
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About PradetiteHide

Formula:
CoCu4(AsO4)2(HAsO4)2 · 9H2O
Colour:
Green
Lustre:
Vitreous
Specific Gravity:
3.33
Crystal System:
Triclinic
Name:
Named for the city of Le Pradet, France, which is near the type locality of the Cap Garonne mine.

Unique IdentifiersHide

Mindat ID:
30767
Long-form identifier:
mindat:1:1:30767:1

Similar NamesHide

PeridotiteA rock classification type

IMA Classification of PradetiteHide

Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
Co2+Cu2+4(As5+O4)2(As5+O3OH)2·9H2O
Approval year:
1991

Classification of PradetiteHide

8.CE.30

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5
39.2.6.5

39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
2 : (AB)5[HXO4]2[XO4]2.xH2O

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
PdeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PradetiteHide

Vitreous
Transparency:
Transparent
Colour:
Green
Streak:
White
Hardness Data:
Could not be measured
Tenacity:
Brittle
Cleavage:
Perfect
Fracture:
Conchoidal
Density:
3.33(1) g/cm3 (Measured)    3.17 g/cm3 (Calculated)
Comment:
Calculated value uses powder data and empirical formula based on 25 O+OH apfu (Burke et al 2007).

Optical Data of PradetiteHide

Type:
Biaxial (+)
RI values:
nα = 1.634(2) nβ = 1.662(2) nγ = 1.720(5)
2V:
Measured: 75° (4), Calculated: 72°
Max. Birefringence:
δ = 0.086
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v, strong
Optical Extinction:
X ∧ b 20.5° on (001); X ∧ b 35° on (100).
Pleochroism:
Weak
Comments:
Z = green, X and Y = colorless.

Chemistry of PradetiteHide

Mindat Formula:
CoCu4(AsO4)2(HAsO4)2 · 9H2O
Element Weights:
Element% weight
O38.723 %
As29.013 %
Cu24.608 %
Co5.705 %
H1.952 %

Calculated from ideal end-member formula.
O
As
Cu
Co
H

Crystallography of PradetiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 6.434(5) Å, b = 8.059(5) Å, c = 10.399(8) Å
α = 85.70(6)°, β = 79.14(7)°, γ = 84.87(2)°
Ratio:
a:b:c = 0.798 : 1 : 1.29
Unit Cell V:
526.9 ų
Z:
1
Morphology:
Fibers, very elongated parallel to [001]. Crystal forms are {001} and
{100}.
Twinning:
Not observed.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.191 Å(100)
8.01 Å(60)
4.001 Å(50)
3.667 Å(60)
3.404 Å(35)
3.258 Å(30)
3.151 Å(50)
3.063 Å(50)
2.674 Å(40)
2.615 Å(35)
Comments:
Cap Garonne

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47d : [Arsenates, antimonates, selenates, bismuthinates]
Stage 10b: Anthropogenic minerals<10 Ka
55 : Anthropogenic mine minerals

Type Occurrence of PradetiteHide

General Appearance of Type Material:
Fibrous aggregates consisting of individual very elongated (parallel to [001]) crystals (0.3 mm x 0.05 mm x 0.15 mm) and massive equidimensional grains (~ 0.2 mm).
Place of Conservation of Type Material:
Departement de Mineralogie du Museum d'Histoire Naturelle de Geneve, Switzerland, no. 477.081 (holotype).
Geological Setting of Type Material:
Secondary alteration mineral.
Associated Minerals at Type Locality:

Synonyms of PradetiteHide

Other Language Names for PradetiteHide

Dutch:Pradetiet
German:Pradetit

Relationship of Pradetite to other SpeciesHide

Other Members of Lindackerite Group:
Hloušekite(Ni,Co)Cu4(AsO4)2(AsO3OH)2 · 9H2OTric. 1 : P1
LindackeriteCuCu4(AsO4)2(HAsO4)2 · 9H2OTric. 1 : P1
VeselovskýiteZnCu4(AsO4)2(HAsO4)2 · 9H2OTric. 1 : P1

Common AssociatesHide

Associations Based on Photo Data:
4 photos of Pradetite associated with ErythriteCo3(AsO4)2 · 8H2O

Related Minerals - Strunz-mindat GroupingHide

8.CE.MonteneroiteCu2+Mn2+2(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.BelmonteiteCaMn2(AsO4)2 · 7H2OOrth. mm2
8.CE.ZincocabreriteZnMg2(AsO4)2(H2O)8Mon. 2/m : B2/m
8.CE.XBabánekiteCu3(AsO4)2 · 8H2O Mon. 2/m : B2/m
8.CE.05ChudobaiteMg5(AsO4)2(AsO3OH)2 · 10H2OTric. 1 : P1
8.CE.05GeigeriteMn2+5(AsO4)2(HAsO4)2 · 10H2OTric. 1 : P1
8.CE.10NewberyiteMg(PO3OH) · 3H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CE.10ManganonewberyiteMn(PO3OH)(H2O)3Orth. mmm(2/m2/m2/m) : Pbca
8.CE.15Fanguangite(MoO2)(PO3OH) · 4H2OTric. 1 : P1
8.CE.15BrassiteMg(HAsO4) · 4H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CE.20PhosphorrössleriteMg(PO3OH) · 7H2OMon. 2/m : P2/b
8.CE.20RössleriteMg(HAsO4) · 7H2OMon. 2/m : B2/b
8.CE.25SwitzeriteMn2+3(PO4)2 · 7H2OMon. 2/m : P21/c
8.CE.25MetaswitzeriteMn2+3(PO4)2 · 4H2OMon. 2/m : P2/b
8.CE.30VeselovskýiteZnCu4(AsO4)2(HAsO4)2 · 9H2OTric. 1 : P1
8.CE.30LindackeriteCuCu4(AsO4)2(HAsO4)2 · 9H2OTric. 1 : P1
8.CE.30KlajiteMnCu4(AsO4)2(HAsO4)2 · 9-10H2OTric. 1 : P1
8.CE.30Hloušekite(Ni,Co)Cu4(AsO4)2(AsO3OH)2 · 9H2OTric. 1 : P1
8.CE.30OndrušiteCaCu4(AsO4)2(HAsO4)2 · 10H2OTric. 1 : P1
8.CE.35BobierriteMg3(PO4)2 · 8H2OMon. 2/m : B2/b
8.CE.40Barićite(Mg,Fe)3(PO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40ParasymplesiteFe2+3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40GritsenkoiteCoMg2(AsO4)2(H2O)8Mon. 2/m : B2/m
8.CE.40CabreriteNiMg2(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40PakhomovskyiteCo3(PO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40VivianiteFe2+Fe2+2(PO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40ArupiteNi3(PO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40ErythriteCo3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40HörnesiteMg3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40ManganohörnesiteMn2+3(AsO4)2 · 8H2OMon. 2/m : P2/c
8.CE.40KöttigiteZn3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.40FerrisymplesiteFe3+3(AsO4)2(OH)3 · 5H2OMon.
8.CE.40AnnabergiteNi3(AsO4)2 · 8H2OMon. 2/m : B2/m
8.CE.45SymplesiteFe2+3(AsO4)2 · 8H2OTric. 1 : P1
8.CE.50CattiiteMg3(PO4)2 · 22H2OTric. 1 : P1
8.CE.55KoninckiteFe3+PO4 · 3H2OTet. 422 : P41212
8.CE.60KaňkiteFeAsO4 · 3.5H2OMon. 2 : P2
8.CE.60HilarioniteFe3+2(SO4)(AsO4)(OH) · 6H2OMon. 2/m : B2/m
8.CE.65SteigeriteAl(VO4) · 3H2OMon. 2/m : P21/m
8.CE.70MetaschoderiteAl2(PO4)(VO4) · 6H2OMon. 2/m : P2/c
8.CE.70SchoderiteAl2(PO4)(VO4) · 8H2OMon.
8.CE.75ZigrasiteMgZr(PO4)2 · 4H2OTric. 1 : P1
8.CE.75'UM2009-11-PO:CaHZr'CaZr[PO4]2 · 4H2OTric.
8.CE.75MalhmooditeFeZr(PO4)2 · 4H2OMon. 2/m : P21/c
8.CE.80SantabarbaraiteFe3+3(PO4)2(OH)3 · 5H2OAmor.
8.CE.85Metaköttigite(Zn,Fe,Fe)3(AsO4)2 · 8(H2O,OH)Tric. 1 : P1
8.CE.90SlavkoviteCu13(AsO4)6(AsO3OH)4 · 23H2OTric. 1 : P1

Fluorescence of PradetiteHide

Not fluorescent.

Other InformationHide

Notes:
Soluble in HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PradetiteHide

References for PradetiteHide

Localities for PradetiteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Czech Republic
 
  • Karlovy Vary Region
Pavel Škácha
France (TL)
 
  • Provence-Alpes-Côte d'Azur
    • Var
      • Toulon
        • Le Pradet
Sarp et al. (1995) +3 other references
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Rottweil
        • Schenkenzell
          • Wittichen
            • Heubach Valley
Slotta (2016)
 
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