Nikischerite

A valid IMA mineral species

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Nikischerite

Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

Nikischerite

Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

Nikischerite

Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

Nikischerite

Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

Nikischerite

Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

Nikischerite

Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

Nikischerite

Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

Nikischerite

Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

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About NikischeriteHide

Tony Nikischer

Formula:

Fe²⁺₆Al₃(OH)₁₈[Na(H₂O)₆](SO₄)₂ · 6H₂O

Colour:

Dark green, brownish

Lustre:

Greasy, Pearly, Dull

Hardness:

Specific Gravity:

2.33

Crystal System:

Trigonal

Member of:

Wermlandite Group > Hydrotalcite Supergroup

Name:

For American mineralogist and mineral dealer, Anthony J. Nikischer (b. 1949), who first analyzed the mineral.

Type Locality:

ⓘ Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

The Fe analogue of shigaite and poellmannite.

May be confused with clinochlore and chamosite.

"Recent material from Huanuni labeled as nikischerite has be confirmed as a chlorite group mineral, not nikischerite. We were offered a number of Huanuni specimens from 2020-2021 and after analysis, returned them all." (Tony Nikischer, Mindat message https://www.mindat.org/mesg-603193.html, 2022).

Unique IdentifiersHide

Mindat ID:

10934

Long-form identifier:

mindat:1:1:10934:3

IMA Classification of NikischeriteHide

IMA status:

Approved

IMA Formula:

NaFe²⁺₆Al₃(S⁶⁺O₄)₂(OH)₁₈(H₂O)₁₂

Approval year:

2001

First published:

2003

Type description reference:

Roberts, Andrew C., Grice, Joel D., Hawthorne, Frank C., Huminicki, Danielle M.C., Jambor, John L. (2003) Nikischerite, a New Mineral from the Huanuni Tin Mine, Dalence Province, Oruro Department, Bolivia. The Mineralogical Record, 34 (2) 155-158

Classification of NikischeriteHide

Strunz-mindat (2026):

7.DD.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H₂O
D : With only medium-sized cations; sheets of edge-sharing octahedra

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference for Standard
Nik	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NikischeriteHide

Lustre:

Greasy, Pearly, Dull

Transparency:

Transparent, Translucent

Colour:

Dark green, brownish

Comment:

Green when fresh; oxidises to ochre brown.

Streak:

Pale grayish green

Hardness:

2 on Mohs scale

Cleavage:

Perfect

Fracture:

Irregular/Uneven

Comment:

Crumbly

Density:

2.33(2) g/cm³ (Measured) 2.30 g/cm³ (Calculated)

Optical Data of NikischeriteHide

Type:

Uniaxial (-)

Pleochroism:

Non-pleochroic

Comments:

ε undetermined

Chemistry of NikischeriteHide

Mindat Formula:

Fe²⁺₆Al₃(OH)₁₈[Na(H₂O)₆](SO₄)₂ · 6H₂O

Element Weights:

Element	% weight
O	52.710 %
Fe	29.050 %
Al	7.018 %
S	5.560 %
H	3.670 %
Na	1.993 %

Calculated from ideal end-member formula.

Elements listed:

Al, Fe, H, Na, O, S - search for minerals with similar chemistry

Crystallography of NikischeriteHide

Crystal System:

Trigonal

Class (H-M):

3 - Rhombohedral

Space Group:

Cell Parameters:

a = 9.347(1) Å, c = 33.000(7) Å

Ratio:

a:c = 1 : 3.531

Unit Cell V:

2497 Å³

Morphology:

Platy habit with dominant {001}.

Twinning:

None observed

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0005826	Nikischerite	Huminicki D M C, Hawthorne F C (2003) The crystal structure of nikischerite, NaFeAl3(SO4)2(OH)18(H2O)12, a mineral of the shigaite group The Canadian Mineralogist 41 79-82		2003		0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Nikischerite'
loop_
_publ_author_name
'Huminicki D M C'
'Hawthorne F C'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 41 
_journal_year 2003
_journal_page_first 79
_journal_page_last 82
_publ_section_title
;
 The crystal structure of nikischerite, NaFeAl3(SO4)2(OH)18(H2O)12,
 a mineral of the shigaite group
;
_database_code_amcsd 0005826
_chemical_formula_sum 'Fe6 Al3 Na S2 O38 H42'
_cell_length_a 9.347
_cell_length_b 9.347
_cell_length_c 33.000
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 2496.831
_exptl_crystal_density_diffrn      2.301
_symmetry_space_group_name_H-M 'R -3'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Fe  -0.00070   0.33410   0.16683   0.02200
Al1   0.00000   0.00000   0.16510   0.02600
Al2   0.33333   0.66667   0.16667   0.02000
Na   0.00000   0.00000   0.00000   0.05000
S   0.66667   0.33333   0.03830   0.03400
O1   0.33333   0.66667   0.00690   0.03800
O2   0.60300   0.16000   0.05430   0.04900
O-H1   0.56500   0.13200   0.13790   0.02100
O-H2   0.20300   0.10100   0.13510   0.02500
O-H3   0.23100   0.46700   0.13570   0.02300
Wat1   0.12700   0.42500   0.05640   0.05600
Wat2   0.21200   0.17800   0.05050   0.05900
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Fe 0.02000 0.02000 0.02400 0.01000 0.00100 0.00100
Al1 0.01700 0.01700 0.04200 0.00900 0.00000 0.00000
Al2 0.02300 0.02300 0.01500 0.01200 0.00000 0.00000
Na 0.05200 0.05200 0.04600 0.02600 0.00000 0.00000
S 0.03400 0.03400 0.03500 0.01700 0.00000 0.00000
O1 0.05700 0.05700 0.00100 0.02600 0.00000 0.00000
O2 0.08400 0.02100 0.03100 0.01900 0.00400 0.00100
O-H1 0.02400 0.01800 0.01900 0.00800 -0.01400 -0.00300
O-H2 0.02400 0.03600 0.02300 0.02200 -0.00400 0.00100
O-H3 0.02500 0.01400 0.03500 0.01500 0.00100 -0.00300
Wat1 0.05200 0.05200 0.07100 0.03200 0.00500 0.01300
Wat2 0.04500 0.05100 0.06700 0.01400 0.00700 0.01100

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
10.980 Å	(100)
5.539 Å	(60)
3.674 Å	(50)
2.425 Å	(30)
1.932 Å	(30)
2.624 Å	(25)
4.311 Å	(20)

Locality:

Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

Reference:

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]

Type Occurrence of NikischeriteHide

Type Locality:

ⓘ Huanuni mine, Huanuni, Pantaleón Dalence Province, Oruro, Bolivia

General Appearance of Type Material:

Small micaceous plates, to 4 mm, forming isolated raditing balls and aggregates reaching 1 cm across.

Place of Conservation of Type Material:

Canadian Museum of Nature, Ottawa, Ontario, Canada (CMNMC 83499).

Geological Setting of Type Material:

Low temperature hydrothermal veins.

Associated Minerals at Type Locality:

Reference:

Synonyms of NikischeriteHide

IMA2001-039

Other Language Names for NikischeriteHide

Dutch:Nikischeriet

German:Nikischerit

Russian:Никишерит

Simplified Chinese:羟铝钠铁矾

Spanish:Nikischerita

Traditional Chinese:羥鋁鈉鐵礬

Relationship of Nikischerite to other SpeciesHide

Member of:

Wermlandite Group > Hydrotalcite Supergroup

Other Members of Wermlandite Group:

Erssonite	Mg₇Fe³⁺₂(OH)₁₈[Ca(H₂O)₆](SO₄)₂ · 12H₂O	Trig. 3m(32/m) : P3c1
Karchevskyite	Mg₁₈Al₉(OH)₅₄Sr₂(CO₃)₉(H₂O)₆(H₃O)₅	Trig.
Motukoreaite	Mg₆Al₃(OH)₁₈[Na(H₂O)₆][SO₄]₂ · 6H₂O	Trig. 3m(32/m) : R3m
Natroglaucocerinite	Zn₆Al₃(OH)₁₈[Na(H₂O)₆](SO₄)₂ · 6H₂O	Hex.
Shigaite	Mn₆Al₃(OH)₁₈[Na(H₂O)₆](SO₄)₂ · 6H₂O	Trig. 3 : R3
Wermlandite	Mg₇Al₂(OH)₁₈[Ca(H₂O)₆][SO₄]₂ · 6H₂O	Trig. 3m(32/m) : P3c1

Common AssociatesHide

Associations Based on Photo Data:

2 photos of Nikischerite associated with Vivianite	Fe²⁺Fe²⁺₂(PO₄)₂ · 8H₂O
2 photos of Nikischerite associated with Siderite	FeCO₃
2 photos of Nikischerite associated with Pyrite	FeS₂

Related Minerals - Strunz-mindat Grouping Hide

7.DD.	Asagiite	NiCu₄(SO₄)₂(OH)₆ · 6H₂O	Mon. 2/m : P2₁/c
7.DD.05	Felsőbányaite	Al₄(SO₄)(OH)₁₀ · 4H₂O	Mon. 2 : P2₁
7.DD.07	Llantenesite	Cu₆Al[SeO₄](OH)₁₂Cl · 3H₂O	Trig. 3m : P31c
7.DD.10	Langite	Cu₄(SO₄)(OH)₆ · 2H₂O	Mon. m
7.DD.10	Fehrite	MgCu₄(SO₄)₂(OH)₆ · 6H₂O	Mon. 2/m : P2₁/c
7.DD.10	Posnjakite	Cu₄(SO₄)(OH)₆ · H₂O	Mon. m : Pm
7.DD.10	Wroewolfeite	Cu₄(SO₄)(OH)₆ · 2H₂O	Mon. m : Pm
7.DD.10	Gobelinite	CoCu₄(SO₄)₂(OH)₆ · 6H₂O	Mon. 2/m : P2₁/m
7.DD.15	Kobyashevite	Cu₅(SO₄)₂(OH)₆ · 4H₂O	Tric. 1 : P1
7.DD.15	Spangolite	Cu₆Al(SO₄)(OH)₁₂Cl · 3H₂O	Trig. 3m : P31c
7.DD.15	'Unnamed (Dimorph of Devilline)'	CaCu₄(SO₄)₂(OH)₆ · 3H₂O	Mon. 2/m : P2₁/c
7.DD.20	Ktenasite	ZnCu₄(SO₄)₂(OH)₆ · 6H₂O	Mon. 2/m : P2₁/c
7.DD.25	Christelite	Cu₂Zn₃(SO₄)₂(OH)₆ · 4H₂O	Tric. 1 : P1
7.DD.30	Edwardsite	Cu₃Cd₂(SO₄)₂(OH)₆ · 4H₂O	Mon. 2/m : P2₁/c
7.DD.30	Niedermayrite	CdCu₄(SO₄)₂(OH)₆ · 4H₂O	Mon. 2/m : P2₁/m
7.DD.30	Serpierite	Ca(Cu²⁺,Zn²⁺)₄(S⁶⁺O₄)₂(OH)₆ · 3H₂O	Mon. 2/m : B2/b
7.DD.30	Campigliaite	Mn²⁺Cu₄(SO₄)₂(OH)₆ · 4H₂O	Mon. 2 : B2
7.DD.30	Orthoserpierite	Ca(Cu,Zn)₄(SO₄)₂(OH)₆ · 3H₂O	Orth. mm2 : Pca2₁
7.DD.30	Devilline	CaCu₄(SO₄)₂(OH)₆ · 3H₂O	Mon. 2/m : P2₁/c
7.DD.35	Shigaite	Mn₆Al₃(OH)₁₈[Na(H₂O)₆](SO₄)₂ · 6H₂O	Trig. 3 : R3
7.DD.35	Zincaluminite	(Zn_1-xAl_x)(SO₄)_x/2(OH)₂ · nH₂O
7.DD.35	Zincowoodwardite	Zn_1-xAl_x(OH)₂[SO₄]_x/2 · nH₂O	Trig.
7.DD.35	Natroglaucocerinite	Zn₆Al₃(OH)₁₈[Na(H₂O)₆](SO₄)₂ · 6H₂O	Hex.
7.DD.35	Hydrowoodwardite	(Cu_1-xAl_x)(OH)₂[SO₄]_x/2 · nH₂O	Trig. 3m(32/m) : R3m
7.DD.35	Honessite	(Ni_1-xFe³⁺_x)(OH)₂[SO₄]_x/2 · nH₂O	Trig.
7.DD.35	Carrboydite	(Ni_1-xAl_x)(SO₄)_x/2(OH)₂ · nH₂O	Hex.
7.DD.35	Glaucocerinite	(Zn_1-xAl_x)(OH)₂(SO₄)_x/2 · nH₂O	Hex.
7.DD.35	Wermlandite	Mg₇Al₂(OH)₁₈[Ca(H₂O)₆][SO₄]₂ · 6H₂O	Trig. 3m(32/m) : P3c1
7.DD.35	Hydrohonessite	(Ni_1-xFe³⁺_x)(OH)₂(SO₄)_x/2 · nH₂O	Hex.
7.DD.35	Woodwardite	Cu_1-xAl_x(OH)₂(SO₄)_x/2 · nH₂O	Trig. 3m(32/m) : R3m
7.DD.35	Motukoreaite	Mg₆Al₃(OH)₁₈[Na(H₂O)₆][SO₄]₂ · 6H₂O	Trig. 3m(32/m) : R3m
7.DD.35	Mountkeithite	[(Mg_1-xFe³⁺_x)(OH)₂][SO₄]_x/2 · nH₂O	Hex.
7.DD.40	Lawsonbauerite	(Mn²⁺,Mg)₉Zn₄(SO₄)₂(OH)₂₂ · 8H₂O	Mon. 2/m : P2₁/c
7.DD.40	Torreyite	(Mg,Mn²⁺)₇◻₂Mn²⁺₂Zn₄(SO₄)₂(OH)₂₂ · 8H₂O	Mon. 2/m : P2₁/c
7.DD.40	Isselite	Cu₆(SO₄)(OH)₁₀(H₂O)₄ · H₂O	Orth. mm2 : Pmn2₁
7.DD.45	Mooreite	Mg₉◻₂Mn₂Zn₄(SO₄)₂(OH)₂₆ · 8H₂O	Mon. 2/m : P2/b
7.DD.45	Hodgesmithite	(Cu,Zn)₆Zn(SO₄)₂(OH)₁₀ · 3H₂O	Trig. 3 : P3
7.DD.47	Lahnsteinite	Zn₄(SO₄)(OH)₆ · 3H2O	Tric. 1 : P1
7.DD.50	Namuwite	Zn₄(SO₄)(OH)₆ · 4H₂O	Trig. 3 : P3
7.DD.50	Minohlite	(Cu,Zn)₇(SO₄)₂(OH)₁₀ · 8H₂O	Hex.
7.DD.52	Lauraniite	Cu₆Cd₂(SO₄)₂(OH)₁₂ · 5H₂O	Mon. 2/m : P2₁/c
7.DD.55	Bechererite	Zn₇Cu(OH)₁₃[(SiO(OH)₃(SO₄)]	Trig. 3 : P3
7.DD.60	Ramsbeckite	(Cu,Zn)₁₅(SO₄)₄(OH)₂₂ · 6H₂O	Mon. 2/m
7.DD.65	Vonbezingite	Ca₆Cu₃(SO₄)₃(OH)₁₂ · 2H₂O	Mon. 2/m : P2₁/c
7.DD.70	Redgillite	Cu₆(SO₄)(OH)₁₀ · H₂O	Mon. 2/m : P2₁/c
7.DD.75	Nickelalumite	NiAl₄(SO₄)(OH)₁₂(H₂O)₃	Mon. 2/m : P2₁/c
7.DD.75	Kyrgyzstanite	ZnAl₄(SO₄)(OH)₁₂ · 3H₂O	Mon. 2/m : P2₁/c
7.DD.75	Chalcoalumite	CuAl₄(SO₄)(OH)₁₂ · 3H₂O	Mon. 2 : P2₁
7.DD.80	Schulenbergite	(Cu,Zn)₇(SO₄)₂(OH)₁₀ · 3H₂O	Trig. 3
7.DD.80	'UM1992-30-SO:CCuHZn'	(Zn,Cu)₇(SO₄,CO₃)₂(OH)₁₀ · 3H₂O	Trig. 3 : P3
7.DD.80	Thérèsemagnanite	NaCo₄(SO₄)(OH)₆Cl · 6H₂O	Trig. 3 : P3
7.DD.80	Guarinoite	Zn₆(SO₄)(OH)₁₀ · 5H₂O	Hex.
7.DD.85	Montetrisaite	Cu₆(SO₄)(OH)₁₀ · 2H₂O	Orth. mm2 : Cmc2₁

Fluorescence of NikischeriteHide

In UV light:

Not fluorescent

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for NikischeriteHide

mindat.org URL:

https://www.mindat.org/min-10934.html
Please feel free to link to this page.

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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

Buy from D. Joyce minerals

References for NikischeriteHide

Reference List:

Jambor, John L., Roberts, Andrew C. (2003) New mineral names. American Mineralogist, 88. 1836-1840

Huminicki, D. M.C., Hawthorne, F. C. (2003) The crystal structure of nikischerite, NaFe²⁺₆Al₃(SO₄)₂ (OH)₁₈(H₂O)₁₂, a mineral of the shigaite group. The Canadian Mineralogist, 41 (1) 79-82 doi:10.2113/gscanmin.41.1.79

Mills, S. J.; Christy, A. G.; Génin, J.-M. R.; Kameda, T.; Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76 (5). 1289-1336 doi:10.1180/minmag.2012.076.5.10

(2021) Nikischerite. Handbook of Mineralogy. Mineralogical Society of America

Localities for NikischeriteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Bolivia (TL)

Oruro

Pantaleón Dalence Province

Huanuni

ⓘ Huanuni mine (TL)

Roberts et al. (2003) +1 other reference

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Nikischerite

About NikischeriteHide

Unique IdentifiersHide

IMA Classification of NikischeriteHide

Classification of NikischeriteHide

Mineral SymbolsHide

Physical Properties of NikischeriteHide

Optical Data of NikischeriteHide

Chemistry of NikischeriteHide

Crystallography of NikischeriteHide

Crystal StructureHide

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of NikischeriteHide

Synonyms of NikischeriteHide

Other Language Names for NikischeriteHide

Relationship of Nikischerite to other SpeciesHide

Common AssociatesHide

Related Minerals - Strunz-mindat GroupingHide

Fluorescence of NikischeriteHide

Other InformationHide

Internet Links for NikischeriteHide

References for NikischeriteHide

Localities for NikischeriteHide

Locality ListHide

Related Minerals - Strunz-mindat Grouping Hide