Harrisonite

A valid IMA mineral species

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Harrisonite

Arcedeckne Island, Kitikmeot Region, Nunavut, Canada

Harrisonite

Arcedeckne Island, Kitikmeot Region, Nunavut, Canada

Harrisonite

Arcedeckne Island, Kitikmeot Region, Nunavut, Canada

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About HarrisoniteHide

Formula:

Ca(Fe²⁺,Mg)₆(PO₄)₂(SiO₄)₂

Colour:

Yellow-brown to orange-brown

Lustre:

Vitreous

Hardness:

4 - 5

Specific Gravity:

4.02

Crystal System:

Trigonal

Name:

Named by A.C. Roberts, J.A.R. Stirling, J.D. Grice, T. Frisch, R.K. Herd, and J.L. Jambor in 1993 in honor of James Merritt Harrison (20 September 1915, Regina, Saskatchewan, Canada – 6 July 1990, Canada), geoscientist and former Director of the Geological Survey of Canada (1956-1964). He was awarded the Logan Medal from the Geological Association of Canada in 1969.

Type Locality:

ⓘ Arcedeckne Island, Kitikmeot Region, Nunavut, Canada

The material from Czech pegmatites is manganese- and phosphorus-bearing. The latter substitution is related to Si deficiency.

The pegmatitic occurrence suggests the mineral to be stable lower P–T conditions than these reported for the holotype (Vácha & Škoda 2022).

Unique IdentifiersHide

Mindat ID:

1821

Long-form identifier:

mindat:1:1:1821:6

IMA Classification of HarrisoniteHide

IMA status:

Approved

IMA Formula:

CaFe²⁺₆(SiO₄)₂(PO₄)₂

Approval year:

1991

First published:

1993

Type description reference:

Roberts, A. C., Stirling, J. A. R., Grice, J. D., Frisch, T., Herd, R. K., Jambor, J. L. (1993) Harrisonite, a new calcium iron silicate-phosphate from Arcedeckne Island, District of Franklin, Arctic Canada. The Canadian Mineralogist, 31 (4) 775-780

Classification of HarrisoniteHide

Strunz-mindat (2026):

8.BH.55

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H₂O
H : With medium-sized and large cations, (OH,etc.):RO₄ = 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference for Standard
Hrs	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HarrisoniteHide

Lustre:

Vitreous

Transparency:

Transparent, Translucent

Colour:

Yellow-brown to orange-brown

Streak:

Pale yellow

Hardness:

4 - 5 on Mohs scale

Tenacity:

Brittle

Cleavage:

Poor/Indistinct

Fracture:

Conchoidal

Density:

4.02 g/cm³ (Measured) 4.01 g/cm³ (Calculated)

Optical Data of HarrisoniteHide

Type:

Uniaxial (-)

RI values:

n_ω = 1.770(5) n_ε = 1.759(3)

2V:

Measured: 5°

Max. Birefringence:

δ = 0.011
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Thickness: 30 µm Order divisions

Rotation:

Surface Relief:

Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.

Focus:

In focus

Interference Figure:

This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Thickness: 30 µm

Pleochroism:

Weak

Comments:

Pale yellow tints

Chemistry of HarrisoniteHide

Mindat Formula:

Ca(Fe²⁺,Mg)₆(PO₄)₂(SiO₄)₂

Element Weights:

Element	% weight
Fe	44.720 %
O	34.166 %
P	8.268 %
Si	7.497 %
Ca	5.349 %

Calculated from ideal end-member formula.

Elements listed:

Ca, Fe, Mg, O, P, Si - search for minerals with similar chemistry

Common Impurities:

Crystallography of HarrisoniteHide

Crystal System:

Trigonal

Class (H-M):

3m(32/m) - Hexagonal Scalenohedral

Space Group:

R3m

Setting:

R3m

Cell Parameters:

a = 6.248(1) Å, c = 26.802(7) Å

Ratio:

a:c = 1 : 4.29

Unit Cell V:

906.11 Å³ (Calculated from Unit Cell)

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0005340	Harrisonite	Grice J D, Roberts A C (1993) Harrisonite, a well-ordered silico-phosphate with a layered crystal structure. Ca(Fe,Mg)6(SiO4)2(PO4)2 The Canadian Mineralogist 31 781-785		1993	Arcedeckne Island, Artic Canada	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Harrisonite'
loop_
_publ_author_name
'Grice J D'
'Roberts A C'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 31 
_journal_year 1993
_journal_page_first 781
_journal_page_last 785
_publ_section_title
;
 Harrisonite, a well-ordered silico-phosphate with a layered crystal structure.
 Ca(Fe,Mg)6(SiO4)2(PO4)2
;
_database_code_amcsd 0005340
_chemical_compound_source 'Arcedeckne Island, Artic Canada'
_chemical_formula_sum 'Ca (Fe5.28 Mg.72) Si2 P2 O16'
_cell_length_a 6.248
_cell_length_b 6.248
_cell_length_c 26.802
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 906.108
_exptl_crystal_density_diffrn      3.994
_symmetry_space_group_name_H-M 'R -3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'x,x-y,z'
  '2/3+x,1/3+x-y,1/3+z'
  '1/3+x,2/3+x-y,2/3+z'
  'y,x,-z'
  '2/3+y,1/3+x,1/3-z'
  '1/3+y,2/3+x,2/3-z'
  '-x+y,y,z'
  '2/3-x+y,1/3+y,1/3+z'
  '1/3-x+y,2/3+y,2/3+z'
  '-x,-x+y,-z'
  '2/3-x,1/3-x+y,1/3-z'
  '1/3-x,2/3-x+y,2/3-z'
  '-y,-x,z'
  '2/3-y,1/3-x,1/3+z'
  '1/3-y,2/3-x,2/3+z'
  'x-y,-y,-z'
  '2/3+x-y,1/3-y,1/3-z'
  '1/3+x-y,2/3-y,2/3-z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Ca   0.00000   0.00000   0.00000   1.00000   0.01130
Fe   0.49690   0.99380   0.09500   0.88000   0.00780
Mg   0.49690   0.99380   0.09500   0.12000   0.00780
Si   0.00000   0.00000   0.86230   1.00000   0.00580
P   0.00000   0.00000   0.68020   1.00000   0.00620
O1   0.00000   0.00000   0.19880   1.00000   0.00900
O2   0.00000   0.00000   0.62240   1.00000   0.00800
O3   0.14290   0.28580   0.11830   1.00000   0.00920
O4   0.79790   0.59580   0.03620   1.00000   0.01040
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Ca 0.00660 0.00660 0.02060 0.00330 0.00000 0.00000
Fe 0.00650 0.00700 0.01010 0.00350 0.00010 -0.00020
Mg 0.00650 0.00700 0.01010 0.00350 0.00010 -0.00020
Si 0.00560 0.00560 0.00620 0.00280 0.00000 0.00000
P 0.00660 0.00660 0.00540 0.00330 0.00000 0.00000
O1 0.00900 0.00900 0.00700 0.00480 0.00000 0.00000
O2 0.00900 0.00900 0.00800 0.00430 0.00000 0.00000
O3 0.00800 0.01200 0.01200 0.00380 0.00110 0.00200
O4 0.01300 0.00800 0.00800 0.00430 0.00020 0.00000

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
5.00 Å	(60)
4.46 Å	(50)
3.119 Å	(100)
2.976 Å	(50)
2.689 Å	(80)
2.558 Å	(100)
2.505 Å	(80)
1.903 Å	(60)
1.560 Å	(80)

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 5: Initiation of plate tectonics	<3.5-2.5
40 : Regional metamorphism (greenschist, amphibolite, granulite facies)

Type Occurrence of HarrisoniteHide

Type Locality:

ⓘ Arcedeckne Island, Kitikmeot Region, Nunavut, Canada

General Appearance of Type Material:

Discrete equidimensional anhedral grains and as a rim around fluorapatite.

Place of Conservation of Type Material:

Canadian Geological Survey, Ottawa, 66402.
Canadian Museum of Nature, Ottawa, Canada, 59685.

Geological Setting of Type Material:

Iron silicate - quartz - apatite layered body found in granulite-facies gneiss.

Associated Minerals at Type Locality:

Almandine	Biotite	Fayalite	Ferrosilite	Fluorapatite
Ilmenite	Monazite-(Ce)	Quartz	Zircon

Reference:

Synonyms of HarrisoniteHide

IMA1991-010

Other Language Names for HarrisoniteHide

Dutch:Harrisoniet

German:Harrisonit

Russian:Харрисонит

Spanish:Harrisonita

Related Minerals - Strunz-mindat Grouping Hide

8.BH.	Peterchinite	Zn₃Zn₂(OH)₆As[O₃(OH)₃]	Mon. 2/m : B2/m
8.BH.	Reznitskyite	CaMg(VO₄)F	Mon. 2/m : B2/b
8.BH.	Plumbogottlobite	PbMg(VO₄)(OH)	Orth. mmm(2/m2/m2/m) : Pnma
8.BH.	Cuprozheshengite	Pb₄CuZn₂(AsO₄)₂(PO₄)₂(OH)₂	Tric. 1 : P1
8.BH.	Zheshengite	Pb₄ZnZn₂(AsO₄)₂(PO₄)₂(OH)₂	Tric. 1 : P1
8.BH.	Crimsonite	PbFe³⁺₂(PO₄)₂(OH)₂	Orth. mmm(2/m2/m2/m) : Cccm
8.BH.05	Thadeuite	Ca(Mg,Fe²⁺)₃(PO₄)₂(OH,F)₂	Orth. 222 : C222₁
8.BH.10	Panasqueiraite	CaMg(PO₄)(OH)	Mon.
8.BH.10	Isokite	CaMg(PO₄)F	Mon. 2/m : B2/b
8.BH.10	Lacroixite	NaAl(PO₄)F	Mon. 2/m : B2/b
8.BH.10	Arsenatrotitanite	NaTi(AsO₄)O	Mon. 2/m : B2/b
8.BH.10	Maxwellite	NaFe³⁺(AsO₄)F	Mon. 2/m : P2/c
8.BH.10	Durangite	NaAl(AsO₄)F	Mon. 2/m : B2/b
8.BH.10	Kononovite	NaMg(SO₄)F	Mon. 2/m : B2/b
8.BH.15	Drugmanite	Pb₂Fe³⁺(PO₄)(PO₃OH)(OH)₂	Mon. 2/m : P2₁/c
8.BH.20	Nigelcookite	PbFe²⁺₂V³⁺₂(PO₄)₃(OH)₃	Mon. 2/m : P2₁/m
8.BH.20	Plumbojohntomaite	PbFe²⁺₂Fe³⁺₂(PO₄)₃(OH)₃	Mon. 2/m : P2₁/m
8.BH.20	Cirrolite	Ca₃Al₂(PO₄)₃(OH)₃ (?)
8.BH.20	Penikisite	Ba(Mg,Fe²⁺,Ca)₂Al₂(PO₄)₃(OH)₃	Mon. 2/m : P2₁/m
8.BH.20	Perloffite	Ba(Mn²⁺,Fe²⁺)₂Fe³⁺₂(PO₄)₃(OH)₃	Mon. 2/m : P2₁/m
8.BH.20	Bjarebyite Group
8.BH.20	Strontioperloffite	SrMn²⁺₂Fe³⁺₂(PO₄)₃(OH)₃	Mon. 2/m : P2₁/m
8.BH.20	Plumboperloffite	PbMn²⁺₂Fe³⁺₂(PO₄)₃(OH)₃	Mon. 2/m : P2₁/m
8.BH.20	Johntomaite	BaFe²⁺₂Fe³⁺₂(PO₄)₃(OH)₃	Mon. 2/m : P2₁/m
8.BH.20	Bjarebyite	(Ba,Sr)(Mn²⁺,Fe²⁺,Mg)₂Al₂(PO₄)₃(OH)₃	Mon. 2/m : P2₁/m
8.BH.20	Kulanite	Ba(Fe²⁺,Mn²⁺,Mg)₂(Al,Fe³⁺)₂(PO₄)₃(OH)₃	Mon. 2/m : P2₁/m
8.BH.25	Bertossaite	Li₂CaAl₄(PO₄)₄(OH)₄	Orth. mmm(2/m2/m2/m)
8.BH.25	Natropalermoite	Na₂SrAl₄(PO₄)₄(OH)₄	Orth. mmm(2/m2/m2/m)
8.BH.25	Palermoite	Li₂SrAl₄(PO₄)₄(OH)₄	Orth. mmm(2/m2/m2/m)
8.BH.30	Sewardite	CaFe³⁺₂(AsO₄)₂(OH)₂	Orth. mmm(2/m2/m2/m) : Cccm
8.BH.30	Carminite	PbFe³⁺₂(AsO₄)₂(OH)₂	Orth. mmm(2/m2/m2/m) : Cccm
8.BH.35	Adelite	CaMg(AsO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.35	Duftite	PbCu(AsO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.35	Cobaltaustinite	CaCo(AsO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.35	Nickelaustinite	CaNi(AsO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.35	Gabrielsonite	PbFe³⁺(As³⁺O₃)O	Orth. mm2 : Pmc2₁
8.BH.35	Conichalcite	CaCu(AsO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.35	Arsendescloizite	PbZn(AsO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.35	'Duftite-alpha'	PbCu(AsO₄)(OH)
8.BH.35	Gottlobite	CaMg(VO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.35	Austinite	CaZn(AsO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.35	Hermannroseite	CaCu(PO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.35	Tangeite	CaCu(VO₄)(OH)	Orth. 222 : P2₁2₁2₁
8.BH.40	Čechite	PbFe²⁺(VO₄)(OH)	Orth. mmm(2/m2/m2/m)
8.BH.40	Khorixasite	(Bi_0.67◻_0.33)Cu(VO₄)(OH)	Mon. 2/m : P2/c
8.BH.40	Mottramite	PbCu(VO₄)(OH)	Orth. mmm(2/m2/m2/m) : Pnma
8.BH.40	Descloizite	PbZn(VO₄)(OH)	Orth. mmm(2/m2/m2/m) : Pnma
8.BH.40	Pyrobelonite	PbMn²⁺(VO₄)(OH)	Orth. mmm(2/m2/m2/m) : Pnma
8.BH.45	Bayldonite	PbCu₃(AsO₄)₂(OH)₂	Mon. 2/m : B2/b
8.BH.45	Vésigniéite	BaCu₃(VO₄)₂(OH)₂	Mon. 2/m : B2/m
8.BH.50	Paganoite	NiBi(AsO₄)O	Tric. 1 : P1
8.BH.55	Jagowerite	BaAl₂(PO₄)₂(OH)₂	Tric.
8.BH.60	Attakolite	CaMn²⁺Al₄(SiO₃OH)(PO₄)₃(OH)₄	Mon. 2/m : B2/m
8.BH.65	Leningradite	PbCu₃(VO₄)₂Cl	Orth. mmm(2/m2/m2/m) : Ibam
8.BH.70	Katiarsite	KTiO(AsO₄)	Orth. mm2 : Pna2₁
8.BH.70	Yurgensonite	K₂SnTiO₂(AsO₄)₂	Orth. mm2 : Pna2₁
8.BH.75	Melanarsite	K₃Cu₇Fe³⁺O₄(AsO₄)₄	Mon. 2/m : B2/b
8.BH.80	Evseevite	Na₂Mg(AsO₄)F	Orth. mmm(2/m2/m2/m) : Pbcn
8.BH.80	Moraskoite	Na₂Mg(PO₄)F	Orth. mmm(2/m2/m2/m) : Pbcn
8.BH.85	Piccoliite	NaCaMn³⁺₂(AsO₄)₂O(OH)	Orth. mmm(2/m2/m2/m) : Pbcm

Fluorescence of HarrisoniteHide

In UV light:

None

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HarrisoniteHide

mindat.org URL:

https://www.mindat.org/min-1821.html
Please feel free to link to this page.

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External Links:

Look for Harrisonite on Webmineral

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Look for Harrisonite on Mineralien Atlas

Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

Buy from D. Joyce minerals

References for HarrisoniteHide

Reference List:

Grice, J. D., Roberts, A. C. (1993) Harrisonite, a well-ordered silico-phosphate with a layered crystal structure. The Canadian Mineralogist, 31 (4) 781-785

Jambor, John L., Roberts, Andrew C., Vanko, David A. (1994) New Mineral Names. American Mineralogist, 79 (9-10) 1009-1014

(2001) Harrisonite. Handbook of Mineralogy. Mineralogical Society of America

Vácha, J., Škoda, R. (2022): Harrisonite, a rare silicate-phosphate from granitic pegmatites of the Bohemian Massif. Acta Musei Moraviae, Scientiae geologicae: 107: 21-32.

Vácha, Jakub; Škoda, Radek; Skřápková, Lenka; Komsa, Hannu-Pekka; Cempírek, Jan (2026) Vibration spectra and new structural data on natural layered silicate-phosphate harrisonite from various geological environments. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 363 (1). p.128409. doi:10.1016/j.saa.2026.128409

Localities for HarrisoniteHide

Showing 5 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Brazil
Minas Gerais Conselheiro Pena Barra do Cuieté ⓘ Cigana claim	Baijot et al. (2014)

Canada (TL)
Nunavut Kitikmeot Region ⓘ Arcedeckne Island (TL)	Roberts et al. (1993)

Czech Republic
Central Bohemian Region Kutná Hora District Vlkaneč ⓘ Přibyslavice	Vácha et al. (2022)
Vysočina Region Žďár nad Sázavou District Bory Horní Bory Cyrilov (Cyrillhof) ⓘ Cyrilov phosphate pegmatite (Cyrillhof)	Škoda et al. (2007) +1 other reference

Germany
Bavaria Upper Bavaria Traunstein District ⓘ ~~Chiemsee pseudocrater~~	Neumair et al. (2016) +1 other reference

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Harrisonite

About HarrisoniteHide

Unique IdentifiersHide

IMA Classification of HarrisoniteHide

Classification of HarrisoniteHide

Mineral SymbolsHide

Physical Properties of HarrisoniteHide

Optical Data of HarrisoniteHide

Chemistry of HarrisoniteHide

Crystallography of HarrisoniteHide

Crystal StructureHide

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of HarrisoniteHide

Synonyms of HarrisoniteHide

Other Language Names for HarrisoniteHide

Related Minerals - Strunz-mindat GroupingHide

Fluorescence of HarrisoniteHide

Other InformationHide

Internet Links for HarrisoniteHide

References for HarrisoniteHide

Localities for HarrisoniteHide

Locality ListHide

Related Minerals - Strunz-mindat Grouping Hide