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Argandite

A valid IMA mineral species
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About ArganditeHide

09095650017272471925043.jpg
Emile Argand
Formula:
Mn7(VO4)2(OH)8
Colour:
Orange
Lustre:
Vitreous
Hardness:
3½ - 4
Specific Gravity:
3.71
Crystal System:
Monoclinic
Member of:
Name:
Named in honour of Emile Argand (1879-1940), Swiss geologist and mineralogist, who studied the tectonics of the Alps and of Asia. Argand was an early supporter of Wegener's theory of continental drift.
Isostructural with:
Vanadate analogue of allactite.


Unique IdentifiersHide

Mindat ID:
40277
Long-form identifier:
mindat:1:1:40277:2

IMA Classification of ArganditeHide

Approved
IMA Formula:
Mn2+7(V5+O4)2(OH)8
Approval year:
2010
First published:
2011

Classification of ArganditeHide

8.BE.30

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
E : With only medium-sized cations, (OH, etc.):RO4 > 2:1
41.2.1.4

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
2 : (AB)7(XO4)2Zq

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
AgdIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ArganditeHide

Vitreous
Transparency:
Transparent
Colour:
Orange
Streak:
Pale orange
Hardness:
3½ - 4 on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
Probably parallel to {001}.
Density:
3.71(5) g/cm3 (Measured)    3.67(1) g/cm3 (Calculated)

Optical Data of ArganditeHide

Type:
Biaxial (-)
RI values:
nα = 1.74 nβ = 1.762(4) nγ = 1.77
2V:
Calculated: 62°
Max. Birefringence:
δ = 0.030
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Pleochroism:
Visible
Comments:
Orange-yellow to orange.

Chemistry of ArganditeHide

Mindat Formula:
Mn7(VO4)2(OH)8
Element Weights:
Element% weight
Mn51.241 %
O34.109 %
V13.575 %
H1.074 %

Calculated from ideal end-member formula.
Mn
O
V
H

Crystallography of ArganditeHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Setting:
P21/m
Cell Parameters:
a = 5.498(2) Å, b = 12.265(3) Å, c = 10.092(2) Å
β = 95.594(3)°
Ratio:
a:b:c = 0.448 : 1 : 0.823
Unit Cell V:
677.29 ų (Calculated from Unit Cell)
Morphology:
Anhedral grains.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018517ArganditeBrugger J, Elliott P, Meisser N, Ansermet S (2011) Argandite, Mn7(VO4)2(OH)8, the V analogue of allactite from the metamorphosed Mn ores at Pipji, Turtmann Valley, Switzerland American Mineralogist 96 1894-19002011Pipji, Turtmann Valley, Switzerland0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.708 Å(50)
3.395 Å(60)
3.074 Å(100)
2.945 Å(50)
2.687 Å(70)
2.522 Å(50)
2.324 Å(40)
1.791 Å(40)
Comments:
Pipjitälli, Valais, Switzerland. The data are from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits

Type Occurrence of ArganditeHide

General Appearance of Type Material:
Argandite occurs as a rock-forming mineral in a manganosite-rich specimen. It forms orange anhedral grains up to 60 micron in diameter.
Place of Conservation of Type Material:
Geological Museum, Lausanne, Switzerland, reg. no. MGL90369.
Geological Setting of Type Material:
Metamorphosed synsedimentary exhalative Mn deposit.
Associated Minerals at Type Locality:

Synonyms of ArganditeHide

Other Language Names for ArganditeHide

Dutch:Argandiet
French:Argandite
German:Argandit
Norwegian:Arganditt

Relationship of Argandite to other SpeciesHide

Member of:
Other Members of Allactite Group:
AllactiteMn2+7(AsO4)2(OH)8Mon. 2/m : P21/c
RaadeiteMg7(PO4)2(OH)8Mon. 2/m

Related Minerals - Strunz-mindat GroupingHide

8.BE.05AugeliteAl2(PO4)(OH)3Mon. 2/m : B2/m
8.BE.10GrattarolaiteFe3+3(PO4)O3Trig. 3m : R3m
8.BE.15CornetiteCu3(PO4)(OH)3Orth. mmm(2/m2/m2/m) : Pbca
8.BE.20ClinoclaseCu3(AsO4)(OH)3Mon. 2/m : P21/c
8.BE.25GilmariteCu3(AsO4)(OH)3Tric. 1 : P1
8.BE.25ArhbariteCu2Mg(AsO4)(OH)3Tric. 1 : P1
8.BE.30FlinkiteMn2+2Mn3+(AsO4)(OH)4Orth. mmm(2/m2/m2/m) : Pnma
8.BE.30RaadeiteMg7(PO4)2(OH)8Mon. 2/m
8.BE.30AllactiteMn2+7(AsO4)2(OH)8Mon. 2/m : P21/c
8.BE.35'Mineral E (of Dunn, et. al., 1982)'Orth. mmm(2/m2/m2/m)
8.BE.35Chlorophoenicite(Mn,Mg)3Zn2(AsO4)(OH,O)6Mon. 2/m : B2/m
8.BE.35Magnesiochlorophoenicite(Mg,Mn)3Zn2(AsO4)(OH,O)6Mon. 2/m : B2/m
8.BE.40Gerdtremmelite(Zn,Fe)(Al,Fe)2(AsO4)(OH)5Tric.
8.BE.45DixeniteCuMn2+14Fe2+(SiO4)2(As5+O4)(As3+O3)5(OH)6Trig. 3 : R3
8.BE.45McgoverniteMn19Zn3(AsO4)3(AsO3)(SiO4)3(OH)21Trig. 3m : R3c
8.BE.45Hematolite(Mn,Mg,Al,Fe3+)15(As5+O4)2(As3+O3)(OH)23Trig. 3 : R3
8.BE.45Turtmannite(Mn,Mg)22.5Mg3-3x((V5+,As5+)O4)3(As3+O3)x(SiO4)3O5-5x(OH)20+xTrig.
8.BE.45CarlfrancisiteMn2+3(Mn2+,Mg,Fe3+,Al)42[As3+O3]2(As5+O4)4[(Si,As5+)O4]6[(As5+,Si)O4]2(OH)42Trig. 3m : R3c
8.BE.45Arakiite(Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As5+O4)2(As3+O3)(OH)23Mon. m : Bb
8.BE.45KraissliteZn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16Orth. 222 : C2221
8.BE.50SynadelphiteMn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2OOrth. mmm(2/m2/m2/m) : Pnma
8.BE.55Holdenite(Mn2+,Mg)6Zn3(AsO4)2(SiO4)(OH)8Orth. mmm(2/m2/m2/m) : Ccca
8.BE.60KoliciteMn2+7Zn4(AsO4)2(SiO4)2(OH)8Orth. mmm(2/m2/m2/m) : Cmca
8.BE.65Sabelliite(Cu,Zn)2Zn(AsO4,SbO4)(OH)3Trig. 3 : P3
8.BE.70JarosewichiteMn2+3Mn3+(AsO4)(OH)6Orth. 222
8.BE.75TheisiteCu5Zn5(AsO4,SbO4)2(OH)14Orth.
8.BE.80CoparsiteCu4(AsO4,VO4)O2ClOrth. mmm(2/m2/m2/m) : Pbcm
8.BE.85WaterhouseiteMn2+7(PO4)2(OH)8Mon. 2/m : P21/c
8.BE.90VasilseverginiteCu9O4(AsO4)2(SO4)2Mon. 2/m : P21/c

Fluorescence of ArganditeHide

Not fluorescent.

Other InformationHide

Notes:
Slowly soluble in cold 10% HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ArganditeHide

References for ArganditeHide

Localities for ArganditeHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy
 
  • Liguria
    • Genoa
      • Ne
        • Reppia
SCXRD: L. Bindi - University of Firenze ... +1 other reference
Switzerland (TL)
 
  • Valais
    • Leuk
      • Turtmann-Unterems
        • Turtmann Valley
Williams et al. (2010) +1 other reference
Ansermet (2012)
 
and/or  
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