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Krasheninnikovite

A valid IMA mineral species
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About KrasheninnikoviteHide

03692300017271951429057.jpg
Stepan P. Krasheninnikov
Formula:
KNa2CaMg(SO4)3F
Colour:
Colorless, White
Lustre:
Vitreous
Hardness:
2½ - 3
Specific Gravity:
2.68
Crystal System:
Hexagonal
Name:
Named in 2011 by I.V. Pekov et al. in honor of Stepan Petrovich Krasheninnikov (Степа́н Петро́вич Крашени́нников) (11 November 1711, Moscow, Russia - 8 March 1755, Saint Petersburg, Russia), one of first scientists to research the Kamchatka Peninsula. He was a naturalist, botanist, and geographer. The Krasheninnikov Volcano on Kamchatka is also named in his honor.
Structurally related to kantorite.


Unique IdentifiersHide

Mindat ID:
41951
Long-form identifier:
mindat:1:1:41951:4

IMA Classification of KrasheninnikoviteHide

Approved
IMA Formula:
KNa2CaMg(S6+O4)3F
Approval year:
2011
First published:
2012

Classification of KrasheninnikoviteHide

7.BC.57

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
KrhIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of KrasheninnikoviteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of KrasheninnikoviteHide

Vitreous
Transparency:
Transparent
Colour:
Colorless, White
Comment:
Colorless in individuals and white in aggregates
Hardness:
2½ - 3 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Density:
2.68(1) g/cm3 (Measured)    2.67 g/cm3 (Calculated)

Optical Data of KrasheninnikoviteHide

Type:
Uniaxial (-)
RI values:
nω = 1.500(2) nε = 1.492(2)
Max. Birefringence:
δ = 0.008
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of KrasheninnikoviteHide

Mindat Formula:
KNa2CaMg(SO4)3F
Element Weights:
Element% weight
O42.044 %
S21.066 %
Na10.069 %
Ca8.777 %
K8.562 %
Mg5.323 %
F4.160 %

Calculated from ideal end-member formula.
O
S
Na
Ca
K
Mg
F

Crystallography of KrasheninnikoviteHide

Crystal System:
Hexagonal
Class (H-M):
6/mmm(6/m2/m2/m) - Dihexagonal Dipyramidal
Space Group:
P63/mcm
Setting:
P63/mcm
Cell Parameters:
a = 16.6682(2) Å, c = 6.9007(1) Å
Ratio:
a:c = 1 : 0.414
Unit Cell V:
1660.36 ų
Z:
6
Morphology:
Long-prismatic to acicular crystals up to 3 mm long and up to 20 μm thick.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.284 Å(23)
3.610 Å(23)
3.566 Å(17)
3.459 Å(41)
3.153 Å(100)
3.117 Å(21)
2.660 Å(39)
2.085 Å(19)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
45b : [Other oxidized fumarolic minerals]

Type Occurrence of KrasheninnikoviteHide

General Appearance of Type Material:
Long-prismatic to acicular crystals up to 3 mm long and up to 20 μm thick. The crystals are combined in sheaf-like, radiating or open-work matted aggregates forming nests up to several cm3 or crusts.
Place of Conservation of Type Material:
Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow,Russia, registration number 4112/1
Geological Setting of Type Material:
Found in sublimates of an active fumarole
Associated Minerals at Type Locality:

Synonyms of KrasheninnikoviteHide

Other Language Names for KrasheninnikoviteHide

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Krasheninnikovite associated with TenoriteCuO

Related Minerals - Strunz-mindat GroupingHide

7.BC.ViskontitePb5Cu2(SO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.ZincochenitePb4Zn(SO4)2(OH)6Tric. 1 : P1
7.BC.D'Ansite-(Mn)Na21Mn2+(SO4)10Cl3Iso. 43m : I43d
7.BC.D'Ansite-(Fe)Na21Fe2+(SO4)10Cl3Iso. 43m : I43d
7.BC.Acmonidesite(NH4,K,Pb)8NaFe2+4(SO4)5Cl8Orth. 222 : C2221
7.BC.Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2Tet. 4/mmm(4/m2/m2/m) : I41/acd
7.BC.ChromviskontitePb5Cu2(CrO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.BackitePb2AlTeO6ClTrig. 32 : P312
7.BC.Adranosite-(Fe)(NH4)4NaFe3+2(SO4)4Cl(OH)2Tet. 4/mmm(4/m2/m2/m) : I41/acd
7.BC.AgaitePb3CuTeO5(OH)2(CO3) Orth. mm2 : Pca21
7.BC.WildcatiteCaFe3+Te6+O5(OH)Trig. 3m(32/m) : P31m
7.BC.HagstromitePb8Cu2+(Te6+O6)2(CO3)Cl4Orth. mmm(2/m2/m2/m) : Ibam
7.BC.05D'AnsiteNa21Mg(SO4)10Cl3Iso. 43m : I43m
7.BC.07'Apatelite'Fe3(SO4)2(OH)5 · 0.5H2O
7.BC.07'Unnamed (Ba-Fe Vanadate)'Ba, Fe, V, O, H
7.BC.10JarositeKFe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10DorallchariteTlFe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10WalthieriteBa0.5Al3(SO4)2(OH)6Trig.
7.BC.10HuangiteCa0.5Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10'Natroalunite-2c'(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Karlseifertite Pb(Ga2Ge)(AsO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
7.BC.10Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.15Ye'elimiteCa4Al6(SO4)O12Iso. 432 : I4132
7.BC.20NabokoiteKCu7(SO4)5(Te4+O3)OClTet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.20PuniniteNa2Cu3O(SO4)3Mon. 2/m : B2/b
7.BC.20AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.25ChlorothioniteK2Cu(SO4)Cl2Orth. mmm(2/m2/m2/m) : Pnma
7.BC.30EuchlorineKNaCu3(SO4)3OMon. 2/m
7.BC.30FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
7.BC.35KamchatkiteKCu3(SO4)2OClOrth. mmm(2/m2/m2/m) : Pnma
7.BC.40PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet. 4 : I4
7.BC.45AlumoklyuchevskiteK3Cu3(Al,Fe3+)(SO4)4O2Tric. 1 : P1
7.BC.45BelousoviteKZn(SO4)ClMon. 2/m : P21/c
7.BC.45KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon. 2
7.BC.47MülleritePb2Fe3+(Te6+O6)ClTrig. 32 : P3112
7.BC.50CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
7.BC.50ElasmochloiteNa3Cu6BiO4(SO4)5Mon. 2/m : P21/c
7.BC.52Eleomelanite(K2Pb)Cu4O2(SO4)4Mon. 2/m : P21/c
7.BC.55FalgariteK4(VO)3(SO4)5Mon. 2/m : B2/b
7.BC.55WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
7.BC.60WulffiteK3NaCu4O2(SO4)4Orth. mm2
7.BC.60ParawulffiteK5Na3Cu8O4(SO4)8Mon. 2/m : P2/b
7.BC.60MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
7.BC.62ShuvaloviteK2(Ca2Na)(SO4)3FOrth. mmm(2/m2/m2/m) : Pnma
7.BC.65SaccoiteCa2Mn3+2F(OH)8 · 0.5(SO4)Tet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.65LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
7.BC.65Therasiaite(NH4)3KNa2Fe2+Fe3+(SO4)3Cl5Mon. m : Bb
7.BC.65FranksousaitePbCu(Se6+O4)(OH)2Mon. 2/m : P21/m
7.BC.65MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
7.BC.65SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon. 2/m : P21/m
7.BC.70ChenitePb4Cu(SO4)2(OH)6Tric. 1 : P1
7.BC.75KrivovichevitePb3Al(OH)6(SO4)(OH)Trig. 3m : R3c
7.BC.80AnhydrokainiteKMg(SO4)Cl

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 8.5620% 2,654 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity: –

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KrasheninnikoviteHide

References for KrasheninnikoviteHide

Localities for KrasheninnikoviteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Kamchatka Krai
    • Milkovsky District
      • Tolbachik Volcanic field
        • Great Fissure eruption (Main Fracture)
          • Northern Breakthrough (North Breach)
Williams et al. (2011) +1 other reference
Pekov et al. (2015) +2 other references
Pekov et al. (2019)
Pekov et al. (2019)
 
and/or  
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