Zorite

A valid IMA mineral species

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Zorite, etc.

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Zorite

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Zorite

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Zorite, etc.

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Zorite

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Zorite

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Zorite, etc.

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Zorite

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

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About ZoriteHide

Formula:

Na₈(Ti,Nb)₅(Si₆O₁₇)₂(OH,O)₅ · 14H₂O

Colour:

Rose-red, pink, can appear white or colourless in individual crystals.

Lustre:

Vitreous

Hardness:

3 - 4

Specific Gravity:

2.27 - 2.40

Crystal System:

Orthorhombic

Member of:

Zorite Group

Name:

From Russian "zoria", meaning "the rosy radiance of the sky at dawn", alluding to its colour.

Type Locality:

ⓘ Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

The structure of Zorite contains double dreier chains of (SiO4) tetrahedra, which are linked by Ti cations into a three-dimensional framework.
A topologically identical framework is found in the structures of Haineaultite (the Ca-analogue of Zorite), Chivruaiite, and the synthetic Zorite analogue ETS-4 (Men'shikov et al., 2006).

Unique IdentifiersHide

Mindat ID:

4431

Long-form identifier:

mindat:1:1:4431:4

Similar NamesHide

Aorite	A variety of 'Gneiss'
Azorite	A synonym of Zircon
Cerit-(La)	A synonym of Ferricerite-(LaCa)
Cerite	A synonym
Cerite-(CeCa)	A valid IMA mineral species - grandfathered	(Ce₇Ca₂)◻Mg(SiO₄)₃(SiO₃OH)₄(OH)₃
Korite	A synonym of 'Ammolite'
Norite	A rock classification type
Sayrite	A valid IMA mineral species	Pb₂(UO₂)₅O₆(OH)₂ · 4H₂O
Surite	A valid IMA mineral species	(Pb,Ca)₃(Al,Fe²⁺,Mg)₂((Si,Al)₄O₁₀)(CO₃)₂(OH)₂
Torite	A synonym of Thorite
Zaïrite	A valid IMA mineral species	BiFe₃³⁺(PO₄)₂(OH)₆
Ziroite	A valid IMA mineral species	ZrO₂
Zonite	A rock subtype
Zorgite

IMA Classification of ZoriteHide

IMA status:

Approved

IMA Formula:

Na₆Ti⁴⁺₅Si₁₂O₃₄(O,OH)₅·11H₂O

Approval year:

1972

First published:

1973

Type description reference:

Mer'kov, A.N., Bussen, I.V., Goiko, E.A., Kul'chitskaya, E.A., Men'shikov, Yu.P., and Nedorezova, A.P. (1973) Raite and zorite - new minerals from the Lovozero Tundra. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 102(1): 54-62.

Classification of ZoriteHide

Strunz-mindat (2026):

9.DG.45

9 : SILICATES (Germanates)
D : Inosilicates
G : Inosilicates with 3-periodic single and multiple chains

Dana 8th ed.:

66.3.1.2

66 : INOSILICATES Double-Width,Unbranched Chains,(W=2)
3 : Amphiboles - Ca-Na subgroup

Hey's CIM Ref.:

16.14.1

16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference for Standard
Zor	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ZoriteHide

Lustre:

Vitreous

Transparency:

Translucent

Colour:

Rose-red, pink, can appear white or colourless in individual crystals.

Hardness:

3 - 4 on Mohs scale

Cleavage:

Perfect
{010} and {001} perfect; {110} less perfect

Density:

2.27 - 2.40 g/cm³ (Measured) 2.23 g/cm³ (Calculated)

Optical Data of ZoriteHide

Type:

Biaxial

Dispersion:

r > v strong

Pleochroism:

Visible

Comments:

X = rose, Y = nearly colorless, Z = bluish.

Chemistry of ZoriteHide

Mindat Formula:

Na₈(Ti,Nb)₅(Si₆O₁₇)₂(OH,O)₅ · 14H₂O

Element Weights:

Element	% weight
O	51.658 %
Si	20.532 %
Ti	14.580 %
Na	11.204 %
H	2.026 %

Calculated from ideal end-member formula.

Elements listed:

H, Na, Nb, O, Si, Ti - search for minerals with similar chemistry

Common Impurities:

Zr,Fe,Nb,Ta,Mn,Mg,Ca,K,F,C,P

Crystallography of ZoriteHide

Crystal System:

Orthorhombic

Cell Parameters:

a = 23.9(1) Å, b = 7.23(2) Å, c = 14.25(5) Å

Ratio:

a:b:c = 3.306 : 1 : 1.971

Unit Cell V:

2,462.36 Å³ (Calculated from Unit Cell)

Comment:

Point Group: 2/m 2/m 2/m or mm2; Space Group: Cmcm; Cmc21 ; or C2cm:

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0015580	Zorite	Sandomirskii P A, Belov N V (1979) The OD structure of zorite Soviet Physics Crystallography 24 686-693		1979	central natrolite region, Yubileinaya pegmatoid vein, Lovozero massif	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Zorite'
loop_
_publ_author_name
'Sandomirskii P A'
'Belov N V'
_journal_name_full 'Soviet Physics Crystallography'
_journal_volume 24 
_journal_year 1979
_journal_page_first 686
_journal_page_last 693
_publ_section_title
;
 The OD structure of zorite
;
_database_code_amcsd 0015580
_chemical_compound_source 'central natrolite region, Yubileinaya pegmatoid vein, Lovozero massif'
_chemical_formula_sum 'Ti2.3 Nb.2 Si6 Na3 O24.75 H10.5'
_cell_length_a 23.241
_cell_length_b 7.238
_cell_length_c 6.955
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1169.959
_exptl_crystal_density_diffrn      2.194
_symmetry_space_group_name_H-M 'C m m m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,y,z'
  '1/2-x,1/2+y,z'
  'x,-y,-z'
  '1/2+x,1/2-y,-z'
  'x,y,-z'
  '1/2+x,1/2+y,-z'
  '-x,-y,z'
  '1/2-x,1/2-y,z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Ti1   0.25000   0.25000   0.00000   0.90000   0.00899
Nb1   0.25000   0.25000   0.00000   0.10000   0.00899
Ti2   0.00000   0.50000   0.04570   0.25000   0.01938
Si1   0.16180   0.00000   0.26970   1.00000   0.00861
Si2   0.06390   0.09430   0.00000   0.50000   0.01039
Na1   0.25000   0.25000   0.50000   0.50000   0.02786
Na2   0.36540   0.00000   0.21820   0.50000   0.04939
O1   0.15450   0.00000   0.50000   1.00000   0.02153
O2   0.09520   0.00000   0.18780   1.00000   0.02026
O3   0.19400   0.18530   0.20360   1.00000   0.02153
O4   0.22080   0.50000   0.00000   1.00000   0.01393
O5   0.00000   0.00000   0.00000   1.00000   0.01267
O6   0.06020   0.31970   0.00000   0.50000   0.02913
O7   0.01120   0.50000   0.28260   0.12500   0.02786
Wat1   0.29490   0.05370   0.50000   0.50000   0.05066
Wat2   0.08110   0.38240   0.50000   0.25000   0.07726
Wat3   0.07200   0.50000   0.50000   0.12500 ?
Wat4   0.10000   0.30000   0.50000   0.25000 ?
Wat5   0.03000   0.09000   0.50000   0.25000 ?

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
11.6 Å	(80)
6.9 Å	(100)
4.45 Å	(50)
3.43 Å	(50)
3.38 Å	(80)
3.067 Å	(80)
2.979 Å	(80)
2.588 Å	(80)
1.742 Å	(80)
1.701 Å	(60)

Locality:

Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

Reference:

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 4b: Highly evolved igneous rocks	>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Stage 7: Great Oxidation Event	<2.4
47a : [Near-surface hydration of prior minerals]

Type Occurrence of ZoriteHide

Type Locality:

ⓘ Yubileinaya pegmatite, Karnasurt Mountain, Lovozersky District, Murmansk Oblast, Russia

General Appearance of Type Material:

Intergrowths of prismatic acicular crystals 1-2 mm long and as polycrystalline plates up to 10x6x0.5 cm.

Place of Conservation of Type Material:

Geology Museum, Kola Branch, Academy of Sciences, Apatity, Russia, 3144, 3207.
Mineralogical Museum, St. Petersburg University, St. Petersburg, Russia, 15286, 18102, 18155.
Mining Institute, St. Petersburg, Russia, 1059/1-5.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 74486-74488.

Geological Setting of Type Material:

Alkalic pegmatite.

Associated Minerals at Type Locality:

Reference:

Synonyms of ZoriteHide

IMA1972-011

Other Language Names for ZoriteHide

Dutch:Zoriet

German:Zorit

Russian:Зорит

Simplified Chinese:佐硅钛钠石

Spanish:Zorita

Traditional Chinese:佐矽鈦鈉石

Relationship of Zorite to other SpeciesHide

Member of:

Zorite Group

Other Members of Zorite Group:

Chivruaiite	Ca₄(Ti,Nb)₅(Si₆O₁₇)₂(OH,O)₅ · 13-14H₂O	Orth. mmm(2/m2/m2/m) : Cmmm
Escheite	Ca₂NaMnTi₅[Si₁₂O₃₄]O₂(OH)₃ · 12H₂O	Orth. mm2 : Ama2
Haineaultite	(Na,Ca)₅Ca(Ti,Nb)₅(Si₆O₁₇)₂(OH,F)₈ · 5H₂O	Orth. 222 : C222

Common AssociatesHide

Associations Based on Photo Data:

29 photos of Zorite associated with Raite	Mn²⁺Mn²⁺₂Na₂(◻_1.75Ti_0.25)Si₈O₂₀(OH)₂(H₂O)₄ · Na(H₂O)₆
10 photos of Zorite associated with Aegirine	NaFe³⁺Si₂O₆
8 photos of Zorite associated with Natrolite	Na₂Al₂Si₃O₁₀ · 2H₂O
6 photos of Zorite associated with Lomonosovite	Na₅Ti₂(Si₂O₇)(PO₄)O₂
4 photos of Zorite associated with Eudialyte	Na₁₅Ca₆Fe₃Zr₃Si(Si₂₅O₇₃)(O,OH,H₂O)₃(Cl,OH)₂
4 photos of Zorite associated with Penkvilksite	Na₄Ti₂Si₈O₂₂ · 4H₂O
4 photos of Zorite associated with Leucosphenite	BaNa₄Ti₂B₂Si₁₀O₃₀
3 photos of Zorite associated with Yofortierite	Mn²⁺Mn²⁺₂Mn²⁺₂◻₂Si₈O₂₀(OH)₂(H₂O)₄ · 4H₂O
3 photos of Zorite associated with Microcline	K(AlSi₃O₈)
1 photo of Zorite associated with Calcite	CaCO₃

Related Minerals - Strunz-mindat Grouping Hide

9.DG.	Barrydawsonite-(Y)	Na_1.5Y_0.5CaSi₃O₈(OH)	Mon. 2/m : P2₁/c
9.DG.	Paratobermorite	Ca₅AlSi₅O₁₆(OH) · 5H₂O	Mon. 2/m
9.DG.	Calcinaksite	KNaCa(Si₄O₁₀) · H₂O	Tric. 1 : P1
9.DG.	Alvesite	NaKZrSi₆O₁₅ · 2H₂O	Orth. mmm(2/m2/m2/m)
9.DG.02	Steedeite	NaMn₂[Si₃BO₉](OH)₂	Tric. 1 : P1
9.DG.02	Nolzeite	NaMn₂[Si₃BO₉](OH)₂ · 2H₂O	Tric. 1 : P1
9.DG.05	Murakamiite	LiCa₂Si₃O₈(OH)	Tric. 1 : P1
9.DG.05	Serandite	NaMn²⁺₂Si₃O₈(OH)	Tric. 1 : P1
9.DG.05	Bustamite	CaMn²⁺(Si₂O₆)	Tric. 1 : P1
9.DG.05	Pectolite	NaCa₂Si₃O₈(OH)	Tric. 1 : P1
9.DG.05	Tanohataite	LiMn₂Si₃O₈(OH)	Tric. 1 : P1
9.DG.05	Dalnegorskite	Ca₅Mn²⁺(Si₃O₉)₂	Tric. 1 : P1
9.DG.05	'Wollastonite-1A'	CaSiO₃	Tric. 1 : P1
9.DG.05	Wollastonite	Ca₃(Si₃O₉)	Tric. 1 : P1
9.DG.05	Ferrobustamite	CaFe²⁺(Si₂O₆)	Tric. 1
9.DG.05	Schizolite	NaCaMnSi₃O₈(OH)	Tric. 1 : P1
9.DG.07	Cascandite	CaScSi₃O₈(OH)	Tric. 1
9.DG.08	Plombièrite	Ca₅Si₆O₁₆(OH)₂ · 7H₂O	Orth.
9.DG.10	Clinotobermorite	Ca₅Si₆O₁₇ · 5H₂O	Mon.
9.DG.10	Riversideite	Ca₅Si₆O₁₆(OH)₂ · 2H₂O	Orth.
9.DG.10	Tobermorite	Ca₅Si₆O₁₇ · 5H₂O	Mon. 2 : P2₁
9.DG.12	Jusite	Na₂Ca₁₅Al₄Si₁₆O₅₄ · 17H₂O
9.DG.12	Kenotobermorite	Ca₄Si₆O₁₅(OH)₂ · 5H₂O	Mon.
9.DG.15	Foshagite	Ca₄(Si₃O₉)(OH)₂	Tric. 1 : P1
9.DG.20	Jennite	Ca₉(Si₃O₉)₂(OH)₈ · 8H₂O	Tric. 1 : P1
9.DG.20	Kamenevite	K₂TiSi₃O₉ · H₂O	Orth. 222 : P2₁2₁2₁
9.DG.25	Paraumbite	K₃Zr₂H(Si₃O₉)₂ · nH₂O	Orth. mm2
9.DG.25	Umbite	K₂(Zr,Ti)Si₃O₉ · H₂O	Orth. 222 : P2₁2₁2₁
9.DG.30	Sørensenite	Na₄SnBe₂Si₆O₁₆(OH)₄	Mon. 2/m : B2/b
9.DG.32	Escheite	Ca₂NaMnTi₅[Si₁₂O₃₄]O₂(OH)₃ · 12H₂O	Orth. mm2 : Ama2
9.DG.35	Xonotlite	Ca₆(Si₆O₁₇)(OH)₂	Mon. 2/m : B2/m
9.DG.40	Hillebrandite	Ca₂(SiO₃)(OH)₂	Orth. mmm(2/m2/m2/m) : Cmcm
9.DG.45	Chivruaiite	Ca₄(Ti,Nb)₅(Si₆O₁₇)₂(OH,O)₅ · 13-14H₂O	Orth. mmm(2/m2/m2/m) : Cmmm
9.DG.50	Haineaultite	(Na,Ca)₅Ca(Ti,Nb)₅(Si₆O₁₇)₂(OH,F)₈ · 5H₂O	Orth. 222 : C222
9.DG.55	Epididymite	Na₂Be₂Si₆O₁₅ · H₂O	Orth. mmm(2/m2/m2/m) : Pnma
9.DG.60	Eudidymite	Na₂Be₂Si₆O₁₅ · H₂O	Mon. 2/m : B2/b
9.DG.65	Elpidite	Na₂ZrSi₆O₁₅ · 3H₂O	Orth.
9.DG.65	Patynite	NaKCa₄[Si₉O₂₃]	Tric. 1 : P1
9.DG.67	Whelanite	Cu²⁺₂Ca₆[Si₆O₁₇(OH)](CO₃)(OH)₃ · 2H₂O	Orth. mm2 : Pnn2
9.DG.70	Enricofrancoite	KNaCaSi₄O₁₀	Tric. 1 : P1
9.DG.70	Yusupovite	Na₂Zr(Si₆O₁₅) · 2.5H₂O	Mon. 2/m : B2/m
9.DG.70	Litidionite	KNaCuSi₄O₁₀	Tric. 1 : P1
9.DG.70	Fenaksite	(K,Na)₄(Fe,Mn)₂(Si₄O₁₀)₂(OH,F)	Tric. 1 : P1
9.DG.70	Manaksite	KNaMnSi₄O₁₀	Tric. 1 : P1
9.DG.75	Senkevichite	CsKNaCa₂TiO[Si₇O₁₈](OH)	Tric. 1 : P1
9.DG.75	Tinaksite	K₂Na(Ca,Mn²⁺)₂TiO[Si₇O₁₈(OH)]	Tric.
9.DG.75	Tokkoite	K₂Ca₄[Si₇O₁₈(OH)](OH,F)	Tric.
9.DG.80	Fluorcanasite	K₃Na₃Ca₅Si₁₂O₃₀F₄ · H₂O	Mon. m : Bm
9.DG.80	Canasite	K₃Na₃Ca₅Si₁₂O₃₀(OH)₄	Mon. m : Bm
9.DG.85	Miserite	K_1.5-x(Ca,Y,REE)₅(Si₆O₁₅)(Si₂O₇)(OH,F)₂ · yH₂O	Tric.
9.DG.90	Frankamenite	K₃Na₃Ca₅(Si₁₂O₃₀)(F,OH)₄ · H₂O	Tric. 1 : P1
9.DG.92	Charoite	(K,Sr)_15-16(Ca,Na)₃₂[Si₆O₁₁(O,OH)₆]₂[Si₁₂O₁₈(O,OH)₁₂]₂[Si₁₇O₂₅(O,OH)₁₈]₂(OH,F)₄ · ~3H₂O	Mon. 2/m : P2₁/m
9.DG.95	Yuksporite	K₄(Ca,Na)₁₄(Sr,Ba)₂(◻,Mn,Fe)(Ti,Nb)₄(O,OH)₄(Si₆O₁₇)₂(Si₂O₇)₃(H₂O,OH)₃	Mon. 2/m : P2₁/m
9.DG.97	Eveslogite	(Na,K,Ca,Sr,Ba)₄₈ [(Ti,Nb,Mn,Fe²⁺)₁₂Si₄₈O₁₄₄(OH)₁₂](F,OH,Cl)₁₄	Mon. 2/m : P2/c

Other InformationHide

Thermal Behaviour:

Before the blowpipe sinters to a white bubbly mass, then melts to a brown glass with n = 1.574.

Notes:

Insoluble in water, slowly decomposed by dilute HCl or HNO3 with the formation of silica gel.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ZoriteHide

mindat.org URL:

https://www.mindat.org/min-4431.html
Please feel free to link to this page.

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

Buy from D. Joyce minerals

References for ZoriteHide

Reference List:

Panikorovskii, T.L. , Yakovenchuk, V.N., Kalashnikova, G.O., Bazai, A.V., Ikkonen, P., Yanicheva N.Yu., Krivovichev, S.V. (2023): Microporous sorbents for Th4+, REE3+, Cs+. Trudy Fersmanovskoy nauchnoy sessii GI KNTS RAN, 20, 632-638.

Fleischer, Michael (1973) New mineral names. American Mineralogist, 58 (11-12) 1111-1115

Sandomirskii, P.A., Belov, N.V. (1979) The OD structure of zorite. Soviet Physics - Crystallography: 24: 686-693.

Cruciani, G, De Luca, P, Nastro, A, Pattison, P (1998) Rietveld refinement of the zorite structure of ETS-4 molecular sieves. Microporous and Mesoporous Materials, 21 (1-3). 143-153 doi:10.1016/s1387-1811(97)00051-6

(2001) Zorite. Handbook of Mineralogy. Mineralogical Society of America

Men'shikov, Y. P. (2006) Chivruaiite, Ca₄(Ti,Nb)₅[(Si₆O₁₇)₂[(OH,O)₅]·13-14H₂O, a new mineral from hydrothermal veins of Khibiny and Lovozero alkaline massifs. American Mineralogist, 91 (5) 922-928 doi:10.2138/am.2006.2032

Localities for ZoriteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

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Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Russia (TL)

Murmansk Oblast

Lovozersky District

Karnasurt Mountain

ⓘ Yubileinaya pegmatite (TL)

Mer'kov et al. (1973) +4 other references

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Zorite

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