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Aleutite

A valid IMA mineral species
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Formula:
[Cu5O2](AsO4)(VO4) · (Cu,K,Pb,Rb,Cs,)Cl
The original paper reports the following formula: [Cu5O2](AsO4)(VO4)·(Cu0.5□0.5)Cl
Colour:
Dark red
Lustre:
Adamantine
Specific Gravity:
4.887 (Calculated)
Crystal System:
Monoclinic
Name:
Named for the Aleuts, the ethnic group who are the original inhabitants living on the Commander Islands, Aleutsky District, Kamchatka Krai.
New structure type. However, it may be compared to averievite which was once reported to be Cu5O2(VO4)2·CuCl2·(Cs, K, Rb)Cl. Also somewhat comparable with piypite.

An example of natural salt-inclusion compound. The structure is a derivative of a kagome-type net. Unique among both natural and synthetic arsenates and vanadates in having these two tetrahedral groups distributed over separate structural positions. The oxygen-centered bands in the structure are also unique.


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Unique IdentifiersHide

Mindat ID:
52922
Long-form identifier:
mindat:1:1:52922:8

Similar NamesHide

Aleutite (rock)A rock subtype
AliettiteA valid IMA mineral speciesCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O
Alluadite (of Bernhardi)A synonym of Dufrénite
AltaiteA valid IMA mineral species - grandfatheredPbTe
ElliottiteA valid IMA mineral speciesNaMgAl3(PO4)2F6 · 9H2O

IMA Classification of AleutiteHide

Classification of AleutiteHide

8.BB.50

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
B : With only medium-sized cations, (OH, etc.):RO4 about 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
AeuIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AleutiteHide

Adamantine
Transparency:
Transparent
Colour:
Dark red
Streak:
Reddish black
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
Not observed
Fracture:
Irregular/Uneven
Density:
4.887 g/cm3 (Calculated)

Chemistry of AleutiteHide

Mindat Formula:
[Cu5O2](AsO4)(VO4) · (Cu,K,Pb,Rb,Cs,)Cl

The original paper reports the following formula: [Cu5O2](AsO4)(VO4)·(Cu0.5□0.5)Cl
Element Weights:
Element% weight
Cu54.268 %
O22.772 %
As10.664 %
V7.251 %
Cl5.046 %

Calculated from ideal end-member formula.
Cu
O
As
V
Cl

Crystallography of AleutiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 18.090(2) Å, b = 6.2248(6) Å, c = 8.2465(9) Å
β = 90.597(2)°
Ratio:
a:b:c = 2.906 : 1 : 1.325
Unit Cell V:
929.1 ų
Z:
4

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
45b : [Other oxidized fumarolic minerals]

Type Occurrence of AleutiteHide

Synonyms of AleutiteHide

Other Language Names for AleutiteHide

Dutch:Aleutiet
French:Aleutite
German:Aleutit
Norwegian:Aleutitt

Related Minerals - Strunz-mindat GroupingHide

8.BB.MoabiteNiFe3+(PO4)OOrth. mmm(2/m2/m2/m) : Pnma
8.BB.TilasiteCaMg(AsO4)FMon.
8.BB.PaulgrothiteCu9Fe3+O4(PO4)4Cl3Orth. mm2 : Cmc21
8.BB.KarlditmariteCu9O4(PO4)2(SO4)2Tric. 1 : P1
8.BB.MilkovoiteCu4O(PO4)(AsO4)Orth. mmm(2/m2/m2/m) : Pnma
8.BB.XArsenowagneriteMg2(AsO4)FMon. 2/m : P21/c
8.BB.05TavoriteLiFe3+(PO4)(OH)Tric. 1 : P1
8.BB.05AmblygoniteLiAl(PO4)FTric. 1 : P1
8.BB.05MontebrasiteLiAl(PO4)(OH)Tric. 1 : P1
8.BB.10ZwieseliteFe2+2(PO4)FMon. 2/m : B2/b
8.BB.10TripliteMn2+2(PO4)FMon. 2/m : B2/b
8.BB.15'Unnamed (Sb-analogue of Auriacusite)'Fe3+Cu2+[(Sb,As)O4]O
8.BB.15JoosteiteMn2+(Mn3+,Fe3+)(PO4)OMon. 2/m : B2/b
8.BB.15HydroxylwagneriteMg2(PO4)(OH)Mon. 2/m : P21/c
8.BB.15WagneriteMg2(PO4)FMon. 2/m : P21/c
8.BB.15Stanĕkite(Mn2+,Fe2+,Mg)Fe3+(PO4)OMon. 2/m : P21/c
8.BB.15TriploiditeMn2+2(PO4)(OH)Mon. 2/m : P21/c
8.BB.15SarkiniteMn2+2(AsO4)(OH)Mon. 2/m : P21/c
8.BB.15WolfeiteFe2+2(PO4)(OH)Mon. 2/m : P21/c
8.BB.20HoltedahliteMg2(PO4)(OH)Trig. 3m : P31m
8.BB.20Satterlyite(Fe2+,Mg,Fe)12(PO4)5(PO3OH)(OH,O)6Trig. 3m(32/m) : P31m
8.BB.25AlthausiteMg4(PO4)2(OH,O)(F,◻)Orth. mmm(2/m2/m2/m) : Pnma
8.BB.30ZincoliveniteCuZn(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30AdamiteZn2(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30LibetheniteCu2(PO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30ZincolibetheniteCuZn(PO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30EveiteMn2+2(AsO4)(OH)Orth. mmm(2/m2/m2/m) : Pnnm
8.BB.30OliveniteCu2(AsO4)(OH)Mon. 2/m : P21/m
8.BB.30AuriacusiteFe3+Cu2+(AsO4)OOrth. mmm(2/m2/m2/m) : Pnnm
8.BB.35ParadamiteZn2(AsO4)(OH)Tric. 1 : P1
8.BB.35TarbuttiteZn2(PO4)(OH)Tric. 1 : P1
8.BB.40BarbosaliteFe2+Fe3+2(PO4)2(OH)2Mon. 2/m : P21/c
8.BB.40ScorzaliteFe2+Al2(PO4)2(OH)2Mon. 2/m : P21/c
8.BB.40LazuliteMgAl2(PO4)2(OH)2Mon. 2/m : P21/c
8.BB.40MeizhouiteFe2+V3+2(PO4)2(OH)2Mon. 2/m : P21/c
8.BB.40HentscheliteCuFe3+2(PO4)2(OH)2Mon. 2/m : P21/m
8.BB.40WilhelmkleiniteZnFe3+2(AsO4)2(OH)2Mon. 2/m : P21/m
8.BB.45DokuchaeviteCu8O2(VO4)3Cl3Tric. 1 : P1
8.BB.45TrolleiteAl4(PO4)3(OH)3Mon. 2/m : B2/b
8.BB.45YaroshevskiteCu9O2(VO4)4Cl2 Tric. 1 : P1
8.BB.50NamibiteCu(BiO)2(VO4)(OH)Tric. 1 : P1
8.BB.52aEriclaxmaniteCu4O(AsO4)2Tric. 1 : P1
8.BB.52bKozyrevskiteCu4O(AsO4)2Orth. mmm(2/m2/m2/m) : Pnma
8.BB.55Phosphoellenbergerite(Mg,◻)2Mg12(PO4,PO3OH)6(PO3OH,CO3)2(OH)6Hex. 6mm : P63mc
8.BB.55PopoviteCu5O2(AsO4)2Tric. 1 : P1
8.BB.60UrusoviteCuAl(AsO4)OMon. 2/m : P21/c
8.BB.65TheoparacelsiteCu3(As2O7)(OH)2Orth. mmm(2/m2/m2/m) : Pmma
8.BB.70TuraniteCu5(VO4)2(OH)4Tric. 1 : P1
8.BB.75StoiberiteCu5(VO4)2O2Mon. 2/m : P21/c
8.BB.80FingeriteCu11(VO4)6O2Tric. 1 : P1
8.BB.85AverieviteCu6(VO4)2O2Cl2Trig. 3 : P3
8.BB.90RichelliteCaFe3+2(PO4)2(OH,F)2Amor.
8.BB.90LipscombiteFe2+Fe3+2(PO4)2(OH)2Tet. 422 : P41212
8.BB.90ZinclipscombiteZnFe3+2(PO4)2(OH)2Tet. 422 : P43212

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for AleutiteHide

References for AleutiteHide

Localities for AleutiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Kamchatka Krai
    • Milkovsky District
      • Tolbachik Volcanic field
        • Great Fissure eruption (Main Fracture)
          • Northern Breakthrough (North Breach)
            • Second scoria cone
Siidra et al. (2019)
 
and/or  
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