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Biagioniite

A valid IMA mineral species
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About BiagioniiteHide

03448150017272473296486.jpg
Cristian Biagioni
Formula:
Tl2SbS2
may also be given as [Tl]4[Sb2][S]4
Colour:
Black
Lustre:
Metallic
Hardness:
3
Specific Gravity:
6.192 (Calculated)
Crystal System:
Monoclinic
Name:
Named in honor of Dr. Cristian Biagioni (b. 28 April 1981, Lucca, Tuscany, Italy), Professor of Mineralogy at the Department of Earth Sciences of the University of Pisa, Italy. Dr. Biagioni co-authored descriptions for more than 50 new mineral species. His research focuses on the mineralogy of Tuscany and systematic mineralogy, with a particular attention paid to sulfosalts. He also contributed to the discovery of the thallium-rich nature of a series of ore deposits in northern Tuscany, with the description of some Tl sulfosalts.
Isostructural with:
The TlSb analogue of dervillite. Chemically similar to weissbergite, pierrotite, parapierrotite, 'stibioellisite', and few unnamed species; also comparable to drechslerite.

Found in a museum sample.

Crystal structure details:
- Tl adopts different coordinations, from quasi linear to quasi tetrahedral;
- Sb forms Sb-Sb pairs


Unique IdentifiersHide

Mindat ID:
54362
Long-form identifier:
mindat:1:1:54362:6

IMA Classification of BiagioniiteHide

Classification of BiagioniiteHide

2.LA.

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
L : Unclassified Sulfosalts
A : Without essential Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BgiIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BiagioniiteHide

Metallic
Transparency:
Opaque
Colour:
Black
Streak:
Black
Hardness:
Comment:
Estimated with respect to surrounding calcite
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
6.192 g/cm3 (Calculated)
Comment:
Calculated based on empirical formula

Optical Data of BiagioniiteHide

Anisotropism:
weak with blueish to light-blue
Bireflectance:
moderately bireflectant
Reflectivity:
WavelengthR1 (%)R2 (%)
471nm35.9% 37.5%
548nm34.7% 36.2%
586nm33.8% 35.3%
652nm31.5% 33.7%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 37.5%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Creamy
Internal Reflections:
None
Pleochroism:
Non-pleochroic

Chemistry of BiagioniiteHide

Mindat Formula:
Tl2SbS2

may also be given as [Tl]4[Sb2][S]4
Element Weights:
Element% weight
Tl68.740 %
Sb20.476 %
S10.784 %

Calculated from ideal end-member formula.
Tl
Sb
S

Crystallography of BiagioniiteHide

Crystal System:
Monoclinic
Class (H-M):
m - Domatic
Space Group:
Pb
Setting:
Pc
Cell Parameters:
a = 11.0895(9) Å, b = 14.3124(11) Å, c = 7.9352(6) Å
β = 96.230(8)°
Ratio:
a:b:c = 0.775 : 1 : 0.554
Unit Cell V:
1252.02 ų
Z:
8

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of BiagioniiteHide

General Appearance of Type Material:
anhedral crystals up to 65 μm (very rare)
Place of Conservation of Type Material:
mineralogical collections of the Museo di Storia Naturale, Università di Firenze, Via La Pira 4, I-50121, Florence, Italy, catalogue number 46582/G
Associated Minerals at Type Locality:

Synonyms of BiagioniiteHide

Other Language Names for BiagioniiteHide

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Biagioniite associated with StibarsenAsSb
1 photo of Biagioniite associated with CalciteCaCO3

Related Minerals - Strunz-mindat GroupingHide

2.LA.ThunderbayiteTlAg3Au3Sb7S6Tric. 1 : P1
2.LA.AuerbakhiteMnTl2As2S5Orth.
2.LA.Ferrofettelite[Ag6As2S7][Ag10FeAs2S8]Mon. 2 : B2
2.LA.GladkovskyiteMnTlAs3S6Trig. 3m : R3c
2.LA.10DervilliteAg2AsS2Mon. m : Pb
2.LA.15DaomaniteCuPtAsS2Orth.
2.LA.20VaughaniteTlHgSb4S7Tric.
2.LA.25CriddleiteTlAg2Au3Sb10S10Mon.
2.LA.30Fettelite[Ag6As2S7][Ag10HgAs2S8] Mon. 2 : B2
2.LA.35Chaméanite(Cu,Fe)4As(Se,S)4Iso.
2.LA.40ArcubisiteAg6CuBiS4
2.LA.45MgriiteCu3AsSe3Iso. m3m(4/m32/m) : Fd3m
2.LA.50Benleonardite[Ag6(Sb,As)2S6Te][Ag9Cu(S,Te)2Te2]Trig. 3m(32/m) : P3m1
2.LA.55TsnigriiteAg9SbTe3S3Mon.
2.LA.60BorovskitePd3SbTe4Iso.
2.LA.65JonassoniteAuBi5S4Mon.
2.LA.65NuwaiteNi6GeS2Tet. 4/mmm(4/m2/m2/m) : I4/mmm
2.LA.65ButianiteNi6SnS2Tet. 4/mmm(4/m2/m2/m) : I4/mmm
2.LA.70RaberiteTl5Ag4As6SbS15 Tric. 1 : P1
2.LA.75SpaltiiteTl2Cu2As2S5Mon. 2/m : P21/c

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BiagioniiteHide

References for BiagioniiteHide

Localities for BiagioniiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada (TL)
 
  • Ontario
    • Thunder Bay District
      • Bomby Township
Bindi et al. (2020) +1 other reference
 
and/or  
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