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Ferraioloite

A valid IMA mineral species
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About FerraioloiteHide

01386560017272472608427.jpg
Jim Ferraiolo
Formula:
MgMn2+4(Fe2+0.5Al3+0.5)4Zn4(PO4)8(OH)4(H2O)20
Colour:
pale blue, greenish grey to lemon yellow
Lustre:
Vitreous, Pearly
Hardness:
2
Specific Gravity:
2.59 (Calculated)
Crystal System:
Monoclinic
Name:
The species is named in honour of the late James (Jim) Anthony Ferraiolo (May 14, 1947-February 6, 2014). The mineral is pronounced /fe..(r) i: ‘Ou lOu ait/. Jim worked as scientific assistant at the American Museum of Natural History (AMNH) from April 1978 until August 1982 and also as transaction coordinator at the Smithsonian Institution’s Museum of Natural History from September 1982 until April 1985. He was best known for his publication A Systematic Classification of Nonsilicate Minerals (Bulletin 172 of the AMNH, 1982), which was widely used in Museum collections, as a basis for collection classification and organisation (e.g. Museums Victoria, Australia). Recently, Jim was a member of the IMA CNMNC subcommittee for mineral group nomenclature and the subcommittee on unnamed minerals. Jim also spent more than a decade as a manager with mindat.org and was instrumental in publishing the description of ferrolaueite (Ferraiolo, 2012; Segeler et al., 2012).
First described from sample found at the eastern dump of the Foote Lithium Company mine, Cleveland Co., North Carolina, USA.

Closely related to falsterite. Chemically somewhat resembles jasonsmithite.

The structure is layered with heteropolyhedra; layers || (100); there are isolated Mg(H2O)6 octahedra and water molecules between the layers.


Unique IdentifiersHide

Mindat ID:
46878
Long-form identifier:
mindat:1:1:46878:7

Similar NamesHide

FerriliteA synonym of 'Dolerite'
FerroliteAn artificial material

IMA Classification of FerraioloiteHide

Classification of FerraioloiteHide

8.CF.

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
F : With large and medium-sized cations, RO4:H2O > 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
FrlIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FerraioloiteHide

Vitreous, Pearly
Transparency:
Transparent
Colour:
Pale blue, greenish grey to lemon yellow
Streak:
Pale blue
Hardness:
Comment:
estimated to be about 2, based upon behaviour when broken
Tenacity:
Flexible
Cleavage:
Perfect
{100}
Fracture:
Irregular/Uneven
Density:
2.59 g/cm3 (Calculated)

Optical Data of FerraioloiteHide

Type:
Biaxial (-)
RI values:
nα = 1.575 nβ = 1.5825(5) nγ = 1.5835(5)
2V:
Measured: 40° , Calculated: 40°
Max. Birefringence:
δ = 0.009
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
weak (r>v)
Pleochroism:
Visible
Comments:
colourless (X, Z), blue grey (Y)

Chemistry of FerraioloiteHide

Mindat Formula:
MgMn2+4(Fe2+0.5Al3+0.5)4Zn4(PO4)8(OH)4(H2O)20
Element Weights:
Element% weight
O48.187 %
Zn14.065 %
P13.327 %
Mn11.819 %
Fe6.007 %
Al2.902 %
H2.385 %
Mg1.307 %

Calculated from ideal end-member formula.
O
Zn
P
Mn
Fe
Al
H
Mg
Common Impurities:
Ca

Crystallography of FerraioloiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
I2/m
Cell Parameters:
a = 25.333(3) Å, b = 6.299(1) Å, c = 15.161(3) Å
β = 90.93(3)°
Ratio:
a:b:c = 4.022 : 1 : 2.407
Unit Cell V:
2419 ų
Z:
2
Morphology:
platelets, blades

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
12.7 Å(100)
4.78 Å(4)
4.22 Å(4)
3.580 Å(4)
3.499 Å(5)
3.245 Å(7)
2.924 Å(8)
2.869 Å(5)

Geological EnvironmentHide

Type Occurrence of FerraioloiteHide

General Appearance of Type Material:
platelets and blades up to ca. 0.2 mm long and a few μm thick
Place of Conservation of Type Material:
Cotype material is deposited in the mineralogical collections of the Museum Victoria, Melbourne, Australia, registration numbers M53492 and M53493, and the Natural History Museum of Los Angeles County, Los Angeles, California,USA, catalogue numbers 65593
Geological Setting of Type Material:
vugs in a thin sugary fine-grained pegmatite seam in a zinc rich boulder
Associated Minerals at Type Locality:

Synonyms of FerraioloiteHide

Other Language Names for FerraioloiteHide

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Ferraioloite associated with PhosphophylliteZn2Fe 2+(PO4)2 · 4H2O
1 photo of Ferraioloite associated with AlbiteNa(AlSi3O8)
1 photo of Ferraioloite associated with VivianiteFe2+Fe2+2(PO4)2 · 8H2O

Related Minerals - Strunz-mindat GroupingHide

8.CF.NaalasiteNaAl(AsO3OH)2 · H2OTrig. 32 : R32
8.CF.NafeasiteNa3Fe3+3(AsO3OH)6 · 3H2OMon. 2 : B2
8.CF.FalsteriteCa2MgMn2+2Fe2+2Fe3+2Zn4(PO4)8(OH)4(H2O)14Mon. 2/m : P21/c
8.CF.EspadaiteNa4Ca3Mg2[AsO3(OH)]2[AsO2(OH)2]10 · 7H2OOrth. mmm(2/m2/m2/m) : Ccca
8.CF.LiraiteNaCa2Mn2+2[Fe3+Fe2+]Mn2+2(PO4)6(H2O)2Orth. mm2
8.CF.05Tassieite(Na,◻)Ca2(Mg,Fe2+,Fe3+)2(Fe2+,Mg)2(Fe3+,Mg)2(PO4)6 · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CF.05BederiteCa2(Mn2+)4(Fe3+)2(PO4)6 · 2H2OOrth. mmm(2/m2/m2/m)
8.CF.05WicksiteNaCa2(Fe2+,Mn2+)4MgFe3+(PO4)6 · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CF.05GrischuniteNaCa2Mn2+5Fe3+(AsO4)6 · 2H2OOrth. mmm(2/m2/m2/m)
8.CF.05Maneckiite(Na◻)Ca2Fe2+2(Fe3+Mg)Mn2(PO4)6 · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
8.CF.10HaigerachiteKFe3+3(PO3OH)2[PO2(OH)2]6 · 4H2OMon. 2/m : B2/b
8.CF.10YazganiteNaFe3+2(Mg,Mn2+)(AsO4)3 · H2OMon. 2/m : B2/b
8.CF.15CurrieriteNa4Ca3MgAl4(AsO3OH)12 · 9H2OHex. 622 : P622
8.CF.20RíosecoiteCa2Mg(AsO3OH)3(H2O)2Tric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FerraioloiteHide

References for FerraioloiteHide

Localities for FerraioloiteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Portugal
 
  • Guarda
    • Gouveia
      • Folgosinho
DOI: ... +1 other reference
USA (TL)
 
  • North Carolina
    • Cleveland County
      • Kings Mountain
Mills et al. (2016)
 
and/or  
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