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Dewitite
A valid IMA mineral species - pending publication
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About Dewitite
Formula:
AgzTl10-x-zPb2xSb42-x-yAsyS68
0.09 ≤ x ≤ 2.13
13.99 ≤ y ≤ 19.79
0.10 ≤ z ≤ 0.50
13.99 ≤ y ≤ 19.79
0.10 ≤ z ≤ 0.50
Crystal System:
Triclinic
Member of:
Name:
After Frank de Wit, intrepid amateur mineralogist from the Netherlands.
Unique Identifiers
Mindat ID:
55616
Long-form identifier:
mindat:1:1:55616:1
IMA Classification of Dewitite
Approved, Pending publication
IMA Formula:
Ag1+zTl1+10-x-zPb2+2xSb3+42-x-yAs3+yS2-68 (0.09 ≤ x ≤ 2.13, 13.99 ≤ y ≤ 19.79, 0.10 ≤ z ≤ 0.50)
Approval year:
2019
Approval history:
IMA No. 2019-098/20-F
Classification of Dewitite
2.HD.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
D : With Tl
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
D : With Tl
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Dwt | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Chemistry of Dewitite
Mindat Formula:
AgzTl10-x-zPb2xSb42-x-yAsyS68
0.09 ≤ x ≤ 2.13
13.99 ≤ y ≤ 19.79
0.10 ≤ z ≤ 0.50
0.09 ≤ x ≤ 2.13
13.99 ≤ y ≤ 19.79
0.10 ≤ z ≤ 0.50
Crystallography of Dewitite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 8.626(2) Å, b = 16.351(3) Å, c = 21.892(4) Å
α = 74.96(3)°, β = 83.59(3)°, γ = 88.91(3)°
α = 74.96(3)°, β = 83.59(3)°, γ = 88.91(3)°
Ratio:
a:b:c = 0.528 : 1 : 1.339
Unit Cell V:
2,963.16 ų (Calculated from Unit Cell)
Comment:
structure determined
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.948 Å | (50) |
| 3.590 Å | (50) |
| 3.561 Å | (100) |
| 3.341 Å | (48) |
| 2.872 Å | (61) |
| 2.813 Å | (62) |
| 2.732 Å | (48) |
| 2.156 Å | (63) |
Type Occurrence of Dewitite
Place of Conservation of Type Material:
mineralogical collections of the Naturhistorisches Museum Wien, Burgring 7, 1010 Vienna, Austria, catalogue no. O1787
Synonyms of Dewitite
Other Language Names for Dewitite
Relationship of Dewitite to other Species
Member of:
Other Members of Chabournéite Group:
| Chabournéite | AgzTl8-x-zPb4+2xSb40-x-yAsyS68 with 0.00 < x < 0.40(9), 16.15(3)< y < 19.11(10), 0.04(4) < z < 0.11(6) | Tric. 1 : P1 |
| Dalnegroite | (Tl4Pb2)(As12Sb8)S34 | Tric. 1 : P1 |
| Protochabournéite | Tl4-xPb2+2xSb20-x-yAsyS34 with 0.02(2) <= x <= 0.34(2), 5.71(9) <= y <= 6.69(9) | Tric. 1 : P1 |
| Shimenite | Tl5Sb21-yAsyS34 | Tric. 1 : P1 |
| Vallouiseite | Ag3Tl21.5PbSb63As41.5S170 | Tric. 1 : P1 |
Related Minerals - Strunz-mindat Grouping
| 2.HD. | Enneasartorite | Tl6Pb32As70S140 |
| 2.HD. | Shimenite | Tl5Sb21-yAsyS34 |
| 2.HD. | Buynite | TlPb14As17S40 |
| 2.HD. | Vallouiseite | Ag3Tl21.5PbSb63As41.5S170 |
| 2.HD. | Giuşcăite | Ag2Tl4Pb4As20Sb2S40 |
| 2.HD. | Boscardinite | TlPb4(Sb7As2)S18 |
| 2.HD. | Gungerite | TlAs5Sb4S13 |
| 2.HD.05e | Dalnegroite | (Tl4Pb2)(As12Sb8)S34 |
| 2.HD.05 | Lorándite | TlAsS2 |
| 2.HD.05 | Weissbergite | TlSbS2 |
| 2.HD.05e | Chabournéite | AgzTl8-x-zPb4+2xSb40-x-yAsyS68 with 0.00 < x < 0.40(9), 16.15(3)< y < 19.11(10), 0.04(4) < z < 0.11(6) |
| 2.HD.15 | Christite | TlHgAsS3 |
| 2.HD.15 | Markwelchite | TlPbSbS3 |
| 2.HD.15 | Richardsollyite | TlPbAsS3 |
| 2.HD.20 | Jankovićite | Tl5Sb9(As,Sb)4S22 |
| 2.HD.25 | Rebulite | Tl5Sb5As8S22 |
| 2.HD.30 | Imhofite | Tl5.8As15.4S26 |
| 2.HD.35 | Edenharterite | PbTlAs3S6 |
| 2.HD.40 | Jentschite | TlPbAs2SbS6 |
| 2.HD.45 | Protochabournéite | Tl4-xPb2+2xSb20-x-yAsyS34 with 0.02(2) <= x <= 0.34(2), 5.71(9) <= y <= 6.69(9) |
| 2.HD.45 | Hutchinsonite | TlPbAs5S9 |
| 2.HD.50 | Bernardite | TlAs5S8 |
| 2.HD.55 | Sicherite | TlAg2(As,Sb)3S6 |
| 2.HD.55 | Geuerite | Ag2Tl4Pb4As22S40 |
| 2.HD.60 | Gabrielite | Tl6Ag3Cu6(As,Sb)9S21 |
| 2.HD.65 | Tsygankoite | Mn8Tl8Hg2(Sb21Pb2Tl)S48 |
| 2.HD.70 | Drechslerite | Tl4(Sb4-xAsx)S8 (1 < x < 2) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Dewitite
mindat.org URL:
https://www.mindat.org/min-55616.html
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References for Dewitite
Reference List:
Makovicky, Emil, Plášil, Jakub, Kasatkin, Anatoly V., Škoda, Radek (2021) The crystal structure of Tl2.36Sb5.98As4.59S17, the lead-free endmember of the chabournéite homeotypic group. The Canadian Mineralogist, 59 (3) 533-549 doi:10.3749/canmin.2000093
Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2021) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) CNMNC Newsletter No 63. Mineralogical Magazine, 85 (6) 910-915 doi:10.1180/mgm.2021.74
Localities for Dewitite
Showing 4 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
France (TL) | |
| Miyawaki et al. (2021) |
Italy | |
| "Eigenfund Lechner Alois - Bestimmung ... |
Portugal | |
| comment added by Uwe Kolitsch Nov. 2022 +1 other reference |
Russia | |
| Makovicky et al. (2021) +2 other references |


symbol to view information about a locality.
The
Monte Arsiccio Mine, Sant'Anna di Stazzema, Stazzema, Lucca Province, Tuscany, Italy